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Mineralogical Ambiguity of Lonar Ejecta
Arif M. Sikder1, Saumitra Misra2, Newsom Horton3, Jose Brum4, Tina Hill5, Xin-
Chen Liu1, Joseph B. McGee Turner6
1. Center for Environnemental Studies (CES), Virginia Commonwealth University (VCU)
2. Department of Geology, University of Kwazulu-Natal, South Africa
3. University of New Mexico, Institute of Meteoritics and Dept. of Earth and Planetary Sciences,
4. Olympus Scientific Solutions Americas
5. Bruker AXS Inc.
6. Department of Chemistry, Virginia Commonwealth University (VCU)
Lonar Crater: India
Indian Space Research Organization’s
Cartosat image of the Lonar Crater
showing the locations of ejecta
samples.
Geologic Setting
The Deccan Traps are one of the largest volcanic provinces in the world,
consisting of more than 2 km-thick, flat-lying basalt lava flows covering an
area of nearly 500,000 km2 in west-central India. Estimates of the original
area covered by the lava flows are as high as 1.5 million km2, and the volume
of basalt is estimated at ~0.5 million km3 (e.g., Mahoney 1988; Cox and
Hawkesworth 1985; Widdowson et al. 2000).
The Deccan basalts were erupted between ~69 and 63 million years ago, with
a main peak in activity around 66 to 65 million years ago (Pandey, 2002 and
Courtillot and Renne 2003). Six basalt flows, ranging in thickness between ~8
and 40 m, are seen in and around Lonar village, while four flows are exposed
on the crater wall (Ghosh and Bhaduri 2003).
Geologic Setting
The comparatively young (50,000 years
old) Lonar crater of India is presumably
one of the two known terrestrial impact
craters that emplaced 65 million year
old Deccan basalt. The impact cratering
occurred tens of million years after the
formation of the Deccan basalt, and it is
very likely that, in the meantime, the
postulated target basalts layers were
extensively altered due to weathering.
The presence of caliche, a carbonate-rich material at the base
of the impact deposits.
Geologic Setting
Reb bole laterally continuous in the Deccan Plateau extensively
cemented by veins of quartz and zeolite. The zeolite was identified to be
of heulandite composition.
The comparatively young (50,000 years
old) Lonar crater of India is presumably
one of the two known terrestrial impact
craters that emplaced 65 million year
old Deccan basalt. The impact cratering
occurred tens of million years after the
formation of the Deccan basalt, and it is
very likely that, in the meantime, the
postulated target basalts layers were
extensively altered due to weathering.
Ejecta of the South Rim
Wt%
Target
Basalt
L2ejecta
bulk
L2ejecta
magnetics
Na2O 3 0.428 0.512
MgO 6.07 2.183 1.844
Al2O3 12.96 10.363 11.381
SiO2 47.82 41.437 41.144
K2O 0.38 0.747 0.577
CaO 9.87 13.135 13.166
TiO2 2.26 3.42 3.663
MnO 0.19 0.306
Fe2O3 15.827 26.903
0
10
20
30
40
50
60
Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO Fe2O3
Major Oxides
Target Basalt L2ejecta bulk
Ejecta of the North Rim
Wt%
Target
Basalt L244B bulk
L244B
magnetics L244B fine
Na2O 3 0.209 0.343 0
MgO 6.07 1.687 1.826 2.08
Al2O3 12.96 10.161 10.511 9.831
SiO2 47.82 39.139 39.385 42.86
K2O 0.38 1.11 0.825 1.149
CaO 9.87 16.262 12.185 8.43
TiO2 2.26 3.566 4.374 3.33
MnO 0.19 0.248 0.294 0.229
Fe2O3 15.827 26.608 29.166 30.854
0
10
20
30
40
50
60
Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO Fe2O3
Major Oxides
Target Basalt L244B bulk L244B magnetics L244B fine
Ejecta Samples of
the Southwest
Rim
Cu target
64%: Orthopyroxene
32%: Diopside
4%: Cristabolite
Ejecta of the Southwestern Rim (L2)
Ejecta of the Southwestern Rim (L2)
Ejecta Samples of Kalapani
XRD Mineralogy with the Olympus®
TERRA® Analyzer: Cobalt Target
0
10
20
30
40
50
60
70
Andesine Diopside Magnetite Zeolite Calcite Cristobalite Quartz
XRD Mineralogy: Cobalt Target
South West Rim Kalapani North Rim South West Rim
XRD (wt%) Location Andesine Diopside Magnetite Zeolite Calcite Cristobalite Quartz
L244B Bulk South West Rim 59.2 16.4 0.9 10.94 9.45 0 2.98
LHN0526 Bulk Kalapani 58 0 1.4 6.4 10.9 0 0
LHN04 08 Bulk North Rim 58.2 15 1.2 3.3 0 2.9 0
L2 Ejecta South West Rim 66 29.4 0 0 3.8 0 0
0
2
4
6
8
10
12
Magnetite Zeolite Calcite Cristobalite Quartz
South West Rim Kalapani North Rim South West Rim
Where is the ambiguity?
