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1
MARKET PROFILE ON ORGANOPHOSPHONATES
2
MARKET PROFILE ON ORGANOPHOSPHONATES
CHAPTER I PRODUCT OVERVIEW.........................................................................................................4
General details ...............................................................................................................................4
Use of organo phosphonatesin boiler water treatment ....................................................................5
Use of organo phosphonatesin cooling water treatment..................................................................6
Advantages of organophosphonates over polyphosphates................................................................7
Choice of organophosphonate:........................................................................................................7
CHAPTER II INDIAN PRODUCTION........................................................................................................8
Indian manufacturers of organo phosphonic acids and phosphonate salts .........................................8
Aquapharm Chemical Company Pvt. Ltd. ......................................................................................8
Excel Industries Ltd......................................................................................................................8
Other suppliers...............................................................................................................................9
Indian supply of organophosphonates for water treatment application .............................................9
CHAPTER III INDIAN TRADE DETAILS...................................................................................................10
Indian import of phosphonates for use in water treatment .............................................................10
Annual import...........................................................................................................................10
Productwise import – Period 2014-2015.....................................................................................11
Portwise import – Period 2014-2015 ..........................................................................................11
Countrywise import...................................................................................................................11
Import details of Dequest (phosphonates) for water treatment application..................................12
Indian export of all phosphonates for water treatment application..................................................16
Annual export...........................................................................................................................16
Portwise export.........................................................................................................................16
Countrywise export...................................................................................................................17
Productwise export ...................................................................................................................17
Brandwise export......................................................................................................................18
3
CHAPTER IV INDIAN DEMAND SUPPLY SCENARIO – PERIOD 2015 ........................................................19
Indian demand .............................................................................................................................19
Indian demand supply scenario......................................................................................................19
Productwise demand pattern ........................................................................................................19
CHAPTER V GLOBAL SCENARIO – PERIOD 2015...................................................................................20
Global Market for chelating agent..................................................................................................20
Global Market for organophosphonates.........................................................................................20
Global manufacturers and their organophosphonate range of products...........................................21
Italmatch Chemicals SpA, Belgium..............................................................................................21
Zschimmer& Schwarz Mohsdorf GmbH & Co.KG, USA .................................................................27
Kemira......................................................................................................................................27
4
CHAPTER I
PRODUCT OVERVIEW
General details
Phosphonicacidsare organicderivativesof phosphonicacid of the formR-PO3H2.
Commonlyusedwatertreatmentchemicals inIndiaare givenbelow.
The introduction of an amine group into the molecule increases the metal binding abilities of the
phosphonate.The stabilityof the metal complexesincreaseswithincreasingnumberof phosphonic acid
groups. Phosphonates are highly water soluble, non-volatile and highly sorptive chemicals.
The other phosphonate used to a much lesser extent are,
 Hexamethylene diamine tetramethylene phosphoric acid (HMDTMP)
 Ethylene diamine tetramethylene phosphoric acid (EDTMP)
The keypropertiesof Organophosphonatesare:
 Thresholdeffectandcrystal distortion.
 HydrolyticStability.
 Sequestrationcharacteristics.
 Deflocculation.
 Chlorine stability
5
Use of organo phosphonates in boiler water treatment
In the operation of steam boiler, the major problems are faced due to scaling and on account of
corrosion.
In the process of making steam in a steam boiler, the steam which leaves the boiler is almost pure
water. The water remaining in the boiler becomes more concentrated with the impurities.
After reaching a certain concentration and due to the inverse solubilities of some of these impurities
they come out of solution and begin to adhere to the hot heat exchange surfaces such as the boiler
tubes. This causes loss of efficiency, corrosion and mechanical failure. As a solution to this condition,
some of the impuritiescanbe removedmechanicallybefore enteringthe boiler. In most cases a certain
percentage of the impurities are removed mechanically followed by the addition of chemicals whose
properties result in the elimination or reduction of deposits caused by the remaining impurities.
The impuritiesthatare mainconcernsina steamboilerare hardness (Ca and Mg) and iron which enters
the boiler via the make-up water as calcium and magnesium bicarbonate. These compounds are quite
soluble.
The problembeginsasheatisaddedto the boiler andmuch of the calcium becomes calcium carbonate.
Calciumcarbonate issparinglysolubleandwill precipitate. Magnesium will also form sparingly soluble
compounds such as magnesium silicate and magnesium hydroxide.
