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Organic Chemistry: The chemistry of carbon
and carbon-based compounds
Organic Chemistry in everyday life:
Smells & tastes: fruits, chocolate, fish, mint
Medications: Aspirin, Tylenol, Decongestants, Sedatives
Addictive substances: Caffeine, Nicotine, Alcohol,
Narcotics
Hormones/Neurotransmitters: Adrenaline, Epinephrine
Food/Nutrients: Carbohydrates, Protein, Fat, Vitamins
 A part of a large molecule; composed of an atom or
group of atom that has characteristics chemical
behavior
 Family Name
 Alkane
 Alkene
 Aromatic
 Alcohol
 Ether
 Functional groups are attached to the
carbon backbone of organic molecules.
They determine the characteristics and
chemical reactivity of molecules.
Functional groups are far less stable than
the carbon backbone and are likely to
participate in chemical reactions. Six
common biological functional groups are
 hydrogen, hydroxyl, carboxyl, carbonyl,
amino, phosphate, and methyl
❍ Hydrocarbons contain only hydrogen and carbon
❍ The hydrocarbon functional groups include
◦ Alkanes
◦ Alkenes
◦ Alkynes
◦ Aromatics
HYDROCARBONS
contain only C and H atoms
ALIPHATIC
hydrocarbons
SATURATED
hydrocarbons
contain C–C and C–H
single bonds only
(ALKANES)
UNSATURATED
hydrocarbons
contain at least 1 C–C
multiple bond
ALKENE
contains the
C=C functional group
ALKYNE
contains the
C≡C functional group
AROMATIC
Hydrocarbons must contain
a
BENZENE ring
GROUP
12 Carbon needs FOUR bonds
14 Nitrogen needs THREE bonds
16 Oxygen needs TWO bonds
17 Fluorine needs ONE bond
❍ Alkanes are the simplest functional group
❍ An older name for alkanes is paraffin's
❍ The functional group is the C-C single bond
❍ Example
CH4 (methane) Simplest Alkane
each Carbon (ethane)
has TETRAHEDRAL
geometry
CH3—CH3
methane
ethane
propane
butane
CH4
CH3CH3
CH3 -CH2 -CH3
pentane CH3 -CH2-CH2-CH2 -CH3
CH3 -CH2-CH2 -CH3 or
CH3 -(CH2)2-CH3
hexane CH3 -CH2-CH2- CH2 -CH2 -CH3
bond-line structures
(molecular graphs)
❍ If a hydrogen is removed from an alkane, it leaves an
“alkyl group”
❍ Alkyl groups are “stick-on” groups that can be attached
to larger molecules
❍ Alkyl groups are named by replacing “-ane” on the
alkane name with “-yl”
R
ethyl
n-propyl generic carbon group
methyl
n-propyl isopropyl cyclopropyl
ethane
an alkane
ethyl chloridean ethyl group
an alkyl group
❍ Functional Group C=C double bond
❍ Generic Formula
❍ Example CH2=CH2
ethene
❍ Functional Group C C triple bond
❍ Generic Formula R—C R’
R’ means that it can be a different alkyl group than R
❍ Example H —C C—H
ethyne
acetylene
C
C
C
C
C
C
H
H
H
H
H
H
CH3
❍ Functional Group
benzene ring (C6H6)
❍ Example
toluene (methylbenzene)
❍ Functional Group a halogen (Cl, Br, I)
generically, a halogen is “X”
❍ Generic Formula R-X
❍ Example CH3-I
methyl iodide
❍ Functional Group OH (hydroxyl group)
❍ Generic Formula R-OH
❍ Example CH3CH2-OH
ethanol
❍ Functional Group
N
N R
3
R
1
R
2
❍ Generic Formula
❍Example
CH3NH2
methylamine
❍ A carbon doubly bonded to an oxygen is a carbonyl group
❍ The carbonyl functional groups include
Aldehydes
Ketones
Carboxylic Acids
Esters
Amides
C
O
❍ Functional Group
carbonyl
❍ Generic Formula
❍ Example
propanone
acetone
C CH3CH3
O
C R'R
O
C
O
C H
O
C HR
O
CH3 C H
O
❍ Functional Group
terminal carbonyl
❍ Generic Formula
❍ Example
ethanal
acetaldehyde
❍ Functional Group
carboxyl
carbonyl + hydroxyl
C O H
O
C O HR
O
C O HC H
3
O
❍ Generic Formula
❍ Example
ethanoic acid
acetic acid
❍ Functional Group oxygen bridge
❍ Generic Formula R-O-R′
❍ Example CH3CH2-O-CH2CH3
diethyl ether
“ether”
C NR
1
R
2
R
3
H
2
N C H
2
C
O
N C H
2
C
O
O H
H
❍ Generic Formula
❍ Example
a small protein
O
 www.wikipedia.com
 Organic chemistry and Experimental Organic
Chemistry lab , Freeman
 Own teaching experience
Organic Chemistry Functional Groups

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Organic Chemistry Functional Groups

  • 1. Niamat ullah Post Rn BSN LIFE SAVING SON
