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#1. Braunschweig
Germany
Circular solutions for
Energy
Materials
WWTP(actual load: 350,000PE)
Lead partner:
Relevant sectors
Horticulture
Water
treatment
Relevant data
Energy
Other partner:
2
1. Objectives of the NextGen solutions
Starting status of sludge treatment at the WWTP:
three full-scale one-stage digesters
NextGen solution implemented in the sludge treatment:
1. Two-stage digestion system
2. Thermal pressure hydrolysis (TPH) between the two stages
3. System for struvite precipitation
4. System for ammonium sulfate production
Benefits of thermal pressure hydrolysis:
- Higher methane yield in second digestion stage
- Improved dewatering process of digested sludge
- Increase in dissolved phosphate and ammonium concentration
3
Technology Evidence Base (TEB).
Braunschweig
Positioning of demo case within the CE
1. Objectives of the NextGen solutions
4 4
T= 53 °C T= 53 °C
2. New NextGen solutions: Two-stage digestion system and TPH
5 5
2. New NextGen solutions: struvite production
Struvite
6
2. New NextGen solution: Ammonium sulphate production
6
NH3
stripping
unit
(NH4)2SO
4
storage
tank
(NH4)2SO4
7
3. Results and key performance indicators (KPIs)
Up to 25% increase in methane production rate during TPH operation
0 200 400 600
Time [d]
0
100
200
300
400
500
Methane
production
rate
[m³/h] F1 (53 °C) + F2 (38 °C) + F3 (38 °C)
Stop
TPH
Start
TPH
8
0 200 400 600
Time [d]
0
1
2
3
4
5
Organic
loading
rate
[kg
DM/(m³*d)] Estimated OLR via flow rates and average DM contents
3. Results and key performance indicators (KPIs)
Organic loading rate ranges mainly between 1 and 3 kg DM/(m³*d)
 Increase in methane production rate due to TPH
Stop
TPH
Start
TPH
9
0 0.5 1 1.5 2 2.5 3 3.5
Time [d]
0
200
400
600
PO
4
-P
[mg/L]
0
25
50
75
100
Recovery
rate
[%]
Influent
Effluent
Recovery rate
90
51
Expected recovery rate:
Full-scale nutrient recovery
GOAL: Phosphorus recovery
T= 53 °C T= 53 °C
Struvite
 Recovery rate is still too low: crystal size is too small
3. Results and key performance indicators (KPIs)
10
Full-scale nutrient recovery
GOAL:Nitrogen recovery
T= 53 °C T= 53 °C
 Recovery rate is higher than required
 Optimization in order to save energy and chemicals
0 2 4 40 42 44 46 48 50 52
Time [d]
0
500
1000
1500
NH
4
-N
[mg/L]
0
25
50
75
100
Recovery
rate
[%]
Influent
Effluent
Recovery rate
Expected range
(NH4)2SO4
3. Results and key performance indicators (KPIs)
11
4. Lessons learned so far
• Thermal pressure hydrolysis:
• High-maintenance product
• Constant high gas quality for steam generator -> avoiding higher fluctuations of
system pressure (< 20 – 30 mbar)
• Struvite precipitation
• Very low concentration of suspended solids in process water needed
(TSS < 600 mg/L)
• Long commissioning time for increasing particle size > 3 mm
• Ammonium sulfate production
• Well-established + fail-safe technique
• Very high recovery rates possible: up to 98%
• System control
• Interaction of single technical units complex -> to be considered in system design
12
5. Outlook
Struvite production:
Optimization of production process aiming at the increase in grain size and a
high P recovery rate via changes in hydrozyclone geometry, different MgCl2
dosages, varying HRT
Ammonium sulfate solution production:
Optimization of production process aiming at a high N recovery rate and low
energy and chemicals consumption ( varying temperature & NaOH
addition)
Heat management:
Analysis of internal heat management for TPH & two stage digestion system
13
Thank you!