Iron enteringthe boiler as iron bicarbonate with the make-up water or as corrosion products from the
condensate,feedwaterorboileritself isespecially troublesome. Because the iron compounds formed
underboilerconditionsare soinsolubleitisimperative thattheybe dealtwith.Itis also speculated that
iron hampers the dispersing ability of polymers by deactivating their functional groups.
The two main chemical methods of dealing with hardness and iron in boilers are to intentionally
precipitate the impuritiesinsome formwhichis lesstroublesome thanthe untreatedspecies or to keep
the impuritiesinsolutionordispersedsothatprecipitationanddepositsare not formed. In fact, usually
a dynamic combination of sequestration and dispersion takes place.
6
Use of organo phosphonates in cooling watertreatment
In the case of cooling water systems, biofouling is the major problem. The problems arise due to
reverse solubilityof calciumcarbonate and the instability of calcium bicarbonate. Calcium bicarbonate
breaks down to form calcium carbonate, which precipitates easily and forms scales.
Phosphonatesact asscale inhibitorsby adsorbingontospecificcrystal nuclei surfacesof insolublesalts,
thuspoisoningfurthercrystal growth.Theyusuallycontainmultiplephosphonate groups(R-PO3H2,R¼
organicchain) most commonlyfoundintheirdeprotonatedform, due tothe particularpHrange of
operation.
Organophosphonates,insubstoichiometricamountspreventorretardthe precipitationof scale forming
salts.Phosphonate interfere with the nucleation of the hardness crystal causing much higher levels of
hardnesstostay insolutionthanwouldbe possible with untreated water. The inhibitor is adsorbed on
the surface of scale forming crystals during the process of crystallization. This retards the growth of
crystalsand whentheyare formedtheyare highlydistortedpreventingorderlylattice type growth. This
changes the adherence characteristics of the scales formed leading to a soft sludge rather than an
adherent scale, which is easily dispersed by the movement of water.
Suspended particles and dirt in cooling water generally have a negative surface charge. Anionic
polymers increase this negative surface charge and keep the particles separated. Cationic dispersant
when used should be carefully controlled, since the positive charge might be expected to co2 agulate
the negatively charged particles, leading to the formation of dense particles. Addition of cationic
dispersants also involves greater expense since a higher dosage is required as the charge on the
suspended particles would neutralize before sufficient positive charge was built up to keep them
separated.
Organophosphonates exhibit good molecules stability towards chlorine, which is commonly used as a
biocide incoolingwatersystem.Incase where greatermoleculesstabilitytochlorine is desired. HEDP is
preferable to ATMP since it contains nitrogen and therefore chlorine demand for the formation of
chloramines is totally absent.
7
Advantages of organophosphonates over polyphosphates
Reductionin sludge formation: Polyphosphates,whenusedascorrosioninhibitor,give rise toexcessive
orthophosphate sludgeswhereasOrganophosphonateswith zincgive good corrosionprotectionwithout
leading to any sludge formation.
Optimum usage level: Due to the sequestering ability of phosphonate, the zinc ions are present in a
complexed form limiting the rate of reaction of zinc with hydroxyl ions. Therefore, optimum
concentrationof zinc hydroxide allows the formation of a thin hydroxide film at the surface giving the
desired corrosion resistance.
Superior sequestering ability of heavy metals: The sequestering ability of phosphonate enables it to
control heavymatter(Fe,Cu& Zn) depositsandthiscontrol isfar superior to other traditional chelants.
Phosphonate also help to disperse suspended particles.Phosphonate provide excellent control of
hydrated ferric oxide deposits which are formed as a result of corrosion. They adsorb on the particle
surfaces and reduce the attractive forces between individual iron particles.
Higher stabilityand resistant to hydrolysis: Phosphonatesdonot hydrolyse easily like Polyphosphates
and are useful to avoid Calcium precipitation even in alkaline waters. The carbon to phosphorus to
oxygen(CPO) bondinginOrganophosphonatesismore resistant to hydrolysis or cleavage than the COP
bond in phosphate esters and the OP bond in polyphosphates. Organophosphonates are extremely
stable to hydrolysis as compared to polyphosphates at elevated temperature and extremes in pH for
extended periods of time.
