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BENZOPHENONE
FREE
UV COATINGS
Ink and Coating Application
By: Sugeng Endarsiwi (Printing Ink Manufacturer)
• key
component
• cost driver
Photoinitiators
(PIs):
for UV curing
products.
PI’s Capability to: Initiating or starting a photoreaction
This occurs when a PI absorbs radiation energy, from light exposure to produce
highly reactive free radicals
• These have the capability of catalyzing or starting
chemical reactions, or changes in certain formulated
materials.
• One such photo initiator is Benzophenone.
• Benzophenone (BP) or Benzo, has been generally recognized as
the most used PI globally.
• It is known for its effectiveness as:
• an initiator
• its relative low cost.
• The European Printing Ink Association (EuPIA) has published a listing of
PIs used in:
• coatings, inks and varnishes for the non-contact side of food packaging.
• These are listed as Group 1-For all packaging types.
• 1A-low migration potential with toxicological data.
• 1B-low migration potential and/or high molecular weight, awaiting
evaluation.
• 1C-evaluated with a migration limit in accordance with EU RG. No.
10/2011, and/or Swiss Ord. 817.023.21.
• The 1C list includes Benzophen-one and derivatives.
Group 2-lists PIs not fully
evaluated specifying use
only with a metal barrier.
This has resulted in
packaging specifiers
requesting that certain PIs
with migration potential not
be used on their (in-direct
contact) food packaging
products.
By replacing:
low molecular
weight
high migration
potential PIs.
As a result:
benzophenone
Free
ITX free
formulations
have been
made available.
Printing ink and coating manufacturers
have responded:
In other moves, raw
material suppliers
continue to develop:
• Self-curing resin solutions
• New large molecule
• Low migration
• Low odor polymeric
photoinitiators (PPIs)
• Co initiators.
Significantly,
these changes
have become
price drivers for
UV curing
products.
• Endarsiwi, Sugeng is a Printing & Ink Technology Expert with a passion for observed and
sharing information on technical topics. He has over 20 years of industry experience in Printing,
including Printing industrial and Printing Ink technology.
• Graduated School Business & Management (EMBA), JUC, Malaysia.
• Registered as Professional Engineer (Ir.) at The Institution of Engineers Indonesia (PII).
• Holds Chartered Management Association as CMA-HK SAR, Hong Kong
• Study Postgraduate: Leadership & Public Policy Program (MAP) at UEU, Jakarta

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Benzophenone Photo-Initiator

  • 1. BENZOPHENONE FREE UV COATINGS Ink and Coating Application By: Sugeng Endarsiwi (Printing Ink Manufacturer)
  • 2. • key component • cost driver Photoinitiators (PIs): for UV curing products.
  • 3. PI’s Capability to: Initiating or starting a photoreaction This occurs when a PI absorbs radiation energy, from light exposure to produce highly reactive free radicals
  • 4. • These have the capability of catalyzing or starting chemical reactions, or changes in certain formulated materials. • One such photo initiator is Benzophenone.
  • 5. • Benzophenone (BP) or Benzo, has been generally recognized as the most used PI globally. • It is known for its effectiveness as: • an initiator • its relative low cost.
  • 6. • The European Printing Ink Association (EuPIA) has published a listing of PIs used in: • coatings, inks and varnishes for the non-contact side of food packaging. • These are listed as Group 1-For all packaging types. • 1A-low migration potential with toxicological data. • 1B-low migration potential and/or high molecular weight, awaiting evaluation. • 1C-evaluated with a migration limit in accordance with EU RG. No. 10/2011, and/or Swiss Ord. 817.023.21. • The 1C list includes Benzophen-one and derivatives.
  • 7. Group 2-lists PIs not fully evaluated specifying use only with a metal barrier. This has resulted in packaging specifiers requesting that certain PIs with migration potential not be used on their (in-direct contact) food packaging products.
  • 8. By replacing: low molecular weight high migration potential PIs. As a result: benzophenone Free ITX free formulations have been made available. Printing ink and coating manufacturers have responded:
  • 9. In other moves, raw material suppliers continue to develop: • Self-curing resin solutions • New large molecule • Low migration • Low odor polymeric photoinitiators (PPIs) • Co initiators. Significantly, these changes have become price drivers for UV curing products.
  • 10.
  • 11. • Endarsiwi, Sugeng is a Printing & Ink Technology Expert with a passion for observed and sharing information on technical topics. He has over 20 years of industry experience in Printing, including Printing industrial and Printing Ink technology. • Graduated School Business & Management (EMBA), JUC, Malaysia. • Registered as Professional Engineer (Ir.) at The Institution of Engineers Indonesia (PII). • Holds Chartered Management Association as CMA-HK SAR, Hong Kong • Study Postgraduate: Leadership & Public Policy Program (MAP) at UEU, Jakarta