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“A STUDY ON CHARACTERIZATION OF COMPRESSIVE STRENGTH
AND LEACHING BEHAVIOR OF STABILIZED SOILS USING FLY ASH AND
          GROUND GRANULATED BLAST FURNACE SLAG”
        Visvesvaraya Technological University, Belgaum




                         Naveen Kumar.S
                         1BM10CEE07



              Under the Guidance of Dr. MAYA NAIK
                   Professor, Dept. of Civil Engineering,
            BMS College of Engineering, Bangalore -560019.

                                                             1
CONTENTS

 Introduction
 Objective
 Literature review
 Materials and Methods
 Results and Discussions
 Conclusions
 Scope for future work
 References

                            2
INTRODUCTION
• Soil stabilization is the permanent physical and chemical alteration
  of soils to enhance their physical properties.
• Stabilization increases the shear strength and controls the shrink-
  swell properties of a soil, and it increase the load-bearing capacity of
  a sub-grade to support pavements and foundations.
• Stabilization can be achieved with a variety of chemical additives
  including lime, cement, fly ash and GGBS mixtures as well as by-
  products of industrial wastes.
• Stabilization of expansive soils with admixtures controls the
  potential of soils for a change in volume behavior.
• Proper design and testing is an important component of any
  stabilization project.
• Fly ash and GGBS mixtures have been utilized in bulk in
  Geotechnical Engineering applications such as construction of
  Embankments, as a Backfill material, etc
                                                                         3
GRADATION OF SOIL, COMPACTION OF
        SOIL FLY ASH MIXTURES
• Soil     gradation      is    an    important    aspect     of    soil
  mechanics and Geotechnical engineering.
• Soil gradation is a classification of a coarse-grained soils based on
  the different particle sizes.
• The compaction of soil with fly ash, GGBS and lime is an
  important parameter since it controls the Strength, Compressibility
  and Permeability behavior of stabilized mixture.
• The compacted unit weight of the material depends on the amount
  and method of energy application, grain size distribution, plasticity
  characteristics and moisture content.
• In the present work gradation of fly ash and GGBS mixtures has
  been carried out in order to bring the effect of gradation on
  stabilization of black cotton soil.

                                                                       4
PRINCIPLES AND NEED FOR SOIL
              STABILIZATION
• Selecting Effective and economical method of soil stabilization and
  designing the stabilized soil mix for intended stability and durability
  values.
• An attempt has been made for utilization of locally available soils
  and other suitable stabilizing agents and encourage the use of
  industrial fly ash and other wastes in construction activities.
    TYPES OF SOIL STABILIZATION
•    Mechanical stabilization
•    Soil-lime stabilization
•    Soil-Fly ash stabilization
•    Soil-cement stabilization
•    Soil-bitumen stabilization
                                                                        5
MECHANICAL STABILIZATION
• The basic principles of mechanical stabilization are mechanical
  strength of coarse mixtures, gradation, properties of the soil, ease of
  compaction.
• This method is suitable for low volume i.e. Village roads in low
  rainfall areas.
• This method involves the correct proportioning of coarse mixtures
  and soil, adequately compacted to get mechanically stable layer.
SOIL-LIME STABILIZATION
• Soil lime imparts some binding action even in granular soils
  and increase in lime content causes slight change in liquid limit
  and considerable increase in plasticity index.
• The strength of soil-lime increases with curing period up to
  certain time. The rate of increase is rapid during initial period.
  The humidity of the surroundings also affects the strength.
• Soil- Lime Stabilization has been widely used as a modifier or a
  binder                                                                6
SOIL-FLY ASH STABILIZATION
• Soil- fly ash Stabilization reduces its plasticity index, and swell
  potential owing to a cat ion exchange process that results in an
  agglomeration of the fine clay particles into coarse particles.
• The stable exchangeable cat ions provided by fly ash, such as
  Ca2+, Al3+, and Fe3+ promote flocculation of the clay particles.
• Formation of cemented compounds characterized by their high
  shear strength and low volume change. In addition to fly ash
  stabilization, lime is widely used to reduce swell and increase shear
  strength of expansive soils.
• The improvement is due to the following two basic reactions, short-
  term reaction including cation exchange and flocculation and long-
  term reaction including pozzolanic reaction.



                                                                      7
SOIL- CEMENT STABILIZATION

• Cement stabilization is generally the best type of admixture to be
  used with soil. It is also commonly available but it is often
  expensive.
• Mixing cement with expansive soils reduces swell potential.
• Generally, the amount of cement required to stabilize expansive
  soils ranges from 2 to 6% by weight.
• When the pore water in soil encounters the cement, hydration of the
  cement occurs rapidly and the major hydration products are
  hydrated calcium silicates, hydrated calcium aluminates, and
  hydrated lime.
• The hydration of cement leads to a rise in pH value of the pore
  water, which is caused by the dissociation of the hydrated lime.


                                                                    8
OBJECTIVES OF THE PRESENT STUDY
In the light of extensive literature survey carried out for the
stabilization of soil fly ash and GGBS mixtures, the following are the
major objectives of the present study.
 To determine the compaction and unconfined compressive strength
   of stabilized black cotton soil using fine and coarse fly ash mixtures.
 To determine the compaction and unconfined compressive strength
   of stabilized black cotton soil using fine and coarse GGBS mixtures.
 To determine the optimum lime content required for stabilizing
   black cotton soil by performing unconfined compressive strength
   test.
 To study the leaching behavior of heavy metal ions from stabilized
   black cotton soil for various types of admixtures used.


                                                                         9
LITERATURE REVIEW

Chen 1975; Liao 1984; Locat et al.1990
• The relationship between the plasticity index and swell-shrinkage
  properties for pre-treated and post-treated soils was brought out.
• The test results show that the plasticity index, activity, free
  swell, swell potential, swelling pressure, and axial shrinkage percent
  decreased with an increase in fly ash or fly ash-lime content.
• With the increase of the curing time for the treated soil, the swell
  potential and swelling pressure decreased.
• Soils immediately treated with fly ash shows a consecutive change
  in the unconfined compressive strength.
• However, after 7 days curing of the fly ash treated soils, the
  unconfined compressive strength increased significantly.


                                                                      10
Contd…
 Phanikumar and Sharma (2004)
 • A study was carried out on the effect of fly ash on engineering
   properties of expansive soil and the effect on parameters like free
   swell       index       (FSI),      swell       potential,    swelling
   pressure, plasticity, compaction, unconfined compressive strength and
   hydraulic conductivity of expansive soil was studied.
 • The ash blended expansive soil with fly ash contents of 0, 5, 10, 15
   and 20% on a dry weight basis and they inferred that increase in fly
   ash content reduces plasticity characteristics and the free swell index
   (FSI) was reduced by about 50% by the addition of 20% fly ash.
 • The hydraulic conductivity of expansive soils mixed with fly ash
   decreases with an increase in fly ash content, due to the increase in
   maximum dry unit weight with an increase in fly ash content.
 • When the fly ash content increases there is a decrease in the optimum
   moisture content and the maximum dry unit weight increases.

                                                                      11
Contd…

 P.V. Sivapullaiah (2000)
 • Fly ashes with high pozzolanic reactivity are widely used but those
    with less pozzolanic reactivity are greatly inhibited.
 • As the strength development in natural expansive soil considered in
    this investigation is very less with different percentages of fine fly
    ash, an attempt is made to increase the same by addition of lime along
    with fly ash.
 • Based on several tests conducted, the optimum lime contents for soft
    soil studied is about 8% as indicated by pH and unconfined
    compressive strength tests.
 • The strength of compacted soil with different fly ash mixtures has
    attained more strength which is determined after curing for different
    periods.
 • The strength improvement for any soil mixture, which is substantial
    with percentage increase of lime, is further improves the strength.
                                                                       12
Contd…
 Pandian et.al. (2002)
 • Studied the effect of two types of fly ashes Raichur fly ash (Class F)
   and Neyveli fly ash (Class C) on Strength characteristics of the
   black cotton soil. The fly ash content was increased from 0 to 100%.
 • The low percentage of BC soil is attributed to the inherent low
   strength, which is due to the dominance of clay fraction. The
   addition of fly ash to BC soil increases the compaction of the mix up
   to the first optimum level due to the frictional resistance from fly
   ash in addition to the cohesion from BC soil.
 • The variation of strength of fly ash black cotton soil mixes can be
   attributed to the relative contribution of frictional or cohesive
   resistance from fly ash or BC soil, respectively.
 • In Neyveli fly ash also there is an increase of strength with the
   increase in the fly ash content, here there will be additional
   pozzolanic reaction forming cementitious compounds resulting in
   good binding between BC soil and fly ash particles.
                                                                       13
Contd…
Dhananjay bhaskar sarode, Sanjay baliram attarde(2009)
• A study was carried out on the leach ability of heavy metals from fly ash,
  bottom ash, dumping site ash, Samples admixture with fly ash in the area of a
  thermal power plant were compared.
• During these studies, extraction and leaching of various heavy metals like Zn,
  Ni, Cu, Fe, Mn and Mg was carried out by applying batch leach test and
  toxicity characteristic leaching procedure (TCLP) to check the possibility of
  ground water contamination.
• The ground water samples in the vicinity of ash dumping sites were analyzed
  for heavy metal concentrations and results obtained were compared WHO
  permissible limits.
• Mg, Mn, and Fe were leached to a larger extent Zn, and Cu to moderate and Ni
  to a smaller extent, from the ash and admixture samples. The concentrations of
  Zn, Fe, Mn, and Mg in groundwater samples were below the permissible limits
  of Indian standards.
• The concentration of Cu was within the permissible limits but slightly higher
  than Indian Standards. The admixture of thermal power plant fly ash in fine
  and coarse seems to be an ecofriendly practice as far as leaching of heavy
  metals in groundwater is concerned.                                       14
MATERIALS AND METHODS
In the present study stabilization of black cotton soil has been carried out
by using the following materials.
• Black cotton soil
• Ground granulated blast slag (Fine and Coarse)
• Fly ash (Fine and Coarse) and lime.
BLACK COTTON SOIL:
• Natural black cotton soil was obtained from Gadag district in
    Karnataka State. The soil was excavated from a depth of 2.0 m from
    the natural ground level.
• The soil is dark grey to black in color with high clay content. The
    obtained soil was air dried and pulverized manually and soil passing
    through 425 µ IS sieved was used in the present study.