Choice of organophosphonate:
From the two most commonly used phosphonate for cooling water treatment HEDP is preferred to
ATMP for the following reasons:
ATMP is more corrosive toCu coolingsystemsinvolving Cu or Cu alloys, are therefore very sensitive to
ATMP. WithATMP one would thenhave to use CucorrosioninhibitorslikeThiazolesandTrizoles making
the treatment more expensive.
HEDP has betterstabilitytochlorine thanthe Nitrogencontaining ATMP.Nitrogencontainingcompound
have a tendency to form chloramines. Though, when complexed with Zinc, ATMP exhibits stability
towardschlorine it should be used with caution in chlorinated cooling water systems especially when
continuous chlorination is used.
The addition of Zinc to ATMP to a certain extent inhibits the dissolution of copper. In the presence of
ATMP, however,the powerfuloxidizing potentialof chlorine promotes the dissolution of copper, when
chlorine is used as a biocide.
8
CHAPTER II
INDIAN PRODUCTION
Indian manufacturers of organo phosphonic acids and phosphonate salts
Name of the organization Location Brand name
Excel IndustriesLtd., Lote Parshuram Unit Codex
Aquapharm Chemical Co. P.
Ltd.,
Pune Aquacid
Aquapharm Chemical Company Pvt. Ltd.
Year of establishment 1977
Share holders Mangwani familyandDesai family
Market share of organophosphonatechemicalinIndia 35%
Brand name of organophosphonates Aquacid
Excel IndustriesLtd
Year of incorporation 1960
Productrange Industrial chemicals,specialitychemicals,bio-fertilisersandbio-
remediationtechnologies
Brand name of organophosphonate Codex, Sequacel and Dispercel.
End user industries served Coolingwatertreatment,boilerwatertreatment,soapsanddetergents,
textile processing, bottle washing, industrial and institutional cleaners, deflocculation of slurries,
antiscalant formulations for oilfields, sea water evaporators, reverse osmosis & sugar processing.
9
Other suppliers
It isreportedthatmost of the playersimportthe productor source fromthe local supplierand
formulate indifferentconcentrationaspercustomer’srequirement.
Name of the organization Location Brand name
Satyajit Chemicals Pvt. Ltd., Mumbai Aquasoft
Acuro Organics Ltd., . Noida
Chemicals
New Delhi Acurotex
Neelam Chemicals, Jaipur -
Chemtex SpecialtyChemicals, WestBengal -
Manhar Specialities, Gujarat -
AVA Chemicals, Mumbai -
Indian supply of organophosphonates for water treatment application
Indian production of organophosphonates
Around 40000 tonnes per annum
10
CHAPTER III
INDIAN TRADE DETAILS
Indian import of phosphonates for use in water treatment
Annual import
2013-2014 2014-2015
Qty in MT 8190.85 7958.04
7800
7850
7900
7950
8000
8050
8100
8150
8200
8250
Qty in MT
11
Productwise import – Period2014-2015
Portwise import – Period2014-2015
Countrywise import
Entire quantitygetsimportedfromChinaandlessthan1% fromSingapore andUK
HEDP 75%
ATMP AND OTHERS
25%
NHAVA 97%
CALCUTTA 2%
CHENNAI 1%
Total import 7958
MT
12
Import detailsof Dequest(phosphonates) forwater treatment application
Period April 2013 to March 2014
Date ITC code Product Indian Port Country
Qty in
MT
Value
in USD
