In this paper, the author Mr H C Rajpoot mathematically analyses & derives analytic formula for a rhombic dodecahedron having 12 congruent faces each as a rhombus, 24 edges & 14 vertices lying on a spherical surface with a certain radius. ‘HCR’s Theory of Polygon’ is used to derive formula to analytically compute the angles & diagonals of rhombic face, radii of circumscribed sphere, inscribed sphere & midsphere, surface area & volume of rhombic dodecahedron in terms of edge length, solid angles subtended at the vertices and dihedral angle between adjacent faces. This convex polyhedron can be constructed by joining 12 congruent elementary-right pyramids with rhombic base & certain normal height.