SlideShare a Scribd company logo
1 of 13
A CRITICAL REVIEW OF NANOTECHNOLOGY APPLICATION IN DRILLING
FLUID OVER THE LAST DECADES
Abstract
Drilling fluid plays an important role during drilling process. In the past few decades, mud
engineers have been trying to modify drilling fluid to improve its quality in term of its viscosity,
density, specific gravity and any other physical properties. The demand of a better drilling fluid
increases when oil and gas company turns their attention to other unexplored areas such as the
unstable shale areas and high pressure and high temperature (HPHT) areas. This is where the
nanotechnology takes part in oil and gas challenges.
The use of nanotechnology in drilling fluid has been proven in many researches and experiments
could improve the physical properties of the drilling fluid. Although there are many papers that
discuss the application of nanotechnology in oil and gas industry, but yet, not many researchers
are focusing on the application of nanotechnology in drilling fluid itself. Therefore, this paper will
provide a better exposure of the application of nanotechnology in drilling fluid over the last
decades. By going through this paper, it will first explain about nanotechnology before providing
more information in details of its application in drilling fluid.
In addition, this paper will only provide information on the areas which shows a promising future
in oil and gas industry, where in reality the involvement of nanotechnology in drilling fluid is still
under research.
Introduction
In the past few decades, nanotechnology has been a prominent research in many areas including
oil and gas industry. The continuous study of nanotechnology and its chemical properties have
lead into numerous applications in many products especially in cosmetics, medical, electronics,
food, fabric, painting and coating industries as well as in oil and gas industries. Nanotechnology
is the any technology that is utilized at the Nano-scale approximately between 1 and 100
nanometers (El-Diasty & Salem, 2013).
Figure 1: The nanoscale (Nanoscience, n.d)
Figure 2: Nanoparticle size vs cells(Barr, 2008)
These tiny particles offer exceptional characteristics which are very useful and can be applied in
various fields. Most of the products or technology developed by those industries used nanoparticles
to deliver drugs, enhance strength and durability, and as a repelling properties which is commonly
used in painting and coating. Some example of nanoparticles and its uses are described herein.
Nanoparticles Uses
Gold nanoparticles It is used to target drugs to certain parts of
body to treat tumor
Silica It is used as an additive to rubber and plastics
Zinc oxide It is used to make the food last longer
Silver nanoparticles It is used to kill bacteria in fabric
Silicon dioxide crystalline It is used to strengthen a racquet by fill in the
gap between carbon fibre
Titanium dioxide It is common ingredients in sunscreen to
protect us from harmful UV ray
Table 1: Examples of nanoparticle and its uses
Some nanoparticles might have more than one uses. For example, apart from treating tumor,
Gold nanoparticles are also used to solve air pollution when embedded with other elements.
Therefore, it is possible that most of these nanoparticles could be having different uses that are
yet to be discovered. As time passes by, the uses and advantages of nanoparticles of every
elements are revealed one after another and its uses are put into application wherever they see fit.
However, there are some serious issues related to nanotechnology. Nanoparticles are very small
compared to its normal size particle. This distinction in size lead to the change in the properties
of the particles. In other words, nanotechnology have a very unique of physical and chemical
properties. As the properties of tiny particles is not easy to handle and predicted there is
uncertainties in that matters. For example, a piece of gold is obviously gold in color but that is
not the case for gold nanoparticles which might have deep red in color or even black if it is mix
with water.
Due to these uncertainties, the application of nanotechnology in oil and gas industries is still
quite limited even though almost every industries have already make use of the benefits and
advantages of nanotechnology. In fact the application of nanotechnology in oil industry is only
limited to the construction and material side, whereas the use of nanotechnology in drilling fluid
is still not applicable. It is because nanotechnology is still new with a lot of uncertainties. As a
precaution step the company is more concern in minimizing the risk by reducing the
uncertainties. Therefore, this paper will provide an exposure on how these unique characteristic,
physical and chemical properties of nanotechnology can improve the drilling fluid, thus increase
the efficiency of the overall process.
Definition
In the year 2005, nanoparticle is defined as a capability to create new matter in an atomic scale or
molecular level with the aim to study and exploit the new matter’s properties (Mansoori & Soelaiman,
2005). Later itisdefined asascience,technologyandengineeringof matterthatare preciselymanipulated
at nano scale dimension. This technology involved the use of materials at a range of 1-100 nanometers
size all bythemselvesortocreate anothernew large material fromthemwhichisbeneficial anduseful to
others.Nanotechnologygotitsname fromprefix “nano”whichmeansone-billionthof ameter(El-Diasty
& Salem, 2013).
Nanotechnology involved the study and application of tiny things which is known as nanoparticles.
Nanoparticles are matter that has all three dimension in the nanoscale ("Nanotechnology and Food
Safety," 2010) and is made up of atoms which has radius below 100nm (El-Diasty & Salem, 2013).
Characterization of Nanoparticles
In order for us to understand the true capabilities of nanoparticles, specified knowledge about them is
needed.We mustdigintothe nanoparticles’worldsothatwe canfurtherexamine howthe nanoparticles
behaves in certain environment and what are its characteristics.
Nanoparticles’sizeissotinyin nature whichisin range of lessthan 100 nanometerleadstothe increase
of total surface area exposedcomparedtomaterial of the same volume.Thus,more particle can forma
bondwithnanoparticlesinvariouswayswhichwill make a strongerlightweightmaterial.Figure 2shows
how nanoparticleshashightotal surface area exposedcomparedtoother material of the same volume.
It also has fine structure of grain and can form a very thin layer of lubricating coating which allow
themselvestoslide smoothlyagainsteachother(Amanullah&Al-Tahini,2009; El-Diasty & Salem, 2013).
Figure 2: Comparison of total surface area exposed("Nanotechnology and Food Safety," 2010)
High total surface area exposed of nanoparticles and its small and tiny sized characteristic make
nanoparticle’s heat transfer coefficient better.Thus, good heat transfer coefficient makes nanoparticles
capable toaccelerate the transmissionof heatfromone pointtoanother.Inasimplerword,the hightotal
surface area characteristics owned by the nanoparticles enhanced them to conduct heat more easily
(Amanullah, AlArfaj, & Al-abdullatif, 2011).
Some of the nanoparticles are water-wet and some are oil-wet depending on the nature of the
nanoparticles themselves. Nanoparticles with oil-wet characteristic will let oil wets its total surface area
exposed thus creating a film of oil on the entire surface of the nanoparticles which in turn lead to
hydrophobicfilmbeingform(El-Diasty&Salem, 2013).Beside oil-wet,there are some nanoparticlesthat
has a water-wet characteristic which is vice versa of oil-wet.
Nanoparticles are also ecofriendly and stable which can be used to drill well that is sensitive to harsh
environment. It is ecofriendly and green because it is added in small amount into the drilling fluid
compared to the conventional drilling fluid that is not green and leads to environmental pollution
(Amanullah et al., 2011). As nanoparticles is so small, once the size get below 100 nanometer, the
attractive forces between one another particle becomes significant to one another. Thus will result in
more viscousfluidatrelativelylow level of concentration.Furthermore,due tothe high particle-particle
interaction,bondingbetweennanoparticlesisstrong.Therefore,certainnanomaterial canwithstandhigh
pressure and high temperature environment (Hoelscher, Young, Friedheim, & De Stefano, 2013).
Table 1: Summaryof Nanoparticleandtheir applicationindrillingfluid.
Application of Nanotechnology in Drilling Fluid
Preventing Fluid Loss into Reservoir Formation: Researcher has been trying to use nanoparticles as a
mediumtopreventfluidlossinto formation.Inconventional methodof drilling,we relyonthe mudcake
formed at the wellbore’swall to prevent further loss of fluid into the formation. The thickness of the
mudcake depends on the amount of fluid loss into the formation. In early years, Dewan and Chenvert
(1993) state that in a low permeability shale, formation of mudcake will be slower as less fluid is going
into the formation. Later, Hoelscher, De Stefano, Riley, and Young (2012) state that impermeable
mudcake may notbe able to format all if formationhasnanosizedporeswhichmakethe permeabilityof
Nanoparticles Sizes (nm) Characteristics Applications in Drilling Fluid
Nanosilica Between 5 to 100 Small and tiny sized - Fluid loss control
- Wellbore stability
- Reduce pipe sticking
- Pipe sticking
Carbon-based Between 15 to 100 Low surface energy - Prevents bit balling
- Prevents corrosion
Nickel-based Below 100 Fine texture and structure - Reduce torque and drag
Zinc Oxide Between 14-25 Higher reactivity than
hydrogen sulphide
- Remove hydrogen sulphide
from crude oil
All Below 100 - Good heat transfer
coefficient
- High total surface area
- Transferheat fromreservoirto
surface efficiently
- Reduce solid content in mud
the formation extremely low. Fluid can still go through it without the formation of mudcake (Figure 3).
Thisfluidlossisuncontrollable.Inordertodeal withthisproblem, nanoparticlesmustbe pluggedintothe
nanosized pores so that no further fluid can go through the tiny pores.
Water that manage to invade the shale through nanosized pores which has the size of 3 to 100
nanometers can lead to fracturing which in turn interferes the wellbore stability. However the invasion
could be stopped by using nanosilica. Sensoy, Chenevert,and Sharma (2009) showed that the fluidflow
through an Atoka shale could be stopped by utilizing 29% by weight of a specific nanosilica (Figure 4).
Then according to Hoelscher et al. (2012), silica nanoparticles that have the size between 5 to 100
nanometer is plugged into the nanosized pores in the formation to reduce the pressure difference
betweenthe wellbore andthe reservoirformationthusshuttingoffthe fluidloss.Mudcake thatisformed
fromnanoparticlesisrelativelythinthanthe one formedbyconventional drillingfluid.Thisverythinlayer
