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Development of an aqueous ammonia-based post-
combustion capture technology for Australian
conditions
Webinar – Thursday, 13 October 2016
 Dr Yu is a senior research scientist at CSIRO Energy. He was
awarded a PhD in Chemical Engineering from the University
of Newcastle, Australia in 2004.
 Since 2000, he has dedicated himself to research on clean
energy technologies and environmental protection, including
development of technologies for utilisation of synthetic
greenhouse gases and post combustion CO2 capture.
 He was lead researcher for the pilot plant demonstration of an
aqueous ammonia-based post-combustion capture process in
Australia, and the project leader for a number of projects
which are aimed to advance the aqueous ammonia-based
CO2 capture technology for application in Australia.
Senior Research Scientist, CSIRO Energy
Dr Hai Yu
 Dr Li is a postdoctoral research scientist at CSIRO Energy.
He was awarded a PhD in Chemical Engineering from Curtin
University of Technology in 2016.
 His research focuses on post combustion CO2 capture
technology and energy harvesting from CO2 capture.
 He participated in the development of an advanced aqueous-
ammonia based CO2 capture process which was funded by
ANLEC R&D, focusing on Aspen process modelling and
techno-economic assessment.
Postdoctoral Research Scientist, CSIRO Energy
Dr Kangkang Li
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ANLEC R&D is a not-for-profit agency, funded by the Australian Government Department Industry, Innovation and Science through the
National Low Emissions Coal Initiative, and by the ACA Low Emissions Technologies Ltd (ACALET) through the COAL21 Fund.
Enabling research to reduce greenhouse emissions from coal technologies
Australian National Low Emissions Coal Research & Development
ANLEC R&D is an Australian National Research
Initiative to support Carbon Capture and Storage
(CCS) deployment in Australia.
$100M+ Invested
In one of the largest partnerships, the Australian
Coal Industry and the Australian Government has
deployed a research effort in over 25 institutions
nationwide since 2010.
Our present focus supports CO2 storage across
3 Australian geological basins:
Surat Basin, Gippsland Basin, Perth Basin
ANLEC R&D funded this project to test concepts that might further reduce the cost of post combustion
capture using advanced aqueous ammonia solutions
For more information please visit www.anlecrd.com.au
Development of an advanced aqueous-ammonia based post-
combustion capture technology for Australian Conditions
13 October 2016
CSIRO Energy
Hai Yu and Kangkang Li
Outline of Presentation
o Research Background
o Project Objectives
o Approaches and Methodology
o Results and Discussion
o Conclusions and Future Work
Levelisedcostofelectricity
AUD/MWh
0
20
40
60
80
100
120
140
160
180
Capital
O&M
Fuel
CO2 T&S
Pulverised black coal
no CCS
Pulverised black coal
MEA CCS
Project background – global state of the art in PCC
The state of the art PCC technology is based on amine solutions
o Costs are high, in particular, capital cost in Australian content
o Environmental concerns
EPRI, Australian Electricity Generation
Technology Costs-Reference Case 2010
Levelisedcostofelectricity
AUD/MWh
0
20
40
60
80
100
120
140
160
180
Capital
O&M
Fuel
CO2 T&S
Pulverised black coal
no CCS, no SOx
Pulverised black coal
amine CCS + SOx
CO2CRC, et al, Australian Power
Generation Technology Report 2015
PCC
Pilot plants Research & Development
Delta Electricity
AGL Loy Yang Power
China Huaneng
(Beijing)
Stanwell
Novel amines Novel processes &
equipment
Adsorbents
Environmental impacts
Learning by doing Learning by searching
Membranes
China Huaneng
(Changchun)
Project background – CSIRO PCC research program
Lean Solvent
Rich Solvent
CO2
Flue gas in
Flue gas out
Absorber Stripper
2HOC2H4NH2 + CO2  HOC2H4NHCOO- + HOC2H4NH3
+
(MEA) (Carbamate)
NH3 + H2O + CO2 {
NH4
+ + HCO3
- (bicarbonate)
NH4
++NH2COO- (carbamate)
NH4
+ + CO3
2- (carbonate) } 
NH4HCO3
(NH4)2CO3
NH2COONH4
Solid precipitation
Project background – Ammonia based PCC process
Project background – Ammonia based PCC process
• Alstom Power – Chilled ammonia process
• CSIRO, Powerspan and Korean Research Institute of Industrial
Science & Technology – Warm ammonia process
Project background – Ammonia PCC development in CSIRO
Trialing a basic process
at Munmorah Power Station
10
1
2185
FLUE4
10
1
5957
LEAN-INP
27
1
1830OFF-GAS
29
1
6312
RICH
107
5
6312
RICH2
45
5
113
RECYCLE
130
5
5921
LEAN1
106
5
504
TOP
29
5
6312RICH1
39
5
5921LEAN2
11
1
1756
VENT1
115
1
1756
VENT2
125
1
2272
FLUE
45
1
2272FLUE1
10
1
5853WASHWA
16
1
5927WASH1
45
5
391
PRODUCT
16
1
2192
FLUE3
10
1
6
CONDEN
45
1
2272
6
96
1
2272
FLUE2
30
1
27WATER
-50
10
9NH3
40
1
59213
16
1
5927
16
1
5927
1
26
1
5853
30
1
0
30
1
0
31
1
6007
31
1
6007
31
1
6007WASH2
31
1
5853
13
31
1
154
31
1
5853
ABSORBER
QC=0.0
QR=0.0
STRIPPER
QC=0.0
QR=307.0
PUMP
W=1.9
LIQHX2
LIQHX1
Q=-624.8
GASHX1
Q=53.0
GASHX2
Q=-53.0
SCRUBER
QC=0.0
QR=0.0
CONDENSE
Q=-77.0
GASCOOL2
Q=-8.3
BLOWER
W=33.6
LIQCOOL
Q=-197.9
WPUMP
W=0.1
Q=-108.8
WCOOLER1
Q=0.0
B5
W=0.0
B6W=0.0
B7
B8
B10
Q=-33.9
B1
Q=0.0
B3
Q=0.0
B4
Q=0.0
Temperature (C)
Pressure (bar)
Mass Flow Rate (kg/hr)
Q Duty (kW)
W Power(kW)
17
B11
Q=0.0
16
1
592718
Initial
Research 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Further development
Trialing an advanced process
at Vales Point Power Station
 Low cost, robust, more benign than other amines
 High CO2 loading capacity
 Low regeneration energy and production of high pressure CO2
 Potential to remove multi-components (SOx, NOx and CO2)
simultaneously and produce value added products
 Established technology
Project background – Ammonia based PCC process
Advantages
Areas for improvement
 Relatively low CO2 absorption rate compared to amine
based solvent
 Relatively high ammonia loss at high CO2 absorption rate.
