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Arsenic Contamination
and Arsenicosis in Jessore
1990-2010
PRESENTED BY – AZAMU SHAHIULLAH (11146018)
BRATAKATHA NATH (11146019)
MYMUNA RASHED (11146024)
SHUVO MONDAL (12210017)
Objectives
 Arsenic – the metal
 Contaminating causes Azamu Shahiullah
 Ingesting modes
 Statistical evaluation Shuvo Mondal
 Impacts of Arsenicosis Bratakatha Nath
 Mitigation Techniques Mymuna Rashed
Arsenic
 What is Arsenic ???
 Ubiquitous element in the nature.
 Widely distributed in
Atmosphere (air)
Geosphere (Soil, Rock)
Biosphere (Plants, Animals)
Arsenic Contamination in Ground Water
Arsenic Contamination in Jessore
According to
WHO, ground
water of Jessore
contains 10 times
higher
concentration of
Arsenic than
recommended
level .
Causes of Water Contamination - Jessore
 Ground Water
 Low level water surface.
 Affected tube wells are typically
more than 20 meters and less than
100 meters deep.
 Water deeper than 100 m is exposed
to much older sediments which have
already been depleted of arsenic.
 Microbial change of sediments to
arsenic.
Surface Water
 Disposing Arsenic rich sludge.
 Using arsenic rich sludge in
Brick making.
Causes of Water Contamination - Jessor
Arsenicosis
 Arsenic poisoning.
 Drinking water rich in arsenic over a long period.
 The health effects are generally delayed.
 Carcinogenic development.
Ways of Ingestion
Drinking
Contaminated
Water
Irrigation with
Arsenic Rich
Water
85% As can
be absorbed
Ways of Ingestion
 Vegetable
Arum
(kochu) can
absorb 28%
of As.
Ways of Ingestion
Arsenic contamination in
Jessore
 Here 98% of the tube wells are found arsenic contaminated (arsenic
concentrations above the Bangladesh standard of 0.05 mg/l).
 90% of the tubewells of Samta village in Jessore are arsenic
contaminated.
 Arsenic is also found in ground water.
 Food items are also contaminated in this part of west bengal.
 Not only in water arsenic is also found in different food items.
 Arsenic contamination was detected in 211 upazilas of 59 district out of
64 in the country.
Arsenic Exposure: The alarming risk
Bangladesh is reported to be the biggest arsenic calamity in the world in
terms of the affected population.
 The people in 59 out of 64 districts comprising 126,134 km2 of
Bangladesh are suffering due to the arsenic contamination in drinking
water.
 Seventy five million people are at risk and 24 million are potentially
exposed to arsenic contamination.
The Cause of Arsenicosis in Jessore
 Arsenicosis is the effect of arsenic poisoning.
 Usually over a long period such as 5-20 years.
 Drinking Arsenic-rich water over a long period results in
various health effects including skin problems.
Health Hazards: Arsenicosis.
Accumulation of Arsenic in the body
Highest levels (ppb)
 – Nails (0.89)
 – Hair (0.18)
 – Bone (0.07 – 0.12)
 – Heart, kidney, liver, lung (0.03 – 0.05)
Stages of Arsenicosis
 Primary stage:
 Melanosis
 Keratosis
 Conjunctivitis
 Gastroentritis
 Inflammation of respiratory tract
Stages of Arsenicosis
 Secondary Stage:
 Leukomelanosis
 Hyperkeratosis
 Non-pitting edema of feet and legs
 Peripheral neuropathy
 Liver and kidney disorders
Stages of Arsenicosis
 Tertiary stage:
 Gangrene of distal organ or parts of the body
 Cancer of skin, lung and urinary bladder
 Kidney and liver failure
Impacts with Environment
 High arsenic level in crops
 Sometimes initiate death of the plants
 Arsenic toxicity in human and animals.
 Contamination of ground freshwater which affects
the availability of drinking water.
 Scarcity of irrigational water in the arsenic
contaminated region.
 Arsenic toxicity of different marine invertebrates and
plants.
Remedy /
Management
 OXIDATION
 CO-PRECIPITATION
 LIME FILTRATION
 ADSORPTION ONTO
SORPTIVE MEDIA
 ION EXCHANGE RESIN
 MEMBRANE TECHNIQUES
oxidation
In-situ Oxidation
Solar Oxidation
Ultra violet
radiation
Passive
sedimentation
Chemical
oxidation
Bashi pani : 50% reduction of As
Reduced to half on addition of ferric
acid
Addition of Potassium permanganate
One third As reduced by SORAS
Accelerate oxidation rate
Chemical OXIDATION
 Present in groundwater in As(III) and As(V) forms in different
proportions.