of mudcake helpsinreducingthe fluidlossintothe formationwhile minimizingformationdamage while
drilling. In addition, not only choosing suitable size of the nanoparticles that matters in the effective
plugging, type of surface treatment is also an important parameters.
Later, Hoelscheretal.(2013) conduct an experimenttoshow the transmissionof pressure through
Mancos shale.The resultof the experimentshowedthata new drillingfluidsystemwith3% of
nanosilicacouldcompletelyshutoff the pressure transmissionacrossthe shale sample.These works
showedthattheoryof pluggingnanosizedporeswithnanoparticlesispossible and canpreventfluidloss
intothe formationwhile maintainingthe wellbore stability.
Figure 3: Filter cake’s thicknessdepends on Figure 4: Sealingperformanceof AtokaShale
amountof fluidloss. (Hoelscheret al., 2012) (Sensoyet al.,2009)
PreventingBit Balling:Bit ballingisaconditionwhere formation’s claysjoinandaccumulate atthe
drillingbitcontinuouslyand stickintothe toothof the drill bitformingasphericallysolidthatcoversthe
bit.Thisin turnreducesdrasticallythe rate of penetrationof the bitwhichwill waste bothtime and
operationcost.This occurs due to the stickycharacteristicsof the clay whenitisin contact withwater.
Therefore, the ultimate solution to this problem is to invent a film that can repel clay and water from
being in contact with the bit. At first, researchers found that hydrophobic coating can be formed either
by using nanochromates and nanotitanium dioxide ((Kendig & Buchheit, 2003);(Shen, Du, Chen, Lin, &
Scantlebury, 2005)).
Then,thisideawas usedin makinga drillingfluidthatcan reduce bitballingproblem.Ithas the abilityto
form a sheet like hydrophobic coating near the surface of the drill bit (Amanullah & Al-Tahini,2009).
Nanoparticleshave thiskindof abilitybecausetheycreate roughnessonthe surface of the drill bitwhich
thenproduce alowsurface energy matteronthe bit.Asthe surface energyislow,contactangle between
water and the surface will be high. Therefore,
hydrophobicfilmwill be formedonthe surface
of the bit. The higher the concentration of
nanoparticles, the higher the water contact
angle whichmeansthe morehydrophobicisthe
coating(Figure 5) (Basu& DineshKumar,2011).
Due to the hydrophobic layer formed by the
nanoparticles,wateraswell asclayare repelled
from the drill bitthus preventingthe formation
of bit balling.
Figure 5: Water contact angle increase with
concentration of nanoparticle (Basu & Dinesh
Kumar, 2011)
ReducingFriction and Drag: Frictionanddrag are one of the problemthatcan affectthe efficiencyof
drillingformationbecause itwastedenergyandcauseswearandtear to the equipmentwhich
consequentlyleadstothe damage of the bottomhole equipment.Inordertoreduce thisproblem,
appropriate type of drillingfluidisselectedforthe operation.The selecteddrillingfluidmusthave good
lubricitytoovercome the frictional forcesthatexistsdue tothe rotationorslidingof the drillingpipe
inside the wellborewitheitherformationwall orwithcasing.Drillingengineershasusedoil based
drillingfluidinordertoreduce frictionanddrag force inside wellbore.Howeverthistype of drillingfluid
isnot ecofriendly andtheirconsumption mustbe below the limitof usage.Therefore,researchersmust
finda wayto create drillingfluidwhichisenvironmentallyfriendlyandcanreduce frictionforce
efficiently.
Researchersbelievedthatnanoparticleshave highpotential tomeet these requirementbecause of their
tinysizeswithfine texture andstructure. Theyhave the abilitytoform a thin layerof lubricatingcoating
between the bottomhole equipment and the borehole wall.The ultra-thin layer of nanoparticles allows
easy slidingof the drill pipe whichis responsible forreducingthe torque and drags probleminborehole
(Amanullah & Al-Tahini, 2009). Their structure and size make them capable to enter the friction region
between two surfaces easily. Furthermore, according to Hareland, Wu, Lei, Husein, and Zakaria (2012),
nanoparticles can seal filter cake completely by producing crack-free and smooth surfaces which then
contribute to slippery film between formation and the drill string. In addition, because nanoparticles is
small insize,kineticenergyandabrasiveforce willbe reducedsignificantlywhichmakeswearandtearof
the bottomholetool becomesnegligible. Theyalsofound outthatfrictioncoefficientcanbe reducedmore
than 25% when nickel-based nanoparticles is added.
Figure 6: Illustration of lubricating coating at the surface of material (Beschichten, n.d)
Solid Content Reduction: During drilling operation, one of the most important things to take into
considerationis the operationtime.Longertime neededsignifieshuge amountof moneythat are going
to spend. In order to reduce the operation time needed during drilling, rate of penetration (ROP) of bit
needtobe increased.AccordingtoAmanullahandAl-Tahini (2009),ROPisdirectlyrelatedtosolidcontent
in drillingmud.Itcan be increasedif the amountof solidcontentin drillingfluidis reduced (Figure 7).In
nano-based mud, only a little amount of volume of nanoparticles are needed due to their large surface
areaperunitvolume.Inthatcase,nanoparticlecanreduce solidcontentof the mudandatthe same time
increase the rate of penetration of drilling bit which in turn saves the time and cost needed for the
operation.
Figure 7: Relationship between rate of penetration and mud solid content (Amanullah & Al-Tahini,
2009)
CorrosionReduction:Corrosionisone of the mainthingthatdrillingengineersare concernaboutbecause
drilling operation involved extreme erosive and friction force between tool and formation. However,
nanoparticle isbelievedtobe abletosolvethisproblem. Shenetal.(2005) state thatnanotitaniumdioxide
particlesare capable of forminghydrophobiccoating.Thisstatementissupportedby AmanullahandAl-
Tahini (2009) that said nanoparticle can form hydrophobic film on the surface of downhole tool.
Unfortunately, hydrophobic coating that has high wettability will be a poor corrosion resistance.
Hydrophobiccoatingonlyrepelwaterandclayfromdownholeequipment.Hydrogensulfide whichisone
of the mainfactor thatcan cause corrosionstill canreachthe equipment.Therefore,nanoparticlesuchas
zincoxide isusedtoremove hydrogensulfidefromthecrude oil(Sayyadnejad,Ghaffarian,&Saeidi,2008).
This will be explained more in removal of toxic gases section.
Later, Zhuk(2010) inventsa perfectcoatingthatcontain TungstenCarbide distributedinmetal Tungsten
matrix whichlevelupmetal’sstrengthanderosionresistance.Ithashightoughnessandimpactresistance
which reduce the probability of getting corrosion. Furthermore, this product has no temperature
limitation compared to organic coating or sealants.
Prevent Pipe Sticking: Pipe sticking problem occurs due to contact made by drill pipe and the wall of
formation containing mudcake. In order to resolve this problem, Baker (2006) has created a nanofluid
polymerwhichcouldgothroughporesandaccumulate atthe wallof wellboreformingthinlowpermeable
mudcake (Figure 8). Thisin turn reduce the differential pressure whichconsequentlyreducesprobability
of differential stickingproblem tooccur. In conclusion,microfracturesinshale or sandcould be plugged
in by the nanoparticles thus reducing pressure transmission which in turn prevent pipe sticking (Li, Xu,
Sun, Yuan, & Li, 2012).
Figure 8: Plugging effect of nanofluid polymer(Li et al., 2012)
Removal ofToxic Gases:Crude oil and natural gassesare the mixture of hydrocarboncontainedmostly
methane,butalsomightcontainsome otheralkane,hydrogensulphide,nitrogen,andoxygen.Mostof
these natural gassesare harmlessandgive noconcernto drillingengineer.However,hydrogensulphide
couldpose a seriousthreatduringdrillingprocess. Duringdrillingprocess,there isapossibility that
hydrogensulphide candiffuseintothe drillingfluidfromthe formation.Whenthishappen,engineers
shouldbe well preparedtohandle the situationashydrogensulphide containedhighlevelof toxicity
whichcan paralyzedthe olfactorynerve whenit isbreathinat highconcentration (Mickelsonetal.,
2013). In addition, Cocuzza,Pirri,Rocca,andVerga(2011), statedthatthe presentof toxicgassuch as
hydrogenchloride andhydrogensulphide couldinduce the corrosionindrillingpipeandother
equipment.Therefore itcouldaffectboththe drillingequipmentandthe worker’shealthapartfrom
raisingenvironmentalpollution.Itisimportanttohandle hydrogensulphidebefore itisvaporize to
atmosphere inordertoreduce riskand majorlossto the company.
Sayyadnejadetal.(2008), proposedthatby using14 to25 nmof zincoxide and44 to 56 m²/g specific
surface area,we can remove hydrogensulphide fromthe drillingfluidinasimple chemical reaction.This
type of chemical reactioniscalleddisplacementreaction.The equationof chemical reactionisas
followed:
(ZnO + H₂S → ZnS + H₂O)
By usingnanoparticle zincoxide,the processof removal of hydrogensulphide isfasterdue tothe
greatersurface area of nanoparticles.Whenthe surface areaof the particlesisgreater,the chemical
reactionbetweenzincoxide andhydrogensulphide takesplace atmuchshortertime.Thisfactis
supportedbyexperimentdone bySayyadnejadetal.,2008 where he comparedthe efficiencybetween
the bulkzincoxide andnanoparticle zincoxide inremovinghydrogen sulphide.The experimentshows
that nanoparticle zincoxide onlytakes15 minutestoremove hydrogensulphidetotallyfromthe drilling
fluidwhereasbulkzincoxide takesalmost1
and a half hour to remove just2.5% of
hydrogensulphide inthe same condition.
Figure 8: Time taken for bulkZnO andnano
ZnO to remove hydrogen sulphide
(Sayyadnejad,Ghaffarianetal.,2008)
The experimentdone by Sayyadnejadetal.(2008), was laterclarifiedfurtherbyAmanullahandAl-
Tahini in2009. Accordingto AmanullahandAl-Tahini (2009),customizednanofluidscontainshydroxyl
groupwhichcan act as a neutralizerandthe nanocompositethatis made of nanosizedsulphide
scavengerscanneutralize acidgassesbychemical reactiontoproduce metal sulphide precipitate.
Then, Cocuzzaet al.(2011), intheirarticle concludedthatnanofluidwillsoonbe furtheralteredto
manage the environmental,healthandsafetyriskissuesthatare causedby the presentof carbon
dioxide andhydrogensulphide inthe hydrocarbonproduced.
High Temperature and High Pressure (HTHP) Challenges:Nowadays,oursource of energyismostly
dependingoncrude oil.Asthe rate of oil consumptionexceedsthe rate of oil produced,the operators
start to explore newareatokeepsupplyingcrude oil (Bland,Mullen,Gonzalez,Harvey,&Pless,2006).
Most of these unexploredareasare highpressure and hightemperature (HPHT) areaswhere they
presentusa verycomplex challenge.WhendealingwithHPHTareas,our mainconcernliesonthe
drillingfluidasthe normal drillingfluidwouldneverbe able towithstandsuchharshcondition.Inthis
case,we have to findsuitable additive foreitherwater- basedornon-aqueous-basedfluids.However,
the optionsare limitedinHPHTconditionespeciallywhenthe temperatureexceeding400˚F (Friedheim
et al.,2012; Hoelscheretal.,2013). Therefore,the researchwasfurthermade andthe use of
nanotechnologywasconsidered.
One of the challengesinHPHTwell istoprovide ahigherdensityfluidfordrillingoperation.Itisnot