 Formation of ammonium-bicarbonate solids
 The available process simulation models were insufficient to
support the process optimisation and scale up
Project Objectives
1. Develop a novel aqueous ammonia based solvent which has fast CO2
absorption rate equivalent to MEA while maintaining a low regeneration
energy requirement.
2. Further advance the combined SO2 removal and ammonia recovery
technology to eliminate additional FGD, reduce the ammonia slip in the
exiting flue gas to acceptable levels and produce a value added fertiliser,
i.e. ammonium sulphate.
3. Further develop CSIRO high pressure absorption to enhance CO2
absorption, reduce ammonia loss and cooling water consumption.
4. Develop and validate a rigorous rate based model for the capture process
and identify new process configurations to achieve further savings on
capture costs.
Ultimately, develop a process which can reduce
1. investment and running cost in the Australian context.
2. potential environmental risks resulting from the
implementation of PCC technologies.
Approaches and Methodology
CO2
Stripper
Steam
Reboiler
Condenser
Pretreatment
Washing
Heat
Exchanger
CO2
absorber
Flue gas
Clean gas
NH3 recycle unitPower station
CO2 capture unit
CO2 product
Combined removal
 Additives
 High pressure
absorption
 Staged absorption-
recycling solvent
Stripper configurations
Rich split
Inter-heating
Rate-based process model
Approaches
Approach and Methodology
2 Process model
Methodology
1 Experimental, pilot plant and bench scale facilities
A rigorous, rate-based model using Aspen Plus RateSep was used to determine
technical performance of the process improvements
3 Cost model
1 Capital cost
2 Operating & maintenance (O&M) cost including electricity cost, fixed cost and cooling water
Aspen Capital Cost Estimator for calculation of cost of each equipment
 Size of equipment, column, packing, pump, etc.
 Cooling water consumption
 Energy consumption including power loss due to steam extraction
 Development and validation of a rate-based model for the system of
NH3-CO2-SO2-H2O
• Pitzer based thermodynamic model
• RateSep module, a rate-based absorption and stripping unit operation model
• Two-film theory;
• Mass and heat transfer resistances;
• Liquid film is discretized into multiple film segments;
• Film segments near the interface are much thinner
Interface
XCO2
int
Tint
YCO2
int
TV
YCO2
bulk
Vapour film Liquid film
Vapour bulk phase Liquid bulk phase
Mass and heat transfer
TL
XCO2
bulk
CO2
NH3
H2O
N2
2NH COO
3HCO
2
3CO 
4NH OH
3H O
3NH
2 2CO SO
2H O
SO2
O
2
3SO 
3HSO
2
2 5S O 
Results and Discussion
Results and Discussion
 Model development of NH3-CO2-SO2-H2O
Equilibrium reactions
No. Reaction
Equilibrium parameter
A B C D
1 NH3 + H2O <--> NH4
+
+ OH-
-1.2566 -3335.7 1.497 -0.0370
2 2H2O <--> H3O+
+ OH-
132.899 -13445.9 -22.477 0
3 HCO3
-
+ H2O <--> CO3
2-
+ H3O+
216.049 -12431.7 -35.481 0
4 H2O + HSO3
-
<--> H3O+
+ SO3
2-
-25.290 1333.400 0 0
5 2H2O + SO2 <--> H3O+
+ HSO3
-
-5.978673 637.395 0 0
6 NH4HCO3(S) <--> NH4
+
+ HCO3
-
8.064 -5013.759 0 0
7 (NH4)2SO3(S) <--> 2 NH4
+
+ SO3
2-
Compute from Gibbs Energies built in Aspen
8 (NH4)2SO3(S)`H2O<--> 2 NH4
+
+ SO3
2-
+H2O Compute from Gibbs Energies built in Aspen
Kinetic reactions
No. Reaction
Kinetic factor
k E(cal/mol)
1 CO2 + OH-
--> HCO3
-
4.32e+13 13249
2 HCO3
-
--> CO2 + OH-
2.38e+17 29451
3 NH3 + CO2 + H2O --> NH2COO-
+ H3O+
1.35e+11 11585
4 NH2COO-
+ H3O+
--> NH3 + CO2 + H2O 4.75e+20 16529
Equilibrium
Kinetic
Results and Discussion
 Model validation of NH3-CO2-SO2-H2O : thermodynamic
 Comparison between experimental and simulation results
CO2 partial pressure Total pressure
Species profile Solution pH
Results and Discussion
 Model validation of NH3-CO2-SO2-H2O : Kinetic (1) – CO2 absorption by NH3
Average relative error
for CO2 absorption rate: ±6%
Simulation results vs pilot plant results
Average relative error
for NH3 loss rate: ±11%
Results and Discussion
 Model validation of NH3-CO2-SO2-H2O : Kinetic (2) – SO2 removal by NH3
08:24 09:36 10:48 12:00 13:12 14:24 15:36
0
2
4
6
8
10
12
1.8kg/hr NH3
1.0kg/hr NH3
0.5kg/hr NH3
0.2kg/hr NH3
Time
Simu.
Water
(a) Expt.
pH
SO2concentration/ppmv
Time
Expt.(b)
08:24 09:36 10:48 12:00 13:12 14:24 15:36
0
50
100
150
200
250 Simu.
1.8kg/hr NH3
1.0kg/hr NH3
0.5kg/hr NH3
0.2kg/hr NH3
Water
0
100
200
300
400
500
1.8kg/hr NH3
1.0kg/hr NH3
0.5kg/hr NH3
0.2kg/hr NH3
Water
Expt.
