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Bioenergy and Biofuel Industry in the USA and Brazil
               – Path to cooperation




                    Geraldo Eugenio de Franca
                            Fulbright Association
                          UNL – IANR & ARS-USDA
               ITEP – The Technology Institute of Pernambuco
                         Lincoln, NE – Nov 28 2012
Acknowledgments



• Brazil                        • USA

• ITEP – The Technology         • UNL – IANR – Dr. Ron Yoder
  Institute of Pernambuco –
  Dr. Frederico Montenegro
                                •   ARS-USDA Lincoln – Dr. Ken
• IPA – The Agriculture             Vogel and ARS team
  Research Institute of PE –
  Dr. Julio Zoe

• Fulbright Association – Dr.   • IIE – International Institute
  Luiz Vlacov                     of Education – Mr. Jake Silva
Summary


. Bioenergy policies in Brazil


. The sugarcane and the ethanol industry


. The second generation ethanol and other hydrocarbons


. Biological and industrial R&D demands


. The cooperation between Brazil and the USA
Biofuels World Map
Bioenergy Policies in Brazil - A brief account


• 1931 – 5% mixture of ethanol in gasoline

• 1966 – 25% is the allowable mixture

• 1975 – Brazilian Alcohol National Program – Proalcool

• 1979 – Proalcool – Second phase
       - Iran-Iraq war – Crude prices jumped from US$ 14.00 to US$
       30.00/barrel

• 1983 – Brazilian Energy Nation Program – Biodiesel research – Univ. Fed.
  of Parana
Bioenergy Policies in Brazil - A brief account


• 2002 - Ethanol – gasoline mixtures ranges from 20 to 25%

• 2003 – Automobile industry launches the ‘flex-fuel’ vehicle –
  (ethanol – gasoline)

• 2005 – Law 10097 – Biodiesel legislation and National Agrienergy
  Plan

• 2010 – The Brazilian National Laboratory of Bioethanol – CTBE
  inaugurated

• 2010 – Embrapa’s National Agrienergy Research Center
Sugarcane acreage in Brazil – million hectares

                                     Gráfico 1 - Evolução da área de cana
                       8,0

                       7,0

                       6,0
 Milhões de Hectares




                       5,0

                       4,0

                       3,0

                       2,0

                       1,0

                       0,0
                             2005          2006    2007     2008       2009        2010   2011

                                    Soca      Reformada    Expansão      Em reforma


                                     Fonte: Elaboração EPE a partir de INPE [20]
Sugarcane production in Brazil – million tonnes
                                  Gráfico 2– Histórico anual de produção de cana


                       700
                                                                             622,6 627,3
                       600
                                                                                           565,8

                       500
Milhões de toneladas




                       400


                       300
                             254,9

                       200


                       100


                        0
                              2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011

                             Fonte: EPE com base em MAPA [26]
Sugarcane primary energy – 1 ton



1/3 juice: ethanol and sugar          – 608 x 109 kcal
      153 kg sugar or 90 l ethanol

1/3 bagasse: vapour and electricity   – 598 x 109 kcal

1/3 leafs and tops                    - 512 x 109 kcal

Total                                 1,718 x 109 kcal

1 crude barrel                        1,386x 109 kcal
Sugarcane geography in Brazil
Brazilian ethanol supply
                                        Gráfico 3 – Oferta de etanol


                30,0                                                                            28,0
                                                                                     26,1

                25,0
                                                                                                          23,0
                                                                                                 19,9
                                                                                         19,1
Milhões de m³




                20,0

                                                                                                         14,3
                15,0
                       11,5

                10,0                                                                            8,0     8,7
                       6,5                                                         7,0
                          5,0
                 5,0


                 0,0
                       2001     2002   2003   2004   2005   2006   2007    2008     2009        2010    2011


                                        Anidro         Hidratado          Etanol Total


           Fonte: Elaboração EPE a partir de MAPA [30]
Flex-fuels vehicles sales in Brazil – 2003 - 2011

                                                             Veículos Flex Fuel
                                     Participação nas vendas de veículos leves - em milhões de unidades


     3.5                                                                                                                                    100%

                                                                                   87.2%           88.2%            86.4%
                                                                     85.6%                                                                  90%
     3.0                                                                                                                            83.1%
                                                             78.1%
                                                                                                                     2.9                    80%
                                                                                                                                     2.8

