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Beverage-ind.pptx
1. Outline
History
Ingreedients
Barley, Hops, Yeast, Water
Brewing process
The processing, and what effects we expect them to have on properties of the
final product
Beer characteristics
The properties that we observe, and how they were derived from the
processing of the ingredients
Conclusion & links for more info
2. RAW MATERIALS
The main raw materials for beer production are:
Cereals Malt ,mainly barley
Water
Hops and
Yeast
4. Grain
Barley
Higher extract, less husk
Preferred by both home and
Industrial breweries
Other Grains
Wheat, Oats, Corn, Rice
5.
6.
7. Malting
Grain (usually barley) is malted
Harvested grain is soaked in water until it germinates
This activates amylases (and proteases)
Grain is dried
This halts the conversion
Acrospires (sprouts) are removed
Grain is cured
usually at least one month
8. Barley Malting
Acrospires eat endosperm as they
grow during malting
Acrospire is the sprout,
endosperm is its food source (full
of starch)
Acrospires will continue to eat
endosperm until it is depleted or
they are stopped by the maltster
by heating and drying
Longer acrospire growth leads to:
More endosperm consumed and less fermentable
sugar
More amylases are activated
More yeast nutrients released
Clearer beer and more complete fermentation
9. Water:The medium for fermentation
3 main concerns
Flavor of water
Nutrients for yeast
Can’t use distilled water
pH effects how well enzymes make maltose
Keep mash pH 5-5.5
Ion concentration important
e.g. Ca2+, Mg2+, CO3
2-
Darker malts lower pH more than lighter malts
Areas with water with natural higher pH produced darker beers than areas with
water with lower pH
10. Hops
Humulus lupulus (family = Cannabinaceae)
Perennial Bitter herb grown on a vine and
composed of leaflike bracts and bracteoles
Bracteoles have lupulin glands that
produce resins containing alpha acids
Alpha acids – provide bitter taste/flavor
and preservative
Oils from the plant add flavor and aroma
11. According to studies the average composition of hop dry weight is
approximately
Bitter substances or hop resins 18.5 %
Hop oil 1.0 %
Polyphenols 3.5 %
Protein 20.0 %
Inorganic 8.0 %
cellulose and other materials 49.0%
12. Yeast fermentation catalyst
The most important and mysterious ingredient
turns wort into beer and produced more of itself
Through anaerobic respiration, it converts the malt sugar into alcohol,
CO2, and other by-products
Often removed after fermentation, and can be re-used
Yeast is essentially a fermentation catalyst
The word “enzyme” (meaning biological catalyst)
13. Yeast
2 main types (for brewing purposes)
Saccharomyces cerevisiae (ale yeast)
Prefers warmer temperatures (20-25°C) and will flocculate on top of the beer
Saccharomyces uvarum (lager yeast)
Prefers cooler temperatures and will flocculate at the bottom of the beer (~5°C)
14. MALTING: The first ingredient to come into play is barley, which is grain
(or, in other words, a seed).
The seeds are soaked in water for about two days and allowed to begin
their development into plants.
Enzymes are released that break down the proteins and starches in each
grain into simple sugars meant to nourish the baby plant. However, once
this process has begun, the barley is cooked in a kiln, arresting the growth
process while the enzymes are at their peak of production. This is called
malting.
15. Malt
Germinated and crushed grain
Amylases (and proteases) accessible but inactive
Starches from endosperm partially broken down
17. Alpha Acids
Humulone R = CH2CH(CH3)2
Cohumulone R = CH(CH3)2
Adhumulone R = CH(CH3)CH2CH3
18. MASHING: In the mashing stage, the grain is actually
transformed into sugar. The grains are crushed into a fine
powder, or grist, and then soaked in water. Proteins are
broken down.
Starches are broken down into simple sugars that nourish the
yeast. Complex sugars remain to give the beer its malty
taste. The mash is heated and strained to yield a substance
called wort.
Next, the wort is brought to a boil and the flowers of the
female hop plant are added. Bitter resins and aromatic hop
oils are released. The variety of hop, the amount added, and
the point or points in the boil at which they are added all
contribute to the flavor of the beer. They add bitterness
when added early to the boil, flavor if added in the middle,
and aroma when added at the end.
19. Mashing & Lautering
Mashing
Malt is soaked in hot water
~155°F (~68°C)
Amylases re-activated
starches broken down to sugars
Primarily maltose = 2 glucose joined by α(14) linkage
Proteins also broken down
Processing of proteins and starches highly dependent on temperature
pH also important for amylase activity
Lautering
Grains are rinsed until water comes through clear
Extract all ingredients into wort to be boiled
21. FERMENTATION: The wort is then cooled and moved into a fermentation
vessel.