                                                                        15
Contd…
  • This soil has a property of high moisture retentively and develops
    cracks in summer. This soil predominantly consists of expansive
    montmorillonite as the principal clay mineral. Physical properties of
    black cotton soil is as shown below.
             Table1 Physical properties of black cotton soil

Natural                     Grain size distribution                    Atterberg’s Limit
           Specific
Water                  Gravel                  Silt and    Liquid     Plastic    Plasticity Shrinkage
           gravity                Sand (%)
content                  (%)                   clay (%)     limit      limit       Index       limit
                                               38.22 and
8.95%        2.68         00           10.06                66%       37.12%      28.88%     11.63%
                                                51.72




    Plate 1 Black cotton soil sample           Plate2 Grain size distribution by hydrometer Analysis
                                                                                                       16
GRAIN SIZE DISTRIBUTION BY HYDROMETER ANALYSIS

                         This test is done according to IS 2720(part 3/ section 1) - 1980
                                Grain size distribution of Black Cotton Soil from Gadag
                   100



                                                                                          % Sand=10.06
                   80
                                                                                          %Silt=38.22
Percentage fines




                                                                                          % Clay=51.72
                   60




                   40




                   20




                     0
                     0.001                0.01                0.1               1                       10

                                                       Particle size, mm
                                                                                                    17
LIQUID LIMIT GRAPH FOR BLACK COTTON SOIL

             80

             70
                                              Flow Curve
             WL
             60

             50
% of Water




             40

             30                                                           % of water

             20

             10

              0
                  0   10   20   N =25   30          40     50   60   70

                                         No of Blows

                                                                                       18
Contd..

  Table 2 Mini compaction and compressive strength of Black cotton soil
                                    optimum moisture content   Compressive Strength in
          Max dry density in g/cc
                                             in %                       Kpa
                   1.48                       21                       112.3




            Plate 3 Compaction test and Compressive strength of Black Cotton Soil


                                                                                         19
COMPACTION RESULTS FOR SOIL ALONE

             Water content   Dry density
   Sl No
                 (%)          Γd g/cc
   Trial1         6             1.22
   Trial2         10            1.29
   Trial3        12.3           1.35
   Trial4        16.1           1.42
   Trial5         18            1.45
   Trial6         20            1.48
   Trial7         26            1.44
   Trial8        37.5           1.28


                                           20
COMPACTION CURVE FOR SOIL ALONE
                      1.6


                      1.5 γ d max
  dry density gm/cc




                      1.4


                      1.3

                                                                                 Series1
                      1.2


                      1.1


                       1                              OMC
                            0       5   10   15      20      25   30   35   40

                                             water content in %


                                                                                           21
GROUND GRANULATED BLAST SLAG (GGBS)
• About10 million tons of blast furnace slag is produced in India annually
  as a byproduct of Iron and Steel Industry.
• Blast furnace slag is composed of silicates and alumino silicates of lime
  and other bases. It is a latent hydraulic product which can be activated
  with anyone- lime, alkalis or Portland cement.
• GGBS procured from Hubli Steel plant has been used in the present
  Fine and coarse GGBS sample is as shown in Plate 5




                    Plate5 Fine and coarse GGBS sample
                                                                         22
Contd….

      Physical and chemical properties are presented in Table 3 and Table4
              Table 3 Physical properties of Ground granulated blast slag
                                         Atterberg’s limit          Mini compaction

                         Specific                                   Maximum dry           Optimum
          Color                     Liquid limit   Plastic limit
                         gravity                                      density in          moisture
                                        (%)            (%)
                                                                           g/cc          content in %

        Off -white        2.81          32         Non plastic             1.38              20


              Table 4 Chemical properties of Ground granulated blast slag
Constituent       SiO2       CaO      AI2O3        MgO             Fe2O3           SO3            L.O.I


Percentage        40%       39.2%     13.5 %       3.6%             1.8           1.7%             0.2


Source UK cementitious slag maker association (CSMA) by Dr. D.D Higgins
Soil stabilization with ground granulated blast furnace slag (GGBS)                                       23
FLY ASH
• Fly ash is a fine residue collected from the burning of pulverized
  coal in thermal power plants. The disposal of the fly ash is a serious
  hazard to the environment that consumes millions of rupees towards
  the cost of its disposal.
• Fly ash has been used in a variety of construction applications, such
  as compacted fills, concretes, bricks, liners, construction of
  embankments in many countries including India.
• In the present study, fly ash of class “F” Category procured from
  Raichur thermal power station (RTPS), in Karnataka, India, called
  Raichur Fly ash (RFA), has been used. The fly ash used was grey in
  color. Fine and coarse fly ash sample is as shown in Plate 6.




                                                                      24
                   Plate 6 Fine and coarse fly ash sample
TYPES OF FLY ASH
Fly ash is categorized into two broad classes
           Class C Fly ash    Class F Fly ash
• Class C Fly ash
 This class of fly ash has a high CaO content and used as a stand-
  alone stabilizing agent.
 The strength characteristics of Class C fly ash having a CaO less
  than 25 percent can be improved by adding lime.
• Class F Fly ash
 This class of fly ash has a low CaO content.
 Class F fly ash has an insufficient CaO content for the pozzolanic
  reaction to occur.
 It is not effective as a stabilizing agent by itself however, when
  mixed with either lime or lime and cement, the fly ash mixture
  becomes an effective agent.
                                                                  25
Contd…
 Physical and chemical properties are presented in Table 5 and Table 6

                   Table 5 Physical properties of Fly ash
  Specific              Grain size distribution                        Atterberg’s limit
  gravity

                                             Silt and         Liquid           Plastic      Shrinkage
                Gravel (%)     Sand (%)
     2.13                                    clay (%)          limit            limit         limit
                   00             58              42           35%           Non plastic     18.50%


                   Table 6 Chemical properties of Fly ash


  Constituent    SiO2 Al2O3      TiO2     Fe2O3    MnO        MgO      CaO       K2O       Na2O   L.O.I


  Percentage     61.1     28      1.3      4.2         0.15   0.8      1.7       0.18      0.18    1.4


  Source:P.V. Sivapullaiah, et al- IISc, Bangalore.
  Enhancement of strength of soft soils with fly ash and lime.
                                                                                                          26
CHEMISTRY OF FLY ASH
• Formation of cementitious material by the reaction of lime with the
  pozzolans (Al2O3, SiO2, Fe2O3)in the presence of water is known as
  hydration of fly ash.




• In the presence of moisture, react with calcium hydroxide at ordinary
  temperature to form compounds possessing cementitious properties
  like calcium silicate hydrates and calcium aluminate hydrates.
                                                                   27
HYDRATED LIME
• This is a type of lime most commonly available in dry powder.
  Often lime is added as a supplement to enhance the properties of
  mixture of soil and fly ash to reduce settlement and increased
  bearing capacity.
• Commercially available pure hydrated lime Ca(OH) 2 was used in
  the study. Hydrated lime, known as slaked lime. Typical hydrated
  lime sample is shown in Plate 6.




                       Plate 6 Hydrated lime sample             28
PREPARATION OF SYNTHETIC SOURCE SOLUTION
 The chemicals used are Copper sulphate, Ferrous Ammonium Sulphate (FAS)
 Crystals, and Nickel Nitrate crystals for determination of copper, iron and nickel.

 • The nickel nitrate [Ni(NO3)26H2O] is used as source of nickel[Ni(II)]. A stock
   solution of 1000mg/l of Ni (II) is prepared by dissolving 4.96g of nickel
   nitrate in 1000ml distilled water. The solution is diluted as required to obtain
   standard solutions containing 100mg/l of Ni (II).
 • The copper sulphate is used as source of copper. A stock solution of 1000mg/l
   is prepared by dissolving 2.51g of copper sulphate in 1000ml distilled water.
   The solution is diluted as required to obtain standard solutions containing
   100mg/l of Cu2+
 • The Ferrous ammonium sulphate is used as source of iron. A stock solution of
   1000mg/l is prepared by dissolving 5.08g of ferrous ammonium sulphate in
   1000ml distilled water. The solution is diluted as required to obtain standard
   solutions containing 100mg/l of iron.


                                                                                29
METHODOLGY
COMPACTION TEST
• Compaction test were carried out by using Mini compaction test apparatus
  accordance with IS 2720 (part7)-1980.Compaction involves an expulsion
  of air without a significant change in the amount of water in the soil mass.
• About 250 grams soil is used for each trial. The soil is mixed with
  consistent quantity of water and is transferred on to the mould of diameter
  3.8 cms and height of 10 cms in three layers, each layer is compacted by 36
  blows.
• The compaction characteristics of soil fly ash mixtures specimens were
  prepared to include optimum water content range for soil fly ash, and soil
  GGBS mixtures The Compaction test were carried out for different
  proportions of fine and coarse combination of fly ash, and soil GGBS
  mixtures.
• For trial mixes the value of Maximum Dry Density and corresponding
  Optimum Moisture content was obtained from Compaction curves.


                                                                           30
Contd…




  Plate 8 Compaction test for different soil mixtures and placing of soil mixtures in desiccators for curing.