uncommonto use a higherdensitydrillingfluidinordertomaintainhighviscosityasone of the
requirementof drillingfluidinHPHTwell.Unfortunately,increasingthe densityof the fluidalsomeans
increasingthe solidloading.Thiswillleadtolow rate of penetrationof drillingbit,extendingtime on
locationandaddeddrillingcosts (Blandetal.,2006). The advancedstudyof nanotechnologyenablethe
highsurface to volume ratioof nanoparticle tointeract withthe surroundingenvironment,thus
reducingthe solidloadinginthe drillingfluid (Cocuzzaetal.,2011). Therefore,the use of
nanotechnologycansignificantlyimprove the rate of penetrationandeliminate the formationdamage
nearthe wellbore.
Some otherchallengesinHPHTwell istoovercome the poorheattransfercoefficientinthe drillingfluid.
The traditional drillingfluidsuchaswater- basedandnon- aqueous- basedfluidare notefficientenough
to withstandthe hightemperature of HPHTwell (Hoelscheretal.,2013). The traditional drillingfluid
that iscommonlyusedinoil andgas industriestodayisnotsuitable forHPHTwell due tolow cooling
efficiencyof the fluid.Inotherwords,the low rate of heatdissipationof the drillingfluidcanleadto
manyproblemsuchas equipmentfailure due tothe effectof hightemperature andreduce the rate of
penetrationandlifetime of the bit,thusincrease the total cost.Byusingnano- baseddrillingfluid,we
can overcome thisproblemasnanoparticlesinthe drillingfluidare more efficientinconductingheat
(Cocuzzaetal.,2011).
Thisideawas supportedbyAmanullah inhisresearch.Accordingto Amanullahetal.(2011),due to the
tinysize,nanoparticle hashuge surface area,high
heattolerance,highthermal conductivity,high
mobility,andcaninteractefficientlywiththe
surrounding.Therefore,he predictedthat
nanotechnologywill playanimportantrole in
solvingmanychallengesinHPHTdrillingcondition.
Figure 1.3: surface area increase with decreasing
size ("Biotoxicity," n.d)
El-DiastyandSalem(2013) explainedfurtherthatthe researchdone byAmanullahmightbe due tohigh
surface area to volume ratio.Whenthe surface areaincrease,more particlesare incontactto each
other,thusprovide abetterthermal conductivity.Therefore,byusingnanotechnologythe coolingof
drillingbitwillbe muchmore efficient,thusreduce the costof drillingprocess.
Figure 9: surface area to
volumeratio (Amanullahetal.,
2011)
Future Applicationof Nanotechnologyin DrillingFluid
Pilotstudy: Oil and gas industryisthe mostchallengingindustrywithalotof limitationsandobstaclesin
itseveryprocess.Therefore,itisone of the most expensiveindustriesinthe world.Whendealingwith
oil and gas industry,moneywouldbe the mainconcern.Itisimportantto maximize the profitapart
fromprovidingasafe workingenvironment.Thus,we shouldalwaysconsidertostudyandapplynew
technologyinordertoimprove oil productionandrecovery.Inthiscase,nanotechnologycouldbe one
of the suitable candidatesthatcanoffera bettersolutionthanourcurrentsystembyeliminating
problemsandlimitationthroughoutdrillingoperation.However,since nanotechnologyisstillunder
research,mostof oil and gas companyfearof the uncertaintiesthatmightstill notyetdiscovered.
Althoughthe experimentconductedinthe laboratoryshowspromisingapplicationindrillingfluid,
nanotechnologyisstillnotdomesticallytestedonthe field.Therefore,itisimportanttoencourage the
oil and gas companyto applythe use of nanotechnologyonthe field.
Mud as a whole:The experimentconductedinthe laboratoryshowsthatnanoparticle canimprove
drillingfluid,howeveritcannotimprove the drillingfluidasawhole.Itmeansthat,the improvementof
drillingfluidisonlyapplicabletoa certainextentdependingonthe type of nanoparticle used.For
example,silicananoparticle cancontrol fluidlossthusincreasewellbore stability,butitcannotact as
viscosifier.There are several componentof drillingfluidwhichare viscosifier,fluidlosscontrol,wetting
agentand emulsifier.We cansay that these componentsare the mainelementof the drillingfluid.
However,there isstill nonanoparticlethatcansatisfyall the componentof drillingfluid.Therefore,the
scientistsshouldkeepdoingthe researchinordertodiscovernew nanoparticle thatcansuitsall
componentof drillingfluid,thusmake aperfectfluidfordrillingoperation.
Cost Analysis:Up until now,there isstill nocompanydare to use nanoparticle intheirdrillingoperation
because itistoo expensive.Itslowavailabilityinthe marketmakesnanoparticleveryhardtoobtainand
veryexpensive tobuy.Soinorderto attract more companyto start utilizingnanoparticleintheir
operationistoanalyze the cost of nanoparticles.Analyze how canthe cost of nanoparticle be reduce.
One of a wayto do the cost analysisisto take intoaccount the overall costof drillingoperationusing
nanoparticle comparedtoconventional one.Nanoparticle hasmore total surface areaexposed
comparedto othermudadditive whichmakesthemmore reactive.Therefore,lessamountof
nanoparticlesneededtoachievesame efficiencyandperformance withthe conventional one thus
decreasinginthe overall cost.Thisaspectmustbe one of the waysto do cost analysisasmany
customersare confusedaboutthe overall costof theiroperationif nanoparticleisbeingused.
Ecofriendlyanalysis: Drillingfluidhasalwaysbeenconcernforthe environmentalist.Mostof the drilling
additives is not environmentally friendly. Therefore, research should be done for certain group of
nanoparticles used in drilling fluid whether it is ecofriendly or not.
Water Cut and Water Coning Prevention: As we know that nanoparticle has the ability to form a
hydrophobic film on the surface of matter. Therefore, instead of preventing water to reach surface of
drillingequipment,thiscoatingshouldentrapswaterpreventingit fromflowingoutof the wellbore thus
maintaining the reservoir pressure with water drives.
Immunity to Vibration: Indeviatedwell,vibrationcancauseddrill stringto damage.Therefore,research
shouldbe done so that nanoparticle couldbe addedin manufacturingthe drill stringto make it tougher
and stronger.
Better Data Transmission: Drilling mud is pumped through drill string to drillbit and up to the annulus.
Measured while drilling used pulse to transfer data of the wellbore to the surface. In order to enhance
this transmission, nanoparticle can be mixed with mud and additive to obtain higher quality of
transmission data.
Increase lifespan:The lifespanof drillingfluidcanbe extendedwhenusingnanoparticle asan additives.
Due toitstinysize,nanoparticlehashighernumberofparticleinacertainamountofvolume.Forexample,
the number of particle of Silver nanoparticle in 10m³ is much higher than in 10m³ of bulk Silver.
Therefore, the viscosity and density of nanofluid is much higher than when using bulk particle as an
additive.So,ittakesalongertime fornanofluidtoreducesitsviscositywhenoperatingindrillingprocess,
thus reduce the cost.
Amanullah,M.,& Al-Tahini,A.M.(2009). Nano-technology-itssignificancein smartfluid development
foroil and gasfield application. Paperpresentedatthe SPESaudiaArabiaSectionTechnical
Symposium.
Amanullah,M.,AlArfaj,M.K.,& Al-abdullatif,Z.A.(2011). Preliminary test results of nano-based drilling
fluidsfor oil and gasfield application. Paperpresentedatthe SPE/IADCDrillingConference and
Exhibition.
Baker.(2006). DrillingContractor:B.H. Corporation.
Barr, W. E. (2008). Nanotechnology:Health &Safety ExposuresIn a Shrinking World. Paperpresentedat
the ASSE Professional DevelopmentConference andExhibition.
Basu,B. J., & DineshKumar,V.(2011). Fabricationof superhydrophobicnanocompositecoatingsusing
polytetrafluoroethyleneandsilicananoparticles. ISRN Nanotechnology,2011.
Beschichten,K.L.(n.d).Anti-friction-coating–an innovative drylubricationforyourproducts.from
http://www.beschichtung.com/en/services/anti-friction-coating/introduction-to-anti-friction-
coating/
Biotoxicity.(n.d).from http://highschoolnanoscience.cnsi.ucla.edu/biotoxicity
Bland,R. G., Mullen,G.A.,Gonzalez,Y.N.,Harvey,F. E., & Pless,M.L. (2006). HPHT drilling fluid
challenges. Paperpresentedatthe IADC/SPEAsiaPacificDrillingTechnologyConference and
Exhibition.
Cocuzza,M., Pirri,F.,Rocca, V.,& Verga,F.(2011). Is The Oil Industry Ready ForNanotechnologies?
Paperpresentedatthe Offshore MediterraneanConference andExhibition.
Dewan,J.T., & Chenvert,M.E. (1993). Mudcakebuildup and invasion in low permeability formations;
application to permeability determination by measurementwhiledrilling.Paperpresentedatthe
SPWLA 34th Annual LoggingSymposium.
El-Diasty,A.I.,& Salem,A.M. (2013). Applicationsof Nanotechnology in theOil & Gasindustry:Latest
TrendsWorldwide & FutureChallengesin Egypt. Paperpresentedatthe NorthAfricaTechnical
Conference andExhibition.
Friedheim,J.,Young,S.,De Stefano,G.,Lee,J.,Guo, Q.,& SWACO,M. (2012). Nanotechnology for
Oilfield Applications-HypeorReality?Paperpresentedatthe SPE International Oilfield
NanotechnologyConferenceandExhibition.
Hareland,G.,Wu, A.,Lei,L., Husein,M.M., & Zakaria,M. F.(2012). InnovativeNanoparticleDrilling Fluid
and Its Benefitsto Horizontalor Extended Reach Drilling. Paperpresentedatthe SPE Canadian
Unconventional ResourcesConference.
Hoelscher,K.P.,De Stefano,G.,Riley,M.,& Young,S. (2012). Application of Nanotechnology in Drilling
Fluids. Paperpresentedatthe SPE International OilfieldNanotechnologyConference and
Exhibition.
Hoelscher,K.P.,Young,S.,Friedheim,J.,&De Stefano, G.(2013). Nanotechnology Application in Drilling
Fluids. Paperpresentedatthe Offshore MediterraneanConference andExhibition.
Kendig,M.,& Buchheit,R.(2003). Corrosioninhibitionof aluminumandaluminumalloysbysoluble
chromates,chromate coatings,andchromate-free coatings. Corrosion,59(5),379-400.
Li, L.,Xu, X.,Sun,J.,Yuan, X.,& Li,Y. (2012). Vital Role of Nanomaterialsin Drilling Fluid and Reservoir
Protection Applications. Paperpresentedatthe AbuDhabi International PetroleumConference
and Exhibition.
Mansoori,G. A.,& Soelaiman,T.F.(2005). Nanotechnology—anintroductionforthe standards
community. Journalof ASTMInternational,2(6),1-21.
Mickelson,W.,Sussman,A.,Zhou,Q.,Veneziani,M.,Ackerman,I.,FrescaFantoni, R.,.. . Milgrome,O.
(2013). An InnovativeWirelessH2S SensorBased On Nanotechnology To ImproveSafety In Oil&
Gas Facilities. Paperpresentedatthe SPE Offshore Europe Oil andGasConference and
Exhibition.
Nanoscience.(n.d).A science curriculum unitfor7thand 8th grade students. Nanosilver:Miracleor
Menace? , from http://nanotechnology.wmwikis.net/Lesson+3+Size+and+Scale
. NanotechnologyandFoodSafety.(2010) Risk AssesmentSection (pp.9-10).Hong Kong:Centre for
FoodSafety.
Sayyadnejad,M.,Ghaffarian,H.,& Saeidi,M.(2008). Removal of hydrogensulfide byzincoxide
nanoparticlesindrillingfluid. InternationalJournalof EnvironmentalScience& Technology,5(4),
565-569.
Sensoy,T.,Chenevert,M.E., & Sharma, M. M. (2009). Minimizing waterinvasion in shalesusing
nanoparticles. Paperpresentedatthe SPEAnnual Technical Conference andExhibition.
Shen,G.,Du, R., Chen,Y.,Lin,C., & Scantlebury,D.(2005). Studyon hydrophobicnano-titaniumdioxide
coatingsfor improvementincorrosionresistance of type 316L stainlesssteel. Corrosion,61(10),
943-950.
Zhuk,Y. N. (2010). Nano-StructuredCvdTungstenCarbide CoatingProtectsAgainstWearAndCorrosion.
CORROSION 2010.

