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Material Safety Data Sheet Page 1 of 5
Material Name: VisiJet
®
FTI Material
MSDS • VisiJet®
FTI • 340700-S02-00-A ENGLISH • US
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product/Trade Name: VisiJet
®
FTI (ZOOM, Ivory, Gray, Black, Red, Blue)
Chemical Family: Organic mixture
Product Use: For use in: ProJet™ 1500 Personal 3D Printer
Manufacturer:
Manufacturer Contact 3D Systems, Inc.
333 Three D Systems Circle
Rock Hill, SC 29730 U.S.A.
For Information Phone: 803.326.3900 or
Toll-free Phone: 800.793.3669
Emergency 800.424.9300 - Chemtrec
II. COMPOSITION INFORMATION
CAS # Component Percent
5888-33-5 Isobornyl acrylate 15-25
42594-17-2 Tricyclodecane dimethanol diacrylate 34-50
proprietary Urethane acrylate oligomers 30-40
III. HAZARDS IDENTIFICATION
Emergency Overview
This product is irritating to the eyes, respiratory tract and skin. Avoid contact with eyes and skin. Do not breathe fumes or spray.
Inhibitor depletion caused by exposure to heat, radiation or oxidizers can cause spontaneous polymerization generating heat and
pressure.
Potential Health Effects:
Eyes: Can cause irritation consisting of redness, swelling and pain.
Skin: Can cause irritation or other allergic reactions, including redness and/or swelling.
Inhalation: Inhalation can cause respiratory irritation.
Ingestion: Ingestion can cause nausea, diarrhea and/or stomach pain.
Chronic: Can cause an allergic skin reaction with repeated or prolonged exposure consisting of redness, swelling and/or rash
(urticaria).
Medical Conditions Aggravated by Exposure
Could irritate an existing dermatitis or respiratory condition.
IV. FIRST AID MEASURES
Skin contact: Immediately flush skin with plenty of soap and water. Remove contaminated clothing and shoes. Get medical
attention if symptoms occur. Wash clothing before reuse.
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists. Avoid
exposure to UV and other light sources.
Inhalation: Move affected person to fresh air. In case of asphyxia, initiate artificial respiration immediately. If breathing is difficult,
give oxygen. Get medical attention immediately.
Ingestion: Ingestion is unlikely. However, if large quantities are swallowed, get medical attention and, if directed by medical
personnel, induce vomiting immediately. Never give anything by mouth to an unconscious person.
Hazardous Materials
Identification System (HMIS):
(Degree of hazard: 0 = low, 4 = extreme);
Health 2
Flammability 1
Physical Hazards 1
Personal Protection:
Skin, eye protection
Product Information
This product is considered to
be an irritant according to
29CFR 1910.1200 (Hazard
Communication Standard).
Material Safety Data Sheet Page 2 of 5
Material Name: VisiJet
®
FTI Material
MSDS • VisiJet®
FTI • 340700-S02-00-A ENGLISH • US
0
12 0
1
Notes to Physician
Allergic dermatitis in susceptible individuals may be delayed. It may appear after weeks or even months of frequent and prolonged
contact.
V. FIRE FIGHTING MEASURES
General Fire Hazards: Inhibitor depletion caused by exposure to heat, radiation or oxidizers can cause spontaneous
polymerization generating heat and pressure.
Hazardous Combustion Products: Thermal decomposition products can include CO2, CO, NOx and smoke.
Extinguishing Media: Use water mist, dry chemical, carbon dioxide, or chemical foam. Avoid the use of a stream of
water to control fire since frothing can occur.
Fire Fighting Equipment/Instructions: Wear full protective clothing, including helmet, self-contained positive-pressure or pressure-
demand breathing apparatus, protective clothing and facemask. Move container from area if it
can be done without risk. Cool containers with water spray. Do not use high-volume water jet.
Avoid inhalation of material or combustion by-products.
VI. ACCIDENTAL RELEASE MEASURES
Containment Procedures: Stop the flow of material, if this is without risk. Ventilate contaminated area. Eliminate sources of ignition.
Do not release material or contaminated water into drains, soil or surface waters.
Clean-Up Procedures: Wear appropriate protective equipment and clothing. Absorb spillage with non-combustible absorbent
materials. Place all waste in an appropriate container for disposal.
Evacuation Procedures: Keep unnecessary personnel away.
Special Procedures: NA
VII. HANDLING AND STORAGE
Handling Procedures: Provide adequate ventilation. Avoid contact with skin and eyes. Do not breathe vapors or mist.
Storage Procedures: Store sealed in the original container at room temperature. Keep this material indoors in a cool, dry, well-
ventilated place. Store out of direct sunlight or UV light sources.
