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8th	
  Dillinger	
  Pressure	
  Vessel	
  Colloquium	
  
	
  Advanced	
  techniques	
  in	
  CrMoV	
  reactors	
  fabrica<on
30th September – 1st	
   October 2015
Authors : G. Fossataro – D. Quintiliani
The Company
340.000 sqm Workshops
500+ Employees
Average Turnover 100 ml. €
Sea Front Workshop
Wide Machine Park
50+ Years Experience
Authors : G. Fossataro – D. Quintiliani
Facts and Figures
Turnover:	
  
100,000,000	
  euro	
  
Employees:	
  	
  
500	
  more	
  
Assets:	
  	
  
75,000,000	
  €	
  
Investments:	
  	
  
50,000,000	
  €	
  in	
  3	
  years	
  
Equity	
  and	
  Reserves:	
  	
  
70,000,000	
  €	
  
	
  
Orders	
  PorEolio:	
  	
  
220,000,000	
  €	
  
Authors : G. Fossataro – D. Quintiliani
Company Products
Authors : G. Fossataro – D. Quintiliani
HYDROCRACKING	
  REACTORS	
  ARE	
  BETWEEN	
  THE	
  MOST	
  CRITICAL	
  ITEMS	
  
OPERATING	
  IN	
  A	
  REFINERY.	
  
CRITICALITIES	
  	
  COME	
  	
  FROM:	
  
-­‐ SEVERE	
  OPERATING	
  CONDITIONS	
  :	
  
	
  
-­‐ CHALLENGES	
  IN	
  FABRICATION,	
  WITH	
  SPECIAL	
  
	
  	
  	
  	
  	
  	
  CONSIDERATION	
  TO	
  FORMING,	
  WELDING	
  
	
  	
  	
  	
  	
  	
  AND	
  HEAT	
  TREATMENT.	
  
	
  
Pressure	
  (Design/Opera<ng):	
  	
  
165÷200	
  Bar	
  /	
  150÷180	
  Bar	
  
Temperature	
  (Design/Opera<ng):	
  	
  
360÷454	
  °C	
  /	
  360÷430	
  °C	
  
H2	
  Par<al	
  Pressure:	
  	
  	
  
140÷175	
  Bar	
  
MDMT:	
  -­‐29°C
Authors : G. Fossataro – D. Quintiliani
TYPICAL	
  MATERIAL	
  SELECTION	
  IS	
  	
  :
SHELL:	
  Plates	
  in	
  SA542DCL4a	
  or	
  Forging	
  SA336GrF22V	
  
HEADS:	
  Plates	
  in	
  SA542DCL4a	
  
NOZZLES:	
  Forging	
  SA336GrF22V	
  
	
  
	
  
Authors : G. Fossataro – D. Quintiliani
SHELL	
  COURSES	
  FABRICATION	
  CAN	
  BE	
  DONE	
  STARTING	
  FROM	
  A	
  	
  
MACHINED	
  FORGING	
  OR	
  BY	
  PLATES	
  ROLLING	
  
Authors : G. Fossataro – D. Quintiliani
TYPICAL SHELL COURSES FABBRICATION
Authors : G. Fossataro – D. Quintiliani
Forming	
  of	
  heavy	
  plates	
  requires:	
  
	
  
-­‐ Powerful	
  rolling	
  machine	
  (9000	
  tons	
  in	
  Walter	
  Tosto)	
  	
  
-­‐ Forming	
  control	
  “near	
  to	
  numeric	
  control”	
  to	
  obtain	
  and	
  guarantee	
  proper	
  roundness	
  
-­‐ Furnace	
  in	
  proximity	
  of	
  the	
  rolling	
  machine	
  to	
  perform	
  warm	
  preheaWng.
Authors : G. Fossataro – D. Quintiliani
CAN	
  HEAVY	
  PLATES	
  (35-­‐40	
  TONS)	
  	
  BE	
  USED	
  AS	
  AN	
  	
  
ALTERNATIVE	
  TO	
  HEAVY	
  FORGINGS	
  (70+	
  TONS)	
  ?	
  	
