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1 
CO2 Capture, Transport, Utilization and Storage Activities at 
Masdar Institute 
Dr. Mohammad Abu Zahra 
Separation Technology Laboratory 
Chemical and Environmental Engineering Department 
GCCSI Conference-Global Status of CCS, Abu DHabi 
November 5th, 2014
2 
RESEARCH – THEMES AND AREAS OF FOCUS
3 
CO2 CAPTURE, TRANSPORT, UTILIZATION AND 
STORAGE ACTIVITIES AT MASDAR INSTITUTE 
April 24th, 2013 
CO2 Capture Technologies 
• The development of novel capture systems and 
processes for post-combustion capture, hydrogen 
production, CO2 utilization and chemical looping. 
• Multiple projects were established in collaboration 
with Siemens, MIT, Masdar Carbon and RTI. 
CO2 storage, injection and monitoring 
• Study the interactions between the injected CO2 and the 
brine saturated rock, geo-chemistry, geo-mechanics, and 
trapping phenomena during CO2 storage 
• CO2 monitoring (GPS and INSAR) 
• Collaboration with MIT, ADNOC, ADCO and PI 
CCS Policies and Regulations 
• Optimal CO2 regulation to Align CCS with EOR and 
CDM 
• Energy Policy and Technology Strategy and 
scenarios 
• Risk analysis, CCS economics and regulations 
Importance for Abu Dhabi 
These activities contribute to the overall vision of Abu 
Dhabi to reduce GHG emissions. One of the 
approaches to reduce carbon emission is by the 
development and deployment of CCS technologies. 
The current R&D projects will encourage the 
deployment of CCS technology in UAE. Having the 
advantage of being an oil producing country, CCS in 
the UAE will serve to be an excellent candidate to 
allow for enhanced oil recovery. 
Researchers 
Dr. Mohammad Abu Zahra 
Prof. Toufic Mezher 
Prof. Mohamed Sassi 
Prof. Tariq Shamim 
Dr. Hosni Ghedira 
Dr. I-Tsung Tsai 
Dr. Ahmed Hajaj 
Dr. Steve Griffiths 
Dr. Enas Nashf
4 
SIEMENS-MASDAR INSTITUTE COLLABORATION 
• This long term collaboration is aiming to the development 
of CO2 post-combustion capture technologies, which 
suitable for deployment in the gulf region. With major focus 
on Siemens PostCap technology 
• Supporting Masdar Institute post-combustion capture 
activities by: 
– Siemens fellowship program (Master and PhD students) 
– R&D projects 
Coordinator 
Dr. Mohammad Abu Zahra 
mabuzahra@masdar.ac.ae 
Evaluation of CO2 Purification Requirements and Techno-Economic Evaluation of Processes for 
Impurities Deep Removal from the CO2 Product Stream 
Concluded in May 2012 
Evaluation of handling approached of solid waste generated from the POSTCAP process considering the 
regulations in UAE 
Concluded in April 2013 
Contactor Design for Hybrid Systems for CO2 Capture 
Started in January 2013 
Liquid Fuels Evaluation and Characterization 
Started in November 2013
5 
DEVELOPMENT OF NEW SORBENTS SYSTEMS FOR CO2 
POST-COMBUSTION CAPTURE 
• Started in September 2011 
• Duration of 30 months 
• Objectives: 
- Development and characterization of amine-based 
solvents for short term post-combustion capture 
application 
- Developing CO2-binding organic sorbents for CO2 
post combustion capture. 
Faculty 
Dr. Mohammad Abu Zahra; Prof. T. Alan Hatton 
mabuzahra@masdar.ac.ae; tahatton@mit.edu
6 
BENCH-SCALE DEVELOPMENT OF ADVANCED SOLID SORBENT MATERIAL 
AND SUITABLE PROCESSES FOR POST-COMBUSTION CO2 CAPTURE 
• Project Partners: 
• Kick off in October 2011 
• Duration of 36 months 
• Overall Objectives: 
- Optimization and production scale-up of advanced MBS 
materials in fluidizable form and development of associated 
fluidized-bed process technology. 
- Collection of critical process engineering data using single-stage 
testing equipment to allow for a detailed design of a 
bench-scale CO2 capture prototype based on MBS 
materials. 