Storage Temperature: 0 °C – 35 °C / 32 °F – 95 °F
VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
No occupational exposure limits have been established.
Engineering Controls
Ventilation must effectively remove any vapors.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face: Wear chemical goggles or face shield.
Skin: Use impervious gloves and apron.
Respiratory: If ventilation cannot effectively keep vapor concentrations below established limits, appropriate certified respiratory
protection must be provided.
General: An eye wash fountain and safety shower are recommended.
Flash Point: >183
o
C Method Used: DIN51758
Upper Flammable Limit (UFL): NA Lower Flammable Limit (LFL): NA
Auto Ignition: NA Rate of Burning: NA
NFPA Ratings
0 = Minimal
1 = Slight
2 = Moderate
3 = Serious
4 = Severe
Material Safety Data Sheet Page 3 of 5
Material Name: VisiJet
®
FTI Material
MSDS • VisiJet®
FTI • 340700-S02-00-A ENGLISH • US
IX. PHYSICAL AND CHEMICAL PROPERTIES
Appearance................................yellow, ivory, gray, black, red or blue Odor .............................................Mild
Physical State ..............................liquid PH ................................................6-7 at 1:1 in Water
Vapor Pressure ............................<2Pa at 20
o
C Vapor Density...............................NA
Boiling Point ................................NA Melting/Freezing Point..................NA
Solubility (H2O) ............................Insoluble @ 20ºC (68 ºF) Density .........................................1.08 g/cm
3
at 30
o
C
Percent Volatile ............................NA Molecular Weight..........................NA
X. CHEMICAL STABILITY AND REACTIVITY
Chemical Stability: Stable under normal conditions of handling, use and transportation.
Conditions to Avoid: Avoid exposure to heat, sunlight and UV light.
Incompatibility: Oxidizing materials, strong acids and strong bases.
Hazardous Decomposition: Thermal decomposition products can include CO2, CO, NOx, and smoke.
Hazardous Polymerization: Can occur, see sections III and V.
XI. TOXICOLOGICAL INFORMATION
Acute and Chronic Toxicity
A: General Product Information: No data available.
B: Component Analysis
Component Oral LD50 Dermal LD50 Inhalation LC50 Irritation Sensitization
Isobornyl acrylate NA NA NA Irritating to eyes and skin NA
Tricyclodecane dimethanol
diacrylate
NA NA NA Irritating to eyes and skin NA
Urethane acrylate oligomers NA NA NA Irritating to eyes and skin Sensitizer
Carcinogenicity
A: General Product Information: None.
B: Component Carcinogenicity: None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP
XII. ECOLOGICAL INFORMATION
Ecotoxicity
A: General Product Information: The ecological assessment of this material is based on an evaluation of its
components.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity: No information available.
Environmental Fate: No information available for product.
XIII. DISPOSAL CONSIDERATIONS
Waste Disposal Instructions
Do not contaminate drains, soil or surface waters with the material or its container. Avoid disposal. Attempt to utilize product
completely. Dispose of in compliance with all applicable regulations. Prior to disposal of unused material, 3D Systems Inc.,
recommends consulting and using an approved waste disposal operative to ensure regulatory compliance.
Material Safety Data Sheet Page 4 of 5
Material Name: VisiJet
®
FTI Material
MSDS • VisiJet®
FTI • 340700-S02-00-A ENGLISH • US
XIV.TRANSPORT INFORMATION
US DOT RID/ADR IMDG IATA IMO Canada TDG
Shipping Name Not Regulated
Hazard Class:
UN Number:
Packing Group:
XV. REGULATORY INFORMATION
US FEDERAL
TSCA:..................................................................All materials are listed on the TSCA Inventory or are not subject to TSCA
requirements
SARA 302 EHS List (40 CFR 355 Appendix A):..1,4-Benzenediol, CAS: 123-31-9, < 0.2%
SARA 313 (40 CFR 372.65):...............................None listed
CERCLA (40 CFR 302.4):...................................1,4-Benzenediol, CAS: 123-31-9, < 0.2%
............................................................................2-Propenoic acid, CAS 79-10-7, < 0.004%
XVI. ADDITIONAL INFORMATION
MSDS Creation Date:.... August 31, 2011
MSDS Revision #: ......... A
MSDS Revision Date:.... NA
Reason for Revision:..... NA
For more information:.... www.3dsystems.com
800.793.3669 (Toll-free in the US GMT-07:00; N. America, Mon – Fri, 6:00 a.m. to 6 p.m.)
803.326.3900 (Outside the U.S. GMT-07:00; N. America, Mon – Fri, 6:00 a.m. to 6 p.m.)
