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SELF HEALING
TECHNOLOGY FOR
FLEXIBLE PAVEMENTS
CHINTADA SAILENDRA KUMAR
NIT Calicut
https://www.linkedin.com/in/sailendra
-kumar-chintada-681283127
3/9/2020
1
INTRODUCTION
 Road network plays an major economic and social role
 Operational health of road network signifies the nation’s
economy role
 Problems
Occurrence of cracks
Cause of CO2 emissions
Traffic disruption
Pavement deterioration
More operational and
More maintenance cost
3/9/2020
2
Benefits of SELF HEALING
TECHNOLOGY
 Improve traffic flow
 Reduce CO2 emissions
 Less Maintenance cost
 Less Operational cost
 Preserving natural resources
 Extend pavement life
3/9/2020
3
Self Healing Process
 It is ability to Restore its stiffness and strength by closing
micro cracks.
 It can be enhanced by adding a modifier
 It mainly consists of three steps
1. Wetting of the faces of two micro cracks
2. Diffusion of molecules from one face to the other.
3. Randomization of the diffused molecules
 These steps of process often termed as “Reversible
Hydrogen bonding”
3/9/2020
4
Self Healing Process
Time and Temperature dependent
It is a viscosity driven process
Schematic Representation of reversible
Hydrogen bonding
3/9/2020
5
 Necessary conditions for Self healing agents
1. Good compatibility with bitumen
2. High temperature stability
3. Ability to survive mixing and construction conditions
4. Healing temperatures between 30℃ and 40℃
5. Capable of continuous/multi-time healing
 Cracks do not heal below 20-30 mm inside
Self Healing Process
3/9/2020
6
Methods of Self-healing
 Self healing for pavements can be done in three methods:
1. Incorporation of nanoparticles
2. Induction heating
3. Rejuvenation
3/9/2020
7
Nanoparticles
 Nano clay
Have capacity to repair micro cracks in pavement
Principle:Nanoclay move towards the tip of crack by
surface energy and stops crack propagation and heal
damaged surface
used in pavement design to improve the ageing, rheological
and thermal properties of mix
Tabatabaee and shafie studied the effect of rest periods on
organo clay-modified mixes and concluded with 3% and 5%
Strain rates has increased fatigue.
3/9/2020
8
Nanoparticles
 Nano rubber
Have capacity to repair micro cracks in pavement
Rubber modifiers and polymers are used
Principle:Nano rubber move towards the tip of crack by surface
energy and stops crack propagation and heal damaged surface
can be used in pavement design to improve the and thermal
properties of mix
Conducted ductility self healing with two different types of
rubber (Nano A and Nano B) with percentages of (0-5%)
Performed on dog bone test ,cut at the centre and heal for 4h at
20-22℃ and self healing up to 70%
3/9/2020
9
Nanoparticles
 Nano rubber
Recovery can be in between 15-90%
Styrene-Butadiene-Rubber (SBR),Styrene-Isoprene-
Styrene are used.
Advantage:double role i.e.Durability & Self healing modifier
Disadvantage : of Polymer modifiers is their
thermodynamic incompatibility with the bitumen results in
variation of material density, polarity, molecular weight,
solubility between the polymer and the asphalt.
Bonding :Nano effect ,ionic and Reverse hydrogen
bonding.
3/9/2020
10
Induction Heating
 Conductive fibers and fillers can be added
 Principle: Three steps
1. Sending an alternating current through the coil
2. Generating electromagnetic field(emf) through the specimen
placed under the coil.
3. Generated emf Induces heat throughthe specimen by the
flow of Eddy currents
 Major healing mechanisms are capilary flow and diffusion of
bitumen at high temperatures.
3/9/2020
11
 Most progressive method of Self-healing reported till now
 transitioned from laboratory from site in a short time.
Induction Heating
3/9/2020
12
 Conductive fibres added to the mixture increases
Conductivity more than that of conductive fillers
 Liu studied the Induction Heating effect of steel wool and steel
fibres on asphalt pavements with equation
HI =C2/C1
where
HI =Healing Index (%)
C1 =No of loading cycles for the first time
C2 =No of loading cycles for the second time
Induction Heating
3/9/2020
13
Rejuvenation
 Rejuvenator-An engineered emulsion containing
maltenes and saturates.
