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IAEA TM On Origin of SUD: A global perspective



  Origin of gray-green sandstone and new
exploration model for Dongsheng sandstone
    uranium deposit in oil-gas and coal
      productive Ordos basin, China

              Dr. Ziying LI
   Beijing Research Institute of Uranium Geology
                   2012.5.29-6.1
          2007.11.1-10, Trivandrum
IAEA TM On Origin of SUD: A global perspective




Outline
1 Geological setting
2 Unique features of the deposit
3 Origin of grey-green sandstone
4 Metallogenic and exploration model
1 Geological Setting
Location:
NE of Ordos Basin in
North China
Size: 3x105 km2
Signature:
Compound basin
since palaeozoic
1 Geological Setting


 Pre-Jurassic
Basements:
Archean and
Proterozoic highly
metamorphic rocks
and migmatic
granites
 Paleozoic lightly
metamorphic rocks
1 Geological Setting




 Energy
resource Basin:
Oil & Gas
Coal and
Coal gas

C-P Coal
(Pink)
T3 Coal
 (light Yellow)
J1-J2 Coal
 (Yellow)
1 Geological Setting
                 Mesozoic covers & ore beds
Series     Group/     Sym. (m) Lith.                                                Dep.
           Fm.
Quat.                 Q     >41    Quaternary sands and soils
Lower      Zhidan     K1    1780   Red    and      gray        sandstone      and
Cretaceous Group                   mudstone;Alluvial, fluvial and eolian origins.

Upper      Fenfanghe J3f    971    conglomerate Poorly developed, Brown-red
Jurassic   Fm.

           Anding     J2a 300      Fine-grained red or brownish red siltstone
           Fm.                     and mudstone
Middle     Zhiluo Fm. J2z   300    Gray, greenish sandstone, siltstone and U
Jurassic                           mudstone
           Yanan Fm. J2y    450    Arkosic sandstones, siltstone and mudstone C, U
                                   interbeds
Lower      Fuxian     J1f   127    Siltstone and arkosic sandstone
Jurassic   Fm.
Upper      Yanchang   T3y >3000 Gravel-bearing sandstone with siltstone and Oil, C
Triassic   Fm.                     mudstone interbeds
1 Geological Setting

  Ore Bed: Zhiluo Formation(J2)




Ore bed
1 Geological Setting
Ore hosting sedimentary formation
   Sedimentary facies: Braided stream
   Lithology: Coarse-grained arkosic sandstones
   Thickness: 20 to 40 meters
   Uranium contents: 3 to 5 ppm
   Cementation: Loosely cemented.
   Ratio of sandstone to mudstone: 2:1
   Extension: stable, connected to each other
   Reducing materials: 0.5 to 1.5%.
Ore sedimentation sequences and lithology
           Outcrop



                              Borehole core




                              Borehole core
Braided stream system



                        Uranium in
                        Braided
                        distributary
                        Channels
1 Geological Setting
Tectonics                 (J)
 The Dongsheng tectonic
  slope block:
  dipping southwards or
  SW with 2o-5o.
 Recharge-runoff-
  discharge
  hydrodynamic             (K)
  system
  Dongsheng block
  provided the basic
  conditions for uranium
  mineralization.
1 Geological Setting
   Tectonics
The Zhungeerzhao-
Wangjiata Fault:
Contributions for
mineralization:
A suitable hydrodynamic
discharge regime
Generate a reducing
environment
2 Unique features of the deposit
(1) Uranium mineralization controlled by the redox
   zone between grey and grey-green sandstones
                              Greenish Sandstone
            Paleo-phreatic oxid.

                             Interlayer oxid.



