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HYDROGEN SULFIDE, PHOSPHATE, COOPER, CHROMIUM,
SELENIUM & ARSENIC REMOVAL MEDIA
Granular Ferric Hydroxide
Based Removal Media
Granular Ferric Hydroxide
Based Removal Media
FILTERSORB HSR®
FILTERSORB HSR®
Leading Manufacturer of Filtration Medias for Water Technology
WATCH FILTRATION TECHNOLOGY
HYDROGEN SULFIDE, PHOSPHATE, COOPER, CHROMIUM,
SELENIUM & ARSENIC REMOVAL MEDIA
Granular Ferric Hydroxide
Based Removal Media
Granular Ferric Hydroxide
Based Removal Media
FILTERSORB HSR®
FILTERSORB HSR®
Leading Manufacturer of Filtration Medias for Water Technology
WATCH FILTRATION TECHNOLOGY
Granular Ferric HydroxideGranular Ferric HydroxideGranular Ferric HydroxideGranular Ferric Hydroxide
Hydrogen Sulfide, Arsenic and Phosphates Removal in Drinking Water
watch water technology
FILTERSORBFILTERSORBFILTERSORBHydrogen Sulfide, Arsenic and Phosphates Removal in Drinking Water
FILTERSORBHydrogen Sulfide, Arsenic and Phosphates Removal in Drinking Water®®
Introduction
Hydrogen sulfide is a colorless gas with an offensive stench
and is said to smell like rotten eggs. The gas can be detected
at a level of 2 parts per billion. It is very erosive in a wet
state and become Sox when it is oxidized.
Physical Properties of H2S
Hydrogen sulfide has a structure similar to that of water.
This is where the similarity ends, however. Sulfur is not
nearly as electronegative as oxygen so that hydrogen sulfide
is not nearly as polar as water. Because of this, comparative-
ly weak intermolecular forces exist for H2S and the melting
and boiling points are much lower than they are in water.
Hydrogen sulfide and water boil at - 60.7 °C and +100.0 °C,
respectively.
General Information Filtersorb HSR
Using a patented process, ferric hydroxide can now be produced in a granular form. Various bead
diameters can be made by combination of crushing and sieving procedures. This gives access to a great
variety of new applications of ferric (III) hydroxide.
The Filter media, containing iron hydroxide Fe(OH)3 has an amorphous structure. The ferric ions
content in the filtering media is about 40% by weigh.
Because of its chemical activity, ferric (III) hydroxide is quite appropriate to bind arsenate, phosphate or
sulfide ions in aqueous media. Due to internal high pH of media it has an additional effect of the reac-
tion with H2S and can reach oxidation capacity up to 20% by its dry weight.
Operation Principles
Arsenic and Phosphate removal
In a first step arsenate or phosphate ions in aqueous solutions were adsorptively bounded to the
surface of Filtersorb HSR. Second step is a chemical conversion to stable ferric arsenate or ferric phos-
phate to the surface of Filtersorb HSR.
Fe(OH)3 + H3PO4 > FePO4 + 3 H2O Fe(OH)3 + H3AsO4 > FeAsO4 + 3 H2O
Hydrogen Sulfide removal
Sulfide ions formed from hydrogen sulfide in water are removed in a similar way under precipitation of
hardly soluble ferric sulfide.
2 Fe(OH)3 + 3 H2S > Fe2S3 + 6 H2O
Hydrogen Sulfide, Arsenic and Phosphates Removal in Drinking Water
Application:
• Water treatment: Filtersorb HSR media is applicable in a
wide range of water treatment processes, from large-scale
municipal systems to small-scale residential treatment units.
Regardless of the system size, there are operational design
parameters that must be considered to ensure effective,
trouble free performance of the Filtersorb HSR media.
Groundwater or surface water is simply pumped in down
flow mode through a single or multiple fixed bed pressure
vessel containing the Filtersorb HSR media, but it can be
also successfully used in up flow filtration. In down flow
filtration is recommended to use oxygen dosing for better
oxidation. It is also being used in systems to remove Chro-
mium, Cooper, Selenium.