NH3concentration/ppmv
Time
08:24 09:36 10:48 12:00 13:12 14:24 15:36
Simu.(c)
Comparison of pilot plant data with simulation results
pH of water
Gas outlet SO2
concentration
Gas outlet NH3
concentration
Results and Discussion
 Process design (1): novel process for removal SO2 and CO2 and recovery of NH3
Pump
Chiller
Heater
Pretreatment
Washing
Heat
Exchanger
Pump
CO2
absorber
Vent gas
SO2
Recovery
SO2 fertilizer
Water makeup
CO2 rich
CO2 lean
Flue gas
NH3 rich
NH3 lean
Coal-fired
Power Station SO2 Removal and NH3 Recycling Process
Typical CO2
Capture Process
Flowrate, 760kg/h
T = 120oC
CO2: 10.7
SO2: 200ppm
H2O: 6.0
Flowrate, 656kg/h
T = 16.9 oC
CO2: 3.23
NH3: 1.2
SO2: 0ppm
H2O: 1.8
T= 10oC
Hot
Results and Discussion
 Rate based modeling results of SO2 removal and NH3 recovery
0 50 100 150 200 250 300 350
0
20
40
60
80
100
SO2 capture efficiency
Outlet SO2 concentration
Number of cycles
SO2captureefficiency/%
0
10
20
30
40
50
60
70
OutletSO2concentration/ppbv
0 50 100 150 200 250 300 350
0
10
20
30
40
(NH4)2S2O5
NH4HSO3
Mass/%
Number of cycles
(NH4)2SO3
0 50 100 150 200 250 300 350
0
20
40
60
80
100
NH3 for SO2 capture
NH3reuseefficiency,%
Number of cycles
NH3 recycle to CO2 absorber
0
5
10
15
20
25
Vent gas NH3
NH3concentration,ppmv
>99% SO2 removal
>99% NH3 reuse
(NH4)2SO3 Low energy consumption
Results and Discussion
 Process design (2): Staged-absorption
Staged Absorption Configuration
Inter-cooling
to 25 oC
CO2
absorption
NH3
mitigation
Benefit: >50% NH3 reduction
Results and Discussion
CO2 lean
Rich/lean
Heat exchanger
Stripper
Steam
Reboiler
Condenser
CO2 product
Pump
Cooler
Cooling water
CO2 rich
from absorber
CO2 lean
to absorber
Cooling water
Drum
CO2
Stripper
Steam
Reboiler
Condenser
Rich/lean
Heat exchanger
Pump
CO2 Rich
from absorber
CO2 Lean
to absorber
CO2 product
Split
unsplit
Cooling water Cooling water
Drum
Cooler
Rich split
CO2 lean
Inter-heating
Heat exchanger
Stripper
Rich/lean
Heat exchanger
CO2 lean
to absorber
CO2 rich
from absorber
Steam
Reboiler
Condenser
CO2 product
Pump
Pump
Cooling water Cooling water
Drum
Cooler
Inter-heating
Reference
 Process design (3): advanced stripper configurations
Results and Discussion
Base case study 500 MW power station, three process trains with
each to capture 1 MT CO2
CO2 regeneration rate =118.4 Tonne/h
NH3 = 6.8%
CO2 loading lean =0.25
CO2 loading rich = 0.42
Solvent T at inlet of absorber = 25oC
Solvent T at inlet of heat exchanger = 40oC
T difference = 10oC
Stripper P =10 bar
Stripper bottom T = 145.5oC
CO2 lean
Rich/lean
Heat exchanger
Stripper
Steam
Reboiler
Condenser
CO2 product
Pump
Cooler
Cooling water
CO2 rich
from absorber
CO2 lean
to absorber
Cooling water
Drum
Item Value
Stripper column Diameter = 6.8 m and Height = 10.75 m,
Mellapack 250Y
Reboiler duty 3.2 GJ/Tonne CO2
Condenser duty
1.5 GJ/Tonne CO2
Results and Discussion
Rich split process
CO2
Stripper
Steam
Reboiler
Condenser
Rich/lean
Heat exchanger
Pump
CO2 Rich
from absorber
CO2 Lean
to absorber
CO2 product
Split
unsplit
Cooling water Cooling water
Drum
Cooler
0.00 0.02 0.04 0.06 0.08 0.10
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
Heatrequirement,MJ/kgCO2
Split fraction
Heat of CO2 desorption
Heat of vaporization
Sensible heat
0.00 0.02 0.04 0.06 0.08 0.10
0.0
0.5
1.0
1.5
2.0
2.5
3.0
3.5
4.0
4.5
5.0
Energyduty,MJ/kgCO2
Split fraction
Reboiler duty
Condenser duty
Total duty
Rich solvent split
Less solid
formation
Results and Discussion
Inter-heating process
CO2 lean
Inter-heating
Heat exchanger
Stripper
Rich/lean
Heat exchanger
CO2 lean
to absorber
CO2 rich
from absorber
Steam
Reboiler
Condenser
CO2 product
Pump
Pump
Cooling water Cooling water
Drum
Cooler
0 2 4 6 8 10 12 14 16
132
134
136
138
140
142
144
146
Temperature,oC
Stage number
Reference stripper
Inter-heated stripper
Inter-heating stage 5
Inter-heating
0
500
1000
1500
2000
2500
3000
3500
4000
4500
Inter-heated stripper
Heatrequirement,kJ/kgCO2
Reference stripper
Heat of vaporisation
Sensible heat
Heat of CO2 desorption
Results and Discussion
Combined rich split and inter-heating
CO2 lean
Inter-heating
heat exchanger
Stripper
Rich/lean
Heat exchanger
CO2 lean
to absorber
CO2 rich
from absorber
Steam
Reboiler
Condenser
CO2 product
Pump
Pump
Cooling water
Cooling water
Split
Un-split
Stripper
Steam
Reboiler
Condenser
Pump
CO2 Rich
from absorber
CO2 Lean
to absorber
CO2 product
Split
Unsplit
Cooling water
Pump
Cooler
Condensate
Cooler
Rich/lean
Heat exchanger
Inter-heating
heat exchanger
(a) Inter-heating integrated rich-split process (b) Inter-heating integrated cold rich bypasss
Drum
Drum
0
0.5
1
1.5
2
2.5
3
3.5
Reference Rich split Inter-heating Inter-heating &
rich-split
Reboiler/Condenserduty,GJ/tonCO2
Reboiler duty
Condenser duty24.8%
83.4%
CO2
Stripper
Steam
CO2Compressor
For transport &
storage
Reboiler
Condenser
Cooler 3
Cooler 2
Cooler 1
Blower 1
Pump 2
Chiller
Heater
Pretreatment
Wash
Heat
Exchanger 1
Heat
Exchanger 2
Pump 1 Pump 3 Pump 5
CO2
absorber
Stage-1
Stage-2
Clean gas
Mixer
H2O and NH3
Makeup
H2O makeup
NH3 recycle &
SO2 removal unit
CO2 compressorCO2 capture unit
CO2 Rich
CO2 Lean
NH3 Rich
NH3 Lean
Water Separation
Unit
CO2 product
Pump 4
Split 1
Split 2
Heat
Exchanger 3