     2.5                                                                                             2.7
                                                                                                                                            70%

                                                                                     2.3
                                                                                                                                            60%
     2.0
Millions




                                             50.2%                    2.0
                                                                                                                                            50%

     1.5
                                                                                                                                            40%
                                                               1.4

     1.0                                                                                                                                    30%
                              21.6%
                                               0.8                                                                                          20%
     0.5            3.7%
                                                                                                                                            10%
                   0.0             0.3
           -                                                                                                                                0%
                   2003           2004        2005            2006   2007           2008            2009            2010            2011


                                          Vendas de veículos flex      Participação de veículos flex nas vendas de veículos leves



               Source: EPE 2012
Brazilian ethanol production and oil price




Fonte: BP e EPE
USA RFS Program requirements
Ethanol Production in the USA and Brazil
Projected ethanol importation from the USA

                                  Gráfico 7 – Projeções de Importação – Estados Unidos

                     3,0
                                                                                                            2,6

                     2,5    2,3
                                                                                                    2,2
                                      2,0
                     2,0
                                                                                            1,7
Bilhõe s de litros




                                               1,6                                  1,6
                                                                           1,5
                     1,5
                                                                  1,4
                                                         1,3


                     1,0



                     0,5



                     0,0
                           200 8      200 9    2010     2011     2012     20 13    20 14    20 15   20 16   20 17


                                              Fonte: elaboração EPE a partir de EIA [19].
USA and Brazil R&D collaborative program



                       Environmental
   Agronomy
                           issues


             Priority areas


Biochemistry and
                       Industrial issues
 Biotechnology
Agronomy - R&D demands

Sugarcane and Corn
•   Abiotic stresses – cold, heat, drought
•   Lignocellulose material - content and quality
•   Water use efficiency
•    Transportation logistics

Sweet Sorghum
•   Total biomass production and quality
•   Juice and fermentable sugars content
•   Lodging tolerance
•   Photoperiod response
•   Leaf diseases resistance

C4 Grasses – Switchgrass, Napier grass
•   Resilience
•   Total biomass production and quality
•   Carbon sequestration
•   Life cycle analysis
Biotechnology and Biochemistry – R&D




Sucrose                    Starch                     Lignocellulose

• Yeast strains tolerant   • Yeast strains tolerant   • Designing enzymes
  to high temperature        to high temperature        for conversion – C5

• Yeast strains tolerant   • Yeast strains tolerant   • Lignin use
  to high ethanol            to high ethanol
  content in the beer        content in the beer      • NIRS analysis

                           • Modified starch          • Identification and use
                             molecules                  of specific traits
Environmental issues




Climate Change            Life Cycle Analysis       Mechanization

• GHG emissions           • Net energy ratio
                                                    • Harvesting
• Carbon sequestration    • Reduction in use of
                                                    • Soil compaction
                            agrochemicals
• Water use efficiency
  in biomass production                             • Transportation of
                          • Biological N fixation
                                                      leafs and tops
• WUE in industrial       • P and K
  activities                bioremediation
Industrial demands




Liquid fuels              Energy                 Byproducts

• Sugar extraction        • Electricity          • Bio-plastics

• Enzymatic conversion    • Thermal conversion   • New materials

• Lignin use              • Biogas

• Hydrocarbons
USA and Brazil – Mechanisms of cooperation

         2007 – Agreement - President Bush and President Lula
         da Silva


         . Bioenergy, ethanol, joint projects


         2011 – MOU on Scientific Cooperation - President Barak
         Obama and President Dilma Roussef


         • Agriculture, health, aerospace engineering, bioenergy



         2011 – The Science without Borders Program
         • Brazil is sending 100,000 students abroad in 4 years
         • 75,000 students with public funds.
         • 18,000 selected. Around 4,000 to the USA
PhD and MSc students graduated – 1998 - 2011




Source: MCTI 2012
Fulbright Association – UNL & ARS-USDA



          Thanking you!