  
	
  
Longitudinal	
  weld	
  followed	
  by	
  warm	
  rolling
Authors : G. Fossataro – D. Quintiliani
-­‐ Special	
  tools	
  for	
  plates	
  handling	
  to	
  avoid	
  stress	
  in	
  the	
  weld	
  region	
  during	
  
plates	
  posiWoning	
  and	
  rotaWon	
  with	
  parWal	
  welding	
  compleWon	
  
	
  
-­‐ ISR	
  to	
  stress	
  relieve	
  the	
  weld	
  and	
  to	
  achieve	
  acceptable	
  toughness	
  
	
  
-­‐ Grind	
  flush	
  of	
  the	
  weld	
  to	
  reach	
  a	
  regular	
  surface	
  
	
  
-­‐ Uniform	
  preheat	
  (350°C)	
  before	
  rolling.	
  
Authors : G. Fossataro – D. Quintiliani
Authors : G. Fossataro – D. Quintiliani
Lower rolls clearence (up to 2500mm) allow to have
progressive stress increase in rolled plates
This	
  process	
  has	
  been	
  qualified	
  with	
  
several	
  PTP	
  that	
  have	
  been	
  rolled	
  and	
  
than	
  subject	
  to	
  severe	
  mechanical	
  tests	
  
	
  
(tensile	
  and	
  impact	
  test	
  at	
  compressed,	
  
neutral	
  and	
  stretched	
  fiber,	
  Z 	
  test	
  in	
  fusion	
  
line	
  and	
  in	
  HAZ,	
  step	
  cooling	
  test)	
  	
  
	
  
Several	
  reactors	
  have	
  been	
  fabricated	
  
by	
  Walter	
  Tosto	
  with	
  this	
  technique	
  
and	
  are	
  in	
  operaRons	
  since	
  	
  years	
  
Authors : G. Fossataro – D. Quintiliani
SHELL	
  BARRELS	
  WITH	
  CATALYST	
  BED	
  SUPPORT	
  RING.	
  
When	
  shell	
  courses	
  are	
  made	
  by	
  heavy	
  forging,	
  the	
  support	
  ring	
  is	
  an	
  integral	
  
part	
  of	
  this	
  forging;	
  this	
  is	
  frequently	
  used	
  in	
  producWon	
  but	
  	
  unfortunately	
  
with	
  a	
  negaWve	
  impact	
  in	
  the	
  project	
  costs.	
  
As	
  an	
  alternate,	
  when	
  barrels	
  are	
  
made	
  by	
  plates,	
  this	
  support	
  ring	
  may	
  
be	
  fabricated	
  with	
  weld	
  build-­‐up
Authors : G. Fossataro – D. Quintiliani
Welding build up in progress
Authors : G. Fossataro – D. Quintiliani
TO	
  PERFORM	
  THIS	
  ACTIVITY	
  	
  IS	
  IMPERATIVE	
  TO	
  HAVE:	
  
	
  
-­‐ Proper	
  weld	
  parameters	
  and	
  temperature	
  control	
  
	
  
-­‐ Large	
  preheaWng	
  zone	
  during	
  welding	
  
	
  
-­‐ Immediate	
  ISR	
  (typ.	
  670°C	
  6H)	
  without	
  allowing	
  
	
  	
  	
  	
  	
  	
  the	
  weld	
  deposit	
  to	
  cool	
  below	
  approx.	
  180°C	
  
-­‐ Scale	
  1:1	
  mock	
  up	
  for	
  UT	
  calibraWon	
  
Authors : G. Fossataro – D. Quintiliani
TYPICAL HEADS FABBRICATION
Authors : G. Fossataro – D. Quintiliani
TO	
  OPTIMIZE	
  THE	
  HEADS	
  FABRICATION	
  AND	
  TO	
  GUARANTEE	
  THE	
  BEST	
  PERFORMANCES	
  IN	
  
QUALITY/PRODUCTIVITY	
  DURING	
  WELDING	
  IT	
  IS	
  IMPORTANT	
  TO	
  PERFORM:	
  
	
  
