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UKCCSRC Bristol, 23 October 2014 
UKCCSRC Bristol 23rd October 2014 Monitoring of the deep subsurface: leakage pathways – understanding and monitoring the mechanics of CO2 storage 
Physics of Rocks for CO2 reservoir characterisation and monitoring 
Angus Best 
Acknowledgements: 
Ismael Falcon, Laurence North, Jeremy Sothcott & Clive McCann 
National Oceanography Centre, University of Southampton Waterfront Campus, European Way, Southampton, SO14 3ZH, United Kingdom, angus.best@noc.ac.uk
UKCCSRC Bristol, 23 October 2014 
• 
Physics of rocks 
• 
DiSECCS study 
• 
Fractured rock/seismic anisotropy 
– 
Pore fluid viscosity 
– 
Sw 
• 
New CO2 rig 
• 
New acoustic pulse tube 
Outline
UKCCSRC Bristol, 23 October 2014 
• 
58 papers 
• 
Seismic attenuation /velocity dispersion 
• 
Seismic anisotropy 
• 
Geomechanics 
• 
Microstructural models 
• 
Digital rock physics 
• 
Elastic properties 
• 
Joint elastic-electrical properties 
• 
Fluids and carbonates 
• 
Reservoir characterisation and monitoring 
Physics of Rocks
UKCCSRC Bristol, 23 October 2014 
• 
Contrast reservoir styles 
– 
Sleipner (sand) 
– 
Snøhvit (sandstone) 
– 
In Salah (tight sandstone) 
DiSECCS Study & Geomechanics 
• 
Diagnostic Seismic toolbox for Efficient Control of CO2 Storage 
• 
BGS, NOC, Leeds, Edinburgh, Manchester 
• 
Statoil, BP
UKCCSRC Bristol, 23 October 2014 
• 
Scale dependent 
• 
Grain alignment 
• 
Bedding fabric 
• 
Aligned fractures 
Images from Armstrong et al. 1994 
Transverse Isotropy 
Seismic Anisotropy (In Salah example)
UKCCSRC Bristol, 23 October 2014 
• 
NOC – lab experiments 
• 
BGS – theoretical models 
Pore fluid viscosity & anisotropy in fractured rocks 
Shear wave splitting (SWS)
UKCCSRC Bristol, 23 October 2014 
Frequency dependent seismic anisotropy (Chapman Theory) 
Wave propagation at 30° to the fracture normal. 
Meso-scale fractures 
Meso-scale fractures 
Microcracks 
Microcracks 
P-waves 
S-waves 
(Chapman 2003) 
• 
Poro-visco-elastic model 
• 
Squirt flow 
• 
Attenuation 
• 
Velocity dispersion 
• 
Vertically fractured reservoirs 
• 
Multi-component seismics 
• 
Azimuthal VSPs 
• 
Fracture characterisation 
• 
Pore fluid detection
UKCCSRC Bristol, 23 October 2014 
Chapman Model 
Chapman (2003), Geophysical Prospecting, 51, 369-379.
UKCCSRC Bristol, 23 October 2014 
• 
P- & S-wave velocity and attenuation 
• 
Very accurate (± 0.3%, ± 0.1 dB/cm) 
• 
400 – 900 kHz 
• 
Effective pressure up to 65 MPa 
• 
Rotating S-wave transducer 
Ultrasonic pulse-echo system 
Best, Sothcott & McCann (2007)
UKCCSRC Bristol, 23 October 2014 
Synthetic sandstones with aligned cracks 
Leach out aluminium disks with acid 
Silica-cemented sand blocks
UKCCSRC Bristol, 23 October 2014 
Rock property 
Value 
Grain size 
120 μm 
Porosity 
30 % 
Permeability 
21 mDarcy 
Fracture density 
0.0314 ± 0.0059 
Ave fracture radius 
2.91 ± 0.06 mm 
Ave fracture aspect ratio 
0.0429 ± 0.0008 
Octagonal sandstone samples
UKCCSRC Bristol, 23 October 2014 
Model predictions 
Blank sample (no fractures) Anisotropic background 
Fractured sample 
Minimise errors in Thomsen weak anisotropy parameters: epsilon, gamma & delta 
SWS = 1.45% 
CD = 3.14% 
Tillotson et al (2014), Geophysical Prospecting, 62, 1238-1252.