Glauconites!
Optical Microscopy with Polarizing Light
Ejecta Spherules: Elemental Mapping
by u-XRF
SEM-EDS Analysis
The most favorable physical environment for the occurrence of
glauconites:
I. Slow deposition in agitated water and paucity of clay minerals
II. Saline, oxidizing environment
III. Sufficient organic matter is necessary to create local reducing
conditions
IV. Higher than normal amounts of iron and potassium
Potassium is probably less restrictive than iron. Magnesium is
also an essential constituent but is likewise readily available in a
normal marine environment.
Observations
The prevalence of andesine presents some ambiguity in matching
the ejecta with tholeiitic basaltic targets and suggests that multiple
phases of pre- and post-impact alterations probably account for
the present mineralogical assemblage. The impact cratering
probably occurred on the weathered basaltic rocks that were
depleted in certain metals, and the zeolites probably developed
due to post-impact hydrothermal alteration. Finally, the climatic
condition probably facilitated the calcification of the ejecta blanket
and the preservation of the ejecta fallout.
The characterization of glauconites are still under investigation!

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Mineralogical Ambiguity of Lonar Ejecta

  • 1. Mineralogical Ambiguity of Lonar Ejecta Arif M. Sikder1, Saumitra Misra2, Newsom Horton3, Jose Brum4, Tina Hill5, Xin- Chen Liu1, Joseph B. McGee Turner6 1. Center for Environnemental Studies (CES), Virginia Commonwealth University (VCU) 2. Department of Geology, University of Kwazulu-Natal, South Africa 3. University of New Mexico, Institute of Meteoritics and Dept. of Earth and Planetary Sciences, 4. Olympus Scientific Solutions Americas 5. Bruker AXS Inc. 6. Department of Chemistry, Virginia Commonwealth University (VCU)
  • 2. Lonar Crater: India Indian Space Research Organization’s Cartosat image of the Lonar Crater showing the locations of ejecta samples.
  • 3. Geologic Setting The Deccan Traps are one of the largest volcanic provinces in the world, consisting of more than 2 km-thick, flat-lying basalt lava flows covering an area of nearly 500,000 km2 in west-central India. Estimates of the original area covered by the lava flows are as high as 1.5 million km2, and the volume of basalt is estimated at ~0.5 million km3 (e.g., Mahoney 1988; Cox and Hawkesworth 1985; Widdowson et al. 2000). The Deccan basalts were erupted between ~69 and 63 million years ago, with a main peak in activity around 66 to 65 million years ago (Pandey, 2002 and Courtillot and Renne 2003). Six basalt flows, ranging in thickness between ~8 and 40 m, are seen in and around Lonar village, while four flows are exposed on the crater wall (Ghosh and Bhaduri 2003).
  • 4. Geologic Setting The comparatively young (50,000 years old) Lonar crater of India is presumably one of the two known terrestrial impact craters that emplaced 65 million year old Deccan basalt. The impact cratering occurred tens of million years after the formation of the Deccan basalt, and it is very likely that, in the meantime, the postulated target basalts layers were extensively altered due to weathering. The presence of caliche, a carbonate-rich material at the base of the impact deposits.