                                                                                                          31
UNCONFINED COMPRESSIVE STRENGTH TEST
               IS2720(PART 10)-1973
• The soil samples were prepared by using steel split mould having a diameter
  of 3.8 cm and a height of 7.6 cm was used.
• The weight of the soil to be taken and the volume of water to be added are
  calculated by knowing the volume of mould and Maximum Dry Density and
  Optimum Moisture content of the soil.
• Once the trial mix is prepared, the mould is oiled thoroughly. The mix is
  transferred to the mould compacted and then extracted from the mould.
• Three identical samples were prepared for their Maximum Dry Density and
  Optimum Moisture content based on the compaction curves obtained.
• The sample was subjected to various curing periods (1, 7, 14, 28 days)
  according to their trial combination chosen. Samples intended for long term
  testing were kept in desiccators to maintain 100% humidity and to prevent
  loss of moisture from samples. Water was sprinkled at regular intervals and
  was cured in the desiccators. All the samples intended for immediate testing
  were tested immediately.
                                                                          32
CHARACTERISTIC LEACHING TEST
• After the Unconfined compressive strength test, has been carried out for the
  combination of fine and coarse soil mixtures the representative sample is
  taken for batch leaching test. according to standard test method (ASTM
  4646-87 reapproved 2001).
• A sample with Solid to liquid ratio of 1:10 is maintained. The soil mixture
  is kept in a shaker for 24 hrs. at a speed of 30 rpm. After that mixture is
  allowed to settle for 5 min, and then aqueous solution is filtered through a
  0.45µm pore size membrane filter. The filtrate is analyzed using Atomic
  absorption spectrophotometer. (AAS)




Plate 6 Unconfined compressive strength for soil mixtures and batch leaching tests for different soil mixtures.

                                                                                                        33
Contd…

 • Atomic absorption spectrophotometer (AAS) A203 Version -04 was used to
   measure the nickel concentration. The, fuel used was acetylene (C2H2) and
   the oxidant used was air or Nitrous oxide for strong flames. Calibration of
   the AAS was done according to the equipment manual using certified
   standards and the analysis of calibrated standards was attained to ensure the
   accuracy of results. Rotary flask shaker used for experiment work




Plate7 Rotary flask shaker used and atomic absorption spectrophotometer used for analysis of heavy metal ions.


                                                                                                       34
RESULTS AND DISCUSSIONS
COMPACTION CHARACTERISTICS OF STABILIZED BLACK COTTON
     SOIL WITH DIFFERENT PROPORTIONS OF FINE FLY ASH

The results of stabilized black cotton soil for various percentages of fine fly
ash mixtures along with optimum water content and corresponding dry
density has been presented below.it can be observed that with increase in fly
ash content the OMC increases and the dry density decreases.

                           Optimum Water Content (%)    Max Dry density(g/cc)
     Soil+ Fine fly ash
         95%+5%                      22.5                       1.35
        90%+10%                      23.8                       1.20
        85%+15%                      25.0                       0.90
        80%+20%                      26.0                       0.80
        75%+25%                      28.0                       0.65
        70%+30%                      30.0                       0.60


                                                                                35
Compaction with Soil and fine Fly ash

                                                Black cotton soil + Fine Fly Ash
                           1.4

                                                                                             5%Fly Ash
                           1.2
Max. Dry density in g/cc




                            1
                                                                                             10% Fly Ash

                           0.8                                                               15%Fly Ash

                           0.6                                                               20% Fly Ash

                           0.4
                                                                                             25%Fly Ash

                           0.2
                                                                                             30%Fly Ash
                            0
                                 0     5   10   15       20       25       30      35   40

                                                Water content in %



                                                                                                           36
COMPACTION CHARACTERISTICS OF STABILIZED
BLACK COTTON SOIL WITH DIFFERENT PROPORTIONS
             OF COARSE FLY ASH
The results of stabilized black cotton soil for various percentages of fine fly
ash mixtures along with optimum water content and corresponding dry
density has been presented below. it can be observed that with increase in fly
ash content the OMC increases and the dry density decreases.


     Soil+ Fly ash(Coarse)   Optimum Water Content (%)    Max Dry density (g/cc)

           95%+5%                      10.5                       1.35

          90%+10%                      14.5                       1.30

          85%+15%                      16.0                       1.22

          80%+20%                      18.5                       1.19

          75%+25%                      20.0                       1.10

          70%+30%                      21.0                       1.00



                                                                                   37
Compaction with Soil and coarse Fly ash

                                              Black cotton Soil+ Coarse Fly ash

                           1.6
                                                                                  5% Coarse Fly ash
                           1.4
Max. Dry density in g/cc




                           1.2                                                    10%Coarse Fly ash
                            1
                                                                                  15%Coarse Fly ash
                           0.8
                                                                                  20%Coarse Fly ash
                           0.6

                           0.4                                                    25%Coarse Fly ash

                           0.2                                                    30%Coarse Fly ash
                            0
                                 0   5   10        15       20       25      30   35

                                              Water content in %



                                                                                                      38
COMPACTION CHARACTERISTICS OF STABILIZED
 BLACK COTTON SOIL WITH DIFFERENT PROPORTIONS
                 OF FINE GGBS

The results of stabilized black cotton soil for various percentages of fine fly
ash mixtures along with optimum water content and corresponding dry density
has been presented below. it can be observed that with increase in GGBS
content the OMC decreases and the dry density increases.

     Soil+ Fine GGBS         Optimum Water Content (%)     Max Dry density(g/cc)

        95%+5%                         18.5                        1.42

        90%+10%                        18.0                        1.45

        85%+15%                        17.5                        1.55

        80%+20%                        17.0                        1.65

        75%+25%                        16.5                        1.68

        70%+30%                        16.0                        1.72

                                                                                   39
Compaction with Soil and Fine GGBS

                                                 Black cotton Soil+ Fine GGBS

                            2                                                             5% Fine ggbs

                                                                                          10%Fine ggbs
Max. Dry density in g/cc




                           1.6
                                                                                          15%Fine ggbs
                           1.2                                                            20%Fine ggbs

                                                                                          25%Fineggbs
                           0.8
                                                                                          30%Fine ggbs
                           0.4



                            0
                                 0      5   10          15       20        25   30   35


                                                 Water Content in %



                                                                                                         40
COMPACTION CHARACTERISTICS OF STABILIZED BLACK
COTTON SOIL WITH DIFFERENT PROPORTIONS OF COARSE
                       GGBS


The results of stabilized black cotton soil for various percentages of fine fly ash
mixtures along with optimum water content and corresponding dry density has
been presented below. it can be observed that with increase in GGBS content
the     OMC         decreases      and      the      dry     density     increases.

     Soil+ Coarse GGBS        Optimum Water Content (%)      Max Dry density (g/cc)

         95%+5%                         18.0                         1.30

         90%+10%                        17.5                         1.38

         85%+15%                        17.0                         1.42

         80%+20%                        16.5                         1.45

         75%+25%                        16.0                         1.50

         70%+30%                        15.0                         1.55


                                                                                      41
Compaction with Soil and Coarse GGBS

                                                Black cotton Soil+ Coarse GGBS

                           1.8
                                                                                      5%coarse ggbs
                           1.6
                                                                                      10%Coarse ggbs
Max. Dry density in g/cc




                           1.4

                           1.2
                                                                                      15%Coarse ggbs
                            1

                           0.8                                                        20%Coarse ggbs

                           0.6
                                                                                      25%Coarse ggbs
                           0.4

                           0.2                                                        30%Coarse ggbs
                            0
                                 0   5   10       15      20       25    30      35

                                              Water Content in %



                                                                                                       42
CHARACTERISTIC UNCONFINED COMPRESSIVE
STRENGTH OF SOIL FLY ASH MIXTURES

The results of unconfined compressive strength of soil fly ash mixtures for
varying percentage of fine and coarse fly ash mixtures have been presented in
the table below.it can be observed that with increase in percentage of fine and
coarse fly ash the UCC strength increases for both the mixtures, however the
increase    is    more     pronounced     with    fine    fly    ash    content

        Sl No             Parameter        UCC in Kpa (fine)   UCC in Kpa(Coarse)
         1.            95%+ 5% Fly Ash         140.704               152.61
         2.            90%+ 10% Fly Ash        249.727              158.336
         3.            85%+ 15% Fly Ash        320.217              164.057
         4.            80%+ 20% Fly Ash        330.098              168.964
         5.            75%+ 25% Fly Ash         209.62              147.871
         6.            70%+ 30% Fly Ash         89.143              118.302
         7.            65%+ 35% Fly Ash         78.238              101.285
                                                                                    43
Effect of fly ash content on the strength of soil

                                         characteristic strength of Fly ash
                      400


                      350


                      300
UCC strength in kpa




                      250


                      200
                                                                               fine fly ash   coarse fly ash
                      150


                      100


                      50


                       0
                            0   5   10   15        20        25        30     35        40

                                         % varying of Fly ash


                                                                                                          44
CHARACTERISTIC UNCONFINED COMPRESSIVE
          STRENGTH OF SOIL GGBS MIXTURES
The results of unconfined compressive strength of soil GGBS mixtures for
varying percentage of fine and coarse GGBS mixtures have been presented in
the table below. it can be observed that with increase in percentage of fine and
coarse GGBS the UCC strength increases for both the mixtures, however the
increase     is    more     pronounced      with     fine    GGBS       content.

       SLNo               Parameter        UCC in Kpa (fine)   UCC in Kpa (Coarse)
         1.             95%+ 5% GGBS            255.073              55.797
         2.            90%+ 10% GGBS            265.742              88.135
         3.            85%+ 15% GGBS            316.451             120.473
         4.            80%+ 20% GGBS            325.587             122.453
         5.            75%+ 25% GGBS            216.856             124.434
         6.            70%+ 30% GGBS            108.125              98.668
         7.            65%+ 35% GGBS            68.265               72.902




                                                                                 45
Effect of GGBS content on the strength of soil

                                    Characteristic strength of GGBS
                      350



                      300
UCC strength in kpa




                      250



                      200                                                            fine GGBS   coarse GGBS

                      150



                      100



                      50
                            0   5     10       15       20       25      30     35       40

                                    % varying of Ground Granulated Blast Slag


                                                                                                         46
CHARACTERISTIC COMPRESSIVE STRENGTH
  OF BOTH FLY ASH AND GGBS MIXTURES
The results of unconfined compressive strength of soil fly ash mixtures for
varying percentage of fine and coarse combination mixtures have been
presented in the table below. it can be observed that with increase in
percentage of fine and coarse combination of mixtures the UCC strength
increases for both the mixtures, however the increase is more pronounced with
fine mixture content.