More Related Content

What's hot

Lotus Effect in Nanotechnology
Lotus Effect in NanotechnologyLotus Effect in Nanotechnology
Lotus Effect in NanotechnologyRohit Mahale
 
Experimental Study on Partial Replacement of Cement with Nano Silica in the C...
Experimental Study on Partial Replacement of Cement with Nano Silica in the C...Experimental Study on Partial Replacement of Cement with Nano Silica in the C...
Experimental Study on Partial Replacement of Cement with Nano Silica in the C...ijtsrd
 
IRJET- Analysing the Behaviour of Nanosilica Stabilized Soil
IRJET- Analysing the Behaviour of Nanosilica Stabilized SoilIRJET- Analysing the Behaviour of Nanosilica Stabilized Soil
IRJET- Analysing the Behaviour of Nanosilica Stabilized SoilIRJET Journal
 
NANO MATERIALS ON CONSTRUCTION
NANO MATERIALS ON CONSTRUCTIONNANO MATERIALS ON CONSTRUCTION
NANO MATERIALS ON CONSTRUCTIONkuntansourav
 
Nano clean up
Nano clean upNano clean up
Nano clean upkimsradha
 
Application of nano-technology in construction Detailed Report
Application of nano-technology in construction Detailed ReportApplication of nano-technology in construction Detailed Report
Application of nano-technology in construction Detailed ReportAmeer Muhammed
 
Nanotechnology for sustainable wastewater treatment
Nanotechnology for sustainable wastewater treatmentNanotechnology for sustainable wastewater treatment
Nanotechnology for sustainable wastewater treatmentTejas Thakur
 
IRJET- An Experimental Study of Geopolymer Brick by Using of Waste Plastics
IRJET-  	  An Experimental Study of Geopolymer Brick by Using of Waste PlasticsIRJET-  	  An Experimental Study of Geopolymer Brick by Using of Waste Plastics
IRJET- An Experimental Study of Geopolymer Brick by Using of Waste PlasticsIRJET Journal
 
Guanghui Song Resume_Nov 24 2014
Guanghui Song Resume_Nov 24 2014Guanghui Song Resume_Nov 24 2014
Guanghui Song Resume_Nov 24 2014Guanghui Song
 
IRJET- Experimental Investigation on Behaviour of Nano Silica in Concrete
IRJET- Experimental Investigation on Behaviour of Nano Silica in ConcreteIRJET- Experimental Investigation on Behaviour of Nano Silica in Concrete
IRJET- Experimental Investigation on Behaviour of Nano Silica in ConcreteIRJET Journal
 
Nano in civil
Nano in civilNano in civil
Nano in civiltatteya
 
Nanotechnology in construction materioal
Nanotechnology in construction materioalNanotechnology in construction materioal
Nanotechnology in construction materioalJitendra Kumar
 
Nano porous membranes for water purification by shrinath ghadge
Nano porous membranes for water purification by shrinath ghadgeNano porous membranes for water purification by shrinath ghadge
Nano porous membranes for water purification by shrinath ghadgeShrinath Ghadge
 
Use of Nanotechnology in Civil Engineering
Use of Nanotechnology in Civil EngineeringUse of Nanotechnology in Civil Engineering
Use of Nanotechnology in Civil EngineeringAkshay D Nicator
 
Preparation of ZnO Nanostructures by Solvothermail Method
Preparation of ZnO Nanostructures by Solvothermail MethodPreparation of ZnO Nanostructures by Solvothermail Method
Preparation of ZnO Nanostructures by Solvothermail MethodHai Yen Dang
 
Nanobioremediation by shreya
Nanobioremediation by shreyaNanobioremediation by shreya
Nanobioremediation by shreyaShreya Modi
 

What's hot (20)

Nanotechnology
NanotechnologyNanotechnology
Nanotechnology
 
Lotus Effect in Nanotechnology
Lotus Effect in NanotechnologyLotus Effect in Nanotechnology
Lotus Effect in Nanotechnology
 
Experimental Study on Partial Replacement of Cement with Nano Silica in the C...
Experimental Study on Partial Replacement of Cement with Nano Silica in the C...Experimental Study on Partial Replacement of Cement with Nano Silica in the C...
Experimental Study on Partial Replacement of Cement with Nano Silica in the C...
 
IRJET- Analysing the Behaviour of Nanosilica Stabilized Soil
IRJET- Analysing the Behaviour of Nanosilica Stabilized SoilIRJET- Analysing the Behaviour of Nanosilica Stabilized Soil
IRJET- Analysing the Behaviour of Nanosilica Stabilized Soil
 
NANO MATERIALS ON CONSTRUCTION
NANO MATERIALS ON CONSTRUCTIONNANO MATERIALS ON CONSTRUCTION
NANO MATERIALS ON CONSTRUCTION
 
Permeable pavement by using titanium dioxide
Permeable pavement by using titanium dioxidePermeable pavement by using titanium dioxide
Permeable pavement by using titanium dioxide
 
Nano clean up
Nano clean upNano clean up
Nano clean up
 
Application of nano-technology in construction Detailed Report
Application of nano-technology in construction Detailed ReportApplication of nano-technology in construction Detailed Report
Application of nano-technology in construction Detailed Report
 
Nanotechnology for sustainable wastewater treatment
Nanotechnology for sustainable wastewater treatmentNanotechnology for sustainable wastewater treatment
Nanotechnology for sustainable wastewater treatment
 
IRJET- An Experimental Study of Geopolymer Brick by Using of Waste Plastics
IRJET-  	  An Experimental Study of Geopolymer Brick by Using of Waste PlasticsIRJET-  	  An Experimental Study of Geopolymer Brick by Using of Waste Plastics
IRJET- An Experimental Study of Geopolymer Brick by Using of Waste Plastics
 
Guanghui Song Resume_Nov 24 2014
Guanghui Song Resume_Nov 24 2014Guanghui Song Resume_Nov 24 2014
Guanghui Song Resume_Nov 24 2014
 
IRJET- Experimental Investigation on Behaviour of Nano Silica in Concrete
IRJET- Experimental Investigation on Behaviour of Nano Silica in ConcreteIRJET- Experimental Investigation on Behaviour of Nano Silica in Concrete
IRJET- Experimental Investigation on Behaviour of Nano Silica in Concrete
 
Nano in civil
Nano in civilNano in civil
Nano in civil
 
Nanotechnology in construction materioal
Nanotechnology in construction materioalNanotechnology in construction materioal
Nanotechnology in construction materioal
 
B0560816
B0560816B0560816
B0560816
 
Nano porous membranes for water purification by shrinath ghadge
Nano porous membranes for water purification by shrinath ghadgeNano porous membranes for water purification by shrinath ghadge
Nano porous membranes for water purification by shrinath ghadge
 
Use of Nanotechnology in Civil Engineering
Use of Nanotechnology in Civil EngineeringUse of Nanotechnology in Civil Engineering
Use of Nanotechnology in Civil Engineering
 
Thesis bh. koti reddy
Thesis  bh. koti reddyThesis  bh. koti reddy
Thesis bh. koti reddy
 
Preparation of ZnO Nanostructures by Solvothermail Method
Preparation of ZnO Nanostructures by Solvothermail MethodPreparation of ZnO Nanostructures by Solvothermail Method
Preparation of ZnO Nanostructures by Solvothermail Method
 
Nanobioremediation by shreya
Nanobioremediation by shreyaNanobioremediation by shreya
Nanobioremediation by shreya
 

Viewers also liked

Динара Шаймерден-Приложение рецептов-Конкуренты
Динара Шаймерден-Приложение рецептов-КонкурентыДинара Шаймерден-Приложение рецептов-Конкуренты
Динара Шаймерден-Приложение рецептов-КонкурентыДинара Шаймерден
 
Кондитерская Sweet time+ Команда Five
Кондитерская Sweet time+ Команда FiveКондитерская Sweet time+ Команда Five
Кондитерская Sweet time+ Команда FiveSymbatik Ospanova
 
Tour nha trang tết âm lịch 2016
Tour nha trang tết âm lịch 2016Tour nha trang tết âm lịch 2016
Tour nha trang tết âm lịch 2016Tour Vietbalo
 
03 tercera sesión interactiva definitiva
03 tercera sesión interactiva definitiva03 tercera sesión interactiva definitiva
03 tercera sesión interactiva definitivaAlfredo Prieto Martín
 
Sistema de Informacion Hidrica de la Cuenca del Lago Poopó
Sistema de Informacion Hidrica de la Cuenca del Lago PoopóSistema de Informacion Hidrica de la Cuenca del Lago Poopó
Sistema de Informacion Hidrica de la Cuenca del Lago Poopócuencapoopo
 
ISO 9001:2008 para Prendamex
ISO 9001:2008 para PrendamexISO 9001:2008 para Prendamex
ISO 9001:2008 para PrendamexPrendamex
 