 Methods are effective in removing arsenic in pentavalent form
 Atmospheric oxygen, hypochloride and permanganate are
commonly used for oxidation in developing countries:
CO-
PRECIPITATION
AND ADSORPTION
Bucket Treatment
Unit (BTU)
Stevens Institute
Technology
Iron-Arsenic
removal plants
Bucket Treatment Unit (BTU)
fails to remove arsenic to the
desired level of 0.05 mg/L
DPHE-Danida Project
based on the principles of
Coagulation
Co-precipitation
Absorption processes
doses of 200 mg/L
aluminum sulfate and 2
mg/L of potassium
permanganate
Stevens Institute Technology
separate flocs
by the
processes of
sedimentation
and filtration.
BAMWSP, DFID,
WaterAid , 2001
effective in
reducing arsenic
levels to less than
0.05 mg/L in case
of 80 to 95% of
the samples
iron sulphate
and calcium
hypochloride
Iron Arsenic
removal plants
DPHE Danida
Arsenic Mitigaton
Pilot Project
Lime treatment
Quick lime
Hydrated lime
pH required 10.6 - 11.2
SorptiveFiltration Activated Alumina -
Granular Ferric Hydroxide - iron removal as pre-
treatment
Read-F Arsenic Removal Unit - (EVOH)-borne hydrous cerium
oxide (CeO2 • n H2O), is the adsorbent.
Iron Coated Sand - effective in removing both As(III) and
As(V)
Indigenous Filters - uses brick chips and inert aggregates
Cartidge Filters - operation costs of these units are high
4% caustic soda, NaOH
Ion Exchage
BAMWSP, DFID and WaterAid,
2000
By Tetrahedron Exchanger
Technology
- chlorine tablet
Promising results but not
recognised
Membrane Filtration
MRT-1000 and Reid System Ltd.
 Jago Corporation Limited
manufactured by B & T
Science Co. Limited
 tested at BUET and showed
a arsenic (III) removal
efficiency more than 80%.
Low-pressure Nanofiltration and
Reverse Osmosis
 applying low pressure by bicycle
pump
 Low recovery and low pressure
range from 0.2 to 0.7MPa.
 average ratio of arsenite to total
arsenic was found to be 0.25.
 high arsenite rejection.
NGOs Working at Jessore on Arsenic Problem
References
1. http://www.sciencedirect.com/science/article/pii/S037842740200084X
2. https://html?state=%7B%22ids%22%3A%5B%220BmVwFMkmiCfWEJkQklEZldIZGM%22%5D%2C%22action%22%3A
%22open%22%2C%22userId%22%3A%22113954926508224231135%22%7D
3. http://www.iwawaterwiki.org/xwiki/bin/view/Articles/Arsenic
4. https://secure.thebiggive.org.uk/projects/view/7750/arsenic-free-drinking-water-jessore-bangladesh
5. http://emedicine.medscape.com/article/812953-overview#a0104
6. http://www.sciencedirect.com/science/article/pii/S0013935111000739
7. Talukder, S.A., Chatterjee, A., Zheng, J., Kosmus, W., “Studies of Drinking Water Quality and Arsenic Calamity in
Groundwater of Bangladesh”, Proceedings of the International Conference on Arsenic Pollution of
Groundwater in Bangladesh: Causes, Effects and Remedies, Dhaka, Bangladesh, February 1998.
8. Khan, A.W. et. al., “Arsenic Contamination in Groundwater and Its Effect on Human Health with Particular
Reference to Bangladesh”, Journal of Preventive and Social Medicine, Vol. 16, No. 1, pp.65-73, 1997.
9. Daily Star Report, “An Urgent Call to Save a Nation”, The Daily Star, A national daily newspaper of
Bangladesh, 10 March 1999.
10. Smith, A.H., Lingas, E.O., and Rahman M., “Contamination of DrinkingWater by Arsenic in Bangladesh: a
Public Health Emergency”, Bulletin of World Health Organization, Vol. 78, No. 8, WHO, pp.1093-1103, 2000
11. Ahmad, S.A. et. al., “Arsenic Contamination in Ground Water and Arsenicosis in Bangladesh”, International
Journal of Environmental Health Research, Vol. 7, pp.271-276, 1997.