Blower 2
Hot flue
gas with
SO2
Water make-up
and disposal
Recovery of
sulfur
Results and Discussion
 Techno-economic assessment of an advanced aqueous ammonia-based CO2
capture technology for a 650 MW coal fired power station, 38.9% net efficiency
U.S. Energy Information Administration, 2013. Updated capital cost estimates for utility scale electricity generating plants
Results and Discussion
Main design parameters
Columns Packing material Packing height Actual column size
CO2 absorber
stage 1 Mellapak-250Y 15m
D=12m; H=26.5m
stage 2 Mellapak-250Y 5m
CO2 stripper Mellapak-250Y 8m D=6.8m;H=10.75m
NH3 washing column Mellapak-500Y 10m D=10m; H=13.25m
Pretreatment column Mellapak-500Y 15m D=10m; H=19.5m
Temperature
°C
Pressure
bar
Total mass flow-rate
Tonne/h
CO2 flow-rate
Tonne/h
Composition, vol/%
CO2 H2O O2 N2
120 1.01 3180 560 10.7 6.0 7.8 75.5
Flue gas properties from power station
Simulation conditions of each column in one process train (4 trains for the whole power station)
 Techno-economic assessment
Results and Discussion
Pulverised black coal
no CO2, no SO2
Pulverised black coal
with MEA CO2 + SO2
Pulverised black coal
with NH3 CO2 + SO2
Powerplantoutputefficiency,%
0
10
20
30
40 38.9%
28.3%
31.3%
 Techno-economic assessment
Pulverised black coal
no CO2, no SO2
Pulverised black coal
with MEA CO2 + SO2
Pulverised black coal
with NH3 CO2 + SO2
Levelisedcostofelectricity,2013US$/MWh
0
20
40
60
80
100
120
140
66
131
110
Conclusions
1. Development of a rigorous rate-based model for the SO2—NH3—CO2—H2O
system
2. Development of an advanced aqueous NH3 based capture process which
incorporates new features including combined SO2 removal and NH3 recycle,
staged absorption and new stripper configurations
3. Technical and economic assessment has shown the advanced process
consumes less energy and reduce capture costs significantly compared to a
reference MEA process
Future research
 Pilot plant trials of the advanced NH3 process to confirm the benefits
 Integration of the capture process with an Australian Power Station
including heat integration to reduce cooling duty
 Integration of SO2 removal, ammonium sulphate fertiliser production
and CO2 capture
 Environmental impact of the capture process including proper
dispersion through the stack
 Economic assessment of the capture process under Australian
conditions
Acknowledgments
o Dr Leigh Wardhaugh, Dr Paul Feron, Dr Merched Azzi, Dr Graeme Puxty, Dr
Will Conway @ CSIRO
o Lichun Li, Prof Marcel Maeder, Dr Robert Burns @ Newcastle University
o Prof Moses Tade @ Curtin University
o Dr Qunyang Xiang, Prof Mengxiang Fang @ Zhejiang University
o Dr Jingwen Yu, Ruize Lu, A/Prof Shujuan Wang, Prof Jian Chen @Tsinghua
University
o Dr Nan Yang, Prof Dongyao Xu @ China University of Mining and Technology
(Beijing)
The authors wish to acknowledge financial assistance provided through both CSIRO Energy and Australian
National Low Emissions Coal Research and Development (ANLEC R&D). ANLEC R&D is supported by Australian
Coal Association Low Emissions Technology Limited and the Australian Government through the Clean Energy
Initiative. The views expressed herein are not necessarily the views of the Commonwealth, and the
Commonwealth does not accept responsibility for any information or advice contained herein.
Publications
1. ANLEC R&D reports
http://www.anlecrd.com.au/projects/development-of-the-advanced-
aqueous-ammonia-based-post-combustion-capture-technology
2. Journal publications
1. Li et al, Techno-economic assessment of an advanced aqueous ammonia-based post-combustion capture process
integrated with a 650-MW coal-fired power station, Environmental Science &Technology, 2016, 50, 10746-10755.
2. Yu et al, Experimental studies and rate-based simulations of CO2 absorption with aqueous ammonia and piperazine
blended solutions, International Journal of Greenhouse Gas Control, 2016, 50, 135-146.
3. Li et al, Technical and Energy Performance of an Advanced, Aqueous Ammonia-Based CO2 Capture Technology for a
500 MW Coal-Fired Power Station, Environmental Science &Technology, 2015, 49, 10243-10252.
4. Li et al, Rate-based modelling of combined SO2 removal and NH3 recycling integrated with an aqueous NH3-based
CO2 capture process. Applied Energy, 2015, 148, 66-77.
5. Fang et al, Experimental study on CO2 absorption by aqueous ammonia solution at elevated pressure to enhance
CO2 absorption and suppress ammonia vaporization, Greenhouse Gases: Science and Technology, 2015, 5, 210-
221.
6. Li, et al, The Effect of piperazine (PZ) on CO2 absorption kinetics into aqueous ammonia solutions at 25.0oC,
International Journal of Greenhouse Gas Control, 2015, 36, 135-143.
7. Yu et al, Modelling analysis of solid precipitation in an ammonia-based CO2 capture process, International Journal of
Greenhouse Gas Control, 2014, 28, 133-9.
8. Li et al, Process modeling of an advanced NH3 abatement and recycling technology in the Ammonia-based CO2
capture process. Environmental Science & Technology, 2014, 48, 7179–7186.
9. Yang et al, Potassium sarcosinate promoted Aqueous ammonia solution for post-combustion capture of CO2,
Greenhouse Gases: Science and Technology, 2014, 4, 555-567.