Guia metodológica para la enseñanza de lenguaje y comunicación
Guia metodológica para la enseñanza de lenguaje y comunicaciónGuia metodológica para la enseñanza de lenguaje y comunicación
Guia metodológica para la enseñanza de lenguaje y comunicaciónguest301f7126
 

Viewers also liked (9)

XXX EBC Data Analysis Biweekly Report
XXX EBC Data Analysis Biweekly ReportXXX EBC Data Analysis Biweekly Report
XXX EBC Data Analysis Biweekly Report
 
Динара Шаймерден-Приложение рецептов-Конкуренты
Динара Шаймерден-Приложение рецептов-КонкурентыДинара Шаймерден-Приложение рецептов-Конкуренты
Динара Шаймерден-Приложение рецептов-Конкуренты
 
Кондитерская Sweet time+ Команда Five
Кондитерская Sweet time+ Команда FiveКондитерская Sweet time+ Команда Five
Кондитерская Sweet time+ Команда Five
 
Tour nha trang tết âm lịch 2016
Tour nha trang tết âm lịch 2016Tour nha trang tết âm lịch 2016
Tour nha trang tết âm lịch 2016
 
03 tercera sesión interactiva definitiva
03 tercera sesión interactiva definitiva03 tercera sesión interactiva definitiva
03 tercera sesión interactiva definitiva
 
Sistema de Informacion Hidrica de la Cuenca del Lago Poopó
Sistema de Informacion Hidrica de la Cuenca del Lago PoopóSistema de Informacion Hidrica de la Cuenca del Lago Poopó
Sistema de Informacion Hidrica de la Cuenca del Lago Poopó
 
ISO 9001:2008 para Prendamex
ISO 9001:2008 para PrendamexISO 9001:2008 para Prendamex
ISO 9001:2008 para Prendamex
 
Housing Market Trends Report: Spring 2016
Housing Market Trends Report: Spring 2016Housing Market Trends Report: Spring 2016
Housing Market Trends Report: Spring 2016
 
Guia metodológica para la enseñanza de lenguaje y comunicación
Guia metodológica para la enseñanza de lenguaje y comunicaciónGuia metodológica para la enseñanza de lenguaje y comunicación
Guia metodológica para la enseñanza de lenguaje y comunicación
 

Similar to A CRITICAL REVIEW OF NANOTECHNOLOGY APPLICATION IN DRILLING FLUID OVER THE LAST DECADES

Commercialize Nanotech
Commercialize NanotechCommercialize Nanotech
Commercialize Nanotechsss64
 
A Review on Nanomaterial Revolution in Oil and Gas Industry for EOR (Enhanced...
A Review on Nanomaterial Revolution in Oil and Gas Industry for EOR (Enhanced...A Review on Nanomaterial Revolution in Oil and Gas Industry for EOR (Enhanced...
A Review on Nanomaterial Revolution in Oil and Gas Industry for EOR (Enhanced...CrimsonPublishersRDMS
 
Safety of nanotechnology
Safety of nanotechnologySafety of nanotechnology
Safety of nanotechnologyTeja Swaroop
 
applied sciencesReviewA State-of-the-Art Review of .docx
applied  sciencesReviewA State-of-the-Art Review of .docxapplied  sciencesReviewA State-of-the-Art Review of .docx
applied sciencesReviewA State-of-the-Art Review of .docxarmitageclaire49
 
Nanotechnology
NanotechnologyNanotechnology
NanotechnologyKishore D
 
Nanotechnology: Understanding the Applications in Nutrition Science
Nanotechnology: Understanding the Applications in Nutrition Science Nanotechnology: Understanding the Applications in Nutrition Science
Nanotechnology: Understanding the Applications in Nutrition Science Neelakshi Tanima
 
Nanotechnology for safe food packaging
Nanotechnology for safe food packagingNanotechnology for safe food packaging
Nanotechnology for safe food packagingDr. Keshab Debnath
 
greennano4344-160813141526.pptx Green Nanotechnology
greennano4344-160813141526.pptx Green Nanotechnologygreennano4344-160813141526.pptx Green Nanotechnology
greennano4344-160813141526.pptx Green NanotechnologySrishanthaKV
 
Application of Nanoparticles in Remediation of Crude Oil Contaminated Soil
Application of  Nanoparticles in Remediation of Crude Oil  Contaminated Soil Application of  Nanoparticles in Remediation of Crude Oil  Contaminated Soil
Application of Nanoparticles in Remediation of Crude Oil Contaminated Soil GIFT KIISI NKIN
 
Nano technology by smitkapdiya
Nano technology by smitkapdiyaNano technology by smitkapdiya
Nano technology by smitkapdiyaSmit Kapadiya
 
Manufacture of Nano Material
Manufacture of Nano MaterialManufacture of Nano Material
Manufacture of Nano MaterialShriSailaxmiS
 
Nanotechnology and its application in postharvest technology by l. jeebit singh
Nanotechnology and its application in postharvest technology by l. jeebit singhNanotechnology and its application in postharvest technology by l. jeebit singh
Nanotechnology and its application in postharvest technology by l. jeebit singhJeebit Singh
 
Applications of nano technology in enhanced oil recovery
Applications of nano technology in enhanced oil recoveryApplications of nano technology in enhanced oil recovery
Applications of nano technology in enhanced oil recoverymahdi shahbazi
 
Application of nanotechnology in agriculture
Application of nanotechnology in agricultureApplication of nanotechnology in agriculture
Application of nanotechnology in agricultureAmit Bishnoi
 
2006 asse teleweb presentation
2006 asse teleweb presentation2006 asse teleweb presentation
2006 asse teleweb presentationAhmad Rashwan
 
EFFECT OF DIFFERENT NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF CO...
EFFECT OF DIFFERENT NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF CO...EFFECT OF DIFFERENT NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF CO...
EFFECT OF DIFFERENT NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF CO...SJ BASHA
 

Similar to A CRITICAL REVIEW OF NANOTECHNOLOGY APPLICATION IN DRILLING FLUID OVER THE LAST DECADES (20)

Commercialize Nanotech
Commercialize NanotechCommercialize Nanotech
Commercialize Nanotech
 
Nanoparticles Essay
Nanoparticles EssayNanoparticles Essay
Nanoparticles Essay
 
A Review on Nanomaterial Revolution in Oil and Gas Industry for EOR (Enhanced...
A Review on Nanomaterial Revolution in Oil and Gas Industry for EOR (Enhanced...A Review on Nanomaterial Revolution in Oil and Gas Industry for EOR (Enhanced...
A Review on Nanomaterial Revolution in Oil and Gas Industry for EOR (Enhanced...
 
Safety of nanotechnology
Safety of nanotechnologySafety of nanotechnology
Safety of nanotechnology
 
applied sciencesReviewA State-of-the-Art Review of .docx
applied  sciencesReviewA State-of-the-Art Review of .docxapplied  sciencesReviewA State-of-the-Art Review of .docx
applied sciencesReviewA State-of-the-Art Review of .docx
 
Nanotechnology
NanotechnologyNanotechnology
Nanotechnology
 
Nanotechnology: Understanding the Applications in Nutrition Science
Nanotechnology: Understanding the Applications in Nutrition Science Nanotechnology: Understanding the Applications in Nutrition Science
Nanotechnology: Understanding the Applications in Nutrition Science
 
Nanotechnology for safe food packaging
Nanotechnology for safe food packagingNanotechnology for safe food packaging
Nanotechnology for safe food packaging
 
greennano4344-160813141526.pptx Green Nanotechnology
greennano4344-160813141526.pptx Green Nanotechnologygreennano4344-160813141526.pptx Green Nanotechnology
greennano4344-160813141526.pptx Green Nanotechnology
 
Green Nanotechnology
Green NanotechnologyGreen Nanotechnology
Green Nanotechnology
 
Application of Nanoparticles in Remediation of Crude Oil Contaminated Soil
Application of  Nanoparticles in Remediation of Crude Oil  Contaminated Soil Application of  Nanoparticles in Remediation of Crude Oil  Contaminated Soil
Application of Nanoparticles in Remediation of Crude Oil Contaminated Soil
 
Nano technology by smitkapdiya
Nano technology by smitkapdiyaNano technology by smitkapdiya
Nano technology by smitkapdiya
 
Nanotechnology.
Nanotechnology.Nanotechnology.
Nanotechnology.
 
Manufacture of Nano Material
Manufacture of Nano MaterialManufacture of Nano Material
Manufacture of Nano Material
 
Nanotechnology and its application in postharvest technology by l. jeebit singh
Nanotechnology and its application in postharvest technology by l. jeebit singhNanotechnology and its application in postharvest technology by l. jeebit singh
Nanotechnology and its application in postharvest technology by l. jeebit singh
 
Applications of nano technology in enhanced oil recovery
Applications of nano technology in enhanced oil recoveryApplications of nano technology in enhanced oil recovery
Applications of nano technology in enhanced oil recovery
 
Application of nanotechnology in agriculture
Application of nanotechnology in agricultureApplication of nanotechnology in agriculture
Application of nanotechnology in agriculture
 
2006 asse teleweb presentation
2006 asse teleweb presentation2006 asse teleweb presentation
2006 asse teleweb presentation
 
EFFECT OF DIFFERENT NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF CO...
EFFECT OF DIFFERENT NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF CO...EFFECT OF DIFFERENT NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF CO...
EFFECT OF DIFFERENT NANOPARTICLES ON PHYSICAL AND MECHANICAL PROPERTIES OF CO...
 