                  Ore body

    Gray Sandstone
2 Unique features of the deposit
(2) Coffinite dominant, not pitchblende
                       Coffinite crystal
2 Unique features of the deposit
 (3) Complex ore body shapes




                         Shape of ore body



Cross section of ore
body shape
3 Origin of grey-green sandstone
Greenish sandstone originated from oil-gas
secondary reduction processes:
Secondary reduction processes: Took place
after the formation of uranium deposit
Green or gray-green sandstones: Paleo-
oxidation zone             chloritization and
epidotization.
3 Origin of grey-green sandstone

Mineralogical
 evidence



                         Oxidization residual
              Limonite

     Pyrite
3 Origin of grey-green sandstone

Geochemistry

                              Fe2O3/
  Elements   CaO CO2    S               U
                              FeO
 Greenish S. 3.96 2.83 0.04    0.41    3.4
  Grey S.    1.64 1.02 0.75    0.12    14.3
3 Origin of grey-green sandstone
Geochemistry
     Contents of hydrocarbon( L/kg)
 No. Lithology          Methane Ethane Propane
    Gray-green fine-
  3                       445     61     19
    grained sandstone
    Gray fine-grained
  4                       255     33     14
    sandstone
    Green medium-fine
  3                       620     81     23
    grained sandstone
    Gray medium-fine
  3                       257     36     13
    grained sandstone
3 Origin of grey-green sandstone

Abundant oil and gas in greenish
 sandstones




         Oil-Gas Inclusions
4 Metallogenic and exploration model
   It can be concluded that the uranium
mineralization mechanism of the sandstone type
uranium deposit in the northeastern Ordos Basin
is very complicated, which underwent multiple
metallogenic processes, and superposition
metallogenic & exploration model established:
  Preliminary enrichment process
  Paleo-phreatic oxidation process
  Paleo-interlayer oxidation process
  Oil-gas secondary reforming process
  Thermal modification process
4 Metallogenic and exploration model
Superposition metallogenic & exploration model
(A) Preliminary enrichment stage
                                        170Ma
4 Metallogenic and exploration model
Superposition metallogenic & exploration model
 (B) Paleo-phreatic oxidation stage
                                    160~135Ma
4 Metallogenic and exploration model


(1)Phreatic oxidation
  process(J3)
  Geochemically
  Vertical Zonations:
  U、V、Mo、Se、
  Re
4 Metallogenic and exploration model

(C) Paleo-phreatic+ Paleo-interlayer
oxidation stages             125~65Ma
4 Metallogenic and exploration model
                        U
(2) Interlayer
  oxidation
  process (K1-E1)
Geochemically
Horizontal Zonations:
                        Mo
U、V、Mo、Re 、
S…
4 Metallogenic and exploration model

(2)Interlayer      S
   oxidation
   process
  Horizontal
  Zonations:     Shape of
  U 、 V 、 Mo 、   ore body
  Re、S …
4 Metallogenic and exploration model
Uranium found in the redox zone: formed
by both paleo-phreatic and interlayer
oxidation processes.




             ilmenite
Superposition metallogenic & exploration model

(D) Oil-gas +Thermal modification stages
                                        20~8Ma
4 Metallogenic and exploration model
Hydrothermal events:
  Temperatures: 70oC to 170oC, Salinity from 8%
  to 20%

   148℃、
8.68Wt%NaCl
                             170℃、
                          3.39Wt%NaCl
4 Metallogenic and exploration model
             Hydrothermal process:
             Hydrothermal mineral association:




Pyrite
Limonite                         Galena
Sphalerite
4 Metallogenic and exploration model
Superposition Metallogenic Model
Superposition of metallogenic processes
  Phreatic+interlayer Oxidation Oil-gas
reworking Hydrothermal reworking
Superposition of different U sources
 Ore beds Provenence area Oil &Gas
Superposition of metallogenic fluids
 U-bearing Water Oil-Gas Thermal Fluid
4 Metallogenic and exploration model
New exploration indication
The Dongsheng deposit has unique features and
underwent complicated metallogenic processes,
among them oil-gas reforming process played
very important roles in uranium mineralization.
So correct identification on greenish sandstones
formed under paleo-oxidization and reformed
by oil-gas secondary reduction is very important
to explore for uranium deposits, especially in
those basin producing oil-gas…
谢 谢
Thank you