The multiple pressure vessel design is either assembled in
Parallel Flow or Series flow. Flow to each vessel is measured
and totalized to record the volume of water treated. Pressure
differential through each vessel is also monitored.
Periodic backwashing is typically performed at start-up and
after each pressure drop of 0,5-1,0 Bar thereafter depending
on usage and water quality.
• Elimination of Arsenic from drinking water
• Binding of Phosphates from rivers and lakes
• Oxydation of Hydrogen Sulfide in water
• Treatment of contaminated ground water
• Filter beds for the separation of phosphates
compounds in wet lands
• “Reactive barriers” for the confinement of
contamination in depositions
• Binding of nutritive substances in aquarium or
garden pond treatment
watch water technology
Physico-Mechanical properties:
Bulk weight 640 kg/m3
Specific surface 270 m2
/g
Colour dark brown
Mesh size 0,5-2,0 mm, 2,0-4,0 mm
Operation condition and exchange capacity:
Bed depth down flow 450-850 mm
Free board down flow 50-75%
Bed depth up flow 50-100%
Free board up flow 10-50%
Service flow rate 10-20 m/h
Back wash flow rate 25-30 m/h
Total adsorbtion capacity as P4+
15 g/kg
Total adsorption capacity as As 5+
12 g/kg
Oxidation capacity as H2S up to 20% of its dry weight
pH 5-9
Filtersorb HSR
Chemical formula and composition: Amorphous Fe(OH)3
Mineralogical composition: Up to 40% of Ferric Ions from its weight
Company presentation:
Since many years Watch GmbH is a leading supplier of high
quality Products for domestic and industrial application
in water treatment technology. As a pollution worldwide
is being increased our company is going to present You a
new concept of Green Chemical Technology with its special
biodegradable 100% chemicals and filtration materials for
drinking, process and waste water technologies
WATCH GREEN PRODUCT RANGE
Filtration material and filtration systems:
Zeosorb (Alumosilicate) – to remove suspended solids up
to 3-5 micron, hardness, ammonium, cesium, nickel, Lead,
Cooper
Titansorb (Titanium dioxide) – to remove Arsenic and other
heavy metals. It is successfully being used as biocide to
disinfect the water
Filtersorb HSR (Iron Hydro-oxide) – to remove Hydrogen Sul-
fide, Arsenic, Phosphor and other heavy metals from water
Greensand FMH (dolomite coated with Manganese dioxide)
– to remove Iron, Manganese and Hydrogen sulfide
Watchox Mn (Manganese dioxide) – to remove Iron, Manga-
nese and Hydrogen sulfide
Filtersorb SP3 (Polymer-carbonate) – modern scale preven-
tion technology based on decarbonization effect
Watch Carbonsorb (bituminous Carbon) – to remove free
chlorine, THM and chloramines
Watchsorb H2O (Polymer) – is a high capacious Superab-
sorber-Polymer, which can store water up to the 1000-fold
of its own net-weight. It is sucessfuly being used in soil for
water storage
Watch Liquid Softener – scale prevention technology and
softening with dosing of Tri-Sodium salts
Filtersorb Calcit – is being used as acidity and CO2 neutral-
ization
Ion exchange resins Watch Ion – SAC, WAC, WBA, SBA, MB, Ultra pure
Watch Membranes – Microfiltration, Ultrafiltration, Nanofiltartion, Reverse Osmosis
Watch Chemicals – chemicals for drinking water, cooling tower, boilers, membrane technology, swimming pools
watch water technology
WATCH GmbH
Mannheimer Straße 8
D 68766 Hockenheim
Telefon: +49 (0)6205 3092 53
Telefax: +49 (0)6205 3092 78
Email: info@watchwater.de
Internet: http://www.watchwater.de
NEWNEWNEW
Watch Liquid Softener
Alternative technology to avoid
scale, based on dosing of Biodegradable
Watch Liquid Softener with specially
made mechanical pumps
Benefits:
100% Efficiency
100% Biodegradability
100% No harmful waste
100% Compatibility for drinking
water processwww.watchwater.de
NEW