-­‐ Very	
  careful	
  	
  warm	
  calibraWon	
  in	
  order	
  to	
  have	
  petals	
  in	
  precise	
  shape	
  and	
  to	
  
avoid	
  extra	
  	
  fit	
  up	
  acWviWes	
  
-­‐ Petals	
  machining	
  before	
  fit	
  up	
  to	
  reach	
  a	
  narrow	
  gap	
  bevel	
  
Authors : G. Fossataro – D. Quintiliani
WELDING	
  
	
  
WELDING	
  IS	
  A	
  CRITICAL	
  ACTIVITY	
  USING	
  CrMoV	
  MATERIALS,	
  AS	
  IT	
  IS	
  WELL	
  
KNOWN	
  THEIR:	
  
-­‐ CRACKS	
  SUSCEPTABILITY	
  	
  
-­‐ LOW	
  TOUGHTNESS	
  IN	
  AS	
  WELDED	
  CONDITIONS	
  
	
  
	
  
MECHANICAL	
  PROPERTIES	
  ARE	
  REACHED	
  ONLY	
  WITHIN	
  VERY	
  SPECIFIC	
  WELDING	
  
PARAMETERS	
  AND	
  AFTER	
  A	
  PROPER	
  POST	
  WELD	
  HEAT	
  TREATMENT.	
  	
  
Authors : G. Fossataro – D. Quintiliani
WELDING	
  ACTIVITIES	
  SHALL	
  BE	
  CONDUCTED	
  FOLLOWING	
  A	
  
ROBUST	
  AND	
  RELIABLE	
  PROCESS:	
  
	
  
-­‐ STATE	
  OF	
  THE	
  ART	
  IS	
  TO	
  IMPLEMENT	
  NARROW	
  GAP	
  WELDING	
  
WITH	
  SPECIAL	
  CONTROL	
  OF	
  THE	
  BEAD	
  SEQUENCE.	
  
-­‐ NOZZLES	
  EQUAL	
  OR	
  GREATER	
  THAN	
  4	
  INCHES	
  SHALL	
  BE	
  
WELDED	
  WITH	
  NARROW	
  GAP	
  SAW	
  PROCESS	
  	
  
-­‐ LOCKED	
  WELDING	
  PARAMETERS	
  AND	
  PROPER	
  ROTATING	
  
EQUIPMENTS	
  ARE	
  MANDATORY	
  TO	
  PERFORM	
  PRODUCTION	
  
WELDING	
  CONSISTENT	
  WITH	
  THE	
  QUALIFIED	
  ONES	
  
	
  
Authors : G. Fossataro – D. Quintiliani
300
mm
-­‐ Proven	
  welding	
  consumable	
  management	
  system	
  
	
  
	
  
Good management of filler metal means, guaranteeing that the filler metal in all phases from Goods-In to welding has
negligible hydrogen absorption. In addition the flux is dried and stored at temperatures indicated by the filler metal
manufacturer, typically 350°C for drying and 150°C for storage, in special distribution equipment, prior to use.
“Drying	
  and	
  flux	
  feeding	
  
system	
  designed	
  and	
  
manufactured	
  in-­‐house.”	
  
-­‐ Intensive	
  training	
  of	
  all	
  involved	
  personnel	
  
Authors : G. Fossataro – D. Quintiliani
WELD	
  	
  OVERLAY	
  IS	
  TIPICALLY	
  PERFORMED	
  IN	
  ONE	
  LAYER	
  WITH	
  ESW	
  PROCESS	
  
USING	
  TANDEM	
  90mm	
  STRIP	
  WELDING	
  EQUIPMENT
Weld overlay
by double heads ESW process type 347
Authors : G. Fossataro – D. Quintiliani
Weld	
  overlay	
  of	
  nozzles,	
  usually	
  performed	
  with	
  FCAW	
  process	
  can	
  be	
  
opWmized	
  implemenWng	
  automaWc	
  robot	
  welding	
  	
  
(2	
  or	
  3	
  layers	
  depending	
  on	
  different	
  project	
  specificaWon	
  or	
  different	
  locaWon)	
  	
  
	