Combination of soil, Fly Ash and 5% Ground granulated slag (Fine and Coarse)

      Sl no              Parameter        UCC in Kpa (fine)   UCC in Kpa (Coarse)

        1.            Soil+ 0% Fly Ash        255.073               55.797

        2.            Soil+ 5% Fly Ash        265.682              173.481

        3.           Soil+ 10% Fly Ash        272.292              180.845

        4.           Soil+ 15% Fly Ash        300.101              190.488

        5.           Soil+ 20% Fly Ash        329.910               103.25

        6.           Soil+ 25% Fly Ash         300.25                44.25

                                                                                    47
Effect of fine and coarse mixtures on the strength of soil

                                      Comparison of fine and coarse Combination

                        350


                        300                                                            Fine Combination
  UCC Strength in Kpa




                        250


                        200                                                            Coarse Combination

                        150


                        100


                        50


                          0
                              0   5    10          15           20   25           30

                                            % varying fly ash


                                                                                                            48
CHARACTERISTIC COMPRESSIVE STRENGTH
  OF BOTH FLY ASH AND GGBS MIXTURES
 The results of unconfined compressive strength of soil GGBS mixtures for
 varying percentage of fine and coarse combination mixtures have been
 presented in the table below. it can be observed that with increase in percentage
 of fine and coarse combination of mixtures the UCC strength increases for both
 the mixtures, however the increase is more pronounced with fine mixture
 content.
Combination of soil, 5%Fly Ash and Ground granulated slag (Fine and Coarse)
     Sl no               Parameter          UCC in Kpa (fine)    UCC in Kpa (Coarse)

      1.               Soil+0% GGBS             140.704                152.61

      2.               Soil+ 5% GGBS            265.682               173.481

      3.              Soil+ 10% GGBS            165.065               136.818

      4.              Soil+ 15% GGBS            141.665               127.331

      5.              Soil+ 20% GGBS            119.266               117.845

      6.              Soil+ 25% GGBS             98.625                 90.25

                                                                                       49
Effect of fine and coarse mixtures on the strength of soil

                                       Comparison of fine and coarse combination


                        300

                                                                                        Fine combination
                        250
  UCC Strength in Kpa




                        200

                                                                                        Coarse combination
                        150


                        100


                        50


                         0
                              0   5        10        15        20        25        30

                                      % Varying ground granulated slag




                                                                                                             50
VARIATION OF STRENGTH OF BLACK COTTON
       SOIL WITH ADDITION OF LIME
The results of variation of strength of stabilized black cotton soil for
different percentage of lime has been presented in the table below.
From the table it can be observed the characteristic compressive
strength of black cotton soil increases with increase in lime content
and also with different curing period.

 Soil, lime in%                  Compressive strength in Kpa

                  1 day curing   7 day curing   14day curing   28 day curing

       2            55.228         60.215         108.188        162.161

       4            68.495         72.625         166.373        248.128

       6            170.708        258.589        350.234        480.453

       8            228.924        312.368        286.581         546.43

       10           186.285        496.325        225.865        404.594
                                                                               51
Variation of unconfined compressive strength with lime
       for different periods of curing soil sample.
                                      Variation of UCC with lime on Curing




                        600


                        500                                                        1day curing
  UCC Strength in Kpa




                        400
                                                                                   7day curing
                        300


                                                                                   14day curing
                        200


                        100
                                                                                   28day curing

                         0
                              0   2     4           6            8       10   12

                                            Lime in percentage


                                                                                                  52
LEACHING OF HEAVY METAL IONS FROM
      STABILIZED SOIL MIXTURES
The leaching behavior of stabilized soil mixtures for heavy metal
ions has been studied for 5% of admixtures used and remaining 95%
of black cotton soil the results of leaching concentration of above
mixtures has been presented in the table below.
  For 5% Soil                    Leaching Concentration in mg/l
  mixtures

    Heavy metal Ions    Nickel               Copper               Iron

      Fine fly ash       1.0                  0.98                1.0

     Coarse fly ash      2.25                 5.8                 0.89

       Fine ggbs         0.95                 0.55                2.85

      Coarse ggbs        2.5                  0.82                0.98

    Fine combination     1.98                 2.2                 2.5

   Coarse combination    2.2                  2.65                2.8
                                                                         53
95% soil+5% admixtures

                                              5% Soil mixture

                        6
                                                                       Fine fly ash

                        5
                                                                       Coarse fly ash
Concentration in mg/l




                        4
                                                                       Fine ggbs
                        3

                                                                       Coarse ggbs
                        2


                        1                                              Fine combination

                        0                                              Coarse combination
                            nickel       copper                 iron




                                                                                            54
Contd…

  The leaching behavior of stabilized soil mixtures for heavy metal
  ions has been studied for 10% of admixtures used and remaining
  90% of black cotton soil the results of leaching concentration of
  above mixtures has been presented in the table below.

   For 10% Soil                   Leaching Concentration in mg/l
   mixtures


     Heavy metal Ions    Nickel              Copper                Iron

         Fine fly ash     1.3                 1.08                 1.1

      Coarse fly ash      2.39                6.48                 2.65

          Fine ggbs       1.1                 0.88                 5.24

       Coarse ggbs        2.39                0.87                 1.06

     Fine combination     2.42                2.93                 3.98

    Coarse combination    2.34                3.65                 3.45

                                                                          55
90% soil+10% admixtures

                                             10% Soil mixture



                                                                       Fine fly ash
                        6


                        5                                              Coarse fly ash
Concentration in mg/l




                        4                                              Fine ggbs

                        3
                                                                       Coarse ggbs
                        2
                                                                       Fine combination
                        1

                                                                       Coarse combination
                        0

                            nickel        copper                iron




                                                                                            56
Contd…

 The leaching behavior of stabilized soil mixtures for heavy metal
 ions has been studied for 15% of admixtures used and remaining
 85% of black cotton soil the results of leaching concentration of
 above mixtures has been presented in the table below.


    For 15% Soil                 Leaching Concentration in mg/l
      mixtures

    Heavy metal Ions    Nickel               Copper               Iron

      Fine fly ash       1.3                  1.2                 1.1

     Coarse fly ash      2.45                 6.54                3.2

       Fine ggbs         1.2                  0.95                5.25

      Coarse ggbs        2.5                  1.0                 1.22

    Fine combination     2.62                 3.2                 4.2

   Coarse combination    2.4                  4.2                 3.55

                                                                         57
85% soil+15% admixtures
                                              15% Soil mixture
                        6
                                                                        Fine fly ash
                        5
                                                                        Coarse fly ash
Concentration in mg/l




                        4
                                                                        Fine ggbs

                        3
                                                                        Coarse ggbs

                        2
                                                                        Fine combination

                        1
                                                                        Coarse combination

                        0
                            nickel          copper               iron


                                                                                             58
Contd…
   The leaching behavior of stabilized soil mixtures for heavy metal
   ions has been studied for 20% of admixtures used and remaining
   80% of black cotton soil the results of leaching concentration of
   above mixtures has been presented in the table below.



    For 20% Soil                 Leaching Concentration in mg/l
      mixtures
    Heavy metal Ions    Nickel               Copper               Iron
                         1.4                  1.25                1.2
      Fine fly ash
                         2.45                 6.64                3.1
     Coarse fly ash
                         1.28                 1.2                 6.24
       Fine ggbs
                         2.58                 1.8                 1.02
      Coarse ggbs
                         2.95                 3.5                 4.25
    Fine combination
                         2.42                 4.5                 3.95
   Coarse combination
                                                                         59
80% soil+20% admixtures
                        8
                                             20% Soil mixture
                                                                       Fine fly ash
                        7



                        6                                              Coarse fly ash
Concentration in mg/l




                        5
                                                                       Fine ggbs

                        4
                                                                       Coarse ggbs

                        3

                                                                       Fine combination
                        2


                                                                       Coarse
                        1
                                                                       combination

                        0

                            nickel         copper               iron
                                                                                        60
CONCLUSIONS
I.     VARIATION OF MAXIMUM DRY DENSITY AND OPTIMUM
       MOISTURE CONTENT FOR FINE AND COARSE FLY ASH MIXTURE
•    It was observed that with the increase in water content the dry density decreases
     up to 20-30% moisture content and with further increase in water content the
     dry density decreases gradually.
•    The maximum dry density was observed to be about 1.35 g/cc for 95% soil and
     5% fly ash mixture and lowest density was about 0.6g/cc for 70% soil and 30%
     fly ash mixture.
II     VARIATION OF MAXIMUM DRY DENSITY AND OPTIMUM
       MOISTURE CONTENT FOR FINE AND COARSE GGBS MIXTURE
•     It was found that with the increase in water content the dry density also
     increases up to 20-30% moisture content and with further increase in water
     content the dry density increases gradually.
•     The lowest dry density was observed to be about 1.42g/cc for 95% soil and 5%
     GGBS mixture and maximum density was about 1.72 g/cc for 70% soil and
     30% GGBS mixture.
                                                                                 61
Contd..
III VARIATION OF UNCONFINED COMPRESSIVE STRENGTH FOR FINE
    AND COARSE FLY ASH MIXTURES
• It was found that percentage variation of strength was maximum for 20-30%
    of fine and coarse combination of fly ash content.
• It was found that percentage variation of strength was maximum for 15-20%
    of fine and coarse combination of GGBS mixture
• It was found that 8% of lime was optimum for stabilization of soil and
    mixture at the end of 28 days of curing period and the corresponding
    maximum strength attained was 500 Kpa.
IV LEACHING BEHAVIOR OF HEAVY METAL IONS FROM STABILIZED
    SOIL MIXTURES (5 TO 20% OF FLY ASH AND GGBS MIXTURES)
• It was observed that Ni ion concentration was relatively low in the extracted
    solution when compared to copper and iron from the stabilized soil mixtures
    for all the combinations.
• The analysis of heavy metal ions reveals that the concentration of all the
    heavy metal ions were invariably well below the permissible limits except
    for copper and iron as per BIS.
                                                                           62
SCOPE FOR FUTURE WORK
• The amount of fly ash and GGBS mixtures to be mixed for
  stabilization of soil may depend on the constituents of soil besides
  the environmental conditions. Hence the effect of the mixtures on
  different types of soil having different characteristics might be
  studied as future research works.
• Scanning electron microscope/ X-ray diffraction studies should be
  carried out primarily to identify the mineral phases for different
  combinations of soil mixtures.
• Further studies are required so as to ascertain the properties of
  absorption behavior for all soil mixtures of heavy metals like
  lead, cadmium, mercury, zinc, magnesium, etc.
• Adsorption processes and its effects on their properties for different
  combination of soil mixtures need to be studied for different heavy
  metals considered.