+44 144-2282600 (Europe GMT+01:00; Mon – Fri, 08:00 a.m. - 17:00 p.m. MEZ)
DISCLAIMER OF LIABILITY: The following supersedes any related provision in your company’s forms, letters, and agreements from, by or with 3D
Systems Corporation. 3D Systems Corporation makes no warranty, whether expressed or implied, including warranties of merchantability or of fitness
for a particular purpose for this product. No statements or recommendations contained in the product literature are to be construed as inducements to
infringe any relevant patent now or hereafter in existence. Under no circumstances shall 3D Systems Corporation be liable for incidental, consequential,
special, or other damages from alleged negligence, breach of warranty, strict liability or any other theory, arising out of the manufacture, use, sale, or
handling of this product. In no event shall the liability of 3D Systems Corporation for any claims arising out of the manufacture, use, handling, or sale of
its products exceed an amount equal to the buyer’s purchase price.
© Copyright 2011 by 3D Systems, Inc. All rights reserved. Subject to change without notice. VisiJet is a registered trademark, and ProJet and the
3D logo are trademarks of 3D Systems, Inc.
Material Safety Data Sheet Page 5 of 5
Material Name: VisiJet
®
FTI Material
MSDS • VisiJet®
FTI • 340700-S02-00-A ENGLISH • US
Key/Legend
ACGIH = American Conference of Governmental Industrial
Hygienists
CAS = Chemical Abstracts Service
CERCLA = Comprehensive Environmental Response,
Compensation, and Liability Act
CFR = Code of Federal Regulations
CPR = Controlled Products Regulations
DOT = Department of Transportation
DSL = Domestic Substances List
EINECS = European Inventory of Existing Commercial Chemical
Substances
EPA = Environmental Protection Agency
IARC = International Agency for Research on Cancer
IATA = International Air Transport Association
IDL = Ingredients Disclosure List
mg/Kg = milligrams per Kilogram
mg/L = milligrams per Liter
mg/m3 = milligrams per Cubic Meter
MSHA = Mine Safety and Health Administration
NA = Not Applicable or Not Available
NIOSH = National Institute for Occupational Safety and Health
NJTSR = New Jersey Trade Secret Registry
NTP = National Toxicology Program
OSHA = Occupational Safety and Health Administration
SARA = Superfund Amendments and Reauthorization Act
STEL = Short Term Exposure Limit
TDG = Transport Dangerous Goods
TSCA = Toxic Substances Control Act
WHMIS = Workplace Hazardous Materials Information System.

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MSDS for the VisiJet FTI

  • 1. Material Safety Data Sheet Page 1 of 5 Material Name: VisiJet ® FTI Material MSDS • VisiJet® FTI • 340700-S02-00-A ENGLISH • US I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product/Trade Name: VisiJet ® FTI (ZOOM, Ivory, Gray, Black, Red, Blue) Chemical Family: Organic mixture Product Use: For use in: ProJet™ 1500 Personal 3D Printer Manufacturer: Manufacturer Contact 3D Systems, Inc. 333 Three D Systems Circle Rock Hill, SC 29730 U.S.A. For Information Phone: 803.326.3900 or Toll-free Phone: 800.793.3669 Emergency 800.424.9300 - Chemtrec II. COMPOSITION INFORMATION CAS # Component Percent 5888-33-5 Isobornyl acrylate 15-25 42594-17-2 Tricyclodecane dimethanol diacrylate 34-50 proprietary Urethane acrylate oligomers 30-40 III. HAZARDS IDENTIFICATION Emergency Overview This product is irritating to the eyes, respiratory tract and skin. Avoid contact with eyes and skin. Do not breathe fumes or spray. Inhibitor depletion caused by exposure to heat, radiation or oxidizers can cause spontaneous polymerization generating heat and pressure. Potential Health Effects: Eyes: Can cause irritation consisting of redness, swelling and pain. Skin: Can cause irritation or other allergic reactions, including redness and/or swelling. Inhalation: Inhalation can cause respiratory irritation. Ingestion: Ingestion can cause nausea, diarrhea and/or stomach pain. Chronic: Can cause an allergic skin reaction with repeated or prolonged exposure consisting of redness, swelling and/or rash (urticaria). Medical Conditions Aggravated by Exposure Could irritate an existing dermatitis or respiratory condition. IV. FIRST AID MEASURES Skin contact: Immediately flush skin with plenty of soap and water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists. Avoid exposure to UV and other light sources. Inhalation: Move affected person to fresh air. In case of asphyxia, initiate artificial respiration immediately. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: Ingestion is unlikely. However, if large quantities are swallowed, get medical attention and, if directed by medical personnel, induce vomiting immediately. Never give anything by mouth to an unconscious person. Hazardous Materials Identification System (HMIS): (Degree of hazard: 0 = low, 4 = extreme); Health 2 Flammability 1 Physical Hazards 1 Personal Protection: Skin, eye protection Product Information This product is considered to be an irritant according to 29CFR 1910.1200 (Hazard Communication Standard).