Thank you
Hai Yu
Senior Research Scientist
CSIRO Energy
t +61 2 4960 6021
e hai.yu@csiro.au
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Development of an aqueous ammonia-based post-combustion capture technology for Australian conditions

  • 1. Development of an aqueous ammonia-based post- combustion capture technology for Australian conditions Webinar – Thursday, 13 October 2016
  • 2.  Dr Yu is a senior research scientist at CSIRO Energy. He was awarded a PhD in Chemical Engineering from the University of Newcastle, Australia in 2004.  Since 2000, he has dedicated himself to research on clean energy technologies and environmental protection, including development of technologies for utilisation of synthetic greenhouse gases and post combustion CO2 capture.  He was lead researcher for the pilot plant demonstration of an aqueous ammonia-based post-combustion capture process in Australia, and the project leader for a number of projects which are aimed to advance the aqueous ammonia-based CO2 capture technology for application in Australia. Senior Research Scientist, CSIRO Energy Dr Hai Yu
  • 3.  Dr Li is a postdoctoral research scientist at CSIRO Energy. He was awarded a PhD in Chemical Engineering from Curtin University of Technology in 2016.  His research focuses on post combustion CO2 capture technology and energy harvesting from CO2 capture.  He participated in the development of an advanced aqueous- ammonia based CO2 capture process which was funded by ANLEC R&D, focusing on Aspen process modelling and techno-economic assessment. Postdoctoral Research Scientist, CSIRO Energy Dr Kangkang Li
  • 4. QUESTIONS  We will collect questions during the presentation.  Your Webinar Host will pose these question to the presenters after the presentation.  Please submit your questions directly into the GoToWebinar control panel. .
  • 5. ANLEC R&D is a not-for-profit agency, funded by the Australian Government Department Industry, Innovation and Science through the National Low Emissions Coal Initiative, and by the ACA Low Emissions Technologies Ltd (ACALET) through the COAL21 Fund. Enabling research to reduce greenhouse emissions from coal technologies Australian National Low Emissions Coal Research & Development ANLEC R&D is an Australian National Research Initiative to support Carbon Capture and Storage (CCS) deployment in Australia. $100M+ Invested In one of the largest partnerships, the Australian Coal Industry and the Australian Government has deployed a research effort in over 25 institutions nationwide since 2010. Our present focus supports CO2 storage across 3 Australian geological basins: Surat Basin, Gippsland Basin, Perth Basin ANLEC R&D funded this project to test concepts that might further reduce the cost of post combustion capture using advanced aqueous ammonia solutions For more information please visit www.anlecrd.com.au
  • 6. Development of an advanced aqueous-ammonia based post- combustion capture technology for Australian Conditions 13 October 2016 CSIRO Energy Hai Yu and Kangkang Li
  • 7. Outline of Presentation o Research Background o Project Objectives o Approaches and Methodology o Results and Discussion o Conclusions and Future Work
  • 8. Levelisedcostofelectricity AUD/MWh 0 20 40 60 80 100 120 140 160 180 Capital O&M Fuel CO2 T&S Pulverised black coal no CCS Pulverised black coal MEA CCS Project background – global state of the art in PCC The state of the art PCC technology is based on amine solutions o Costs are high, in particular, capital cost in Australian content o Environmental concerns EPRI, Australian Electricity Generation Technology Costs-Reference Case 2010 Levelisedcostofelectricity AUD/MWh 0 20 40 60 80 100 120 140 160 180 Capital O&M Fuel CO2 T&S Pulverised black coal no CCS, no SOx Pulverised black coal amine CCS + SOx CO2CRC, et al, Australian Power Generation Technology Report 2015
  • 9. PCC Pilot plants Research & Development Delta Electricity AGL Loy Yang Power China Huaneng (Beijing) Stanwell Novel amines Novel processes & equipment Adsorbents Environmental impacts Learning by doing Learning by searching Membranes China Huaneng (Changchun) Project background – CSIRO PCC research program
  • 10. Lean Solvent Rich Solvent CO2 Flue gas in Flue gas out Absorber Stripper 2HOC2H4NH2 + CO2  HOC2H4NHCOO- + HOC2H4NH3 + (MEA) (Carbamate) NH3 + H2O + CO2 { NH4 + + HCO3 - (bicarbonate) NH4 ++NH2COO- (carbamate) NH4 + + CO3 2- (carbonate) }  NH4HCO3 (NH4)2CO3 NH2COONH4 Solid precipitation Project background – Ammonia based PCC process
  • 11. Project background – Ammonia based PCC process • Alstom Power – Chilled ammonia process • CSIRO, Powerspan and Korean Research Institute of Industrial Science & Technology – Warm ammonia process
  • 12. Project background – Ammonia PCC development in CSIRO Trialing a basic process at Munmorah Power Station 10 1 2185 FLUE4 10 1 5957 LEAN-INP 27 1 1830OFF-GAS 29 1 6312 RICH 107 5 6312 RICH2 45 5 113 RECYCLE 130 5 5921 LEAN1 106 5 504 TOP 29 5 6312RICH1 39 5 5921LEAN2 11 1 1756 VENT1 115 1 1756 VENT2 125 1 2272 FLUE 45 1 2272FLUE1 10 1 5853WASHWA 16 1 5927WASH1 45 5 391 PRODUCT 16 1 2192 FLUE3 10 1 6 CONDEN 45 1 2272 6 96 1 2272 FLUE2 30 1 27WATER -50 10 9NH3 40 1 59213 16 1 5927 16 1 5927 1 26 1 5853 30 1 0 30 1 0 31 1 6007 31 1 6007 31 1 6007WASH2 31 1 5853 13 31 1 154 31 1 5853 ABSORBER QC=0.0 QR=0.0 STRIPPER QC=0.0 QR=307.0 PUMP W=1.9 LIQHX2 LIQHX1 Q=-624.8 GASHX1 Q=53.0 GASHX2 Q=-53.0 SCRUBER QC=0.0 QR=0.0 CONDENSE Q=-77.0 GASCOOL2 Q=-8.3 BLOWER W=33.6 LIQCOOL Q=-197.9 WPUMP W=0.1 Q=-108.8 WCOOLER1 Q=0.0 B5 W=0.0 B6W=0.0 B7 B8 B10 Q=-33.9 B1 Q=0.0 B3 Q=0.0 B4 Q=0.0 Temperature (C) Pressure (bar) Mass Flow Rate (kg/hr) Q Duty (kW) W Power(kW) 17 B11 Q=0.0 16 1 592718 Initial Research 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Further development Trialing an advanced process at Vales Point Power Station
  • 13.  Low cost, robust, more benign than other amines  High CO2 loading capacity  Low regeneration energy and production of high pressure CO2  Potential to remove multi-components (SOx, NOx and CO2) simultaneously and produce value added products  Established technology Project background – Ammonia based PCC process Advantages Areas for improvement  Relatively low CO2 absorption rate compared to amine based solvent  Relatively high ammonia loss at high CO2 absorption rate.  Formation of ammonium-bicarbonate solids  The available process simulation models were insufficient to support the process optimisation and scale up
  • 14. Project Objectives 1. Develop a novel aqueous ammonia based solvent which has fast CO2 absorption rate equivalent to MEA while maintaining a low regeneration energy requirement. 2. Further advance the combined SO2 removal and ammonia recovery technology to eliminate additional FGD, reduce the ammonia slip in the exiting flue gas to acceptable levels and produce a value added fertiliser, i.e. ammonium sulphate. 3. Further develop CSIRO high pressure absorption to enhance CO2 absorption, reduce ammonia loss and cooling water consumption. 4. Develop and validate a rigorous rate based model for the capture process and identify new process configurations to achieve further savings on capture costs. Ultimately, develop a process which can reduce 1. investment and running cost in the Australian context. 2. potential environmental risks resulting from the implementation of PCC technologies.