  
Authors : G. Fossataro – D. Quintiliani
FOLLOWING	
  SPECIFIC	
  QUALIFICATION	
  PROCESS	
  ROBOT	
  WELDING	
  IN	
  LIEAU	
  
OF	
  MANUAL	
  OVERLAY	
  WELDING,	
  BRINGS	
  IMPROVEMENTS	
  IN	
  :	
  
	
  
-­‐ FERRITE	
  CONTROL	
  (uniform	
  readings	
  of	
  FN	
  between	
  5	
  and	
  7)	
  
-­‐ COSTANT	
  OVERLAP	
  BETWEEN	
  WELD	
  PASSES	
  	
  
-­‐ SIGNIFICANT	
  INCREASE	
  IN	
  PRODUCTIVITY	
  
Authors : G. Fossataro – D. Quintiliani
HEAT	
  TREATMENT	
  
ISR	
   (intermediate	
   stress	
   releaving)	
   is	
  
typically	
  performed	
  in	
  fournace	
  for	
  reactor	
  
secWons	
  (heads,	
  shell	
  courses	
  with	
  nozzles)	
  
while	
  circunferencial	
   welds	
  are	
  subject	
  to	
  
DHT	
  
When ISR is requested also for
circunferencials weld, to avoid potential
detrimental effects on base metal due to
multiple ISR + max PWHT, Localized ISR
can be performed.
Authors : G. Fossataro – D. Quintiliani
POST	
  WELD	
  HEAT	
  TREATMENT	
  
Authors : G. Fossataro – D. Quintiliani
Example	
  of	
  reactor	
  treated	
  with	
  temperature	
  range	
  710°C	
  +/-­‐5°C.	
  
It	
  is	
  essenWal	
  to	
  have	
  a	
  reliable	
  PWHT	
  procedure,	
  state	
  of	
  the	
  art	
  furnace	
  &	
  skilled	
  personnel	
  to	
  
guarantee	
  precise	
  temperature	
  (+/-­‐5°C)
Thanks	
  for	
  your	
  aUenRon	
  
Authors : G. Fossataro – D. Quintiliani

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04_Walter Tosto_Fossataro.pdf