                                                                      63
REFERENCES
• KanirajS R, Havanagi V.G Geo technical characteristics of fly- ash soil
  mixtures. Geo technical Engineering journal, 1999, 30 (2):129-147
• Bardet, J P and Young, J (1997) Grain size analysis by Buoyancy
  method, Geotechnical testing Journal, Vol20, No-4, 1997, pg 481-485
• Sivapullaiah P.V Prashanth J. P Reactive silica and strength of fly
  ash, Geotechnical and Geological Engineering Vol.16, 1998, pp239-
  250
• D.D. Higgins, J.M. Kinuthia and S. Wild “Soil Stabilization using
  Lime-Activated Ground Granulated Blast Furnace Slag” volume
  178, pp.1057-1074June 1, 1998
• Joan E Mclean., Bert E,. Behavior of metals in soils, report no 540 S-
  92-018, Environmental protection agency, USA,1992.


                                                                      64
Contd…

• Arif Ali Baig, Sivapullaiah.P.V, Heavy metal leachability of low
  lime fly ashes, in Indian Geotechnical Conference-2008, Advances
  in geotechnical Engineering Vol II, 2008, PP470-473.
• Joris.J.Dijkstra, R.N.J Comans, W.HW Van Riemsdijk, Development
  of a consistent geochemical modeling approach for leaching and
  reactive transport processes in contaminated materials,. Wageningen
  University, Netherlands, 2007.
• Zhou,C.,Yin, J. H. and Ming,J.P. (2002) Bearing capacity and
  settlement of weak fly ash Ground improved using Lime Fly ash
  Canadian Geotechnical Journal, 39: 585-596.
• ASTM, Standard test method for 24-h batch –type measurement of
  Contaminant by soils and sediments, International American
  Standard testing method D4646-87(reapproved 2001., USA,2001.


                                                                   65
THANK YOU



            66

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A study on characterization of compressive strength. seminar pptx