  • 15. Approaches and Methodology CO2 Stripper Steam Reboiler Condenser Pretreatment Washing Heat Exchanger CO2 absorber Flue gas Clean gas NH3 recycle unitPower station CO2 capture unit CO2 product Combined removal  Additives  High pressure absorption  Staged absorption- recycling solvent Stripper configurations Rich split Inter-heating Rate-based process model Approaches
  • 16. Approach and Methodology 2 Process model Methodology 1 Experimental, pilot plant and bench scale facilities A rigorous, rate-based model using Aspen Plus RateSep was used to determine technical performance of the process improvements 3 Cost model 1 Capital cost 2 Operating & maintenance (O&M) cost including electricity cost, fixed cost and cooling water Aspen Capital Cost Estimator for calculation of cost of each equipment  Size of equipment, column, packing, pump, etc.  Cooling water consumption  Energy consumption including power loss due to steam extraction
  • 17.  Development and validation of a rate-based model for the system of NH3-CO2-SO2-H2O • Pitzer based thermodynamic model • RateSep module, a rate-based absorption and stripping unit operation model • Two-film theory; • Mass and heat transfer resistances; • Liquid film is discretized into multiple film segments; • Film segments near the interface are much thinner Interface XCO2 int Tint YCO2 int TV YCO2 bulk Vapour film Liquid film Vapour bulk phase Liquid bulk phase Mass and heat transfer TL XCO2 bulk CO2 NH3 H2O N2 2NH COO 3HCO 2 3CO  4NH OH 3H O 3NH 2 2CO SO 2H O SO2 O 2 3SO  3HSO 2 2 5S O  Results and Discussion
  • 18. Results and Discussion  Model development of NH3-CO2-SO2-H2O Equilibrium reactions No. Reaction Equilibrium parameter A B C D 1 NH3 + H2O <--> NH4 + + OH- -1.2566 -3335.7 1.497 -0.0370 2 2H2O <--> H3O+ + OH- 132.899 -13445.9 -22.477 0 3 HCO3 - + H2O <--> CO3 2- + H3O+ 216.049 -12431.7 -35.481 0 4 H2O + HSO3 - <--> H3O+ + SO3 2- -25.290 1333.400 0 0 5 2H2O + SO2 <--> H3O+ + HSO3 - -5.978673 637.395 0 0 6 NH4HCO3(S) <--> NH4 + + HCO3 - 8.064 -5013.759 0 0 7 (NH4)2SO3(S) <--> 2 NH4 + + SO3 2- Compute from Gibbs Energies built in Aspen 8 (NH4)2SO3(S)`H2O<--> 2 NH4 + + SO3 2- +H2O Compute from Gibbs Energies built in Aspen Kinetic reactions No. Reaction Kinetic factor k E(cal/mol) 1 CO2 + OH- --> HCO3 - 4.32e+13 13249 2 HCO3 - --> CO2 + OH- 2.38e+17 29451 3 NH3 + CO2 + H2O --> NH2COO- + H3O+ 1.35e+11 11585 4 NH2COO- + H3O+ --> NH3 + CO2 + H2O 4.75e+20 16529 Equilibrium Kinetic
  • 19. Results and Discussion  Model validation of NH3-CO2-SO2-H2O : thermodynamic  Comparison between experimental and simulation results CO2 partial pressure Total pressure Species profile Solution pH
  • 20. Results and Discussion  Model validation of NH3-CO2-SO2-H2O : Kinetic (1) – CO2 absorption by NH3 Average relative error for CO2 absorption rate: ±6% Simulation results vs pilot plant results Average relative error for NH3 loss rate: ±11%
  • 21. Results and Discussion  Model validation of NH3-CO2-SO2-H2O : Kinetic (2) – SO2 removal by NH3 08:24 09:36 10:48 12:00 13:12 14:24 15:36 0 2 4 6 8 10 12 1.8kg/hr NH3 1.0kg/hr NH3 0.5kg/hr NH3 0.2kg/hr NH3 Time Simu. Water (a) Expt. pH SO2concentration/ppmv Time Expt.(b) 08:24 09:36 10:48 12:00 13:12 14:24 15:36 0 50 100 150 200 250 Simu. 1.8kg/hr NH3 1.0kg/hr NH3 0.5kg/hr NH3 0.2kg/hr NH3 Water 0 100 200 300 400 500 1.8kg/hr NH3 1.0kg/hr NH3 0.5kg/hr NH3 0.2kg/hr NH3 Water Expt. NH3concentration/ppmv Time 08:24 09:36 10:48 12:00 13:12 14:24 15:36 Simu.(c) Comparison of pilot plant data with simulation results pH of water Gas outlet SO2 concentration Gas outlet NH3 concentration
  • 22. Results and Discussion  Process design (1): novel process for removal SO2 and CO2 and recovery of NH3 Pump Chiller Heater Pretreatment Washing Heat Exchanger Pump CO2 absorber Vent gas SO2 Recovery SO2 fertilizer Water makeup CO2 rich CO2 lean Flue gas NH3 rich NH3 lean Coal-fired Power Station SO2 Removal and NH3 Recycling Process Typical CO2 Capture Process Flowrate, 760kg/h T = 120oC CO2: 10.7 SO2: 200ppm H2O: 6.0 Flowrate, 656kg/h T = 16.9 oC CO2: 3.23 NH3: 1.2 SO2: 0ppm H2O: 1.8 T= 10oC Hot
  • 23. Results and Discussion  Rate based modeling results of SO2 removal and NH3 recovery 0 50 100 150 200 250 300 350 0 20 40 60 80 100 SO2 capture efficiency Outlet SO2 concentration Number of cycles SO2captureefficiency/% 0 10 20 30 40 50 60 70 OutletSO2concentration/ppbv 0 50 100 150 200 250 300 350 0 10 20 30 40 (NH4)2S2O5 NH4HSO3 Mass/% Number of cycles (NH4)2SO3 0 50 100 150 200 250 300 350 0 20 40 60 80 100 NH3 for SO2 capture NH3reuseefficiency,% Number of cycles NH3 recycle to CO2 absorber 0 5 10 15 20 25 Vent gas NH3 NH3concentration,ppmv >99% SO2 removal >99% NH3 reuse (NH4)2SO3 Low energy consumption
  • 24. Results and Discussion  Process design (2): Staged-absorption Staged Absorption Configuration Inter-cooling to 25 oC CO2 absorption NH3 mitigation Benefit: >50% NH3 reduction
  • 25. Results and Discussion CO2 lean Rich/lean Heat exchanger Stripper Steam Reboiler Condenser CO2 product Pump Cooler Cooling water CO2 rich from absorber CO2 lean to absorber Cooling water Drum CO2 Stripper Steam Reboiler Condenser Rich/lean Heat exchanger Pump CO2 Rich from absorber CO2 Lean to absorber CO2 product Split unsplit Cooling water Cooling water Drum Cooler Rich split CO2 lean Inter-heating Heat exchanger Stripper Rich/lean Heat exchanger CO2 lean to absorber CO2 rich from absorber Steam Reboiler Condenser CO2 product Pump Pump Cooling water Cooling water Drum Cooler Inter-heating Reference  Process design (3): advanced stripper configurations