F047038044
F047038044F047038044
F047038044
 

A CRITICAL REVIEW OF NANOTECHNOLOGY APPLICATION IN DRILLING FLUID OVER THE LAST DECADES

  • 1. A CRITICAL REVIEW OF NANOTECHNOLOGY APPLICATION IN DRILLING FLUID OVER THE LAST DECADES Abstract Drilling fluid plays an important role during drilling process. In the past few decades, mud engineers have been trying to modify drilling fluid to improve its quality in term of its viscosity, density, specific gravity and any other physical properties. The demand of a better drilling fluid increases when oil and gas company turns their attention to other unexplored areas such as the unstable shale areas and high pressure and high temperature (HPHT) areas. This is where the nanotechnology takes part in oil and gas challenges. The use of nanotechnology in drilling fluid has been proven in many researches and experiments could improve the physical properties of the drilling fluid. Although there are many papers that discuss the application of nanotechnology in oil and gas industry, but yet, not many researchers are focusing on the application of nanotechnology in drilling fluid itself. Therefore, this paper will provide a better exposure of the application of nanotechnology in drilling fluid over the last decades. By going through this paper, it will first explain about nanotechnology before providing more information in details of its application in drilling fluid. In addition, this paper will only provide information on the areas which shows a promising future in oil and gas industry, where in reality the involvement of nanotechnology in drilling fluid is still under research. Introduction In the past few decades, nanotechnology has been a prominent research in many areas including oil and gas industry. The continuous study of nanotechnology and its chemical properties have lead into numerous applications in many products especially in cosmetics, medical, electronics, food, fabric, painting and coating industries as well as in oil and gas industries. Nanotechnology is the any technology that is utilized at the Nano-scale approximately between 1 and 100 nanometers (El-Diasty & Salem, 2013). Figure 1: The nanoscale (Nanoscience, n.d)
  • 2. Figure 2: Nanoparticle size vs cells(Barr, 2008) These tiny particles offer exceptional characteristics which are very useful and can be applied in various fields. Most of the products or technology developed by those industries used nanoparticles to deliver drugs, enhance strength and durability, and as a repelling properties which is commonly used in painting and coating. Some example of nanoparticles and its uses are described herein. Nanoparticles Uses Gold nanoparticles It is used to target drugs to certain parts of body to treat tumor Silica It is used as an additive to rubber and plastics Zinc oxide It is used to make the food last longer Silver nanoparticles It is used to kill bacteria in fabric Silicon dioxide crystalline It is used to strengthen a racquet by fill in the gap between carbon fibre Titanium dioxide It is common ingredients in sunscreen to protect us from harmful UV ray Table 1: Examples of nanoparticle and its uses Some nanoparticles might have more than one uses. For example, apart from treating tumor, Gold nanoparticles are also used to solve air pollution when embedded with other elements. Therefore, it is possible that most of these nanoparticles could be having different uses that are yet to be discovered. As time passes by, the uses and advantages of nanoparticles of every elements are revealed one after another and its uses are put into application wherever they see fit. However, there are some serious issues related to nanotechnology. Nanoparticles are very small compared to its normal size particle. This distinction in size lead to the change in the properties of the particles. In other words, nanotechnology have a very unique of physical and chemical properties. As the properties of tiny particles is not easy to handle and predicted there is uncertainties in that matters. For example, a piece of gold is obviously gold in color but that is not the case for gold nanoparticles which might have deep red in color or even black if it is mix with water.
  • 3. Due to these uncertainties, the application of nanotechnology in oil and gas industries is still quite limited even though almost every industries have already make use of the benefits and advantages of nanotechnology. In fact the application of nanotechnology in oil industry is only limited to the construction and material side, whereas the use of nanotechnology in drilling fluid is still not applicable. It is because nanotechnology is still new with a lot of uncertainties. As a precaution step the company is more concern in minimizing the risk by reducing the uncertainties. Therefore, this paper will provide an exposure on how these unique characteristic, physical and chemical properties of nanotechnology can improve the drilling fluid, thus increase the efficiency of the overall process. Definition In the year 2005, nanoparticle is defined as a capability to create new matter in an atomic scale or molecular level with the aim to study and exploit the new matter’s properties (Mansoori & Soelaiman, 2005). Later itisdefined asascience,technologyandengineeringof matterthatare preciselymanipulated at nano scale dimension. This technology involved the use of materials at a range of 1-100 nanometers size all bythemselvesortocreate anothernew large material fromthemwhichisbeneficial anduseful to others.Nanotechnologygotitsname fromprefix “nano”whichmeansone-billionthof ameter(El-Diasty & Salem, 2013). Nanotechnology involved the study and application of tiny things which is known as nanoparticles. Nanoparticles are matter that has all three dimension in the nanoscale ("Nanotechnology and Food Safety," 2010) and is made up of atoms which has radius below 100nm (El-Diasty & Salem, 2013). Characterization of Nanoparticles In order for us to understand the true capabilities of nanoparticles, specified knowledge about them is needed.We mustdigintothe nanoparticles’worldsothatwe canfurtherexamine howthe nanoparticles behaves in certain environment and what are its characteristics. Nanoparticles’sizeissotinyin nature whichisin range of lessthan 100 nanometerleadstothe increase of total surface area exposedcomparedtomaterial of the same volume.Thus,more particle can forma bondwithnanoparticlesinvariouswayswhichwill make a strongerlightweightmaterial.Figure 2shows how nanoparticleshashightotal surface area exposedcomparedtoother material of the same volume. It also has fine structure of grain and can form a very thin layer of lubricating coating which allow themselvestoslide smoothlyagainsteachother(Amanullah&Al-Tahini,2009; El-Diasty & Salem, 2013). Figure 2: Comparison of total surface area exposed("Nanotechnology and Food Safety," 2010)
  • 4. High total surface area exposed of nanoparticles and its small and tiny sized characteristic make nanoparticle’s heat transfer coefficient better.Thus, good heat transfer coefficient makes nanoparticles capable toaccelerate the transmissionof heatfromone pointtoanother.Inasimplerword,the hightotal surface area characteristics owned by the nanoparticles enhanced them to conduct heat more easily (Amanullah, AlArfaj, & Al-abdullatif, 2011). Some of the nanoparticles are water-wet and some are oil-wet depending on the nature of the nanoparticles themselves. Nanoparticles with oil-wet characteristic will let oil wets its total surface area exposed thus creating a film of oil on the entire surface of the nanoparticles which in turn lead to hydrophobicfilmbeingform(El-Diasty&Salem, 2013).Beside oil-wet,there are some nanoparticlesthat has a water-wet characteristic which is vice versa of oil-wet. Nanoparticles are also ecofriendly and stable which can be used to drill well that is sensitive to harsh environment. It is ecofriendly and green because it is added in small amount into the drilling fluid compared to the conventional drilling fluid that is not green and leads to environmental pollution (Amanullah et al., 2011). As nanoparticles is so small, once the size get below 100 nanometer, the attractive forces between one another particle becomes significant to one another. Thus will result in more viscousfluidatrelativelylow level of concentration.Furthermore,due tothe high particle-particle interaction,bondingbetweennanoparticlesisstrong.Therefore,certainnanomaterial canwithstandhigh pressure and high temperature environment (Hoelscher, Young, Friedheim, & De Stefano, 2013). Table 1: Summaryof Nanoparticleandtheir applicationindrillingfluid. Application of Nanotechnology in Drilling Fluid Preventing Fluid Loss into Reservoir Formation: Researcher has been trying to use nanoparticles as a mediumtopreventfluidlossinto formation.Inconventional methodof drilling,we relyonthe mudcake formed at the wellbore’swall to prevent further loss of fluid into the formation. The thickness of the mudcake depends on the amount of fluid loss into the formation. In early years, Dewan and Chenvert (1993) state that in a low permeability shale, formation of mudcake will be slower as less fluid is going into the formation. Later, Hoelscher, De Stefano, Riley, and Young (2012) state that impermeable mudcake may notbe able to format all if formationhasnanosizedporeswhichmakethe permeabilityof Nanoparticles Sizes (nm) Characteristics Applications in Drilling Fluid Nanosilica Between 5 to 100 Small and tiny sized - Fluid loss control - Wellbore stability - Reduce pipe sticking - Pipe sticking Carbon-based Between 15 to 100 Low surface energy - Prevents bit balling - Prevents corrosion Nickel-based Below 100 Fine texture and structure - Reduce torque and drag Zinc Oxide Between 14-25 Higher reactivity than hydrogen sulphide - Remove hydrogen sulphide from crude oil All Below 100 - Good heat transfer coefficient - High total surface area - Transferheat fromreservoirto surface efficiently - Reduce solid content in mud