  • 1. 8th  Dillinger  Pressure  Vessel  Colloquium    Advanced  techniques  in  CrMoV  reactors  fabrica<on 30th September – 1st   October 2015 Authors : G. Fossataro – D. Quintiliani
  • 2. The Company 340.000 sqm Workshops 500+ Employees Average Turnover 100 ml. € Sea Front Workshop Wide Machine Park 50+ Years Experience Authors : G. Fossataro – D. Quintiliani
  • 3. Facts and Figures Turnover:   100,000,000  euro   Employees:     500  more   Assets:     75,000,000  €   Investments:     50,000,000  €  in  3  years   Equity  and  Reserves:     70,000,000  €     Orders  PorEolio:     220,000,000  €   Authors : G. Fossataro – D. Quintiliani
  • 4. Company Products Authors : G. Fossataro – D. Quintiliani
  • 5. HYDROCRACKING  REACTORS  ARE  BETWEEN  THE  MOST  CRITICAL  ITEMS   OPERATING  IN  A  REFINERY.   CRITICALITIES    COME    FROM:   -­‐ SEVERE  OPERATING  CONDITIONS  :     -­‐ CHALLENGES  IN  FABRICATION,  WITH  SPECIAL              CONSIDERATION  TO  FORMING,  WELDING              AND  HEAT  TREATMENT.     Pressure  (Design/Opera<ng):     165÷200  Bar  /  150÷180  Bar   Temperature  (Design/Opera<ng):     360÷454  °C  /  360÷430  °C   H2  Par<al  Pressure:       140÷175  Bar   MDMT:  -­‐29°C Authors : G. Fossataro – D. Quintiliani
  • 6. TYPICAL  MATERIAL  SELECTION  IS    : SHELL:  Plates  in  SA542DCL4a  or  Forging  SA336GrF22V   HEADS:  Plates  in  SA542DCL4a   NOZZLES:  Forging  SA336GrF22V       Authors : G. Fossataro – D. Quintiliani
  • 7. SHELL  COURSES  FABRICATION  CAN  BE  DONE  STARTING  FROM  A     MACHINED  FORGING  OR  BY  PLATES  ROLLING   Authors : G. Fossataro – D. Quintiliani
  • 8. TYPICAL SHELL COURSES FABBRICATION Authors : G. Fossataro – D. Quintiliani
  • 9. Forming  of  heavy  plates  requires:     -­‐ Powerful  rolling  machine  (9000  tons  in  Walter  Tosto)     -­‐ Forming  control  “near  to  numeric  control”  to  obtain  and  guarantee  proper  roundness   -­‐ Furnace  in  proximity  of  the  rolling  machine  to  perform  warm  preheaWng. Authors : G. Fossataro – D. Quintiliani
  • 10. CAN  HEAVY  PLATES  (35-­‐40  TONS)    BE  USED  AS  AN     ALTERNATIVE  TO  HEAVY  FORGINGS  (70+  TONS)  ?       Longitudinal  weld  followed  by  warm  rolling Authors : G. Fossataro – D. Quintiliani
  • 11. -­‐ Special  tools  for  plates  handling  to  avoid  stress  in  the  weld  region  during   plates  posiWoning  and  rotaWon  with  parWal  welding  compleWon     -­‐ ISR  to  stress  relieve  the  weld  and  to  achieve  acceptable  toughness     -­‐ Grind  flush  of  the  weld  to  reach  a  regular  surface     -­‐ Uniform  preheat  (350°C)  before  rolling.   Authors : G. Fossataro – D. Quintiliani
  • 12. Authors : G. Fossataro – D. Quintiliani Lower rolls clearence (up to 2500mm) allow to have progressive stress increase in rolled plates
  • 13. This  process  has  been  qualified  with   several  PTP  that  have  been  rolled  and   than  subject  to  severe  mechanical  tests     (tensile  and  impact  test  at  compressed,   neutral  and  stretched  fiber,  Z  test  in  fusion   line  and  in  HAZ,  step  cooling  test)       Several  reactors  have  been  fabricated   by  Walter  Tosto  with  this  technique   and  are  in  operaRons  since    years   Authors : G. Fossataro – D. Quintiliani
  • 14. SHELL  BARRELS  WITH  CATALYST  BED  SUPPORT  RING.   When  shell  courses  are  made  by  heavy  forging,  the  support  ring  is  an  integral   part  of  this  forging;  this  is  frequently  used  in  producWon  but    unfortunately   with  a  negaWve  impact  in  the  project  costs.   As  an  alternate,  when  barrels  are   made  by  plates,  this  support  ring  may   be  fabricated  with  weld  build-­‐up Authors : G. Fossataro – D. Quintiliani
  • 15. Welding build up in progress Authors : G. Fossataro – D. Quintiliani
