1. SRI KRUSHNA CHANDRA GAJAPATI (AUTONOMOUS) COLLEGE
PARALAKHEMUNDI
DEPARTMENT OF PHYSICS
“QUANTUM DOT HETEROSTRUCTURE”
Under the supervision of
NIBEDITA SASMAL
Representator:
1. JOSOBANTA BIDIKA
2. PAPU SAHU
3. BADAL KUMAR PANI
4. DEBASISH PAIK
5. K. KRISHNAMURTHY
PAPER: DSE IV
DATE:
3. INTRODUCTION
What is a Quantum Dot?
The term quantum dot was coined in 1986.
A quantum dot is a nanometer-sized
semiconductor particle traditionally with a
core-shell structure.
This Photo by Unknown Author is licensed under CC BY-NC
4. HETEROSTRUCTURE:
Any crystal consisting of one or more junction
between different semiconductors with
different band gaps, lattice constants , and
layer thickness are termed as heterostructure.
5. Quantum Dot Heterostructure(QDHS):
Quantum-dot (QD) heterostructures are
nanoscale coherent insertions of narrow-gap
material in a single-crystalline matrix.
Quantum dot possess atom-like discrete
energy level separated by regions of forbidden
states.
Energy pumped into the system goes to excite
carriers between discrete levels and random
motion.
6. FABRICATION OF QDHS
There are three main way to confine excitons
in semiconductors:
Lithography
Colloidal synthesis
Epitaxy:
• Patterned growth
• Self-organized growth
7. 1. LITHOGRAPHY
Quantum wells are covered with a polymer
mask and exposed to an electron or ion beam.
The surface is covered with a thin later of
metal, then cleaned and only the exposed
areas keep the metal layer.
Pillars are etched into the entire surface.
Multiple layers are applied this way to build
up the properties and size wanted.
8. 2. COLLOIDAL SYNTHESIS
Emersion of semiconductor microcrystals in
glass dielectric matrices.
Taking a silicate glass with 1% semiconducting
phase(CdS, CuCl, CdSe or CuBr).
Heating for several hour at high temperature.
• Formation of microcrystal of nearly equal size.
9. 3(a). EPITAXY: PATTERNED GROWTH
Semiconducting
compound with a smaller
band gap (GaAs) are
grown on the surface of a
compound with a larger
band gap(AlGaAs).
Growth is restricted by
coating it with a masking
compound(SiO2) and
etching that mask with
the shape of the required
crystal cell wall shape.
10. 3(b). EPITAXY: SELF-ORGANIZED
GROWTH
• Uses a large difference in
the lattice constants of
the substrate and the
crystallizing material.
• When the crystallized
later is thicker than the
critical thickness, there is
a strong strength on the
layers.
• The breakdown results in
a randomly distributed
islets of regular shape
and size.
11. PROPERTIES OF QDHS
Within a quantum dot, there are confined
valence band holes, conduction band
electrons, or excitons.
There are particles that carry the electricity
and because of this confinement the quantum
dot has a distinct energy level.
The electrons within a quantum dot have to
occupy an energy level that fits inside it.
12. When excitation occurs
these elecron emit a
photon.
Excitation can be
caused by the quantum
dot coming into contact
with a light or
electricity source.
The longest wavelength
of light produced by
biggest quantum dot
and shortest
wavelength of light are
generated by smallest
quantum dot.
13. ADVANTAGES
• Very narrow spectral lines width, depending
on the quantum dot’s size.
• Multiplexed detection.
• Large absorption coefficient across a wide
spectral range.
• Small size/high surface -to- volume ratio.
• Very high levels of brightness.
• Blinking
16. Future approaches of QDHS:
• Quantum dots are great potential utility in
solar harvesting and light-sensing
technologies.
• Due to their tunable bandgap, they can be
engineered to target a particular range of
wavelengths.
17. CONCLUSION
Quantum Dot Heterostructure
• Semiconductor particle with a size in the order
of the Bohr’s radius of the excitation.
• Energy level depend on the size of the dot.
Different method for fabrication quantum dot
• Lithography
• Colloidal synthesis
• Epitaxy
18. References
1. G. Bastard; JA Brum; R Ferreria(1991). “
Figure 10 in Electronic states in
semiconductor heterostructure”. In Henry
Ehrenreich, David Turnbull (ed). Solid state
physics: Semiconductor heterostructure and
Nanostructure. P. 259.