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03 li ziying iaea2012.5.29

  • 1. IAEA TM On Origin of SUD: A global perspective Origin of gray-green sandstone and new exploration model for Dongsheng sandstone uranium deposit in oil-gas and coal productive Ordos basin, China Dr. Ziying LI Beijing Research Institute of Uranium Geology 2012.5.29-6.1 2007.11.1-10, Trivandrum
  • 2. IAEA TM On Origin of SUD: A global perspective Outline 1 Geological setting 2 Unique features of the deposit 3 Origin of grey-green sandstone 4 Metallogenic and exploration model
  • 3. 1 Geological Setting Location: NE of Ordos Basin in North China Size: 3x105 km2 Signature: Compound basin since palaeozoic
  • 4. 1 Geological Setting  Pre-Jurassic Basements: Archean and Proterozoic highly metamorphic rocks and migmatic granites  Paleozoic lightly metamorphic rocks
  • 5. 1 Geological Setting  Energy resource Basin: Oil & Gas
  • 6. Coal and Coal gas C-P Coal (Pink) T3 Coal (light Yellow) J1-J2 Coal (Yellow)
  • 7. 1 Geological Setting Mesozoic covers & ore beds Series Group/ Sym. (m) Lith. Dep. Fm. Quat. Q >41 Quaternary sands and soils Lower Zhidan K1 1780 Red and gray sandstone and Cretaceous Group mudstone;Alluvial, fluvial and eolian origins. Upper Fenfanghe J3f 971 conglomerate Poorly developed, Brown-red Jurassic Fm. Anding J2a 300 Fine-grained red or brownish red siltstone Fm. and mudstone Middle Zhiluo Fm. J2z 300 Gray, greenish sandstone, siltstone and U Jurassic mudstone Yanan Fm. J2y 450 Arkosic sandstones, siltstone and mudstone C, U interbeds Lower Fuxian J1f 127 Siltstone and arkosic sandstone Jurassic Fm. Upper Yanchang T3y >3000 Gravel-bearing sandstone with siltstone and Oil, C Triassic Fm. mudstone interbeds
  • 8. 1 Geological Setting Ore Bed: Zhiluo Formation(J2) Ore bed
  • 9. 1 Geological Setting Ore hosting sedimentary formation  Sedimentary facies: Braided stream  Lithology: Coarse-grained arkosic sandstones  Thickness: 20 to 40 meters  Uranium contents: 3 to 5 ppm  Cementation: Loosely cemented.  Ratio of sandstone to mudstone: 2:1  Extension: stable, connected to each other  Reducing materials: 0.5 to 1.5%.
  • 10. Ore sedimentation sequences and lithology Outcrop Borehole core Borehole core
  • 11. Braided stream system Uranium in Braided distributary Channels
  • 12. 1 Geological Setting Tectonics (J)  The Dongsheng tectonic slope block: dipping southwards or SW with 2o-5o.  Recharge-runoff- discharge hydrodynamic (K) system Dongsheng block provided the basic conditions for uranium mineralization.
  • 13. 1 Geological Setting  Tectonics The Zhungeerzhao- Wangjiata Fault: Contributions for mineralization: A suitable hydrodynamic discharge regime Generate a reducing environment
  • 14. 2 Unique features of the deposit (1) Uranium mineralization controlled by the redox zone between grey and grey-green sandstones Greenish Sandstone Paleo-phreatic oxid. Interlayer oxid. Ore body Gray Sandstone
  • 15. 2 Unique features of the deposit (2) Coffinite dominant, not pitchblende Coffinite crystal
  • 16. 2 Unique features of the deposit (3) Complex ore body shapes Shape of ore body Cross section of ore body shape
  • 17. 3 Origin of grey-green sandstone Greenish sandstone originated from oil-gas secondary reduction processes: Secondary reduction processes: Took place after the formation of uranium deposit Green or gray-green sandstones: Paleo- oxidation zone chloritization and epidotization.
