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Ka=-log(Ka)=-log(5.6*10^-10)=9.25
According to Henderson Hasselbalch Equation
pH = pka + log[salt]/[acid]
pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.2/0.6)
pH=8.77
(2)
NH3 + HCl =======> NH4Cl
I 0.2 0.10 0.6
C 0.2-0.1 -0.1 +0.1
E 0.1 0 0.7
pH = pka + log[salt]/[acid]
pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.1/0.7)
pH=8.40
(3)
NH4Cl + NaOH =============> NH3 + NaCl + H2O
I 0.6 0.20 0.2
C -0.20 -0.20 +0.20
E 0.4 0 0.4
pH = pka + log[salt]/[acid]
pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.4/0.4) = 9.25
Solution
Ka=-log(Ka)=-log(5.6*10^-10)=9.25
According to Henderson Hasselbalch Equation
pH = pka + log[salt]/[acid]
pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.2/0.6)
pH=8.77
(2)
NH3 + HCl =======> NH4Cl
I 0.2 0.10 0.6
C 0.2-0.1 -0.1 +0.1
E 0.1 0 0.7
pH = pka + log[salt]/[acid]
pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.1/0.7)
pH=8.40
(3)
NH4Cl + NaOH =============> NH3 + NaCl + H2O
I 0.6 0.20 0.2
C -0.20 -0.20 +0.20
E 0.4 0 0.4
pH = pka + log[salt]/[acid]
pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.4/0.4) = 9.25

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Ka=-log(Ka)=-log(5.610^-10)=9.25 According to Henderson Hasselb.pdf

  • 1. Ka=-log(Ka)=-log(5.6*10^-10)=9.25 According to Henderson Hasselbalch Equation pH = pka + log[salt]/[acid] pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.2/0.6) pH=8.77 (2) NH3 + HCl =======> NH4Cl I 0.2 0.10 0.6 C 0.2-0.1 -0.1 +0.1 E 0.1 0 0.7 pH = pka + log[salt]/[acid] pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.1/0.7) pH=8.40 (3) NH4Cl + NaOH =============> NH3 + NaCl + H2O I 0.6 0.20 0.2 C -0.20 -0.20 +0.20 E 0.4 0 0.4 pH = pka + log[salt]/[acid] pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.4/0.4) = 9.25 Solution
  • 2. Ka=-log(Ka)=-log(5.6*10^-10)=9.25 According to Henderson Hasselbalch Equation pH = pka + log[salt]/[acid] pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.2/0.6) pH=8.77 (2) NH3 + HCl =======> NH4Cl I 0.2 0.10 0.6 C 0.2-0.1 -0.1 +0.1 E 0.1 0 0.7 pH = pka + log[salt]/[acid] pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.1/0.7) pH=8.40 (3) NH4Cl + NaOH =============> NH3 + NaCl + H2O I 0.6 0.20 0.2 C -0.20 -0.20 +0.20 E 0.4 0 0.4 pH = pka + log[salt]/[acid] pH = 9.25 log[Nh3]/[Nh4+] = 9.25+log(0.4/0.4) = 9.25