UKCCSRC Bristol, 23 October 2014 
Results - pore fluid viscosity 
SWS = 4.59% (1.45% + 3.14%) 
Tillotson et al (2014), Geophysical Prospecting, 62, 1238-1252.
UKCCSRC Bristol, 23 October 2014 
Results – attenuation & Sw 
Blank 
Fractured 
Amalokwu et al (2014), Geophysical Journal International, 197, 943-947.
UKCCSRC Bristol, 23 October 2014 
New CO2 rig (Falcon, North, Best) 
• 
THMC (Thermal-Hydro- Mechanical-Chemical)
UKCCSRC Bristol, 23 October 2014 
New CO2 rig (Falcon, North, Best) 
1 
Ultrasonicpulse-echoBufferroad-topBufferroad-bottomElectrodesSampleσ3σ1Lateral strain gageAxial strain gage 
Static moduli vs Dynamic moduli
UKCCSRC Bristol, 23 October 2014 
New CO2 rig (example data) 
1
UKCCSRC Bristol, 23 October 2014 
• 
Geophysics 
• 
Seabed gas quantification 
• 
CH4 & CO2 
• 
Hydrates 
• 
P-waves 500 Hz – 10 kHz 
• 
Frequency-dependence 
• 
Samples 7 cm diameter, 50 cm long 
• 
60 MPa fluid/confining 
• 
4 to 100 degC 
• 
S-waves ~ 1 kHz 
• 
ERT 
• 
Sands, muds 
Greenhouse Gas Pulse Tube 
Sat. 5th July 2014
UKCCSRC Bristol, 23 October 2014 
Greenhouse Gas Pulse Tube a)b) c)d) 
McCann et al (2014), Geophysical Prospecting, 62, 97-116. 
1 – 10 kHz
UKCCSRC Bristol, 23 October 2014 
Acoustic Bubble Resonance 
Anderson & Hampton (1980a, b) 
Recent theoretical developments: Leighton (2007) 
Kuhs et al (2004) 
Velocity 
Attenuation 
Bubble size distributions
UKCCSRC Bristol, 23 October 2014 
• 
Need controlled lab studies to understand: 
– 
Seismic anisotropy in fractured porous rocks 
– 
Pore fluid viscosity effects 
– 
Gas saturation effects 
– 
Geomechanical response to CO2 injection 
– 
Validate theoretical models for application to reservoir characterisation & monitoring 
• 
Acoustic pulse tube studies 
– 
Seabed greenhouse gas quantification 
– 
Gas bubble resonance phenomena 
Conclusions

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Physics of Rocks for CO2 reservoir characterisation and monitoring - presentation by Angus Best of at the UKCCSRC meeting Monitoring of the deep subsurface: leakage pathways – understanding and monitoring the mechanics of CO2 storage, 23 October 2014

  • 1. UKCCSRC Bristol, 23 October 2014 UKCCSRC Bristol 23rd October 2014 Monitoring of the deep subsurface: leakage pathways – understanding and monitoring the mechanics of CO2 storage Physics of Rocks for CO2 reservoir characterisation and monitoring Angus Best Acknowledgements: Ismael Falcon, Laurence North, Jeremy Sothcott & Clive McCann National Oceanography Centre, University of Southampton Waterfront Campus, European Way, Southampton, SO14 3ZH, United Kingdom, angus.best@noc.ac.uk
  • 2. UKCCSRC Bristol, 23 October 2014 • Physics of rocks • DiSECCS study • Fractured rock/seismic anisotropy – Pore fluid viscosity – Sw • New CO2 rig • New acoustic pulse tube Outline
  • 3. UKCCSRC Bristol, 23 October 2014 • 58 papers • Seismic attenuation /velocity dispersion • Seismic anisotropy • Geomechanics • Microstructural models • Digital rock physics • Elastic properties • Joint elastic-electrical properties • Fluids and carbonates • Reservoir characterisation and monitoring Physics of Rocks
  • 4. UKCCSRC Bristol, 23 October 2014 • Contrast reservoir styles – Sleipner (sand) – Snøhvit (sandstone) – In Salah (tight sandstone) DiSECCS Study & Geomechanics • Diagnostic Seismic toolbox for Efficient Control of CO2 Storage • BGS, NOC, Leeds, Edinburgh, Manchester • Statoil, BP
  • 5. UKCCSRC Bristol, 23 October 2014 • Scale dependent • Grain alignment • Bedding fabric • Aligned fractures Images from Armstrong et al. 1994 Transverse Isotropy Seismic Anisotropy (In Salah example)
  • 6. UKCCSRC Bristol, 23 October 2014 • NOC – lab experiments • BGS – theoretical models Pore fluid viscosity & anisotropy in fractured rocks Shear wave splitting (SWS)
  • 7. UKCCSRC Bristol, 23 October 2014 Frequency dependent seismic anisotropy (Chapman Theory) Wave propagation at 30° to the fracture normal. Meso-scale fractures Meso-scale fractures Microcracks Microcracks P-waves S-waves (Chapman 2003) • Poro-visco-elastic model • Squirt flow • Attenuation • Velocity dispersion • Vertically fractured reservoirs • Multi-component seismics • Azimuthal VSPs • Fracture characterisation • Pore fluid detection
  • 8. UKCCSRC Bristol, 23 October 2014 Chapman Model Chapman (2003), Geophysical Prospecting, 51, 369-379.