 Asphalt binder - Asphaltenes + Maltenes
 Purpose: Rejuvenator is to reduce the stiffness
of oxidised asphalt binder and to flux the binder
 Self-assembled mono layer
When cracks within the surface of pavement
layer, a Rejuvenator can be applied to stop
the propagation of cracks
Life span of the pavement can be extended
3/9/2020
14
 Disadvantages:
1. applicable to the top few centimetres only
2. reduction in the surface friction of the road and it could be
harmful to the environment
Micro capsulation
Inclusion of Rejuvenator into mix via microcapsules
Principle :
 Micro cracks inside the pavement, microcapsules in the
propagation path encounter them
Rejuvenation
3/9/2020
15
The fracture energy at the tip opens the microcapsules
and releases the healing agent and then mixes with
binder to seal the crack
 Generally rejuvenators in microcapsules are aromatic oils
3/9/2020
16
Rejuvenation
Rejuvenation
3/9/2020
17
Rejuvenation
 Synthesis of micro capsules by fabrication process
 Waste cooking oil can be encapsulated as a rejuvenator
 The size of the capsule can be controlled by regulating
the core/shell ratio
 Most successful capsules have been made of a
prepolymer of melamine-formaldehyde modified as
methanol
 This approach is most favourable method for self healing
3/9/2020
18
Rejuvenation
3/9/2020
19
Evaluation of self healing capability
 Self healing capability can be investigated by fatigue test
which is complex and time consuming process
 Displacement Controlled tensile loading but Later it is
modified as Direct Tension Test (DTT).
 Fracture-Healing-Refracture test used to evaluate self healing
capacity which is done by DTT.
 Experimentally done for two types of materials
1. A standard 70/100 penetration bitumen called PBmas
2. A styrene-butadien-styrene polymer modified bitumen called
SBSmas
3/9/2020
20
Evaluation of self healing capability
 Along with DTT specimen, two types of stress
concentrated specimens are developed
Double-edge notched shaped specimen(DN)
Double-edge parabolic shaped specimen (DP)
 These two are compared with a standard DTT
specimen
3/9/2020
21
Specimen Geometrics
Special geometrics (from to
bottom : DTT,DN,DP)
ABAQUS simulation of special
geometrics (from to bottom :
DTT,DN,DP)
3/9/2020
22
 Test Procedure
Preparation: Samples are prepared in preheated silicone
rubber mould and then de-moulded after cooling
Fracture : Samples are fractured with displacement
speed of 100 mm/min
Healing : The broken pieces are placed in silicone
mould at temperatures of 10℃,20℃ and 40℃ and observe
the healing temperatures for both PBmas and SBSmas
Microscopy is used to observe the morphological change
during healing
Evaluation of self healing capability
3/9/2020
23
3/9/2020
24
Evaluation of self healing capability
• Re-fracture : Samples are Re-fractured with
displacement speed of 100 mm/min
3/9/2020
25
Self healing percentage, H =( Srefracture / Sfracture )x 100
Where
Srefracture – strength of the re-fractured sample
Sfracture – strength of the fractured sample
Evaluation of self healing capability
Conclusions
Test results of PBmas with
different geometrics at a
speed of 100 mm/min
Self healing results of the PBmas
and SBSmas at temperatures of
10℃,20℃ and 40℃
3/9/2020
26
Conclusions
Self healing master curves
of re-fracture strength at
20℃
Comparison of the crack closure
process and the strength recovery
process of both Pbmas and SBSmas
at 25℃
3/9/2020
27
Conclusions
Fluorescence microscopy of
c/s of the PBmas with different
healing times( 0,1,3,18hr)
Fluorescence microscopy of c/s of
the SBSmas with different healing
times ( 0,3,8 hr) 3/9/2020
28
Conclusions
 The healing process includes two phases
Crack closure
Strength gain
 The negative effect of the polymer modification on the self
healing capability observed
 A strength recovery master curve at any temperature can be
obtained with time-temperature superposition principle
 Finally this test procedure is able to find the self healing
capability.