  • 5. the formation extremely low. Fluid can still go through it without the formation of mudcake (Figure 3). Thisfluidlossisuncontrollable.Inordertodeal withthisproblem, nanoparticlesmustbe pluggedintothe nanosized pores so that no further fluid can go through the tiny pores. Water that manage to invade the shale through nanosized pores which has the size of 3 to 100 nanometers can lead to fracturing which in turn interferes the wellbore stability. However the invasion could be stopped by using nanosilica. Sensoy, Chenevert,and Sharma (2009) showed that the fluidflow through an Atoka shale could be stopped by utilizing 29% by weight of a specific nanosilica (Figure 4). Then according to Hoelscher et al. (2012), silica nanoparticles that have the size between 5 to 100 nanometer is plugged into the nanosized pores in the formation to reduce the pressure difference betweenthe wellbore andthe reservoirformationthusshuttingoffthe fluidloss.Mudcake thatisformed fromnanoparticlesisrelativelythinthanthe one formedbyconventional drillingfluid.Thisverythinlayer of mudcake helpsinreducingthe fluidlossintothe formationwhile minimizingformationdamage while drilling. In addition, not only choosing suitable size of the nanoparticles that matters in the effective plugging, type of surface treatment is also an important parameters. Later, Hoelscheretal.(2013) conduct an experimenttoshow the transmissionof pressure through Mancos shale.The resultof the experimentshowedthata new drillingfluidsystemwith3% of nanosilicacouldcompletelyshutoff the pressure transmissionacrossthe shale sample.These works showedthattheoryof pluggingnanosizedporeswithnanoparticlesispossible and canpreventfluidloss intothe formationwhile maintainingthe wellbore stability. Figure 3: Filter cake’s thicknessdepends on Figure 4: Sealingperformanceof AtokaShale amountof fluidloss. (Hoelscheret al., 2012) (Sensoyet al.,2009) PreventingBit Balling:Bit ballingisaconditionwhere formation’s claysjoinandaccumulate atthe drillingbitcontinuouslyand stickintothe toothof the drill bitformingasphericallysolidthatcoversthe bit.Thisin turnreducesdrasticallythe rate of penetrationof the bitwhichwill waste bothtime and operationcost.This occurs due to the stickycharacteristicsof the clay whenitisin contact withwater. Therefore, the ultimate solution to this problem is to invent a film that can repel clay and water from being in contact with the bit. At first, researchers found that hydrophobic coating can be formed either by using nanochromates and nanotitanium dioxide ((Kendig & Buchheit, 2003);(Shen, Du, Chen, Lin, & Scantlebury, 2005)).
  • 6. Then,thisideawas usedin makinga drillingfluidthatcan reduce bitballingproblem.Ithas the abilityto form a sheet like hydrophobic coating near the surface of the drill bit (Amanullah & Al-Tahini,2009). Nanoparticleshave thiskindof abilitybecausetheycreate roughnessonthe surface of the drill bitwhich thenproduce alowsurface energy matteronthe bit.Asthe surface energyislow,contactangle between water and the surface will be high. Therefore, hydrophobicfilmwill be formedonthe surface of the bit. The higher the concentration of nanoparticles, the higher the water contact angle whichmeansthe morehydrophobicisthe coating(Figure 5) (Basu& DineshKumar,2011). Due to the hydrophobic layer formed by the nanoparticles,wateraswell asclayare repelled from the drill bitthus preventingthe formation of bit balling. Figure 5: Water contact angle increase with concentration of nanoparticle (Basu & Dinesh Kumar, 2011) ReducingFriction and Drag: Frictionanddrag are one of the problemthatcan affectthe efficiencyof drillingformationbecause itwastedenergyandcauseswearandtear to the equipmentwhich consequentlyleadstothe damage of the bottomhole equipment.Inordertoreduce thisproblem, appropriate type of drillingfluidisselectedforthe operation.The selecteddrillingfluidmusthave good lubricitytoovercome the frictional forcesthatexistsdue tothe rotationorslidingof the drillingpipe inside the wellborewitheitherformationwall orwithcasing.Drillingengineershasusedoil based drillingfluidinordertoreduce frictionanddrag force inside wellbore.Howeverthistype of drillingfluid isnot ecofriendly andtheirconsumption mustbe below the limitof usage.Therefore,researchersmust finda wayto create drillingfluidwhichisenvironmentallyfriendlyandcanreduce frictionforce efficiently. Researchersbelievedthatnanoparticleshave highpotential tomeet these requirementbecause of their tinysizeswithfine texture andstructure. Theyhave the abilitytoform a thin layerof lubricatingcoating between the bottomhole equipment and the borehole wall.The ultra-thin layer of nanoparticles allows easy slidingof the drill pipe whichis responsible forreducingthe torque and drags probleminborehole (Amanullah & Al-Tahini, 2009). Their structure and size make them capable to enter the friction region between two surfaces easily. Furthermore, according to Hareland, Wu, Lei, Husein, and Zakaria (2012), nanoparticles can seal filter cake completely by producing crack-free and smooth surfaces which then contribute to slippery film between formation and the drill string. In addition, because nanoparticles is small insize,kineticenergyandabrasiveforce willbe reducedsignificantlywhichmakeswearandtearof the bottomholetool becomesnegligible. Theyalsofound outthatfrictioncoefficientcanbe reducedmore than 25% when nickel-based nanoparticles is added.
  • 7. Figure 6: Illustration of lubricating coating at the surface of material (Beschichten, n.d) Solid Content Reduction: During drilling operation, one of the most important things to take into considerationis the operationtime.Longertime neededsignifieshuge amountof moneythat are going to spend. In order to reduce the operation time needed during drilling, rate of penetration (ROP) of bit needtobe increased.AccordingtoAmanullahandAl-Tahini (2009),ROPisdirectlyrelatedtosolidcontent in drillingmud.Itcan be increasedif the amountof solidcontentin drillingfluidis reduced (Figure 7).In nano-based mud, only a little amount of volume of nanoparticles are needed due to their large surface areaperunitvolume.Inthatcase,nanoparticlecanreduce solidcontentof the mudandatthe same time increase the rate of penetration of drilling bit which in turn saves the time and cost needed for the operation. Figure 7: Relationship between rate of penetration and mud solid content (Amanullah & Al-Tahini, 2009) CorrosionReduction:Corrosionisone of the mainthingthatdrillingengineersare concernaboutbecause drilling operation involved extreme erosive and friction force between tool and formation. However, nanoparticle isbelievedtobe abletosolvethisproblem. Shenetal.(2005) state thatnanotitaniumdioxide particlesare capable of forminghydrophobiccoating.Thisstatementissupportedby AmanullahandAl- Tahini (2009) that said nanoparticle can form hydrophobic film on the surface of downhole tool. Unfortunately, hydrophobic coating that has high wettability will be a poor corrosion resistance.
  • 8. Hydrophobiccoatingonlyrepelwaterandclayfromdownholeequipment.Hydrogensulfide whichisone of the mainfactor thatcan cause corrosionstill canreachthe equipment.Therefore,nanoparticlesuchas zincoxide isusedtoremove hydrogensulfidefromthecrude oil(Sayyadnejad,Ghaffarian,&Saeidi,2008). This will be explained more in removal of toxic gases section. Later, Zhuk(2010) inventsa perfectcoatingthatcontain TungstenCarbide distributedinmetal Tungsten matrix whichlevelupmetal’sstrengthanderosionresistance.Ithashightoughnessandimpactresistance which reduce the probability of getting corrosion. Furthermore, this product has no temperature limitation compared to organic coating or sealants. Prevent Pipe Sticking: Pipe sticking problem occurs due to contact made by drill pipe and the wall of formation containing mudcake. In order to resolve this problem, Baker (2006) has created a nanofluid polymerwhichcouldgothroughporesandaccumulate atthe wallof wellboreformingthinlowpermeable mudcake (Figure 8). Thisin turn reduce the differential pressure whichconsequentlyreducesprobability of differential stickingproblem tooccur. In conclusion,microfracturesinshale or sandcould be plugged in by the nanoparticles thus reducing pressure transmission which in turn prevent pipe sticking (Li, Xu, Sun, Yuan, & Li, 2012). Figure 8: Plugging effect of nanofluid polymer(Li et al., 2012) Removal ofToxic Gases:Crude oil and natural gassesare the mixture of hydrocarboncontainedmostly methane,butalsomightcontainsome otheralkane,hydrogensulphide,nitrogen,andoxygen.Mostof these natural gassesare harmlessandgive noconcernto drillingengineer.However,hydrogensulphide couldpose a seriousthreatduringdrillingprocess. Duringdrillingprocess,there isapossibility that hydrogensulphide candiffuseintothe drillingfluidfromthe formation.Whenthishappen,engineers shouldbe well preparedtohandle the situationashydrogensulphide containedhighlevelof toxicity whichcan paralyzedthe olfactorynerve whenit isbreathinat highconcentration (Mickelsonetal., 2013). In addition, Cocuzza,Pirri,Rocca,andVerga(2011), statedthatthe presentof toxicgassuch as hydrogenchloride andhydrogensulphide couldinduce the corrosionindrillingpipeandother equipment.Therefore itcouldaffectboththe drillingequipmentandthe worker’shealthapartfrom raisingenvironmentalpollution.Itisimportanttohandle hydrogensulphidebefore itisvaporize to atmosphere inordertoreduce riskand majorlossto the company. Sayyadnejadetal.(2008), proposedthatby using14 to25 nmof zincoxide and44 to 56 m²/g specific surface area,we can remove hydrogensulphide fromthe drillingfluidinasimple chemical reaction.This type of chemical reactioniscalleddisplacementreaction.The equationof chemical reactionisas followed: (ZnO + H₂S → ZnS + H₂O)
  • 9. By usingnanoparticle zincoxide,the processof removal of hydrogensulphide isfasterdue tothe greatersurface area of nanoparticles.Whenthe surface areaof the particlesisgreater,the chemical reactionbetweenzincoxide andhydrogensulphide takesplace atmuchshortertime.Thisfactis supportedbyexperimentdone bySayyadnejadetal.,2008 where he comparedthe efficiencybetween the bulkzincoxide andnanoparticle zincoxide inremovinghydrogen sulphide.The experimentshows that nanoparticle zincoxide onlytakes15 minutestoremove hydrogensulphidetotallyfromthe drilling fluidwhereasbulkzincoxide takesalmost1 and a half hour to remove just2.5% of hydrogensulphide inthe same condition. Figure 8: Time taken for bulkZnO andnano ZnO to remove hydrogen sulphide (Sayyadnejad,Ghaffarianetal.,2008) The experimentdone by Sayyadnejadetal.(2008), was laterclarifiedfurtherbyAmanullahandAl- Tahini in2009. Accordingto AmanullahandAl-Tahini (2009),customizednanofluidscontainshydroxyl groupwhichcan act as a neutralizerandthe nanocompositethatis made of nanosizedsulphide scavengerscanneutralize acidgassesbychemical reactiontoproduce metal sulphide precipitate. Then, Cocuzzaet al.(2011), intheirarticle concludedthatnanofluidwillsoonbe furtheralteredto manage the environmental,healthandsafetyriskissuesthatare causedby the presentof carbon dioxide andhydrogensulphide inthe hydrocarbonproduced. High Temperature and High Pressure (HTHP) Challenges:Nowadays,oursource of energyismostly dependingoncrude oil.Asthe rate of oil consumptionexceedsthe rate of oil produced,the operators start to explore newareatokeepsupplyingcrude oil (Bland,Mullen,Gonzalez,Harvey,&Pless,2006). Most of these unexploredareasare highpressure and hightemperature (HPHT) areaswhere they presentusa verycomplex challenge.WhendealingwithHPHTareas,our mainconcernliesonthe drillingfluidasthe normal drillingfluidwouldneverbe able towithstandsuchharshcondition.Inthis case,we have to findsuitable additive foreitherwater- basedornon-aqueous-basedfluids.However, the optionsare limitedinHPHTconditionespeciallywhenthe temperatureexceeding400˚F (Friedheim et al.,2012; Hoelscheretal.,2013). Therefore,the researchwasfurthermade andthe use of nanotechnologywasconsidered. One of the challengesinHPHTwell istoprovide ahigherdensityfluidfordrillingoperation.Itisnot uncommonto use a higherdensitydrillingfluidinordertomaintainhighviscosityasone of the requirementof drillingfluidinHPHTwell.Unfortunately,increasingthe densityof the fluidalsomeans increasingthe solidloading.Thiswillleadtolow rate of penetrationof drillingbit,extendingtime on locationandaddeddrillingcosts (Blandetal.,2006). The advancedstudyof nanotechnologyenablethe highsurface to volume ratioof nanoparticle tointeract withthe surroundingenvironment,thus reducingthe solidloadinginthe drillingfluid (Cocuzzaetal.,2011). Therefore,the use of