               Geraldo Eugenio
              geugenio@itep.br
1G Ethanol – Opportunities and challenges in the industry


  1G – Sugarcane ethanol refinery         Sugar
                                                              Energy source
                                       Bioethanol GI           (liquid fuel)
                             Juice
                           (sucrose)
                                          Yeast                  Polymers
                 stalks
     Sugarcane
                                          Others

                                          Energy to the plant
        Trash              Bagasse      (thermal and electric)

                                             Bioelectricity
                                             (to the grid)
Burn before
                  Field
harvesting                                    Cattle feed

  Source: CTBE
2G Ethanol – Opportunities and challenges in the industry

  2G – Bio-refinery
                                               Bioethanol GII
                                               Furane Chemistry
                                               Xilose - Xilytol
                               Pentoses
Bagasse                                                   Energy to the plant
                                                          (thermal and electric)
                                      Energy (biogas)
            Pretreatment                                  Bioelectricity
                                                          (to the grid)
                                                               Bioethanol GII
 Trash
            Lignin cellulose                  Hexoses
                 slurry                                        Sugar Chemistry
                                Hydrolysis
                                                               Lignin Chemistry
                                                               Phenolic route
                      Energy

Source: CTBE

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Bioenergy in br and usa path to coop - final - nov 27 2012