12. Biswas, B.K. et.al. “Detailed Study Report of Samta, One of the ArsenicAffected Villages of Jessore District,
Bangladesh”, Current Science, Vol. 74, pp.134-145, 1998

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Arsenic contamination and arsenicosis in jessore, bangladesh (1990 2010)

  • 1. Arsenic Contamination and Arsenicosis in Jessore 1990-2010 PRESENTED BY – AZAMU SHAHIULLAH (11146018) BRATAKATHA NATH (11146019) MYMUNA RASHED (11146024) SHUVO MONDAL (12210017)
  • 2. Objectives  Arsenic – the metal  Contaminating causes Azamu Shahiullah  Ingesting modes  Statistical evaluation Shuvo Mondal  Impacts of Arsenicosis Bratakatha Nath  Mitigation Techniques Mymuna Rashed
  • 3. Arsenic  What is Arsenic ???  Ubiquitous element in the nature.  Widely distributed in Atmosphere (air) Geosphere (Soil, Rock) Biosphere (Plants, Animals)
  • 5. Arsenic Contamination in Jessore According to WHO, ground water of Jessore contains 10 times higher concentration of Arsenic than recommended level .
  • 6. Causes of Water Contamination - Jessore  Ground Water  Low level water surface.  Affected tube wells are typically more than 20 meters and less than 100 meters deep.  Water deeper than 100 m is exposed to much older sediments which have already been depleted of arsenic.  Microbial change of sediments to arsenic.
  • 7. Surface Water  Disposing Arsenic rich sludge.  Using arsenic rich sludge in Brick making. Causes of Water Contamination - Jessor
  • 8. Arsenicosis  Arsenic poisoning.  Drinking water rich in arsenic over a long period.  The health effects are generally delayed.  Carcinogenic development.
  • 10. Irrigation with Arsenic Rich Water 85% As can be absorbed Ways of Ingestion
  • 11.  Vegetable Arum (kochu) can absorb 28% of As. Ways of Ingestion
  • 12. Arsenic contamination in Jessore  Here 98% of the tube wells are found arsenic contaminated (arsenic concentrations above the Bangladesh standard of 0.05 mg/l).  90% of the tubewells of Samta village in Jessore are arsenic contaminated.  Arsenic is also found in ground water.  Food items are also contaminated in this part of west bengal.  Not only in water arsenic is also found in different food items.  Arsenic contamination was detected in 211 upazilas of 59 district out of 64 in the country.
  • 13.
  • 14.
  • 15.
  • 16. Arsenic Exposure: The alarming risk Bangladesh is reported to be the biggest arsenic calamity in the world in terms of the affected population.  The people in 59 out of 64 districts comprising 126,134 km2 of Bangladesh are suffering due to the arsenic contamination in drinking water.  Seventy five million people are at risk and 24 million are potentially exposed to arsenic contamination.
  • 17. The Cause of Arsenicosis in Jessore  Arsenicosis is the effect of arsenic poisoning.  Usually over a long period such as 5-20 years.  Drinking Arsenic-rich water over a long period results in various health effects including skin problems.
  • 19. Accumulation of Arsenic in the body Highest levels (ppb)  – Nails (0.89)  – Hair (0.18)  – Bone (0.07 – 0.12)  – Heart, kidney, liver, lung (0.03 – 0.05)
  • 20. Stages of Arsenicosis  Primary stage:  Melanosis  Keratosis  Conjunctivitis  Gastroentritis  Inflammation of respiratory tract
  • 21. Stages of Arsenicosis  Secondary Stage:  Leukomelanosis  Hyperkeratosis  Non-pitting edema of feet and legs  Peripheral neuropathy  Liver and kidney disorders
  • 22. Stages of Arsenicosis  Tertiary stage:  Gangrene of distal organ or parts of the body  Cancer of skin, lung and urinary bladder  Kidney and liver failure
  • 23. Impacts with Environment  High arsenic level in crops  Sometimes initiate death of the plants  Arsenic toxicity in human and animals.  Contamination of ground freshwater which affects the availability of drinking water.  Scarcity of irrigational water in the arsenic contaminated region.  Arsenic toxicity of different marine invertebrates and plants.
  • 24. Remedy / Management  OXIDATION  CO-PRECIPITATION  LIME FILTRATION  ADSORPTION ONTO SORPTIVE MEDIA  ION EXCHANGE RESIN  MEMBRANE TECHNIQUES
  • 25. oxidation In-situ Oxidation Solar Oxidation Ultra violet radiation Passive sedimentation Chemical oxidation Bashi pani : 50% reduction of As Reduced to half on addition of ferric acid Addition of Potassium permanganate One third As reduced by SORAS Accelerate oxidation rate
  • 26. Chemical OXIDATION  Present in groundwater in As(III) and As(V) forms in different proportions.  Methods are effective in removing arsenic in pentavalent form  Atmospheric oxygen, hypochloride and permanganate are commonly used for oxidation in developing countries:
  • 27. CO- PRECIPITATION AND ADSORPTION Bucket Treatment Unit (BTU) Stevens Institute Technology Iron-Arsenic removal plants
  • 28. Bucket Treatment Unit (BTU) fails to remove arsenic to the desired level of 0.05 mg/L DPHE-Danida Project based on the principles of Coagulation Co-precipitation Absorption processes doses of 200 mg/L aluminum sulfate and 2 mg/L of potassium permanganate
  • 29. Stevens Institute Technology separate flocs by the processes of sedimentation and filtration. BAMWSP, DFID, WaterAid , 2001 effective in reducing arsenic levels to less than 0.05 mg/L in case of 80 to 95% of the samples iron sulphate and calcium hypochloride
  • 30.