  • 2. Material Safety Data Sheet Page 2 of 5 Material Name: VisiJet ® FTI Material MSDS • VisiJet® FTI • 340700-S02-00-A ENGLISH • US 0 12 0 1 Notes to Physician Allergic dermatitis in susceptible individuals may be delayed. It may appear after weeks or even months of frequent and prolonged contact. V. FIRE FIGHTING MEASURES General Fire Hazards: Inhibitor depletion caused by exposure to heat, radiation or oxidizers can cause spontaneous polymerization generating heat and pressure. Hazardous Combustion Products: Thermal decomposition products can include CO2, CO, NOx and smoke. Extinguishing Media: Use water mist, dry chemical, carbon dioxide, or chemical foam. Avoid the use of a stream of water to control fire since frothing can occur. Fire Fighting Equipment/Instructions: Wear full protective clothing, including helmet, self-contained positive-pressure or pressure- demand breathing apparatus, protective clothing and facemask. Move container from area if it can be done without risk. Cool containers with water spray. Do not use high-volume water jet. Avoid inhalation of material or combustion by-products. VI. ACCIDENTAL RELEASE MEASURES Containment Procedures: Stop the flow of material, if this is without risk. Ventilate contaminated area. Eliminate sources of ignition. Do not release material or contaminated water into drains, soil or surface waters. Clean-Up Procedures: Wear appropriate protective equipment and clothing. Absorb spillage with non-combustible absorbent materials. Place all waste in an appropriate container for disposal. Evacuation Procedures: Keep unnecessary personnel away. Special Procedures: NA VII. HANDLING AND STORAGE Handling Procedures: Provide adequate ventilation. Avoid contact with skin and eyes. Do not breathe vapors or mist. Storage Procedures: Store sealed in the original container at room temperature. Keep this material indoors in a cool, dry, well- ventilated place. Store out of direct sunlight or UV light sources. Storage Temperature: 0 °C – 35 °C / 32 °F – 95 °F VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines No occupational exposure limits have been established. Engineering Controls Ventilation must effectively remove any vapors. PERSONAL PROTECTIVE EQUIPMENT Eyes/Face: Wear chemical goggles or face shield. Skin: Use impervious gloves and apron. Respiratory: If ventilation cannot effectively keep vapor concentrations below established limits, appropriate certified respiratory protection must be provided. General: An eye wash fountain and safety shower are recommended. Flash Point: >183 o C Method Used: DIN51758 Upper Flammable Limit (UFL): NA Lower Flammable Limit (LFL): NA Auto Ignition: NA Rate of Burning: NA NFPA Ratings 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
  • 3. Material Safety Data Sheet Page 3 of 5 Material Name: VisiJet ® FTI Material MSDS • VisiJet® FTI • 340700-S02-00-A ENGLISH • US IX. PHYSICAL AND CHEMICAL PROPERTIES Appearance................................yellow, ivory, gray, black, red or blue Odor .............................................Mild Physical State ..............................liquid PH ................................................6-7 at 1:1 in Water Vapor Pressure ............................<2Pa at 20 o C Vapor Density...............................NA Boiling Point ................................NA Melting/Freezing Point..................NA Solubility (H2O) ............................Insoluble @ 20ºC (68 ºF) Density .........................................1.08 g/cm 3 at 30 o C Percent Volatile ............................NA Molecular Weight..........................NA X. CHEMICAL STABILITY AND REACTIVITY Chemical Stability: Stable under normal conditions of handling, use and transportation. Conditions to Avoid: Avoid exposure to heat, sunlight and UV light. Incompatibility: Oxidizing materials, strong acids and strong bases. Hazardous Decomposition: Thermal decomposition products can include CO2, CO, NOx, and smoke. Hazardous Polymerization: Can occur, see sections III and V. XI. TOXICOLOGICAL INFORMATION Acute and Chronic Toxicity A: General Product Information: No data available. B: Component Analysis Component Oral LD50 Dermal LD50 Inhalation LC50 Irritation Sensitization Isobornyl acrylate NA NA NA Irritating to eyes and skin NA Tricyclodecane dimethanol diacrylate NA NA NA Irritating to eyes and skin NA Urethane acrylate oligomers NA NA NA Irritating to eyes and skin Sensitizer Carcinogenicity A: General Product Information: None. B: Component Carcinogenicity: None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP XII. ECOLOGICAL INFORMATION Ecotoxicity A: General Product Information: The ecological assessment of this material is based on an evaluation of its components. B: Component Analysis - Ecotoxicity - Aquatic Toxicity: No information available. Environmental Fate: No information available for product. XIII. DISPOSAL CONSIDERATIONS Waste Disposal Instructions Do not contaminate drains, soil or surface waters with the material or its container. Avoid disposal. Attempt to utilize product completely. Dispose of in compliance with all applicable regulations. Prior to disposal of unused material, 3D Systems Inc., recommends consulting and using an approved waste disposal operative to ensure regulatory compliance.