3/9/2020
29
Future Research towards SHT
 Development of damage sensing and repair triggering
elements
Elements incorporated should have ability to sense the
damaged part
 Development of multiple self-healing processes
 Development of self healing assessment processes
3/9/2020
30
THANK YOU
3/9/2020
31

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Self healing technology for flexible pavements

  • 1. SELF HEALING TECHNOLOGY FOR FLEXIBLE PAVEMENTS CHINTADA SAILENDRA KUMAR NIT Calicut https://www.linkedin.com/in/sailendra -kumar-chintada-681283127 3/9/2020 1
  • 2. INTRODUCTION  Road network plays an major economic and social role  Operational health of road network signifies the nation’s economy role  Problems Occurrence of cracks Cause of CO2 emissions Traffic disruption Pavement deterioration More operational and More maintenance cost 3/9/2020 2
  • 3. Benefits of SELF HEALING TECHNOLOGY  Improve traffic flow  Reduce CO2 emissions  Less Maintenance cost  Less Operational cost  Preserving natural resources  Extend pavement life 3/9/2020 3
  • 4. Self Healing Process  It is ability to Restore its stiffness and strength by closing micro cracks.  It can be enhanced by adding a modifier  It mainly consists of three steps 1. Wetting of the faces of two micro cracks 2. Diffusion of molecules from one face to the other. 3. Randomization of the diffused molecules  These steps of process often termed as “Reversible Hydrogen bonding” 3/9/2020 4
  • 5. Self Healing Process Time and Temperature dependent It is a viscosity driven process Schematic Representation of reversible Hydrogen bonding 3/9/2020 5
  • 6.  Necessary conditions for Self healing agents 1. Good compatibility with bitumen 2. High temperature stability 3. Ability to survive mixing and construction conditions 4. Healing temperatures between 30℃ and 40℃ 5. Capable of continuous/multi-time healing  Cracks do not heal below 20-30 mm inside Self Healing Process 3/9/2020 6
  • 7. Methods of Self-healing  Self healing for pavements can be done in three methods: 1. Incorporation of nanoparticles 2. Induction heating 3. Rejuvenation 3/9/2020 7
  • 8. Nanoparticles  Nano clay Have capacity to repair micro cracks in pavement Principle:Nanoclay move towards the tip of crack by surface energy and stops crack propagation and heal damaged surface used in pavement design to improve the ageing, rheological and thermal properties of mix Tabatabaee and shafie studied the effect of rest periods on organo clay-modified mixes and concluded with 3% and 5% Strain rates has increased fatigue. 3/9/2020 8
  • 9. Nanoparticles  Nano rubber Have capacity to repair micro cracks in pavement Rubber modifiers and polymers are used Principle:Nano rubber move towards the tip of crack by surface energy and stops crack propagation and heal damaged surface can be used in pavement design to improve the and thermal properties of mix Conducted ductility self healing with two different types of rubber (Nano A and Nano B) with percentages of (0-5%) Performed on dog bone test ,cut at the centre and heal for 4h at 20-22℃ and self healing up to 70% 3/9/2020 9
  • 10. Nanoparticles  Nano rubber Recovery can be in between 15-90% Styrene-Butadiene-Rubber (SBR),Styrene-Isoprene- Styrene are used. Advantage:double role i.e.Durability & Self healing modifier Disadvantage : of Polymer modifiers is their thermodynamic incompatibility with the bitumen results in variation of material density, polarity, molecular weight, solubility between the polymer and the asphalt. Bonding :Nano effect ,ionic and Reverse hydrogen bonding. 3/9/2020 10
  • 11. Induction Heating  Conductive fibers and fillers can be added  Principle: Three steps 1. Sending an alternating current through the coil 2. Generating electromagnetic field(emf) through the specimen placed under the coil. 3. Generated emf Induces heat throughthe specimen by the flow of Eddy currents  Major healing mechanisms are capilary flow and diffusion of bitumen at high temperatures. 3/9/2020 11
  • 12.  Most progressive method of Self-healing reported till now  transitioned from laboratory from site in a short time. Induction Heating 3/9/2020 12
  • 13.  Conductive fibres added to the mixture increases Conductivity more than that of conductive fillers  Liu studied the Induction Heating effect of steel wool and steel fibres on asphalt pavements with equation HI =C2/C1 where HI =Healing Index (%) C1 =No of loading cycles for the first time C2 =No of loading cycles for the second time Induction Heating 3/9/2020 13