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Filtration media

  • 1. HYDROGEN SULFIDE, PHOSPHATE, COOPER, CHROMIUM, SELENIUM & ARSENIC REMOVAL MEDIA Granular Ferric Hydroxide Based Removal Media Granular Ferric Hydroxide Based Removal Media FILTERSORB HSR® FILTERSORB HSR® Leading Manufacturer of Filtration Medias for Water Technology WATCH FILTRATION TECHNOLOGY HYDROGEN SULFIDE, PHOSPHATE, COOPER, CHROMIUM, SELENIUM & ARSENIC REMOVAL MEDIA Granular Ferric Hydroxide Based Removal Media Granular Ferric Hydroxide Based Removal Media FILTERSORB HSR® FILTERSORB HSR® Leading Manufacturer of Filtration Medias for Water Technology WATCH FILTRATION TECHNOLOGY Granular Ferric HydroxideGranular Ferric HydroxideGranular Ferric HydroxideGranular Ferric Hydroxide
  • 2. Hydrogen Sulfide, Arsenic and Phosphates Removal in Drinking Water watch water technology FILTERSORBFILTERSORBFILTERSORBHydrogen Sulfide, Arsenic and Phosphates Removal in Drinking Water FILTERSORBHydrogen Sulfide, Arsenic and Phosphates Removal in Drinking Water®® Introduction Hydrogen sulfide is a colorless gas with an offensive stench and is said to smell like rotten eggs. The gas can be detected at a level of 2 parts per billion. It is very erosive in a wet state and become Sox when it is oxidized. Physical Properties of H2S Hydrogen sulfide has a structure similar to that of water. This is where the similarity ends, however. Sulfur is not nearly as electronegative as oxygen so that hydrogen sulfide is not nearly as polar as water. Because of this, comparative- ly weak intermolecular forces exist for H2S and the melting and boiling points are much lower than they are in water. Hydrogen sulfide and water boil at - 60.7 °C and +100.0 °C, respectively. General Information Filtersorb HSR Using a patented process, ferric hydroxide can now be produced in a granular form. Various bead diameters can be made by combination of crushing and sieving procedures. This gives access to a great variety of new applications of ferric (III) hydroxide. The Filter media, containing iron hydroxide Fe(OH)3 has an amorphous structure. The ferric ions content in the filtering media is about 40% by weigh. Because of its chemical activity, ferric (III) hydroxide is quite appropriate to bind arsenate, phosphate or sulfide ions in aqueous media. Due to internal high pH of media it has an additional effect of the reac- tion with H2S and can reach oxidation capacity up to 20% by its dry weight. Operation Principles Arsenic and Phosphate removal In a first step arsenate or phosphate ions in aqueous solutions were adsorptively bounded to the surface of Filtersorb HSR. Second step is a chemical conversion to stable ferric arsenate or ferric phos- phate to the surface of Filtersorb HSR. Fe(OH)3 + H3PO4 > FePO4 + 3 H2O Fe(OH)3 + H3AsO4 > FeAsO4 + 3 H2O Hydrogen Sulfide removal Sulfide ions formed from hydrogen sulfide in water are removed in a similar way under precipitation of hardly soluble ferric sulfide. 2 Fe(OH)3 + 3 H2S > Fe2S3 + 6 H2O
  • 3. Hydrogen Sulfide, Arsenic and Phosphates Removal in Drinking Water Application: • Water treatment: Filtersorb HSR media is applicable in a wide range of water treatment processes, from large-scale municipal systems to small-scale residential treatment units. Regardless of the system size, there are operational design parameters that must be considered to ensure effective, trouble free performance of the Filtersorb HSR media. Groundwater or surface water is simply pumped in down flow mode through a single or multiple fixed bed pressure vessel containing the Filtersorb HSR media, but it can be also successfully used in up flow filtration. In down flow filtration is recommended to use oxygen dosing for better oxidation. It is also being used in systems to remove