  • 5. Geologic Setting Reb bole laterally continuous in the Deccan Plateau extensively cemented by veins of quartz and zeolite. The zeolite was identified to be of heulandite composition. The comparatively young (50,000 years old) Lonar crater of India is presumably one of the two known terrestrial impact craters that emplaced 65 million year old Deccan basalt. The impact cratering occurred tens of million years after the formation of the Deccan basalt, and it is very likely that, in the meantime, the postulated target basalts layers were extensively altered due to weathering.
  • 6. Ejecta of the South Rim Wt% Target Basalt L2ejecta bulk L2ejecta magnetics Na2O 3 0.428 0.512 MgO 6.07 2.183 1.844 Al2O3 12.96 10.363 11.381 SiO2 47.82 41.437 41.144 K2O 0.38 0.747 0.577 CaO 9.87 13.135 13.166 TiO2 2.26 3.42 3.663 MnO 0.19 0.306 Fe2O3 15.827 26.903 0 10 20 30 40 50 60 Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO Fe2O3 Major Oxides Target Basalt L2ejecta bulk
  • 7. Ejecta of the North Rim Wt% Target Basalt L244B bulk L244B magnetics L244B fine Na2O 3 0.209 0.343 0 MgO 6.07 1.687 1.826 2.08 Al2O3 12.96 10.161 10.511 9.831 SiO2 47.82 39.139 39.385 42.86 K2O 0.38 1.11 0.825 1.149 CaO 9.87 16.262 12.185 8.43 TiO2 2.26 3.566 4.374 3.33 MnO 0.19 0.248 0.294 0.229 Fe2O3 15.827 26.608 29.166 30.854 0 10 20 30 40 50 60 Na2O MgO Al2O3 SiO2 K2O CaO TiO2 MnO Fe2O3 Major Oxides Target Basalt L244B bulk L244B magnetics L244B fine
  • 8. Ejecta Samples of the Southwest Rim Cu target 64%: Orthopyroxene 32%: Diopside 4%: Cristabolite
  • 9. Ejecta of the Southwestern Rim (L2)
  • 10. Ejecta of the Southwestern Rim (L2)
  • 11. Ejecta Samples of Kalapani
  • 12. XRD Mineralogy with the Olympus® TERRA® Analyzer: Cobalt Target 0 10 20 30 40 50 60 70 Andesine Diopside Magnetite Zeolite Calcite Cristobalite Quartz XRD Mineralogy: Cobalt Target South West Rim Kalapani North Rim South West Rim XRD (wt%) Location Andesine Diopside Magnetite Zeolite Calcite Cristobalite Quartz L244B Bulk South West Rim 59.2 16.4 0.9 10.94 9.45 0 2.98 LHN0526 Bulk Kalapani 58 0 1.4 6.4 10.9 0 0 LHN04 08 Bulk North Rim 58.2 15 1.2 3.3 0 2.9 0 L2 Ejecta South West Rim 66 29.4 0 0 3.8 0 0 0 2 4 6 8 10 12 Magnetite Zeolite Calcite Cristobalite Quartz South West Rim Kalapani North Rim South West Rim
  • 13. Where is the ambiguity? Glauconites!
  • 14. Optical Microscopy with Polarizing Light
  • 15. Ejecta Spherules: Elemental Mapping by u-XRF
  • 17.
  • 18. The most favorable physical environment for the occurrence of glauconites: I. Slow deposition in agitated water and paucity of clay minerals II. Saline, oxidizing environment III. Sufficient organic matter is necessary to create local reducing conditions IV. Higher than normal amounts of iron and potassium Potassium is probably less restrictive than iron. Magnesium is also an essential constituent but is likewise readily available in a normal marine environment.
  • 19. Observations The prevalence of andesine presents some ambiguity in matching the ejecta with tholeiitic basaltic targets and suggests that multiple phases of pre- and post-impact alterations probably account for the present mineralogical assemblage. The impact cratering probably occurred on the weathered basaltic rocks that were depleted in certain metals, and the zeolites probably developed due to post-impact hydrothermal alteration. Finally, the climatic condition probably facilitated the calcification of the ejecta blanket and the preservation of the ejecta fallout. The characterization of glauconites are still under investigation!