  • 10. nanotechnologycansignificantlyimprove the rate of penetrationandeliminate the formationdamage nearthe wellbore. Some otherchallengesinHPHTwell istoovercome the poorheattransfercoefficientinthe drillingfluid. The traditional drillingfluidsuchaswater- basedandnon- aqueous- basedfluidare notefficientenough to withstandthe hightemperature of HPHTwell (Hoelscheretal.,2013). The traditional drillingfluid that iscommonlyusedinoil andgas industriestodayisnotsuitable forHPHTwell due tolow cooling efficiencyof the fluid.Inotherwords,the low rate of heatdissipationof the drillingfluidcanleadto manyproblemsuchas equipmentfailure due tothe effectof hightemperature andreduce the rate of penetrationandlifetime of the bit,thusincrease the total cost.Byusingnano- baseddrillingfluid,we can overcome thisproblemasnanoparticlesinthe drillingfluidare more efficientinconductingheat (Cocuzzaetal.,2011). Thisideawas supportedbyAmanullah inhisresearch.Accordingto Amanullahetal.(2011),due to the tinysize,nanoparticle hashuge surface area,high heattolerance,highthermal conductivity,high mobility,andcaninteractefficientlywiththe surrounding.Therefore,he predictedthat nanotechnologywill playanimportantrole in solvingmanychallengesinHPHTdrillingcondition. Figure 1.3: surface area increase with decreasing size ("Biotoxicity," n.d) El-DiastyandSalem(2013) explainedfurtherthatthe researchdone byAmanullahmightbe due tohigh surface area to volume ratio.Whenthe surface areaincrease,more particlesare incontactto each other,thusprovide abetterthermal conductivity.Therefore,byusingnanotechnologythe coolingof drillingbitwillbe muchmore efficient,thusreduce the costof drillingprocess. Figure 9: surface area to volumeratio (Amanullahetal., 2011) Future Applicationof Nanotechnologyin DrillingFluid Pilotstudy: Oil and gas industryisthe mostchallengingindustrywithalotof limitationsandobstaclesin itseveryprocess.Therefore,itisone of the most expensiveindustriesinthe world.Whendealingwith oil and gas industry,moneywouldbe the mainconcern.Itisimportantto maximize the profitapart
  • 11. fromprovidingasafe workingenvironment.Thus,we shouldalwaysconsidertostudyandapplynew technologyinordertoimprove oil productionandrecovery.Inthiscase,nanotechnologycouldbe one of the suitable candidatesthatcanoffera bettersolutionthanourcurrentsystembyeliminating problemsandlimitationthroughoutdrillingoperation.However,since nanotechnologyisstillunder research,mostof oil and gas companyfearof the uncertaintiesthatmightstill notyetdiscovered. Althoughthe experimentconductedinthe laboratoryshowspromisingapplicationindrillingfluid, nanotechnologyisstillnotdomesticallytestedonthe field.Therefore,itisimportanttoencourage the oil and gas companyto applythe use of nanotechnologyonthe field. Mud as a whole:The experimentconductedinthe laboratoryshowsthatnanoparticle canimprove drillingfluid,howeveritcannotimprove the drillingfluidasawhole.Itmeansthat,the improvementof drillingfluidisonlyapplicabletoa certainextentdependingonthe type of nanoparticle used.For example,silicananoparticle cancontrol fluidlossthusincreasewellbore stability,butitcannotact as viscosifier.There are several componentof drillingfluidwhichare viscosifier,fluidlosscontrol,wetting agentand emulsifier.We cansay that these componentsare the mainelementof the drillingfluid. However,there isstill nonanoparticlethatcansatisfyall the componentof drillingfluid.Therefore,the scientistsshouldkeepdoingthe researchinordertodiscovernew nanoparticle thatcansuitsall componentof drillingfluid,thusmake aperfectfluidfordrillingoperation. Cost Analysis:Up until now,there isstill nocompanydare to use nanoparticle intheirdrillingoperation because itistoo expensive.Itslowavailabilityinthe marketmakesnanoparticleveryhardtoobtainand veryexpensive tobuy.Soinorderto attract more companyto start utilizingnanoparticleintheir operationistoanalyze the cost of nanoparticles.Analyze how canthe cost of nanoparticle be reduce. One of a wayto do the cost analysisisto take intoaccount the overall costof drillingoperationusing nanoparticle comparedtoconventional one.Nanoparticle hasmore total surface areaexposed comparedto othermudadditive whichmakesthemmore reactive.Therefore,lessamountof nanoparticlesneededtoachievesame efficiencyandperformance withthe conventional one thus decreasinginthe overall cost.Thisaspectmustbe one of the waysto do cost analysisasmany customersare confusedaboutthe overall costof theiroperationif nanoparticleisbeingused. Ecofriendlyanalysis: Drillingfluidhasalwaysbeenconcernforthe environmentalist.Mostof the drilling additives is not environmentally friendly. Therefore, research should be done for certain group of nanoparticles used in drilling fluid whether it is ecofriendly or not. Water Cut and Water Coning Prevention: As we know that nanoparticle has the ability to form a hydrophobic film on the surface of matter. Therefore, instead of preventing water to reach surface of drillingequipment,thiscoatingshouldentrapswaterpreventingit fromflowingoutof the wellbore thus maintaining the reservoir pressure with water drives. Immunity to Vibration: Indeviatedwell,vibrationcancauseddrill stringto damage.Therefore,research shouldbe done so that nanoparticle couldbe addedin manufacturingthe drill stringto make it tougher and stronger. Better Data Transmission: Drilling mud is pumped through drill string to drillbit and up to the annulus. Measured while drilling used pulse to transfer data of the wellbore to the surface. In order to enhance this transmission, nanoparticle can be mixed with mud and additive to obtain higher quality of transmission data. Increase lifespan:The lifespanof drillingfluidcanbe extendedwhenusingnanoparticle asan additives. Due toitstinysize,nanoparticlehashighernumberofparticleinacertainamountofvolume.Forexample, the number of particle of Silver nanoparticle in 10m³ is much higher than in 10m³ of bulk Silver.
  • 12. Therefore, the viscosity and density of nanofluid is much higher than when using bulk particle as an additive.So,ittakesalongertime fornanofluidtoreducesitsviscositywhenoperatingindrillingprocess, thus reduce the cost. Amanullah,M.,& Al-Tahini,A.M.(2009). Nano-technology-itssignificancein smartfluid development foroil and gasfield application. Paperpresentedatthe SPESaudiaArabiaSectionTechnical Symposium. Amanullah,M.,AlArfaj,M.K.,& Al-abdullatif,Z.A.(2011). Preliminary test results of nano-based drilling fluidsfor oil and gasfield application. Paperpresentedatthe SPE/IADCDrillingConference and Exhibition. Baker.(2006). DrillingContractor:B.H. Corporation. Barr, W. E. (2008). Nanotechnology:Health &Safety ExposuresIn a Shrinking World. Paperpresentedat the ASSE Professional DevelopmentConference andExhibition. Basu,B. J., & DineshKumar,V.(2011). Fabricationof superhydrophobicnanocompositecoatingsusing polytetrafluoroethyleneandsilicananoparticles. ISRN Nanotechnology,2011. Beschichten,K.L.(n.d).Anti-friction-coating–an innovative drylubricationforyourproducts.from http://www.beschichtung.com/en/services/anti-friction-coating/introduction-to-anti-friction- coating/ Biotoxicity.(n.d).from http://highschoolnanoscience.cnsi.ucla.edu/biotoxicity Bland,R. G., Mullen,G.A.,Gonzalez,Y.N.,Harvey,F. E., & Pless,M.L. (2006). HPHT drilling fluid challenges. Paperpresentedatthe IADC/SPEAsiaPacificDrillingTechnologyConference and Exhibition. Cocuzza,M., Pirri,F.,Rocca, V.,& Verga,F.(2011). Is The Oil Industry Ready ForNanotechnologies? Paperpresentedatthe Offshore MediterraneanConference andExhibition. Dewan,J.T., & Chenvert,M.E. (1993). Mudcakebuildup and invasion in low permeability formations; application to permeability determination by measurementwhiledrilling.Paperpresentedatthe SPWLA 34th Annual LoggingSymposium. El-Diasty,A.I.,& Salem,A.M. (2013). Applicationsof Nanotechnology in theOil & Gasindustry:Latest TrendsWorldwide & FutureChallengesin Egypt. Paperpresentedatthe NorthAfricaTechnical Conference andExhibition.
  • 13. Friedheim,J.,Young,S.,De Stefano,G.,Lee,J.,Guo, Q.,& SWACO,M. (2012). Nanotechnology for Oilfield Applications-HypeorReality?Paperpresentedatthe SPE International Oilfield NanotechnologyConferenceandExhibition. Hareland,G.,Wu, A.,Lei,L., Husein,M.M., & Zakaria,M. F.(2012). InnovativeNanoparticleDrilling Fluid and Its Benefitsto Horizontalor Extended Reach Drilling. Paperpresentedatthe SPE Canadian Unconventional ResourcesConference. Hoelscher,K.P.,De Stefano,G.,Riley,M.,& Young,S. (2012). Application of Nanotechnology in Drilling Fluids. Paperpresentedatthe SPE International OilfieldNanotechnologyConference and Exhibition. Hoelscher,K.P.,Young,S.,Friedheim,J.,&De Stefano, G.(2013). Nanotechnology Application in Drilling Fluids. Paperpresentedatthe Offshore MediterraneanConference andExhibition. Kendig,M.,& Buchheit,R.(2003). Corrosioninhibitionof aluminumandaluminumalloysbysoluble chromates,chromate coatings,andchromate-free coatings. Corrosion,59(5),379-400. Li, L.,Xu, X.,Sun,J.,Yuan, X.,& Li,Y. (2012). Vital Role of Nanomaterialsin Drilling Fluid and Reservoir Protection Applications. Paperpresentedatthe AbuDhabi International PetroleumConference and Exhibition. Mansoori,G. A.,& Soelaiman,T.F.(2005). Nanotechnology—anintroductionforthe standards community. Journalof ASTMInternational,2(6),1-21. Mickelson,W.,Sussman,A.,Zhou,Q.,Veneziani,M.,Ackerman,I.,FrescaFantoni, R.,.. . Milgrome,O. (2013). An InnovativeWirelessH2S SensorBased On Nanotechnology To ImproveSafety In Oil& Gas Facilities. Paperpresentedatthe SPE Offshore Europe Oil andGasConference and Exhibition. Nanoscience.(n.d).A science curriculum unitfor7thand 8th grade students. Nanosilver:Miracleor Menace? , from http://nanotechnology.wmwikis.net/Lesson+3+Size+and+Scale . NanotechnologyandFoodSafety.(2010) Risk AssesmentSection (pp.9-10).Hong Kong:Centre for FoodSafety. Sayyadnejad,M.,Ghaffarian,H.,& Saeidi,M.(2008). Removal of hydrogensulfide byzincoxide nanoparticlesindrillingfluid. InternationalJournalof EnvironmentalScience& Technology,5(4), 565-569. Sensoy,T.,Chenevert,M.E., & Sharma, M. M. (2009). Minimizing waterinvasion in shalesusing nanoparticles. Paperpresentedatthe SPEAnnual Technical Conference andExhibition. Shen,G.,Du, R., Chen,Y.,Lin,C., & Scantlebury,D.(2005). Studyon hydrophobicnano-titaniumdioxide coatingsfor improvementincorrosionresistance of type 316L stainlesssteel. Corrosion,61(10), 943-950. Zhuk,Y. N. (2010). Nano-StructuredCvdTungstenCarbide CoatingProtectsAgainstWearAndCorrosion. CORROSION 2010.