  • 16. TO  PERFORM  THIS  ACTIVITY    IS  IMPERATIVE  TO  HAVE:     -­‐ Proper  weld  parameters  and  temperature  control     -­‐ Large  preheaWng  zone  during  welding     -­‐ Immediate  ISR  (typ.  670°C  6H)  without  allowing              the  weld  deposit  to  cool  below  approx.  180°C   -­‐ Scale  1:1  mock  up  for  UT  calibraWon   Authors : G. Fossataro – D. Quintiliani
  • 17. TYPICAL HEADS FABBRICATION Authors : G. Fossataro – D. Quintiliani
  • 18. TO  OPTIMIZE  THE  HEADS  FABRICATION  AND  TO  GUARANTEE  THE  BEST  PERFORMANCES  IN   QUALITY/PRODUCTIVITY  DURING  WELDING  IT  IS  IMPORTANT  TO  PERFORM:     -­‐ Very  careful    warm  calibraWon  in  order  to  have  petals  in  precise  shape  and  to   avoid  extra    fit  up  acWviWes   -­‐ Petals  machining  before  fit  up  to  reach  a  narrow  gap  bevel   Authors : G. Fossataro – D. Quintiliani
  • 19. WELDING     WELDING  IS  A  CRITICAL  ACTIVITY  USING  CrMoV  MATERIALS,  AS  IT  IS  WELL   KNOWN  THEIR:   -­‐ CRACKS  SUSCEPTABILITY     -­‐ LOW  TOUGHTNESS  IN  AS  WELDED  CONDITIONS       MECHANICAL  PROPERTIES  ARE  REACHED  ONLY  WITHIN  VERY  SPECIFIC  WELDING   PARAMETERS  AND  AFTER  A  PROPER  POST  WELD  HEAT  TREATMENT.     Authors : G. Fossataro – D. Quintiliani
  • 20. WELDING  ACTIVITIES  SHALL  BE  CONDUCTED  FOLLOWING  A   ROBUST  AND  RELIABLE  PROCESS:     -­‐ STATE  OF  THE  ART  IS  TO  IMPLEMENT  NARROW  GAP  WELDING   WITH  SPECIAL  CONTROL  OF  THE  BEAD  SEQUENCE.   -­‐ NOZZLES  EQUAL  OR  GREATER  THAN  4  INCHES  SHALL  BE   WELDED  WITH  NARROW  GAP  SAW  PROCESS     -­‐ LOCKED  WELDING  PARAMETERS  AND  PROPER  ROTATING   EQUIPMENTS  ARE  MANDATORY  TO  PERFORM  PRODUCTION   WELDING  CONSISTENT  WITH  THE  QUALIFIED  ONES     Authors : G. Fossataro – D. Quintiliani 300 mm
  • 21. -­‐ Proven  welding  consumable  management  system       Good management of filler metal means, guaranteeing that the filler metal in all phases from Goods-In to welding has negligible hydrogen absorption. In addition the flux is dried and stored at temperatures indicated by the filler metal manufacturer, typically 350°C for drying and 150°C for storage, in special distribution equipment, prior to use. “Drying  and  flux  feeding   system  designed  and   manufactured  in-­‐house.”   -­‐ Intensive  training  of  all  involved  personnel   Authors : G. Fossataro – D. Quintiliani
  • 22. WELD    OVERLAY  IS  TIPICALLY  PERFORMED  IN  ONE  LAYER  WITH  ESW  PROCESS   USING  TANDEM  90mm  STRIP  WELDING  EQUIPMENT Weld overlay by double heads ESW process type 347 Authors : G. Fossataro – D. Quintiliani
  • 23. Weld  overlay  of  nozzles,  usually  performed  with  FCAW  process  can  be   opWmized  implemenWng  automaWc  robot  welding     (2  or  3  layers  depending  on  different  project  specificaWon  or  different  locaWon)       Authors : G. Fossataro – D. Quintiliani
  • 24. FOLLOWING  SPECIFIC  QUALIFICATION  PROCESS  ROBOT  WELDING  IN  LIEAU   OF  MANUAL  OVERLAY  WELDING,  BRINGS  IMPROVEMENTS  IN  :     -­‐ FERRITE  CONTROL  (uniform  readings  of  FN  between  5  and  7)   -­‐ COSTANT  OVERLAP  BETWEEN  WELD  PASSES     -­‐ SIGNIFICANT  INCREASE  IN  PRODUCTIVITY   Authors : G. Fossataro – D. Quintiliani
  • 25. HEAT  TREATMENT   ISR   (intermediate   stress   releaving)   is   typically  performed  in  fournace  for  reactor   secWons  (heads,  shell  courses  with  nozzles)   while  circunferencial   welds  are  subject  to   DHT   When ISR is requested also for circunferencials weld, to avoid potential detrimental effects on base metal due to multiple ISR + max PWHT, Localized ISR can be performed. Authors : G. Fossataro – D. Quintiliani
  • 26. POST  WELD  HEAT  TREATMENT   Authors : G. Fossataro – D. Quintiliani Example  of  reactor  treated  with  temperature  range  710°C  +/-­‐5°C.   It  is  essenWal  to  have  a  reliable  PWHT  procedure,  state  of  the  art  furnace  &  skilled  personnel  to   guarantee  precise  temperature  (+/-­‐5°C)
  • 27. Thanks  for  your  aUenRon   Authors : G. Fossataro – D. Quintiliani