  • 2. Organic Chemistry: The chemistry of carbon and carbon-based compounds Organic Chemistry in everyday life: Smells & tastes: fruits, chocolate, fish, mint Medications: Aspirin, Tylenol, Decongestants, Sedatives Addictive substances: Caffeine, Nicotine, Alcohol, Narcotics Hormones/Neurotransmitters: Adrenaline, Epinephrine Food/Nutrients: Carbohydrates, Protein, Fat, Vitamins
  • 3.  A part of a large molecule; composed of an atom or group of atom that has characteristics chemical behavior  Family Name  Alkane  Alkene  Aromatic  Alcohol  Ether
  • 4.  Functional groups are attached to the carbon backbone of organic molecules. They determine the characteristics and chemical reactivity of molecules. Functional groups are far less stable than the carbon backbone and are likely to participate in chemical reactions. Six common biological functional groups are  hydrogen, hydroxyl, carboxyl, carbonyl, amino, phosphate, and methyl
  • 5. ❍ Hydrocarbons contain only hydrogen and carbon ❍ The hydrocarbon functional groups include ◦ Alkanes ◦ Alkenes ◦ Alkynes ◦ Aromatics
  • 6. HYDROCARBONS contain only C and H atoms ALIPHATIC hydrocarbons SATURATED hydrocarbons contain C–C and C–H single bonds only (ALKANES) UNSATURATED hydrocarbons contain at least 1 C–C multiple bond ALKENE contains the C=C functional group ALKYNE contains the C≡C functional group AROMATIC Hydrocarbons must contain a BENZENE ring
  • 7. GROUP 12 Carbon needs FOUR bonds 14 Nitrogen needs THREE bonds 16 Oxygen needs TWO bonds 17 Fluorine needs ONE bond
  • 8. ❍ Alkanes are the simplest functional group ❍ An older name for alkanes is paraffin's ❍ The functional group is the C-C single bond ❍ Example CH4 (methane) Simplest Alkane each Carbon (ethane) has TETRAHEDRAL geometry CH3—CH3
  • 9. methane ethane propane butane CH4 CH3CH3 CH3 -CH2 -CH3 pentane CH3 -CH2-CH2-CH2 -CH3 CH3 -CH2-CH2 -CH3 or CH3 -(CH2)2-CH3 hexane CH3 -CH2-CH2- CH2 -CH2 -CH3 bond-line structures (molecular graphs)
  • 10. ❍ If a hydrogen is removed from an alkane, it leaves an “alkyl group” ❍ Alkyl groups are “stick-on” groups that can be attached to larger molecules ❍ Alkyl groups are named by replacing “-ane” on the alkane name with “-yl” R ethyl n-propyl generic carbon group methyl n-propyl isopropyl cyclopropyl
  • 11. ethane an alkane ethyl chloridean ethyl group an alkyl group
  • 12. ❍ Functional Group C=C double bond ❍ Generic Formula ❍ Example CH2=CH2 ethene
  • 13. ❍ Functional Group C C triple bond ❍ Generic Formula R—C R’ R’ means that it can be a different alkyl group than R ❍ Example H —C C—H ethyne acetylene
  • 14. C C C C C C H H H H H H CH3 ❍ Functional Group benzene ring (C6H6) ❍ Example toluene (methylbenzene)
  • 15. ❍ Functional Group a halogen (Cl, Br, I) generically, a halogen is “X” ❍ Generic Formula R-X ❍ Example CH3-I methyl iodide
  • 16. ❍ Functional Group OH (hydroxyl group) ❍ Generic Formula R-OH ❍ Example CH3CH2-OH ethanol
  • 17. ❍ Functional Group N N R 3 R 1 R 2 ❍ Generic Formula ❍Example CH3NH2 methylamine
  • 18. ❍ A carbon doubly bonded to an oxygen is a carbonyl group ❍ The carbonyl functional groups include Aldehydes Ketones Carboxylic Acids Esters Amides C O
  • 19. ❍ Functional Group carbonyl ❍ Generic Formula ❍ Example propanone acetone C CH3CH3 O C R'R O C O
  • 20. C H O C HR O CH3 C H O ❍ Functional Group terminal carbonyl ❍ Generic Formula ❍ Example ethanal acetaldehyde
  • 21. ❍ Functional Group carboxyl carbonyl + hydroxyl C O H O C O HR O C O HC H 3 O ❍ Generic Formula ❍ Example ethanoic acid acetic acid
  • 22. ❍ Functional Group oxygen bridge ❍ Generic Formula R-O-R′ ❍ Example CH3CH2-O-CH2CH3 diethyl ether “ether”
  • 23. C NR 1 R 2 R 3 H 2 N C H 2 C O N C H 2 C O O H H ❍ Generic Formula ❍ Example a small protein O
  • 24.
  • 25.  www.wikipedia.com  Organic chemistry and Experimental Organic Chemistry lab , Freeman  Own teaching experience