- Demonstrate technical and economic feasibility of a 
commercial embodiement of the MBS-based CO2 capture 
process 
• Masdar Institute tasks: 
- Techno-Economic Evaluation of the advanced solid 
material for the natural gas combined cycle power plant 
case 
- Evaluation of scale-up challenges and issues related to the 
application for NG case 
- Sorbent single-stage and bench scale long term testing 
using flue gas from NGCC power plant 
University of North Carolina 
Pennsylvania State University 
Sud-Chemie Inc 
Unitel 
Technologies 
Foster Wheelers USA 
Faculty 
Dr. Mohammad Abu Zahra 
mabuzahra@masdar.ac.ae
7 
CO2 CAPTURE BY USING CHEMICAL LOOPING 
COMBUSTION (CLC) 
• Research Issues: 
- Development of a suitable oxygen carrier 
material 
- Efficient design of oxidation and reduction 
reactors 
- Integration of CLC technology with various 
power cycles 
• Objective: 
- To develop an innovative CO2 capture process which has 
minimum energy penalty 
• Approach: 
- To split the combustion of the fuel into two separate 
reactions carried out in two separate reactors: an 
oxidation reaction and a reduction reaction, by introducing 
suitable metal oxide as an oxygen-carrier that circulates 
between the two reactors 
• Impact: 
- Contribute to the development of efficient CO2 capture 
technologies 
• Contact: 
Dr. Tariq Shamim 
Professor of Mechanical Engineering 
tshamim@masdar.ac.ae , Ph: +971 (2) 810-9158
8 
EXPERIMENTAL AND NUMERICAL STUDIES OF CO2 INJECTION INTO 
BRINE-SATURATED ROCKS: CO2 DISSOLUTION-DIFFUSION-CONVECTION 
PROCESS 
• Objective: 
- This work studies the dissolution-diffusion-convection 
phenomena of the buoyant CO2 gasket between the cap 
rock and the brine saturated formation 
• Approach: 
- To visualize the phenomena in a Hele-Shaw cell filled 
with few layers of granular medium saturated with brine. 
- To numerically simulate the phenomena 
• Research Issues 
- To visualize the different CO2 trapping mechanisms 
- To develop an understanding of the coupled phenomena 
- To correctly simulate the phenomena 
• Impact: 
- Contribute to the development of efficient CO2 storage 
technologies 
• Faculty: Prof. Mohamed Sassi, 
msassi@masdar.ac.ae
THANK YOU 
9

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Dr Mohammad Abu Zahra - CO2 Capture, Transport, Utilization and Storage Activities at Masdar Institute

  • 1. 1 CO2 Capture, Transport, Utilization and Storage Activities at Masdar Institute Dr. Mohammad Abu Zahra Separation Technology Laboratory Chemical and Environmental Engineering Department GCCSI Conference-Global Status of CCS, Abu DHabi November 5th, 2014
  • 2. 2 RESEARCH – THEMES AND AREAS OF FOCUS
  • 3. 3 CO2 CAPTURE, TRANSPORT, UTILIZATION AND STORAGE ACTIVITIES AT MASDAR INSTITUTE April 24th, 2013 CO2 Capture Technologies • The development of novel capture systems and processes for post-combustion capture, hydrogen production, CO2 utilization and chemical looping. • Multiple projects were established in collaboration with Siemens, MIT, Masdar Carbon and RTI. CO2 storage, injection and monitoring • Study the interactions between the injected CO2 and the brine saturated rock, geo-chemistry, geo-mechanics, and trapping phenomena during CO2 storage • CO2 monitoring (GPS and INSAR) • Collaboration with MIT, ADNOC, ADCO and PI CCS Policies and Regulations • Optimal CO2 regulation to Align CCS with EOR and CDM • Energy Policy and Technology Strategy and scenarios • Risk analysis, CCS economics and regulations Importance for Abu Dhabi These activities contribute to the overall vision of Abu Dhabi to reduce GHG emissions. One of the approaches to reduce carbon emission is by the development and deployment of CCS technologies. The current R&D projects will encourage the deployment of CCS technology in UAE. Having the advantage of being an oil producing country, CCS in the UAE will serve to be an excellent candidate to allow for enhanced oil recovery. Researchers Dr. Mohammad Abu Zahra Prof. Toufic Mezher Prof. Mohamed Sassi Prof. Tariq Shamim Dr. Hosni Ghedira Dr. I-Tsung Tsai Dr. Ahmed Hajaj Dr. Steve Griffiths Dr. Enas Nashf