  • 9. UKCCSRC Bristol, 23 October 2014 • P- & S-wave velocity and attenuation • Very accurate (± 0.3%, ± 0.1 dB/cm) • 400 – 900 kHz • Effective pressure up to 65 MPa • Rotating S-wave transducer Ultrasonic pulse-echo system Best, Sothcott & McCann (2007)
  • 10. UKCCSRC Bristol, 23 October 2014 Synthetic sandstones with aligned cracks Leach out aluminium disks with acid Silica-cemented sand blocks
  • 11. UKCCSRC Bristol, 23 October 2014 Rock property Value Grain size 120 μm Porosity 30 % Permeability 21 mDarcy Fracture density 0.0314 ± 0.0059 Ave fracture radius 2.91 ± 0.06 mm Ave fracture aspect ratio 0.0429 ± 0.0008 Octagonal sandstone samples
  • 12. UKCCSRC Bristol, 23 October 2014 Model predictions Blank sample (no fractures) Anisotropic background Fractured sample Minimise errors in Thomsen weak anisotropy parameters: epsilon, gamma & delta SWS = 1.45% CD = 3.14% Tillotson et al (2014), Geophysical Prospecting, 62, 1238-1252.
  • 13. UKCCSRC Bristol, 23 October 2014 Results - pore fluid viscosity SWS = 4.59% (1.45% + 3.14%) Tillotson et al (2014), Geophysical Prospecting, 62, 1238-1252.
  • 14. UKCCSRC Bristol, 23 October 2014 Results – attenuation & Sw Blank Fractured Amalokwu et al (2014), Geophysical Journal International, 197, 943-947.
  • 15. UKCCSRC Bristol, 23 October 2014 New CO2 rig (Falcon, North, Best) • THMC (Thermal-Hydro- Mechanical-Chemical)
  • 16. UKCCSRC Bristol, 23 October 2014 New CO2 rig (Falcon, North, Best) 1 Ultrasonicpulse-echoBufferroad-topBufferroad-bottomElectrodesSampleσ3σ1Lateral strain gageAxial strain gage Static moduli vs Dynamic moduli
  • 17. UKCCSRC Bristol, 23 October 2014 New CO2 rig (example data) 1
  • 18. UKCCSRC Bristol, 23 October 2014 • Geophysics • Seabed gas quantification • CH4 & CO2 • Hydrates • P-waves 500 Hz – 10 kHz • Frequency-dependence • Samples 7 cm diameter, 50 cm long • 60 MPa fluid/confining • 4 to 100 degC • S-waves ~ 1 kHz • ERT • Sands, muds Greenhouse Gas Pulse Tube Sat. 5th July 2014
  • 19. UKCCSRC Bristol, 23 October 2014 Greenhouse Gas Pulse Tube a)b) c)d) McCann et al (2014), Geophysical Prospecting, 62, 97-116. 1 – 10 kHz
  • 20. UKCCSRC Bristol, 23 October 2014 Acoustic Bubble Resonance Anderson & Hampton (1980a, b) Recent theoretical developments: Leighton (2007) Kuhs et al (2004) Velocity Attenuation Bubble size distributions
  • 21. UKCCSRC Bristol, 23 October 2014 • Need controlled lab studies to understand: – Seismic anisotropy in fractured porous rocks – Pore fluid viscosity effects – Gas saturation effects – Geomechanical response to CO2 injection – Validate theoretical models for application to reservoir characterisation & monitoring • Acoustic pulse tube studies – Seabed greenhouse gas quantification – Gas bubble resonance phenomena Conclusions