  • 1. “A STUDY ON CHARACTERIZATION OF COMPRESSIVE STRENGTH AND LEACHING BEHAVIOR OF STABILIZED SOILS USING FLY ASH AND GROUND GRANULATED BLAST FURNACE SLAG” Visvesvaraya Technological University, Belgaum Naveen Kumar.S 1BM10CEE07 Under the Guidance of Dr. MAYA NAIK Professor, Dept. of Civil Engineering, BMS College of Engineering, Bangalore -560019. 1
  • 2. CONTENTS  Introduction  Objective  Literature review  Materials and Methods  Results and Discussions  Conclusions  Scope for future work  References 2
  • 3. INTRODUCTION • Soil stabilization is the permanent physical and chemical alteration of soils to enhance their physical properties. • Stabilization increases the shear strength and controls the shrink- swell properties of a soil, and it increase the load-bearing capacity of a sub-grade to support pavements and foundations. • Stabilization can be achieved with a variety of chemical additives including lime, cement, fly ash and GGBS mixtures as well as by- products of industrial wastes. • Stabilization of expansive soils with admixtures controls the potential of soils for a change in volume behavior. • Proper design and testing is an important component of any stabilization project. • Fly ash and GGBS mixtures have been utilized in bulk in Geotechnical Engineering applications such as construction of Embankments, as a Backfill material, etc 3
  • 4. GRADATION OF SOIL, COMPACTION OF SOIL FLY ASH MIXTURES • Soil gradation is an important aspect of soil mechanics and Geotechnical engineering. • Soil gradation is a classification of a coarse-grained soils based on the different particle sizes. • The compaction of soil with fly ash, GGBS and lime is an important parameter since it controls the Strength, Compressibility and Permeability behavior of stabilized mixture. • The compacted unit weight of the material depends on the amount and method of energy application, grain size distribution, plasticity characteristics and moisture content. • In the present work gradation of fly ash and GGBS mixtures has been carried out in order to bring the effect of gradation on stabilization of black cotton soil. 4
  • 5. PRINCIPLES AND NEED FOR SOIL STABILIZATION • Selecting Effective and economical method of soil stabilization and designing the stabilized soil mix for intended stability and durability values. • An attempt has been made for utilization of locally available soils and other suitable stabilizing agents and encourage the use of industrial fly ash and other wastes in construction activities. TYPES OF SOIL STABILIZATION • Mechanical stabilization • Soil-lime stabilization • Soil-Fly ash stabilization • Soil-cement stabilization • Soil-bitumen stabilization 5
  • 6. MECHANICAL STABILIZATION • The basic principles of mechanical stabilization are mechanical strength of coarse mixtures, gradation, properties of the soil, ease of compaction. • This method is suitable for low volume i.e. Village roads in low rainfall areas. • This method involves the correct proportioning of coarse mixtures and soil, adequately compacted to get mechanically stable layer. SOIL-LIME STABILIZATION • Soil lime imparts some binding action even in granular soils and increase in lime content causes slight change in liquid limit and considerable increase in plasticity index. • The strength of soil-lime increases with curing period up to certain time. The rate of increase is rapid during initial period. The humidity of the surroundings also affects the strength. • Soil- Lime Stabilization has been widely used as a modifier or a binder 6
  • 7. SOIL-FLY ASH STABILIZATION • Soil- fly ash Stabilization reduces its plasticity index, and swell potential owing to a cat ion exchange process that results in an agglomeration of the fine clay particles into coarse particles. • The stable exchangeable cat ions provided by fly ash, such as Ca2+, Al3+, and Fe3+ promote flocculation of the clay particles. • Formation of cemented compounds characterized by their high shear strength and low volume change. In addition to fly ash stabilization, lime is widely used to reduce swell and increase shear strength of expansive soils. • The improvement is due to the following two basic reactions, short- term reaction including cation exchange and flocculation and long- term reaction including pozzolanic reaction. 7
  • 8. SOIL- CEMENT STABILIZATION • Cement stabilization is generally the best type of admixture to be used with soil. It is also commonly available but it is often expensive. • Mixing cement with expansive soils reduces swell potential. • Generally, the amount of cement required to stabilize expansive soils ranges from 2 to 6% by weight. • When the pore water in soil encounters the cement, hydration of the cement occurs rapidly and the major hydration products are hydrated calcium silicates, hydrated calcium aluminates, and hydrated lime. • The hydration of cement leads to a rise in pH value of the pore water, which is caused by the dissociation of the hydrated lime. 8
  • 9. OBJECTIVES OF THE PRESENT STUDY In the light of extensive literature survey carried out for the stabilization of soil fly ash and GGBS mixtures, the following are the major objectives of the present study.  To determine the compaction and unconfined compressive strength of stabilized black cotton soil using fine and coarse fly ash mixtures.  To determine the compaction and unconfined compressive strength of stabilized black cotton soil using fine and coarse GGBS mixtures.  To determine the optimum lime content required for stabilizing black cotton soil by performing unconfined compressive strength test.  To study the leaching behavior of heavy metal ions from stabilized black cotton soil for various types of admixtures used. 9
  • 10. LITERATURE REVIEW Chen 1975; Liao 1984; Locat et al.1990 • The relationship between the plasticity index and swell-shrinkage properties for pre-treated and post-treated soils was brought out. • The test results show that the plasticity index, activity, free swell, swell potential, swelling pressure, and axial shrinkage percent decreased with an increase in fly ash or fly ash-lime content. • With the increase of the curing time for the treated soil, the swell potential and swelling pressure decreased. • Soils immediately treated with fly ash shows a consecutive change in the unconfined compressive strength. • However, after 7 days curing of the fly ash treated soils, the unconfined compressive strength increased significantly. 10
  • 11. Contd… Phanikumar and Sharma (2004) • A study was carried out on the effect of fly ash on engineering properties of expansive soil and the effect on parameters like free swell index (FSI), swell potential, swelling pressure, plasticity, compaction, unconfined compressive strength and hydraulic conductivity of expansive soil was studied. • The ash blended expansive soil with fly ash contents of 0, 5, 10, 15 and 20% on a dry weight basis and they inferred that increase in fly ash content reduces plasticity characteristics and the free swell index (FSI) was reduced by about 50% by the addition of 20% fly ash. • The hydraulic conductivity of expansive soils mixed with fly ash decreases with an increase in fly ash content, due to the increase in maximum dry unit weight with an increase in fly ash content. • When the fly ash content increases there is a decrease in the optimum moisture content and the maximum dry unit weight increases. 11
  • 12. Contd… P.V. Sivapullaiah (2000) • Fly ashes with high pozzolanic reactivity are widely used but those with less pozzolanic reactivity are greatly inhibited. • As the strength development in natural expansive soil considered in this investigation is very less with different percentages of fine fly ash, an attempt is made to increase the same by addition of lime along with fly ash. • Based on several tests conducted, the optimum lime contents for soft soil studied is about 8% as indicated by pH and unconfined compressive strength tests. • The strength of compacted soil with different fly ash mixtures has attained more strength which is determined after curing for different periods. • The strength improvement for any soil mixture, which is substantial with percentage increase of lime, is further improves the strength. 12
  • 13. Contd… Pandian et.al. (2002) • Studied the effect of two types of fly ashes Raichur fly ash (Class F) and Neyveli fly ash (Class C) on Strength characteristics of the black cotton soil. The fly ash content was increased from 0 to 100%. • The low percentage of BC soil is attributed to the inherent low strength, which is due to the dominance of clay fraction. The addition of fly ash to BC soil increases the compaction of the mix up to the first optimum level due to the frictional resistance from fly ash in addition to the cohesion from BC soil. • The variation of strength of fly ash black cotton soil mixes can be attributed to the relative contribution of frictional or cohesive resistance from fly ash or BC soil, respectively. • In Neyveli fly ash also there is an increase of strength with the increase in the fly ash content, here there will be additional pozzolanic reaction forming cementitious compounds resulting in good binding between BC soil and fly ash particles. 13
  • 14. Contd… Dhananjay bhaskar sarode, Sanjay baliram attarde(2009) • A study was carried out on the leach ability of heavy metals from fly ash, bottom ash, dumping site ash, Samples admixture with fly ash in the area of a thermal power plant were compared. • During these studies, extraction and leaching of various heavy metals like Zn, Ni, Cu, Fe, Mn and Mg was carried out by applying batch leach test and toxicity characteristic leaching procedure (TCLP) to check the possibility of ground water contamination. • The ground water samples in the vicinity of ash dumping sites were analyzed for heavy metal concentrations and results obtained were compared WHO permissible limits. • Mg, Mn, and Fe were leached to a larger extent Zn, and Cu to moderate and Ni to a smaller extent, from the ash and admixture samples. The concentrations of Zn, Fe, Mn, and Mg in groundwater samples were below the permissible limits of Indian standards. • The concentration of Cu was within the permissible limits but slightly higher than Indian Standards. The admixture of thermal power plant fly ash in fine and coarse seems to be an ecofriendly practice as far as leaching of heavy metals in groundwater is concerned. 14
  • 15. MATERIALS AND METHODS In the present study stabilization of black cotton soil has been carried out by using the following materials. • Black cotton soil • Ground granulated blast slag (Fine and Coarse) • Fly ash (Fine and Coarse) and lime. BLACK COTTON SOIL: • Natural black cotton soil was obtained from Gadag district in Karnataka State. The soil was excavated from a depth of 2.0 m from the natural ground level. • The soil is dark grey to black in color with high clay content. The obtained soil was air dried and pulverized manually and soil passing through 425 µ IS sieved was used in the present study. 15
  • 16. Contd… • This soil has a property of high moisture retentively and develops cracks in summer. This soil predominantly consists of expansive montmorillonite as the principal clay mineral. Physical properties of black cotton soil is as shown below. Table1 Physical properties of black cotton soil Natural Grain size distribution Atterberg’s Limit Specific Water Gravel Silt and Liquid Plastic Plasticity Shrinkage gravity Sand (%) content (%) clay (%) limit limit Index limit 38.22 and 8.95% 2.68 00 10.06 66% 37.12% 28.88% 11.63% 51.72 Plate 1 Black cotton soil sample Plate2 Grain size distribution by hydrometer Analysis 16
  • 17. GRAIN SIZE DISTRIBUTION BY HYDROMETER ANALYSIS This test is done according to IS 2720(part 3/ section 1) - 1980 Grain size distribution of Black Cotton Soil from Gadag 100 % Sand=10.06 80 %Silt=38.22 Percentage fines % Clay=51.72 60 40 20 0 0.001 0.01 0.1 1 10 Particle size, mm 17
  • 18. LIQUID LIMIT GRAPH FOR BLACK COTTON SOIL 80 70 Flow Curve WL 60 50 % of Water 40 30 % of water 20 10 0 0 10 20 N =25 30 40 50 60 70 No of Blows 18