  • 26. Results and Discussion Base case study 500 MW power station, three process trains with each to capture 1 MT CO2 CO2 regeneration rate =118.4 Tonne/h NH3 = 6.8% CO2 loading lean =0.25 CO2 loading rich = 0.42 Solvent T at inlet of absorber = 25oC Solvent T at inlet of heat exchanger = 40oC T difference = 10oC Stripper P =10 bar Stripper bottom T = 145.5oC CO2 lean Rich/lean Heat exchanger Stripper Steam Reboiler Condenser CO2 product Pump Cooler Cooling water CO2 rich from absorber CO2 lean to absorber Cooling water Drum Item Value Stripper column Diameter = 6.8 m and Height = 10.75 m, Mellapack 250Y Reboiler duty 3.2 GJ/Tonne CO2 Condenser duty 1.5 GJ/Tonne CO2
  • 27. Results and Discussion Rich split process CO2 Stripper Steam Reboiler Condenser Rich/lean Heat exchanger Pump CO2 Rich from absorber CO2 Lean to absorber CO2 product Split unsplit Cooling water Cooling water Drum Cooler 0.00 0.02 0.04 0.06 0.08 0.10 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 Heatrequirement,MJ/kgCO2 Split fraction Heat of CO2 desorption Heat of vaporization Sensible heat 0.00 0.02 0.04 0.06 0.08 0.10 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 Energyduty,MJ/kgCO2 Split fraction Reboiler duty Condenser duty Total duty Rich solvent split Less solid formation
  • 28. Results and Discussion Inter-heating process CO2 lean Inter-heating Heat exchanger Stripper Rich/lean Heat exchanger CO2 lean to absorber CO2 rich from absorber Steam Reboiler Condenser CO2 product Pump Pump Cooling water Cooling water Drum Cooler 0 2 4 6 8 10 12 14 16 132 134 136 138 140 142 144 146 Temperature,oC Stage number Reference stripper Inter-heated stripper Inter-heating stage 5 Inter-heating 0 500 1000 1500 2000 2500 3000 3500 4000 4500 Inter-heated stripper Heatrequirement,kJ/kgCO2 Reference stripper Heat of vaporisation Sensible heat Heat of CO2 desorption
  • 29. Results and Discussion Combined rich split and inter-heating CO2 lean Inter-heating heat exchanger Stripper Rich/lean Heat exchanger CO2 lean to absorber CO2 rich from absorber Steam Reboiler Condenser CO2 product Pump Pump Cooling water Cooling water Split Un-split Stripper Steam Reboiler Condenser Pump CO2 Rich from absorber CO2 Lean to absorber CO2 product Split Unsplit Cooling water Pump Cooler Condensate Cooler Rich/lean Heat exchanger Inter-heating heat exchanger (a) Inter-heating integrated rich-split process (b) Inter-heating integrated cold rich bypasss Drum Drum 0 0.5 1 1.5 2 2.5 3 3.5 Reference Rich split Inter-heating Inter-heating & rich-split Reboiler/Condenserduty,GJ/tonCO2 Reboiler duty Condenser duty24.8% 83.4%
  • 30. CO2 Stripper Steam CO2Compressor For transport & storage Reboiler Condenser Cooler 3 Cooler 2 Cooler 1 Blower 1 Pump 2 Chiller Heater Pretreatment Wash Heat Exchanger 1 Heat Exchanger 2 Pump 1 Pump 3 Pump 5 CO2 absorber Stage-1 Stage-2 Clean gas Mixer H2O and NH3 Makeup H2O makeup NH3 recycle & SO2 removal unit CO2 compressorCO2 capture unit CO2 Rich CO2 Lean NH3 Rich NH3 Lean Water Separation Unit CO2 product Pump 4 Split 1 Split 2 Heat Exchanger 3 Blower 2 Hot flue gas with SO2 Water make-up and disposal Recovery of sulfur Results and Discussion  Techno-economic assessment of an advanced aqueous ammonia-based CO2 capture technology for a 650 MW coal fired power station, 38.9% net efficiency U.S. Energy Information Administration, 2013. Updated capital cost estimates for utility scale electricity generating plants
  • 31. Results and Discussion Main design parameters Columns Packing material Packing height Actual column size CO2 absorber stage 1 Mellapak-250Y 15m D=12m; H=26.5m stage 2 Mellapak-250Y 5m CO2 stripper Mellapak-250Y 8m D=6.8m;H=10.75m NH3 washing column Mellapak-500Y 10m D=10m; H=13.25m Pretreatment column Mellapak-500Y 15m D=10m; H=19.5m Temperature °C Pressure bar Total mass flow-rate Tonne/h CO2 flow-rate Tonne/h Composition, vol/% CO2 H2O O2 N2 120 1.01 3180 560 10.7 6.0 7.8 75.5 Flue gas properties from power station Simulation conditions of each column in one process train (4 trains for the whole power station)  Techno-economic assessment
  • 32. Results and Discussion Pulverised black coal no CO2, no SO2 Pulverised black coal with MEA CO2 + SO2 Pulverised black coal with NH3 CO2 + SO2 Powerplantoutputefficiency,% 0 10 20 30 40 38.9% 28.3% 31.3%  Techno-economic assessment Pulverised black coal no CO2, no SO2 Pulverised black coal with MEA CO2 + SO2 Pulverised black coal with NH3 CO2 + SO2 Levelisedcostofelectricity,2013US$/MWh 0 20 40 60 80 100 120 140 66 131 110
  • 33. Conclusions 1. Development of a rigorous rate-based model for the SO2—NH3—CO2—H2O system 2. Development of an advanced aqueous NH3 based capture process which incorporates new features including combined SO2 removal and NH3 recycle, staged absorption and new stripper configurations 3. Technical and economic assessment has shown the advanced process consumes less energy and reduce capture costs significantly compared to a reference MEA process