xtGen - Community of Practice
13
anna.serra@eurecat.org
sandra.cases@eurecat.org

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NextGen Braunschweig Germany

  • 1. 1 #1. Braunschweig Germany Circular solutions for Energy Materials WWTP(actual load: 350,000PE) Lead partner: Relevant sectors Horticulture Water treatment Relevant data Energy Other partner:
  • 2. 2 1. Objectives of the NextGen solutions Starting status of sludge treatment at the WWTP: three full-scale one-stage digesters NextGen solution implemented in the sludge treatment: 1. Two-stage digestion system 2. Thermal pressure hydrolysis (TPH) between the two stages 3. System for struvite precipitation 4. System for ammonium sulfate production Benefits of thermal pressure hydrolysis: - Higher methane yield in second digestion stage - Improved dewatering process of digested sludge - Increase in dissolved phosphate and ammonium concentration
  • 3. 3 Technology Evidence Base (TEB). Braunschweig Positioning of demo case within the CE 1. Objectives of the NextGen solutions
  • 4. 4 4 T= 53 °C T= 53 °C 2. New NextGen solutions: Two-stage digestion system and TPH
  • 5. 5 5 2. New NextGen solutions: struvite production Struvite
  • 6. 6 2. New NextGen solution: Ammonium sulphate production 6 NH3 stripping unit (NH4)2SO 4 storage tank (NH4)2SO4
  • 7. 7 3. Results and key performance indicators (KPIs) Up to 25% increase in methane production rate during TPH operation 0 200 400 600 Time [d] 0 100 200 300 400 500 Methane production rate [m³/h] F1 (53 °C) + F2 (38 °C) + F3 (38 °C) Stop TPH Start TPH
  • 8. 8 0 200 400 600 Time [d] 0 1 2 3 4 5 Organic loading rate [kg DM/(m³*d)] Estimated OLR via flow rates and average DM contents 3. Results and key performance indicators (KPIs) Organic loading rate ranges mainly between 1 and 3 kg DM/(m³*d)  Increase in methane production rate due to TPH Stop TPH Start TPH
  • 9. 9 0 0.5 1 1.5 2 2.5 3 3.5 Time [d] 0 200 400 600 PO 4 -P [mg/L] 0 25 50 75 100 Recovery rate [%] Influent Effluent Recovery rate 90 51 Expected recovery rate: Full-scale nutrient recovery GOAL: Phosphorus recovery T= 53 °C T= 53 °C Struvite  Recovery rate is still too low: crystal size is too small 3. Results and key performance indicators (KPIs)
  • 10. 10 Full-scale nutrient recovery GOAL:Nitrogen recovery T= 53 °C T= 53 °C  Recovery rate is higher than required  Optimization in order to save energy and chemicals 0 2 4 40 42 44 46 48 50 52 Time [d] 0 500 1000 1500 NH 4 -N [mg/L] 0 25 50 75 100 Recovery rate [%] Influent Effluent Recovery rate Expected range (NH4)2SO4 3. Results and key performance indicators (KPIs)
  • 11. 11 4. Lessons learned so far • Thermal pressure hydrolysis: • High-maintenance product • Constant high gas quality for steam generator -> avoiding higher fluctuations of system pressure (< 20 – 30 mbar) • Struvite precipitation • Very low concentration of suspended solids in process water needed (TSS < 600 mg/L) • Long commissioning time for increasing particle size > 3 mm • Ammonium sulfate production • Well-established + fail-safe technique • Very high recovery rates possible: up to 98% • System control • Interaction of single technical units complex -> to be considered in system design
  • 12. 12 5. Outlook Struvite production: Optimization of production process aiming at the increase in grain size and a high P recovery rate via changes in hydrozyclone geometry, different MgCl2 dosages, varying HRT Ammonium sulfate solution production: Optimization of production process aiming at a high N recovery rate and low energy and chemicals consumption ( varying temperature & NaOH addition) Heat management: Analysis of internal heat management for TPH & two stage digestion system
  • 13. 13 Thank you! xtGen - Community of Practice 13 anna.serra@eurecat.org sandra.cases@eurecat.org