  • 31. Iron Arsenic removal plants DPHE Danida Arsenic Mitigaton Pilot Project
  • 32. Lime treatment Quick lime Hydrated lime pH required 10.6 - 11.2
  • 33. SorptiveFiltration Activated Alumina - Granular Ferric Hydroxide - iron removal as pre- treatment Read-F Arsenic Removal Unit - (EVOH)-borne hydrous cerium oxide (CeO2 • n H2O), is the adsorbent. Iron Coated Sand - effective in removing both As(III) and As(V) Indigenous Filters - uses brick chips and inert aggregates Cartidge Filters - operation costs of these units are high 4% caustic soda, NaOH
  • 34. Ion Exchage BAMWSP, DFID and WaterAid, 2000 By Tetrahedron Exchanger Technology - chlorine tablet Promising results but not recognised
  • 35. Membrane Filtration MRT-1000 and Reid System Ltd.  Jago Corporation Limited manufactured by B & T Science Co. Limited  tested at BUET and showed a arsenic (III) removal efficiency more than 80%. Low-pressure Nanofiltration and Reverse Osmosis  applying low pressure by bicycle pump  Low recovery and low pressure range from 0.2 to 0.7MPa.  average ratio of arsenite to total arsenic was found to be 0.25.  high arsenite rejection.
  • 36. NGOs Working at Jessore on Arsenic Problem
  • 37. References 1. http://www.sciencedirect.com/science/article/pii/S037842740200084X 2. https://html?state=%7B%22ids%22%3A%5B%220BmVwFMkmiCfWEJkQklEZldIZGM%22%5D%2C%22action%22%3A %22open%22%2C%22userId%22%3A%22113954926508224231135%22%7D 3. http://www.iwawaterwiki.org/xwiki/bin/view/Articles/Arsenic 4. https://secure.thebiggive.org.uk/projects/view/7750/arsenic-free-drinking-water-jessore-bangladesh 5. http://emedicine.medscape.com/article/812953-overview#a0104 6. http://www.sciencedirect.com/science/article/pii/S0013935111000739 7. Talukder, S.A., Chatterjee, A., Zheng, J., Kosmus, W., “Studies of Drinking Water Quality and Arsenic Calamity in Groundwater of Bangladesh”, Proceedings of the International Conference on Arsenic Pollution of Groundwater in Bangladesh: Causes, Effects and Remedies, Dhaka, Bangladesh, February 1998. 8. Khan, A.W. et. al., “Arsenic Contamination in Groundwater and Its Effect on Human Health with Particular Reference to Bangladesh”, Journal of Preventive and Social Medicine, Vol. 16, No. 1, pp.65-73, 1997. 9. Daily Star Report, “An Urgent Call to Save a Nation”, The Daily Star, A national daily newspaper of Bangladesh, 10 March 1999. 10. Smith, A.H., Lingas, E.O., and Rahman M., “Contamination of DrinkingWater by Arsenic in Bangladesh: a Public Health Emergency”, Bulletin of World Health Organization, Vol. 78, No. 8, WHO, pp.1093-1103, 2000 11. Ahmad, S.A. et. al., “Arsenic Contamination in Ground Water and Arsenicosis in Bangladesh”, International Journal of Environmental Health Research, Vol. 7, pp.271-276, 1997. 12. Biswas, B.K. et.al. “Detailed Study Report of Samta, One of the ArsenicAffected Villages of Jessore District, Bangladesh”, Current Science, Vol. 74, pp.134-145, 1998

Editor's Notes

  1. Ethylenevinyl alcohol copolymer(EVOH)- Raw water having 300 µg/L of arsenic when filtered through iron coated sand becomes essentially arsenic-free. Sono 3-Kolshi Filter § Granet Home-made Filter § Chari Filter § Adarsha Filter § Shafi Filter § Bijoypur Clay/Processed Cellulose filter