  • 4. 4 SIEMENS-MASDAR INSTITUTE COLLABORATION • This long term collaboration is aiming to the development of CO2 post-combustion capture technologies, which suitable for deployment in the gulf region. With major focus on Siemens PostCap technology • Supporting Masdar Institute post-combustion capture activities by: – Siemens fellowship program (Master and PhD students) – R&D projects Coordinator Dr. Mohammad Abu Zahra mabuzahra@masdar.ac.ae Evaluation of CO2 Purification Requirements and Techno-Economic Evaluation of Processes for Impurities Deep Removal from the CO2 Product Stream Concluded in May 2012 Evaluation of handling approached of solid waste generated from the POSTCAP process considering the regulations in UAE Concluded in April 2013 Contactor Design for Hybrid Systems for CO2 Capture Started in January 2013 Liquid Fuels Evaluation and Characterization Started in November 2013
  • 5. 5 DEVELOPMENT OF NEW SORBENTS SYSTEMS FOR CO2 POST-COMBUSTION CAPTURE • Started in September 2011 • Duration of 30 months • Objectives: - Development and characterization of amine-based solvents for short term post-combustion capture application - Developing CO2-binding organic sorbents for CO2 post combustion capture. Faculty Dr. Mohammad Abu Zahra; Prof. T. Alan Hatton mabuzahra@masdar.ac.ae; tahatton@mit.edu
  • 6. 6 BENCH-SCALE DEVELOPMENT OF ADVANCED SOLID SORBENT MATERIAL AND SUITABLE PROCESSES FOR POST-COMBUSTION CO2 CAPTURE • Project Partners: • Kick off in October 2011 • Duration of 36 months • Overall Objectives: - Optimization and production scale-up of advanced MBS materials in fluidizable form and development of associated fluidized-bed process technology. - Collection of critical process engineering data using single-stage testing equipment to allow for a detailed design of a bench-scale CO2 capture prototype based on MBS materials. - Demonstrate technical and economic feasibility of a commercial embodiement of the MBS-based CO2 capture process • Masdar Institute tasks: - Techno-Economic Evaluation of the advanced solid material for the natural gas combined cycle power plant case - Evaluation of scale-up challenges and issues related to the application for NG case - Sorbent single-stage and bench scale long term testing using flue gas from NGCC power plant University of North Carolina Pennsylvania State University Sud-Chemie Inc Unitel Technologies Foster Wheelers USA Faculty Dr. Mohammad Abu Zahra mabuzahra@masdar.ac.ae
  • 7. 7 CO2 CAPTURE BY USING CHEMICAL LOOPING COMBUSTION (CLC) • Research Issues: - Development of a suitable oxygen carrier material - Efficient design of oxidation and reduction reactors - Integration of CLC technology with various power cycles • Objective: - To develop an innovative CO2 capture process which has minimum energy penalty • Approach: - To split the combustion of the fuel into two separate reactions carried out in two separate reactors: an oxidation reaction and a reduction reaction, by introducing suitable metal oxide as an oxygen-carrier that circulates between the two reactors • Impact: - Contribute to the development of efficient CO2 capture technologies • Contact: Dr. Tariq Shamim Professor of Mechanical Engineering tshamim@masdar.ac.ae , Ph: +971 (2) 810-9158
  • 8. 8 EXPERIMENTAL AND NUMERICAL STUDIES OF CO2 INJECTION INTO BRINE-SATURATED ROCKS: CO2 DISSOLUTION-DIFFUSION-CONVECTION PROCESS • Objective: - This work studies the dissolution-diffusion-convection phenomena of the buoyant CO2 gasket between the cap rock and the brine saturated formation • Approach: - To visualize the phenomena in a Hele-Shaw cell filled with few layers of granular medium saturated with brine. - To numerically simulate the phenomena • Research Issues - To visualize the different CO2 trapping mechanisms - To develop an understanding of the coupled phenomena - To correctly simulate the phenomena • Impact: - Contribute to the development of efficient CO2 storage technologies • Faculty: Prof. Mohamed Sassi, msassi@masdar.ac.ae