  • 19. Contd.. Table 2 Mini compaction and compressive strength of Black cotton soil optimum moisture content Compressive Strength in Max dry density in g/cc in % Kpa 1.48 21 112.3 Plate 3 Compaction test and Compressive strength of Black Cotton Soil 19
  • 20. COMPACTION RESULTS FOR SOIL ALONE Water content Dry density Sl No (%) Γd g/cc Trial1 6 1.22 Trial2 10 1.29 Trial3 12.3 1.35 Trial4 16.1 1.42 Trial5 18 1.45 Trial6 20 1.48 Trial7 26 1.44 Trial8 37.5 1.28 20
  • 21. COMPACTION CURVE FOR SOIL ALONE 1.6 1.5 γ d max dry density gm/cc 1.4 1.3 Series1 1.2 1.1 1 OMC 0 5 10 15 20 25 30 35 40 water content in % 21
  • 22. GROUND GRANULATED BLAST SLAG (GGBS) • About10 million tons of blast furnace slag is produced in India annually as a byproduct of Iron and Steel Industry. • Blast furnace slag is composed of silicates and alumino silicates of lime and other bases. It is a latent hydraulic product which can be activated with anyone- lime, alkalis or Portland cement. • GGBS procured from Hubli Steel plant has been used in the present Fine and coarse GGBS sample is as shown in Plate 5 Plate5 Fine and coarse GGBS sample 22
  • 23. Contd…. Physical and chemical properties are presented in Table 3 and Table4 Table 3 Physical properties of Ground granulated blast slag Atterberg’s limit Mini compaction Specific Maximum dry Optimum Color Liquid limit Plastic limit gravity density in moisture (%) (%) g/cc content in % Off -white 2.81 32 Non plastic 1.38 20 Table 4 Chemical properties of Ground granulated blast slag Constituent SiO2 CaO AI2O3 MgO Fe2O3 SO3 L.O.I Percentage 40% 39.2% 13.5 % 3.6% 1.8 1.7% 0.2 Source UK cementitious slag maker association (CSMA) by Dr. D.D Higgins Soil stabilization with ground granulated blast furnace slag (GGBS) 23
  • 24. FLY ASH • Fly ash is a fine residue collected from the burning of pulverized coal in thermal power plants. The disposal of the fly ash is a serious hazard to the environment that consumes millions of rupees towards the cost of its disposal. • Fly ash has been used in a variety of construction applications, such as compacted fills, concretes, bricks, liners, construction of embankments in many countries including India. • In the present study, fly ash of class “F” Category procured from Raichur thermal power station (RTPS), in Karnataka, India, called Raichur Fly ash (RFA), has been used. The fly ash used was grey in color. Fine and coarse fly ash sample is as shown in Plate 6. 24 Plate 6 Fine and coarse fly ash sample
  • 25. TYPES OF FLY ASH Fly ash is categorized into two broad classes Class C Fly ash Class F Fly ash • Class C Fly ash  This class of fly ash has a high CaO content and used as a stand- alone stabilizing agent.  The strength characteristics of Class C fly ash having a CaO less than 25 percent can be improved by adding lime. • Class F Fly ash  This class of fly ash has a low CaO content.  Class F fly ash has an insufficient CaO content for the pozzolanic reaction to occur.  It is not effective as a stabilizing agent by itself however, when mixed with either lime or lime and cement, the fly ash mixture becomes an effective agent. 25
  • 26. Contd… Physical and chemical properties are presented in Table 5 and Table 6 Table 5 Physical properties of Fly ash Specific Grain size distribution Atterberg’s limit gravity Silt and Liquid Plastic Shrinkage Gravel (%) Sand (%) 2.13 clay (%) limit limit limit 00 58 42 35% Non plastic 18.50% Table 6 Chemical properties of Fly ash Constituent SiO2 Al2O3 TiO2 Fe2O3 MnO MgO CaO K2O Na2O L.O.I Percentage 61.1 28 1.3 4.2 0.15 0.8 1.7 0.18 0.18 1.4 Source:P.V. Sivapullaiah, et al- IISc, Bangalore. Enhancement of strength of soft soils with fly ash and lime. 26
  • 27. CHEMISTRY OF FLY ASH • Formation of cementitious material by the reaction of lime with the pozzolans (Al2O3, SiO2, Fe2O3)in the presence of water is known as hydration of fly ash. • In the presence of moisture, react with calcium hydroxide at ordinary temperature to form compounds possessing cementitious properties like calcium silicate hydrates and calcium aluminate hydrates. 27
  • 28. HYDRATED LIME • This is a type of lime most commonly available in dry powder. Often lime is added as a supplement to enhance the properties of mixture of soil and fly ash to reduce settlement and increased bearing capacity. • Commercially available pure hydrated lime Ca(OH) 2 was used in the study. Hydrated lime, known as slaked lime. Typical hydrated lime sample is shown in Plate 6. Plate 6 Hydrated lime sample 28
  • 29. PREPARATION OF SYNTHETIC SOURCE SOLUTION The chemicals used are Copper sulphate, Ferrous Ammonium Sulphate (FAS) Crystals, and Nickel Nitrate crystals for determination of copper, iron and nickel. • The nickel nitrate [Ni(NO3)26H2O] is used as source of nickel[Ni(II)]. A stock solution of 1000mg/l of Ni (II) is prepared by dissolving 4.96g of nickel nitrate in 1000ml distilled water. The solution is diluted as required to obtain standard solutions containing 100mg/l of Ni (II). • The copper sulphate is used as source of copper. A stock solution of 1000mg/l is prepared by dissolving 2.51g of copper sulphate in 1000ml distilled water. The solution is diluted as required to obtain standard solutions containing 100mg/l of Cu2+ • The Ferrous ammonium sulphate is used as source of iron. A stock solution of 1000mg/l is prepared by dissolving 5.08g of ferrous ammonium sulphate in 1000ml distilled water. The solution is diluted as required to obtain standard solutions containing 100mg/l of iron. 29
  • 30. METHODOLGY COMPACTION TEST • Compaction test were carried out by using Mini compaction test apparatus accordance with IS 2720 (part7)-1980.Compaction involves an expulsion of air without a significant change in the amount of water in the soil mass. • About 250 grams soil is used for each trial. The soil is mixed with consistent quantity of water and is transferred on to the mould of diameter 3.8 cms and height of 10 cms in three layers, each layer is compacted by 36 blows. • The compaction characteristics of soil fly ash mixtures specimens were prepared to include optimum water content range for soil fly ash, and soil GGBS mixtures The Compaction test were carried out for different proportions of fine and coarse combination of fly ash, and soil GGBS mixtures. • For trial mixes the value of Maximum Dry Density and corresponding Optimum Moisture content was obtained from Compaction curves. 30
  • 31. Contd… Plate 8 Compaction test for different soil mixtures and placing of soil mixtures in desiccators for curing. 31
  • 32. UNCONFINED COMPRESSIVE STRENGTH TEST IS2720(PART 10)-1973 • The soil samples were prepared by using steel split mould having a diameter of 3.8 cm and a height of 7.6 cm was used. • The weight of the soil to be taken and the volume of water to be added are calculated by knowing the volume of mould and Maximum Dry Density and Optimum Moisture content of the soil. • Once the trial mix is prepared, the mould is oiled thoroughly. The mix is transferred to the mould compacted and then extracted from the mould. • Three identical samples were prepared for their Maximum Dry Density and Optimum Moisture content based on the compaction curves obtained. • The sample was subjected to various curing periods (1, 7, 14, 28 days) according to their trial combination chosen. Samples intended for long term testing were kept in desiccators to maintain 100% humidity and to prevent loss of moisture from samples. Water was sprinkled at regular intervals and was cured in the desiccators. All the samples intended for immediate testing were tested immediately. 32
  • 33. CHARACTERISTIC LEACHING TEST • After the Unconfined compressive strength test, has been carried out for the combination of fine and coarse soil mixtures the representative sample is taken for batch leaching test. according to standard test method (ASTM 4646-87 reapproved 2001). • A sample with Solid to liquid ratio of 1:10 is maintained. The soil mixture is kept in a shaker for 24 hrs. at a speed of 30 rpm. After that mixture is allowed to settle for 5 min, and then aqueous solution is filtered through a 0.45µm pore size membrane filter. The filtrate is analyzed using Atomic absorption spectrophotometer. (AAS) Plate 6 Unconfined compressive strength for soil mixtures and batch leaching tests for different soil mixtures. 33
  • 34. Contd… • Atomic absorption spectrophotometer (AAS) A203 Version -04 was used to measure the nickel concentration. The, fuel used was acetylene (C2H2) and the oxidant used was air or Nitrous oxide for strong flames. Calibration of the AAS was done according to the equipment manual using certified standards and the analysis of calibrated standards was attained to ensure the accuracy of results. Rotary flask shaker used for experiment work Plate7 Rotary flask shaker used and atomic absorption spectrophotometer used for analysis of heavy metal ions. 34
  • 35. RESULTS AND DISCUSSIONS COMPACTION CHARACTERISTICS OF STABILIZED BLACK COTTON SOIL WITH DIFFERENT PROPORTIONS OF FINE FLY ASH The results of stabilized black cotton soil for various percentages of fine fly ash mixtures along with optimum water content and corresponding dry density has been presented below.it can be observed that with increase in fly ash content the OMC increases and the dry density decreases. Optimum Water Content (%) Max Dry density(g/cc) Soil+ Fine fly ash 95%+5% 22.5 1.35 90%+10% 23.8 1.20 85%+15% 25.0 0.90 80%+20% 26.0 0.80 75%+25% 28.0 0.65 70%+30% 30.0 0.60 35
  • 36. Compaction with Soil and fine Fly ash Black cotton soil + Fine Fly Ash 1.4 5%Fly Ash 1.2 Max. Dry density in g/cc 1 10% Fly Ash 0.8 15%Fly Ash 0.6 20% Fly Ash 0.4 25%Fly Ash 0.2 30%Fly Ash 0 0 5 10 15 20 25 30 35 40 Water content in % 36
  • 37. COMPACTION CHARACTERISTICS OF STABILIZED BLACK COTTON SOIL WITH DIFFERENT PROPORTIONS OF COARSE FLY ASH The results of stabilized black cotton soil for various percentages of fine fly ash mixtures along with optimum water content and corresponding dry density has been presented below. it can be observed that with increase in fly ash content the OMC increases and the dry density decreases. Soil+ Fly ash(Coarse) Optimum Water Content (%) Max Dry density (g/cc) 95%+5% 10.5 1.35 90%+10% 14.5 1.30 85%+15% 16.0 1.22 80%+20% 18.5 1.19 75%+25% 20.0 1.10 70%+30% 21.0 1.00 37
  • 38. Compaction with Soil and coarse Fly ash Black cotton Soil+ Coarse Fly ash 1.6 5% Coarse Fly ash 1.4 Max. Dry density in g/cc 1.2 10%Coarse Fly ash 1 15%Coarse Fly ash 0.8 20%Coarse Fly ash 0.6 0.4 25%Coarse Fly ash 0.2 30%Coarse Fly ash 0 0 5 10 15 20 25 30 35 Water content in % 38
  • 39. COMPACTION CHARACTERISTICS OF STABILIZED BLACK COTTON SOIL WITH DIFFERENT PROPORTIONS OF FINE GGBS The results of stabilized black cotton soil for various percentages of fine fly ash mixtures along with optimum water content and corresponding dry density has been presented below. it can be observed that with increase in GGBS content the OMC decreases and the dry density increases. Soil+ Fine GGBS Optimum Water Content (%) Max Dry density(g/cc) 95%+5% 18.5 1.42 90%+10% 18.0 1.45 85%+15% 17.5 1.55 80%+20% 17.0 1.65 75%+25% 16.5 1.68 70%+30% 16.0 1.72 39
  • 40. Compaction with Soil and Fine GGBS Black cotton Soil+ Fine GGBS 2 5% Fine ggbs 10%Fine ggbs Max. Dry density in g/cc 1.6 15%Fine ggbs 1.2 20%Fine ggbs 25%Fineggbs 0.8 30%Fine ggbs 0.4 0 0 5 10 15 20 25 30 35 Water Content in % 40
  • 41. COMPACTION CHARACTERISTICS OF STABILIZED BLACK COTTON SOIL WITH DIFFERENT PROPORTIONS OF COARSE GGBS The results of stabilized black cotton soil for various percentages of fine fly ash mixtures along with optimum water content and corresponding dry density has been presented below. it can be observed that with increase in GGBS content the OMC decreases and the dry density increases. Soil+ Coarse GGBS Optimum Water Content (%) Max Dry density (g/cc) 95%+5% 18.0 1.30 90%+10% 17.5 1.38 85%+15% 17.0 1.42 80%+20% 16.5 1.45 75%+25% 16.0 1.50 70%+30% 15.0 1.55 41
  • 42. Compaction with Soil and Coarse GGBS Black cotton Soil+ Coarse GGBS 1.8 5%coarse ggbs 1.6 10%Coarse ggbs Max. Dry density in g/cc 1.4 1.2 15%Coarse ggbs 1 0.8 20%Coarse ggbs 0.6 25%Coarse ggbs 0.4 0.2 30%Coarse ggbs 0 0 5 10 15 20 25 30 35 Water Content in % 42