  • 4. Material Safety Data Sheet Page 4 of 5 Material Name: VisiJet ® FTI Material MSDS • VisiJet® FTI • 340700-S02-00-A ENGLISH • US XIV.TRANSPORT INFORMATION US DOT RID/ADR IMDG IATA IMO Canada TDG Shipping Name Not Regulated Hazard Class: UN Number: Packing Group: XV. REGULATORY INFORMATION US FEDERAL TSCA:..................................................................All materials are listed on the TSCA Inventory or are not subject to TSCA requirements SARA 302 EHS List (40 CFR 355 Appendix A):..1,4-Benzenediol, CAS: 123-31-9, < 0.2% SARA 313 (40 CFR 372.65):...............................None listed CERCLA (40 CFR 302.4):...................................1,4-Benzenediol, CAS: 123-31-9, < 0.2% ............................................................................2-Propenoic acid, CAS 79-10-7, < 0.004% XVI. ADDITIONAL INFORMATION MSDS Creation Date:.... August 31, 2011 MSDS Revision #: ......... A MSDS Revision Date:.... NA Reason for Revision:..... NA For more information:.... www.3dsystems.com 800.793.3669 (Toll-free in the US GMT-07:00; N. America, Mon – Fri, 6:00 a.m. to 6 p.m.) 803.326.3900 (Outside the U.S. GMT-07:00; N. America, Mon – Fri, 6:00 a.m. to 6 p.m.) +44 144-2282600 (Europe GMT+01:00; Mon – Fri, 08:00 a.m. - 17:00 p.m. MEZ) DISCLAIMER OF LIABILITY: The following supersedes any related provision in your company’s forms, letters, and agreements from, by or with 3D Systems Corporation. 3D Systems Corporation makes no warranty, whether expressed or implied, including warranties of merchantability or of fitness for a particular purpose for this product. No statements or recommendations contained in the product literature are to be construed as inducements to infringe any relevant patent now or hereafter in existence. Under no circumstances shall 3D Systems Corporation be liable for incidental, consequential, special, or other damages from alleged negligence, breach of warranty, strict liability or any other theory, arising out of the manufacture, use, sale, or handling of this product. In no event shall the liability of 3D Systems Corporation for any claims arising out of the manufacture, use, handling, or sale of its products exceed an amount equal to the buyer’s purchase price. © Copyright 2011 by 3D Systems, Inc. All rights reserved. Subject to change without notice. VisiJet is a registered trademark, and ProJet and the 3D logo are trademarks of 3D Systems, Inc.
  • 5. Material Safety Data Sheet Page 5 of 5 Material Name: VisiJet ® FTI Material MSDS • VisiJet® FTI • 340700-S02-00-A ENGLISH • US Key/Legend ACGIH = American Conference of Governmental Industrial Hygienists CAS = Chemical Abstracts Service CERCLA = Comprehensive Environmental Response, Compensation, and Liability Act CFR = Code of Federal Regulations CPR = Controlled Products Regulations DOT = Department of Transportation DSL = Domestic Substances List EINECS = European Inventory of Existing Commercial Chemical Substances EPA = Environmental Protection Agency IARC = International Agency for Research on Cancer IATA = International Air Transport Association IDL = Ingredients Disclosure List mg/Kg = milligrams per Kilogram mg/L = milligrams per Liter mg/m3 = milligrams per Cubic Meter MSHA = Mine Safety and Health Administration NA = Not Applicable or Not Available NIOSH = National Institute for Occupational Safety and Health NJTSR = New Jersey Trade Secret Registry NTP = National Toxicology Program OSHA = Occupational Safety and Health Administration SARA = Superfund Amendments and Reauthorization Act STEL = Short Term Exposure Limit TDG = Transport Dangerous Goods TSCA = Toxic Substances Control Act WHMIS = Workplace Hazardous Materials Information System.