  • 34. Future research  Pilot plant trials of the advanced NH3 process to confirm the benefits  Integration of the capture process with an Australian Power Station including heat integration to reduce cooling duty  Integration of SO2 removal, ammonium sulphate fertiliser production and CO2 capture  Environmental impact of the capture process including proper dispersion through the stack  Economic assessment of the capture process under Australian conditions
  • 35. Acknowledgments o Dr Leigh Wardhaugh, Dr Paul Feron, Dr Merched Azzi, Dr Graeme Puxty, Dr Will Conway @ CSIRO o Lichun Li, Prof Marcel Maeder, Dr Robert Burns @ Newcastle University o Prof Moses Tade @ Curtin University o Dr Qunyang Xiang, Prof Mengxiang Fang @ Zhejiang University o Dr Jingwen Yu, Ruize Lu, A/Prof Shujuan Wang, Prof Jian Chen @Tsinghua University o Dr Nan Yang, Prof Dongyao Xu @ China University of Mining and Technology (Beijing) The authors wish to acknowledge financial assistance provided through both CSIRO Energy and Australian National Low Emissions Coal Research and Development (ANLEC R&D). ANLEC R&D is supported by Australian Coal Association Low Emissions Technology Limited and the Australian Government through the Clean Energy Initiative. The views expressed herein are not necessarily the views of the Commonwealth, and the Commonwealth does not accept responsibility for any information or advice contained herein.
  • 36. Publications 1. ANLEC R&D reports http://www.anlecrd.com.au/projects/development-of-the-advanced- aqueous-ammonia-based-post-combustion-capture-technology 2. Journal publications 1. Li et al, Techno-economic assessment of an advanced aqueous ammonia-based post-combustion capture process integrated with a 650-MW coal-fired power station, Environmental Science &Technology, 2016, 50, 10746-10755. 2. Yu et al, Experimental studies and rate-based simulations of CO2 absorption with aqueous ammonia and piperazine blended solutions, International Journal of Greenhouse Gas Control, 2016, 50, 135-146. 3. Li et al, Technical and Energy Performance of an Advanced, Aqueous Ammonia-Based CO2 Capture Technology for a 500 MW Coal-Fired Power Station, Environmental Science &Technology, 2015, 49, 10243-10252. 4. Li et al, Rate-based modelling of combined SO2 removal and NH3 recycling integrated with an aqueous NH3-based CO2 capture process. Applied Energy, 2015, 148, 66-77. 5. Fang et al, Experimental study on CO2 absorption by aqueous ammonia solution at elevated pressure to enhance CO2 absorption and suppress ammonia vaporization, Greenhouse Gases: Science and Technology, 2015, 5, 210- 221. 6. Li, et al, The Effect of piperazine (PZ) on CO2 absorption kinetics into aqueous ammonia solutions at 25.0oC, International Journal of Greenhouse Gas Control, 2015, 36, 135-143. 7. Yu et al, Modelling analysis of solid precipitation in an ammonia-based CO2 capture process, International Journal of Greenhouse Gas Control, 2014, 28, 133-9. 8. Li et al, Process modeling of an advanced NH3 abatement and recycling technology in the Ammonia-based CO2 capture process. Environmental Science & Technology, 2014, 48, 7179–7186. 9. Yang et al, Potassium sarcosinate promoted Aqueous ammonia solution for post-combustion capture of CO2, Greenhouse Gases: Science and Technology, 2014, 4, 555-567.
  • 37. Thank you Hai Yu Senior Research Scientist CSIRO Energy t +61 2 4960 6021 e hai.yu@csiro.au
  • 38. QUESTIONS / DISCUSSION Please submit your questions in English directly into the GoToWebinar control panel.
  • 39. Please submit any feedback to: webinar@globalccsinstitute.com

Editor's Notes

  1. For ammonia, advantages include: supported by our pilot plant trials
  2. Firstly we need to determine the technical parameters of the process. We used a rate-based model for this purpose. for example, determine the column size, packing height, heat exchanger size. etc. --- capital cost Cooling water consumption, energy consumption- steam, electricity. Steam consumption needs to be converted to electricity.
  3. Describe reaction sets
  4. Analyze process improvement and describe the benefits Start from combined removal
  5. In this talk, I would like to present some of process improvements in the stripping process (solvent regeneration part). The rich solvent will be heated in the desorber/stripper to produce CO2 product and itself is regenerated. The energy for solvent regeneration come from steam extracted from the power station. So less steam is available for power generation which reduces power output. 25-30% of the output of the power station is lost due to the steam extraction and electivity to run pump, blower etc. Three components of the regeneration energy
  6. Less vapor is wasted and at the same time also cooling duty. Split ratio is fraction of liquid split from the rich solvent. 0.05 can have a total duty consumption. Regeneration energy decreased from 3.2 to 2.9 GJ/ton co2. 1.5 to 0.4.
  7. Inter heating configuration involves the exchange of heat between lean solvent and semi lean solvent. This approach can change the temperature file in the stripper.. We divided stripper to 15 stages. Bottom is stripper and top is condenser. Rich solvent was introduced from stage 5. The left one is liquid T profile in the stripper. At bottom is 145oc and inlet is 135. with implementation of inter heating, the temperature profile is changed. Inlet T is lower but the rest, T is higher. Delta is lower. Less than 9 oc. The regeneration energy decreases from 3.2 to 3.