  • 14. Rejuvenation  Rejuvenator-An engineered emulsion containing maltenes and saturates.  Asphalt binder - Asphaltenes + Maltenes  Purpose: Rejuvenator is to reduce the stiffness of oxidised asphalt binder and to flux the binder  Self-assembled mono layer When cracks within the surface of pavement layer, a Rejuvenator can be applied to stop the propagation of cracks Life span of the pavement can be extended 3/9/2020 14
  • 15.  Disadvantages: 1. applicable to the top few centimetres only 2. reduction in the surface friction of the road and it could be harmful to the environment Micro capsulation Inclusion of Rejuvenator into mix via microcapsules Principle :  Micro cracks inside the pavement, microcapsules in the propagation path encounter them Rejuvenation 3/9/2020 15
  • 16. The fracture energy at the tip opens the microcapsules and releases the healing agent and then mixes with binder to seal the crack  Generally rejuvenators in microcapsules are aromatic oils 3/9/2020 16 Rejuvenation
  • 18. Rejuvenation  Synthesis of micro capsules by fabrication process  Waste cooking oil can be encapsulated as a rejuvenator  The size of the capsule can be controlled by regulating the core/shell ratio  Most successful capsules have been made of a prepolymer of melamine-formaldehyde modified as methanol  This approach is most favourable method for self healing 3/9/2020 18
  • 20. Evaluation of self healing capability  Self healing capability can be investigated by fatigue test which is complex and time consuming process  Displacement Controlled tensile loading but Later it is modified as Direct Tension Test (DTT).  Fracture-Healing-Refracture test used to evaluate self healing capacity which is done by DTT.  Experimentally done for two types of materials 1. A standard 70/100 penetration bitumen called PBmas 2. A styrene-butadien-styrene polymer modified bitumen called SBSmas 3/9/2020 20
  • 21. Evaluation of self healing capability  Along with DTT specimen, two types of stress concentrated specimens are developed Double-edge notched shaped specimen(DN) Double-edge parabolic shaped specimen (DP)  These two are compared with a standard DTT specimen 3/9/2020 21
  • 22. Specimen Geometrics Special geometrics (from to bottom : DTT,DN,DP) ABAQUS simulation of special geometrics (from to bottom : DTT,DN,DP) 3/9/2020 22
  • 23.  Test Procedure Preparation: Samples are prepared in preheated silicone rubber mould and then de-moulded after cooling Fracture : Samples are fractured with displacement speed of 100 mm/min Healing : The broken pieces are placed in silicone mould at temperatures of 10℃,20℃ and 40℃ and observe the healing temperatures for both PBmas and SBSmas Microscopy is used to observe the morphological change during healing Evaluation of self healing capability 3/9/2020 23
  • 24. 3/9/2020 24 Evaluation of self healing capability • Re-fracture : Samples are Re-fractured with displacement speed of 100 mm/min
  • 25. 3/9/2020 25 Self healing percentage, H =( Srefracture / Sfracture )x 100 Where Srefracture – strength of the re-fractured sample Sfracture – strength of the fractured sample Evaluation of self healing capability
  • 26. Conclusions Test results of PBmas with different geometrics at a speed of 100 mm/min Self healing results of the PBmas and SBSmas at temperatures of 10℃,20℃ and 40℃ 3/9/2020 26
  • 27. Conclusions Self healing master curves of re-fracture strength at 20℃ Comparison of the crack closure process and the strength recovery process of both Pbmas and SBSmas at 25℃ 3/9/2020 27
  • 28. Conclusions Fluorescence microscopy of c/s of the PBmas with different healing times( 0,1,3,18hr) Fluorescence microscopy of c/s of the SBSmas with different healing times ( 0,3,8 hr) 3/9/2020 28
  • 29. Conclusions  The healing process includes two phases Crack closure Strength gain  The negative effect of the polymer modification on the self healing capability observed  A strength recovery master curve at any temperature can be obtained with time-temperature superposition principle  Finally this test procedure is able to find the self healing capability. 3/9/2020 29
  • 30. Future Research towards SHT  Development of damage sensing and repair triggering elements Elements incorporated should have ability to sense the damaged part  Development of multiple self-healing processes  Development of self healing assessment processes 3/9/2020 30