  • 18. 3 Origin of grey-green sandstone Mineralogical evidence Oxidization residual Limonite Pyrite
  • 19. 3 Origin of grey-green sandstone Geochemistry Fe2O3/ Elements CaO CO2 S U FeO Greenish S. 3.96 2.83 0.04 0.41 3.4 Grey S. 1.64 1.02 0.75 0.12 14.3
  • 20. 3 Origin of grey-green sandstone Geochemistry Contents of hydrocarbon( L/kg) No. Lithology Methane Ethane Propane Gray-green fine- 3 445 61 19 grained sandstone Gray fine-grained 4 255 33 14 sandstone Green medium-fine 3 620 81 23 grained sandstone Gray medium-fine 3 257 36 13 grained sandstone
  • 21. 3 Origin of grey-green sandstone Abundant oil and gas in greenish sandstones Oil-Gas Inclusions
  • 22. 4 Metallogenic and exploration model It can be concluded that the uranium mineralization mechanism of the sandstone type uranium deposit in the northeastern Ordos Basin is very complicated, which underwent multiple metallogenic processes, and superposition metallogenic & exploration model established: Preliminary enrichment process Paleo-phreatic oxidation process Paleo-interlayer oxidation process Oil-gas secondary reforming process Thermal modification process
  • 23. 4 Metallogenic and exploration model Superposition metallogenic & exploration model (A) Preliminary enrichment stage 170Ma
  • 24. 4 Metallogenic and exploration model Superposition metallogenic & exploration model (B) Paleo-phreatic oxidation stage 160~135Ma
  • 25. 4 Metallogenic and exploration model (1)Phreatic oxidation process(J3) Geochemically Vertical Zonations: U、V、Mo、Se、 Re
  • 26. 4 Metallogenic and exploration model (C) Paleo-phreatic+ Paleo-interlayer oxidation stages 125~65Ma
  • 27. 4 Metallogenic and exploration model U (2) Interlayer oxidation process (K1-E1) Geochemically Horizontal Zonations: Mo U、V、Mo、Re 、 S…
  • 28. 4 Metallogenic and exploration model (2)Interlayer S oxidation process Horizontal Zonations: Shape of U 、 V 、 Mo 、 ore body Re、S …
  • 29. 4 Metallogenic and exploration model Uranium found in the redox zone: formed by both paleo-phreatic and interlayer oxidation processes. ilmenite
  • 30. Superposition metallogenic & exploration model (D) Oil-gas +Thermal modification stages 20~8Ma
  • 31. 4 Metallogenic and exploration model Hydrothermal events: Temperatures: 70oC to 170oC, Salinity from 8% to 20% 148℃、 8.68Wt%NaCl 170℃、 3.39Wt%NaCl
  • 32. 4 Metallogenic and exploration model Hydrothermal process: Hydrothermal mineral association: Pyrite Limonite Galena Sphalerite
  • 33. 4 Metallogenic and exploration model Superposition Metallogenic Model Superposition of metallogenic processes Phreatic+interlayer Oxidation Oil-gas reworking Hydrothermal reworking Superposition of different U sources Ore beds Provenence area Oil &Gas Superposition of metallogenic fluids U-bearing Water Oil-Gas Thermal Fluid
  • 34. 4 Metallogenic and exploration model New exploration indication The Dongsheng deposit has unique features and underwent complicated metallogenic processes, among them oil-gas reforming process played very important roles in uranium mineralization. So correct identification on greenish sandstones formed under paleo-oxidization and reformed by oil-gas secondary reduction is very important to explore for uranium deposits, especially in those basin producing oil-gas…