Chro- mium, Cooper, Selenium. The multiple pressure vessel design is either assembled in Parallel Flow or Series flow. Flow to each vessel is measured and totalized to record the volume of water treated. Pressure differential through each vessel is also monitored. Periodic backwashing is typically performed at start-up and after each pressure drop of 0,5-1,0 Bar thereafter depending on usage and water quality. • Elimination of Arsenic from drinking water • Binding of Phosphates from rivers and lakes • Oxydation of Hydrogen Sulfide in water • Treatment of contaminated ground water • Filter beds for the separation of phosphates compounds in wet lands • “Reactive barriers” for the confinement of contamination in depositions • Binding of nutritive substances in aquarium or garden pond treatment watch water technology Physico-Mechanical properties: Bulk weight 640 kg/m3 Specific surface 270 m2 /g Colour dark brown Mesh size 0,5-2,0 mm, 2,0-4,0 mm Operation condition and exchange capacity: Bed depth down flow 450-850 mm Free board down flow 50-75% Bed depth up flow 50-100% Free board up flow 10-50% Service flow rate 10-20 m/h Back wash flow rate 25-30 m/h Total adsorbtion capacity as P4+ 15 g/kg Total adsorption capacity as As 5+ 12 g/kg Oxidation capacity as H2S up to 20% of its dry weight pH 5-9 Filtersorb HSR Chemical formula and composition: Amorphous Fe(OH)3 Mineralogical composition: Up to 40% of Ferric Ions from its weight
  • 4. Company presentation: Since many years Watch GmbH is a leading supplier of high quality Products for domestic and industrial application in water treatment technology. As a pollution worldwide is being increased our company is going to present You a new concept of Green Chemical Technology with its special biodegradable 100% chemicals and filtration materials for drinking, process and waste water technologies WATCH GREEN PRODUCT RANGE Filtration material and filtration systems: Zeosorb (Alumosilicate) – to remove suspended solids up to 3-5 micron, hardness, ammonium, cesium, nickel, Lead, Cooper Titansorb (Titanium dioxide) – to remove Arsenic and other heavy metals. It is successfully being used as biocide to disinfect the water Filtersorb HSR (Iron Hydro-oxide) – to remove Hydrogen Sul- fide, Arsenic, Phosphor and other heavy metals from water Greensand FMH (dolomite coated with Manganese dioxide) – to remove Iron, Manganese and Hydrogen sulfide Watchox Mn (Manganese dioxide) – to remove Iron, Manga- nese and Hydrogen sulfide Filtersorb SP3 (Polymer-carbonate) – modern scale preven- tion technology based on decarbonization effect Watch Carbonsorb (bituminous Carbon) – to remove free chlorine, THM and chloramines Watchsorb H2O (Polymer) – is a high capacious Superab- sorber-Polymer, which can store water up to the 1000-fold of its own net-weight. It is sucessfuly being used in soil for water storage Watch Liquid Softener – scale prevention technology and softening with dosing of Tri-Sodium salts Filtersorb Calcit – is being used as acidity and CO2 neutral- ization Ion exchange resins Watch Ion – SAC, WAC, WBA, SBA, MB, Ultra pure Watch Membranes – Microfiltration, Ultrafiltration, Nanofiltartion, Reverse Osmosis Watch Chemicals – chemicals for drinking water, cooling tower, boilers, membrane technology, swimming pools watch water technology WATCH GmbH Mannheimer Straße 8 D 68766 Hockenheim Telefon: +49 (0)6205 3092 53 Telefax: +49 (0)6205 3092 78 Email: info@watchwater.de Internet: http://www.watchwater.de NEWNEWNEW Watch Liquid Softener Alternative technology to avoid scale, based on dosing of Biodegradable Watch Liquid Softener with specially made mechanical pumps Benefits: 100% Efficiency 100% Biodegradability 100% No harmful waste 100% Compatibility for drinking water processwww.watchwater.de NEW