  • 43. CHARACTERISTIC UNCONFINED COMPRESSIVE STRENGTH OF SOIL FLY ASH MIXTURES The results of unconfined compressive strength of soil fly ash mixtures for varying percentage of fine and coarse fly ash mixtures have been presented in the table below.it can be observed that with increase in percentage of fine and coarse fly ash the UCC strength increases for both the mixtures, however the increase is more pronounced with fine fly ash content Sl No Parameter UCC in Kpa (fine) UCC in Kpa(Coarse) 1. 95%+ 5% Fly Ash 140.704 152.61 2. 90%+ 10% Fly Ash 249.727 158.336 3. 85%+ 15% Fly Ash 320.217 164.057 4. 80%+ 20% Fly Ash 330.098 168.964 5. 75%+ 25% Fly Ash 209.62 147.871 6. 70%+ 30% Fly Ash 89.143 118.302 7. 65%+ 35% Fly Ash 78.238 101.285 43
  • 44. Effect of fly ash content on the strength of soil characteristic strength of Fly ash 400 350 300 UCC strength in kpa 250 200 fine fly ash coarse fly ash 150 100 50 0 0 5 10 15 20 25 30 35 40 % varying of Fly ash 44
  • 45. CHARACTERISTIC UNCONFINED COMPRESSIVE STRENGTH OF SOIL GGBS MIXTURES The results of unconfined compressive strength of soil GGBS mixtures for varying percentage of fine and coarse GGBS mixtures have been presented in the table below. it can be observed that with increase in percentage of fine and coarse GGBS the UCC strength increases for both the mixtures, however the increase is more pronounced with fine GGBS content. SLNo Parameter UCC in Kpa (fine) UCC in Kpa (Coarse) 1. 95%+ 5% GGBS 255.073 55.797 2. 90%+ 10% GGBS 265.742 88.135 3. 85%+ 15% GGBS 316.451 120.473 4. 80%+ 20% GGBS 325.587 122.453 5. 75%+ 25% GGBS 216.856 124.434 6. 70%+ 30% GGBS 108.125 98.668 7. 65%+ 35% GGBS 68.265 72.902 45
  • 46. Effect of GGBS content on the strength of soil Characteristic strength of GGBS 350 300 UCC strength in kpa 250 200 fine GGBS coarse GGBS 150 100 50 0 5 10 15 20 25 30 35 40 % varying of Ground Granulated Blast Slag 46
  • 47. CHARACTERISTIC COMPRESSIVE STRENGTH OF BOTH FLY ASH AND GGBS MIXTURES The results of unconfined compressive strength of soil fly ash mixtures for varying percentage of fine and coarse combination mixtures have been presented in the table below. it can be observed that with increase in percentage of fine and coarse combination of mixtures the UCC strength increases for both the mixtures, however the increase is more pronounced with fine mixture content. Combination of soil, Fly Ash and 5% Ground granulated slag (Fine and Coarse) Sl no Parameter UCC in Kpa (fine) UCC in Kpa (Coarse) 1. Soil+ 0% Fly Ash 255.073 55.797 2. Soil+ 5% Fly Ash 265.682 173.481 3. Soil+ 10% Fly Ash 272.292 180.845 4. Soil+ 15% Fly Ash 300.101 190.488 5. Soil+ 20% Fly Ash 329.910 103.25 6. Soil+ 25% Fly Ash 300.25 44.25 47
  • 48. Effect of fine and coarse mixtures on the strength of soil Comparison of fine and coarse Combination 350 300 Fine Combination UCC Strength in Kpa 250 200 Coarse Combination 150 100 50 0 0 5 10 15 20 25 30 % varying fly ash 48
  • 49. CHARACTERISTIC COMPRESSIVE STRENGTH OF BOTH FLY ASH AND GGBS MIXTURES The results of unconfined compressive strength of soil GGBS mixtures for varying percentage of fine and coarse combination mixtures have been presented in the table below. it can be observed that with increase in percentage of fine and coarse combination of mixtures the UCC strength increases for both the mixtures, however the increase is more pronounced with fine mixture content. Combination of soil, 5%Fly Ash and Ground granulated slag (Fine and Coarse) Sl no Parameter UCC in Kpa (fine) UCC in Kpa (Coarse) 1. Soil+0% GGBS 140.704 152.61 2. Soil+ 5% GGBS 265.682 173.481 3. Soil+ 10% GGBS 165.065 136.818 4. Soil+ 15% GGBS 141.665 127.331 5. Soil+ 20% GGBS 119.266 117.845 6. Soil+ 25% GGBS 98.625 90.25 49
  • 50. Effect of fine and coarse mixtures on the strength of soil Comparison of fine and coarse combination 300 Fine combination 250 UCC Strength in Kpa 200 Coarse combination 150 100 50 0 0 5 10 15 20 25 30 % Varying ground granulated slag 50
  • 51. VARIATION OF STRENGTH OF BLACK COTTON SOIL WITH ADDITION OF LIME The results of variation of strength of stabilized black cotton soil for different percentage of lime has been presented in the table below. From the table it can be observed the characteristic compressive strength of black cotton soil increases with increase in lime content and also with different curing period. Soil, lime in% Compressive strength in Kpa 1 day curing 7 day curing 14day curing 28 day curing 2 55.228 60.215 108.188 162.161 4 68.495 72.625 166.373 248.128 6 170.708 258.589 350.234 480.453 8 228.924 312.368 286.581 546.43 10 186.285 496.325 225.865 404.594 51
  • 52. Variation of unconfined compressive strength with lime for different periods of curing soil sample. Variation of UCC with lime on Curing 600 500 1day curing UCC Strength in Kpa 400 7day curing 300 14day curing 200 100 28day curing 0 0 2 4 6 8 10 12 Lime in percentage 52
  • 53. LEACHING OF HEAVY METAL IONS FROM STABILIZED SOIL MIXTURES The leaching behavior of stabilized soil mixtures for heavy metal ions has been studied for 5% of admixtures used and remaining 95% of black cotton soil the results of leaching concentration of above mixtures has been presented in the table below. For 5% Soil Leaching Concentration in mg/l mixtures Heavy metal Ions Nickel Copper Iron Fine fly ash 1.0 0.98 1.0 Coarse fly ash 2.25 5.8 0.89 Fine ggbs 0.95 0.55 2.85 Coarse ggbs 2.5 0.82 0.98 Fine combination 1.98 2.2 2.5 Coarse combination 2.2 2.65 2.8 53
  • 54. 95% soil+5% admixtures 5% Soil mixture 6 Fine fly ash 5 Coarse fly ash Concentration in mg/l 4 Fine ggbs 3 Coarse ggbs 2 1 Fine combination 0 Coarse combination nickel copper iron 54
  • 55. Contd… The leaching behavior of stabilized soil mixtures for heavy metal ions has been studied for 10% of admixtures used and remaining 90% of black cotton soil the results of leaching concentration of above mixtures has been presented in the table below. For 10% Soil Leaching Concentration in mg/l mixtures Heavy metal Ions Nickel Copper Iron Fine fly ash 1.3 1.08 1.1 Coarse fly ash 2.39 6.48 2.65 Fine ggbs 1.1 0.88 5.24 Coarse ggbs 2.39 0.87 1.06 Fine combination 2.42 2.93 3.98 Coarse combination 2.34 3.65 3.45 55
  • 56. 90% soil+10% admixtures 10% Soil mixture Fine fly ash 6 5 Coarse fly ash Concentration in mg/l 4 Fine ggbs 3 Coarse ggbs 2 Fine combination 1 Coarse combination 0 nickel copper iron 56
  • 57. Contd… The leaching behavior of stabilized soil mixtures for heavy metal ions has been studied for 15% of admixtures used and remaining 85% of black cotton soil the results of leaching concentration of above mixtures has been presented in the table below. For 15% Soil Leaching Concentration in mg/l mixtures Heavy metal Ions Nickel Copper Iron Fine fly ash 1.3 1.2 1.1 Coarse fly ash 2.45 6.54 3.2 Fine ggbs 1.2 0.95 5.25 Coarse ggbs 2.5 1.0 1.22 Fine combination 2.62 3.2 4.2 Coarse combination 2.4 4.2 3.55 57
  • 58. 85% soil+15% admixtures 15% Soil mixture 6 Fine fly ash 5 Coarse fly ash Concentration in mg/l 4 Fine ggbs 3 Coarse ggbs 2 Fine combination 1 Coarse combination 0 nickel copper iron 58
  • 59. Contd… The leaching behavior of stabilized soil mixtures for heavy metal ions has been studied for 20% of admixtures used and remaining 80% of black cotton soil the results of leaching concentration of above mixtures has been presented in the table below. For 20% Soil Leaching Concentration in mg/l mixtures Heavy metal Ions Nickel Copper Iron 1.4 1.25 1.2 Fine fly ash 2.45 6.64 3.1 Coarse fly ash 1.28 1.2 6.24 Fine ggbs 2.58 1.8 1.02 Coarse ggbs 2.95 3.5 4.25 Fine combination 2.42 4.5 3.95 Coarse combination 59
  • 60. 80% soil+20% admixtures 8 20% Soil mixture Fine fly ash 7 6 Coarse fly ash Concentration in mg/l 5 Fine ggbs 4 Coarse ggbs 3 Fine combination 2 Coarse 1 combination 0 nickel copper iron 60
  • 61. CONCLUSIONS I. VARIATION OF MAXIMUM DRY DENSITY AND OPTIMUM MOISTURE CONTENT FOR FINE AND COARSE FLY ASH MIXTURE • It was observed that with the increase in water content the dry density decreases up to 20-30% moisture content and with further increase in water content the dry density decreases gradually. • The maximum dry density was observed to be about 1.35 g/cc for 95% soil and 5% fly ash mixture and lowest density was about 0.6g/cc for 70% soil and 30% fly ash mixture. II VARIATION OF MAXIMUM DRY DENSITY AND OPTIMUM MOISTURE CONTENT FOR FINE AND COARSE GGBS MIXTURE • It was found that with the increase in water content the dry density also increases up to 20-30% moisture content and with further increase in water content the dry density increases gradually. • The lowest dry density was observed to be about 1.42g/cc for 95% soil and 5% GGBS mixture and maximum density was about 1.72 g/cc for 70% soil and 30% GGBS mixture. 61
  • 62. Contd.. III VARIATION OF UNCONFINED COMPRESSIVE STRENGTH FOR FINE AND COARSE FLY ASH MIXTURES • It was found that percentage variation of strength was maximum for 20-30% of fine and coarse combination of fly ash content. • It was found that percentage variation of strength was maximum for 15-20% of fine and coarse combination of GGBS mixture • It was found that 8% of lime was optimum for stabilization of soil and mixture at the end of 28 days of curing period and the corresponding maximum strength attained was 500 Kpa. IV LEACHING BEHAVIOR OF HEAVY METAL IONS FROM STABILIZED SOIL MIXTURES (5 TO 20% OF FLY ASH AND GGBS MIXTURES) • It was observed that Ni ion concentration was relatively low in the extracted solution when compared to copper and iron from the stabilized soil mixtures for all the combinations. • The analysis of heavy metal ions reveals that the concentration of all the heavy metal ions were invariably well below the permissible limits except for copper and iron as per BIS. 62
  • 63. SCOPE FOR FUTURE WORK • The amount of fly ash and GGBS mixtures to be mixed for stabilization of soil may depend on the constituents of soil besides the environmental conditions. Hence the effect of the mixtures on different types of soil having different characteristics might be studied as future research works. • Scanning electron microscope/ X-ray diffraction studies should be carried out primarily to identify the mineral phases for different combinations of soil mixtures. • Further studies are required so as to ascertain the properties of absorption behavior for all soil mixtures of heavy metals like lead, cadmium, mercury, zinc, magnesium, etc. • Adsorption processes and its effects on their properties for different combination of soil mixtures need to be studied for different heavy metals considered. 63
  • 64. REFERENCES • KanirajS R, Havanagi V.G Geo technical characteristics of fly- ash soil mixtures. Geo technical Engineering journal, 1999, 30 (2):129-147 • Bardet, J P and Young, J (1997) Grain size analysis by Buoyancy method, Geotechnical testing Journal, Vol20, No-4, 1997, pg 481-485 • Sivapullaiah P.V Prashanth J. P Reactive silica and strength of fly ash, Geotechnical and Geological Engineering Vol.16, 1998, pp239- 250 • D.D. Higgins, J.M. Kinuthia and S. Wild “Soil Stabilization using Lime-Activated Ground Granulated Blast Furnace Slag” volume 178, pp.1057-1074June 1, 1998 • Joan E Mclean., Bert E,. Behavior of metals in soils, report no 540 S- 92-018, Environmental protection agency, USA,1992. 64
  • 65. Contd… • Arif Ali Baig, Sivapullaiah.P.V, Heavy metal leachability of low lime fly ashes, in Indian Geotechnical Conference-2008, Advances in geotechnical Engineering Vol II, 2008, PP470-473. • Joris.J.Dijkstra, R.N.J Comans, W.HW Van Riemsdijk, Development of a consistent geochemical modeling approach for leaching and reactive transport processes in contaminated materials,. Wageningen University, Netherlands, 2007. • Zhou,C.,Yin, J. H. and Ming,J.P. (2002) Bearing capacity and settlement of weak fly ash Ground improved using Lime Fly ash Canadian Geotechnical Journal, 39: 585-596. • ASTM, Standard test method for 24-h batch –type measurement of Contaminant by soils and sediments, International American Standard testing method D4646-87(reapproved 2001., USA,2001. 65
  • 66. THANK YOU 66