  • 1. Bioenergy and Biofuel Industry in the USA and Brazil – Path to cooperation Geraldo Eugenio de Franca Fulbright Association UNL – IANR & ARS-USDA ITEP – The Technology Institute of Pernambuco Lincoln, NE – Nov 28 2012
  • 2. Acknowledgments • Brazil • USA • ITEP – The Technology • UNL – IANR – Dr. Ron Yoder Institute of Pernambuco – Dr. Frederico Montenegro • ARS-USDA Lincoln – Dr. Ken • IPA – The Agriculture Vogel and ARS team Research Institute of PE – Dr. Julio Zoe • Fulbright Association – Dr. • IIE – International Institute Luiz Vlacov of Education – Mr. Jake Silva
  • 3. Summary . Bioenergy policies in Brazil . The sugarcane and the ethanol industry . The second generation ethanol and other hydrocarbons . Biological and industrial R&D demands . The cooperation between Brazil and the USA
  • 5. Bioenergy Policies in Brazil - A brief account • 1931 – 5% mixture of ethanol in gasoline • 1966 – 25% is the allowable mixture • 1975 – Brazilian Alcohol National Program – Proalcool • 1979 – Proalcool – Second phase - Iran-Iraq war – Crude prices jumped from US$ 14.00 to US$ 30.00/barrel • 1983 – Brazilian Energy Nation Program – Biodiesel research – Univ. Fed. of Parana
  • 6. Bioenergy Policies in Brazil - A brief account • 2002 - Ethanol – gasoline mixtures ranges from 20 to 25% • 2003 – Automobile industry launches the ‘flex-fuel’ vehicle – (ethanol – gasoline) • 2005 – Law 10097 – Biodiesel legislation and National Agrienergy Plan • 2010 – The Brazilian National Laboratory of Bioethanol – CTBE inaugurated • 2010 – Embrapa’s National Agrienergy Research Center
  • 7.
  • 8.
  • 9. Sugarcane acreage in Brazil – million hectares Gráfico 1 - Evolução da área de cana 8,0 7,0 6,0 Milhões de Hectares 5,0 4,0 3,0 2,0 1,0 0,0 2005 2006 2007 2008 2009 2010 2011 Soca Reformada Expansão Em reforma Fonte: Elaboração EPE a partir de INPE [20]
  • 10. Sugarcane production in Brazil – million tonnes Gráfico 2– Histórico anual de produção de cana 700 622,6 627,3 600 565,8 500 Milhões de toneladas 400 300 254,9 200 100 0 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 Fonte: EPE com base em MAPA [26]
  • 11. Sugarcane primary energy – 1 ton 1/3 juice: ethanol and sugar – 608 x 109 kcal 153 kg sugar or 90 l ethanol 1/3 bagasse: vapour and electricity – 598 x 109 kcal 1/3 leafs and tops - 512 x 109 kcal Total 1,718 x 109 kcal 1 crude barrel 1,386x 109 kcal
  • 13. Brazilian ethanol supply Gráfico 3 – Oferta de etanol 30,0 28,0 26,1 25,0 23,0 19,9 19,1 Milhões de m³ 20,0 14,3 15,0 11,5 10,0 8,0 8,7 6,5 7,0 5,0 5,0 0,0 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 Anidro Hidratado Etanol Total Fonte: Elaboração EPE a partir de MAPA [30]
  • 14. Flex-fuels vehicles sales in Brazil – 2003 - 2011 Veículos Flex Fuel Participação nas vendas de veículos leves - em milhões de unidades 3.5 100% 87.2% 88.2% 86.4% 85.6% 90% 3.0 83.1% 78.1% 2.9 80% 2.8 2.5 2.7 70% 2.3 60% 2.0 Millions 50.2% 2.0 50% 1.5 40% 1.4 1.0 30% 21.6% 0.8 20% 0.5 3.7% 10% 0.0 0.3 - 0% 2003 2004 2005 2006 2007 2008 2009 2010 2011 Vendas de veículos flex Participação de veículos flex nas vendas de veículos leves Source: EPE 2012
  • 15. Brazilian ethanol production and oil price Fonte: BP e EPE
  • 16. USA RFS Program requirements
  • 17. Ethanol Production in the USA and Brazil
  • 18. Projected ethanol importation from the USA Gráfico 7 – Projeções de Importação – Estados Unidos 3,0 2,6 2,5 2,3 2,2 2,0 2,0 1,7 Bilhõe s de litros 1,6 1,6 1,5 1,5 1,4 1,3 1,0 0,5 0,0 200 8 200 9 2010 2011 2012 20 13 20 14 20 15 20 16 20 17 Fonte: elaboração EPE a partir de EIA [19].
  • 19. USA and Brazil R&D collaborative program Environmental Agronomy issues Priority areas Biochemistry and Industrial issues Biotechnology
  • 20. Agronomy - R&D demands Sugarcane and Corn • Abiotic stresses – cold, heat, drought • Lignocellulose material - content and quality • Water use efficiency • Transportation logistics Sweet Sorghum • Total biomass production and quality • Juice and fermentable sugars content • Lodging tolerance • Photoperiod response • Leaf diseases resistance C4 Grasses – Switchgrass, Napier grass • Resilience • Total biomass production and quality • Carbon sequestration • Life cycle analysis
  • 21. Biotechnology and Biochemistry – R&D Sucrose Starch Lignocellulose • Yeast strains tolerant • Yeast strains tolerant • Designing enzymes to high temperature to high temperature for conversion – C5 • Yeast strains tolerant • Yeast strains tolerant • Lignin use to high ethanol to high ethanol content in the beer content in the beer • NIRS analysis • Modified starch • Identification and use molecules of specific traits
  • 22. Environmental issues Climate Change Life Cycle Analysis Mechanization • GHG emissions • Net energy ratio • Harvesting • Carbon sequestration • Reduction in use of • Soil compaction agrochemicals • Water use efficiency in biomass production • Transportation of • Biological N fixation leafs and tops • WUE in industrial • P and K activities bioremediation
  • 23. Industrial demands Liquid fuels Energy Byproducts • Sugar extraction • Electricity • Bio-plastics • Enzymatic conversion • Thermal conversion • New materials • Lignin use • Biogas • Hydrocarbons
  • 24. USA and Brazil – Mechanisms of cooperation 2007 – Agreement - President Bush and President Lula da Silva . Bioenergy, ethanol, joint projects 2011 – MOU on Scientific Cooperation - President Barak Obama and President Dilma Roussef • Agriculture, health, aerospace engineering, bioenergy 2011 – The Science without Borders Program • Brazil is sending 100,000 students abroad in 4 years • 75,000 students with public funds. • 18,000 selected. Around 4,000 to the USA
  • 25. PhD and MSc students graduated – 1998 - 2011 Source: MCTI 2012
  • 26. Fulbright Association – UNL & ARS-USDA Thanking you! Geraldo Eugenio geugenio@itep.br
  • 27.
  • 28.
  • 29. 1G Ethanol – Opportunities and challenges in the industry 1G – Sugarcane ethanol refinery Sugar Energy source Bioethanol GI (liquid fuel) Juice (sucrose) Yeast Polymers stalks Sugarcane Others Energy to the plant Trash Bagasse (thermal and electric) Bioelectricity (to the grid) Burn before Field harvesting Cattle feed Source: CTBE
  • 30. 2G Ethanol – Opportunities and challenges in the industry 2G – Bio-refinery Bioethanol GII Furane Chemistry Xilose - Xilytol Pentoses Bagasse Energy to the plant (thermal and electric) Energy (biogas) Pretreatment Bioelectricity (to the grid) Bioethanol GII Trash Lignin cellulose Hexoses slurry Sugar Chemistry Hydrolysis Lignin Chemistry Phenolic route Energy Source: CTBE