Yeast is added and allowed to consume most or all of the sugars in the
wort. This is the fermentation process during which alcohol is produced.
The process takes about ten days. Each brewery has its own strains of
yeast, and it is the yeast that determines the character of the beer.
22. Pitching Yeast
Addition of yeast to allow fermentation
Wort must be at proper temperature for yeast to survive and flourish
Slightly off temperatures lead to off flavors
Far off temperatures lead to stuck fermentation
Oxygen must be kept out
Yeast only converts sugars to alcohol and CO2 under anaerobic respiration
With oxygen present, aerobic respiration will dominate
23.
24. Fermentation
Yeast absorbs oxygen and sugar, and reproduces asexually
When oxygen is used up, reproduction stops and fermentation (anaerobic
respiration) begins
Each glucose produces two molecules of ethyl alcohol and CO2
C6H12O6 2 CH3CH2OH + 2 CO2 + 118 kJ (2 ATP)
Large amounts of CO2 are produced and must be removed without letting
oxygen in
Airlock or water bubbler
25. Fermentation
When all fermentable sugars have been consumed, fermentation stops and
yeast begins to go dormant
Yeast settle out and the beer clarifies
This yields a “young beer”
Bad taste and smell
High concentrations of diacetyl and other organic byproducts
26. STORAGE: The beer is then separated from the yeast (racked). Once the
yeast is removed the beer is passed from fermentation to storage vessels.
During transfer the beer is cooled to minus one degree centigrade. The
beer stays in storage at this temperature, and any material which might
impair the appearance, flavour and shelf-life of the beer settles out.
FILTRATION: Following a set time in storage,
carbon dioxide gas collected during
fermentation is added to give beer its
characteristic head and sparkling taste. The
beer is then passed through a filtration system
to remove surplus yeast and protein.
27. Conditioning
Small amounts of remaining yeast continue to consume byproducts of initial
fermentation
Conditioning or aging, development of flavor
28. PASTEURISATION: This is a process of heating and rapid cooling which
prolongs shelf-life and destroys any bacteria or other organisms in the
beer. Canned and bottled beers are pasteurised in their containers, while
draught beer is pasteurised by means of a special heat exchanger called a
flash pasteuriser.
PACKAGING: The filtered and sparkling beer is packaged into bottles, cans
and stainless steel casks, or kegs, ready for distribution.
29. Packaging
Flat beer is packaged (bottle or keg) and must be carbonated
Add extra sugar for natural carbonation by fermentation
Artificially carbonate from gas source
31. Alcohol Content
Measured by density
Original gravity – density of wort prior to fermentation
Final gravity – density of beer after fermentation
Dissolved sugars lead to high density
As sugars convert to ethyl alcohol, the density decreases
The decrease in the density is directly proportional to the amount of alcohol
present
32. Flavor
Sweet flavors from malt
Dependent on types of grain and on grain modification
Bitter flavors from hops
Isoalpha acids balance sweetness of grain
15 – 100 ppm depending on beer type
Aroma from hop oils mainly from later additions of hops
33. Aroma
Hop oils
Small organic molecules
Often aromatics
Polyphenols
Mainly from late addition of hops
Aroma hops boiled for a short time (~5 minutes)
Dry hops (added after wort has cooled or just before packaging)
Phenol
34. Clarity
Filtering, siphoning, settling, racking
Yeast
Flocculency of yeast
Polyphenols from hops
Larger polyphenols become insoluble and form a “permanent haze”
Small polyphenols agglomerate when chilled to form a “chill haze”
35. Head
Protein from grains
Wheat proteins stabilize head
Isoalpha acids
Tensioactive properties of isoalpha acids stabilize head
36. Preservation
Alcohol is a natural preservative
Alpha acids
Act as a preservative by inhibiting the growth of bacteria
Beta acids (also from hops) also help
Decomposition on exposure to light
Isoalpha acids are
light sensitive
Skunky flavor
Only a few ppb
http://www.scielo.br/scielo.php?pid=S0100-
40422000000100019&script=sci_arttext
37. More Info
Stephen Snyder, The Brewmaster’s Bible, New York: HarperPerennial, 1997
http://www.scientiaevitae.de/gb/2/5/beer.htm
Hop Chemistry: http://www.scielo.br/scielo.php?pid=S0100-
40422000000100019&script=sci_arttext