Pricein
USD per
MT
24.05.2013 29319090 DEQUEST 2046 NHAVA UK 0.27 968 3585
21.06.2013 29319090
DEQUEST 2060S
SAMPLE QTY 0 600
KSG 1 BOTTLE NCV MUMBAI UK 0.001 617 616640
12.08.2013 29319090 DEQUEST D2066 NHAVA UK 1.08 5236 4848
24.08.2013 29319090 DEQUEST 2006 MUMBAI UK 0.025 809 32362
04.09.2013 29319090
DEQUEST 2010 290K
DNN OTHER ORGANO
- INORGANIC
COMPOUNDS NHAVA UK 2.32 9890 4263
12.09.2013 29319090
DEQUEST 2010
SAMPLE 1 200 KGS HYDERABA UK 2 808 404
16.09.2013 29319090
DEQUEST 2010
SAMPLE MUMBAI UK 0.001 32 31510
20.09.2013 29319090
DEQUEST 206OS
DIETHYLENETRIAMINE
PENTA NHAVA UK 0.29 2153 7425
27.09.2013 29319090
DEQUEST 2010
SAMPLE 2 BOTTLE HYDERABA UK 0.001 808 808000
09.10.2013 29319090
FOC ITEM - DEQUEST
2010 - 50 GRMS
ORGANIC CHEMICALS BANGALOR
SINGAP
ORE 0.001 3 3330
01.11.2013 29319090 17967 DEQUEST 2010 MUMBAI UK 0.025 848 33936
10.12.2013 29319090 DEQUEST D2066 NHAVA UK 1.08 5236 4848
19.12.2013 29319090 DEQUEST 2006 MUMBAI UK 0.025 814 32572
19.12.2013 29319090
DEQUEST 2010
SAMPLE 6 X 0 6 KG
BOTTLE HYDERABA UK 0.004 2020 504995
21.12.2013 29319090 DEQUEST 2046 MUMBAI UK 0.05 278 5555
24.12.2013 29319090
CHEMICAL DEQUEST
2016D MUMBAI UK 0.025 950 38014
24.12.2013 29319090
CHEMICALS DEQUEST
2047 MUMBAI UK 0.025 1125 45016
06.01.2014 29319090
ORGANIC CHEMICALS
- DEQUEST 2060S 2
BOTTLE MUMBAI UK 0.001 1667 1666500
07.02.2014 29319090 DEQUEST 2046 NHAVA UK 0.27 889 3293
25.03.2014 29319090 DEQUEST 2046 MUMBAI UK 0.27 1663 6161
26.03.2014 29319090 DEQUEST 2046 NHAVA UK 0.27 931 3448
31.03.2014 29319090 DEQUEST 2010 - NHAVA GERMA 0.5 2320 4639
13
1665490
ELECTROPLATING
CHEMICALS
NY
07.09.2013 34029099
1 BAG 25 KG
SP102548 DEQUEST
DQ 2047 G FOR R & D MUMBAI
NETHER
LANDS 1 89 89
07.09.2013 34029099
1 BAG 25 KG
SP133543 DEQUEST
2016DG EHDP FOR R
& D MUMBAI
NETHER
LANDS 1 89 89
26.10.2013 34029099
SP135217 DEQUEST
DQ2047 G 1 BAG R &
D MUMBAI
NETHER
LANDS 1 133 133
14.10.2013 38119000
AMINO TRIS TRADE
NAME DEQUEST
SAMPLE FOR TESTING
PURPOSES DELHI AIR
SOUTH
AFRICA 0.004 16 3975
30.08.2013 38123090
DEQUEST 2060S
ANTIFOAMING AGENT NHAVA
BELGIU
M 0.29 1630 5619
13.02.2014 38249021
DEQUEST 2010
ELECTROPLATING
PREPARATION DELHI AIR
GERMA
NY 0.5 2628 5256
06.01.2014 38249090
M - 02580 DEQUEST
SAMPLE FOR R & D &
TESTING PURPOSE DELHI AIR
SOUTH
AFRICA 0.005 13 2656
14
Period April 2014 to March 2015
I.E
DATE
ITC
CODE PRODUCT
INDIAN
PORT COUNTRY
QTY IN
MT VALUE US$ PRICE US$
27.11.
2014
293190
90 DEQUEST 2066 NHAVA UK 3.240 11,453.40 3,535.00
12.05.
2014
293190
90 DEQUEST 2066 NHAVA UK 2.160 7,962.84 3,686.50
10.12.
2014
293190
90
DEQUEST D2066 USE
IN PRINTING INDUSTRY MUMBAI UK 1.080 7,690.14 7,120.50
12.11.
2014
291619
90
DEQUEST 2010 DQ
D2010 1 PLT STC 4
DRUMS CHENNAI SINGAPORE 1.160 5,678.22 4,895.01
19.11.
2014
291619
90
DEQUEST 2010 DQ
D2010 1 PLT STC 4
DRUMS CHENNAI SINGAPORE 1.160 5,678.22 4,895.01
04.02.
2015
293190
90
DEQUEST D2066 USE
IN PRINTING INDUSTRY
NHAVA UK 1.080 5,235.84 4,848.00
06.05.
2014
293190
90
DEQUEST D2066
CLEAR AMBER
SOLUTION NHAVA UK 1.080 5,231.54 4,844.01
23.09.
2014
293190
90
DEQUEST 2010 290K
DNN OTHER ORGANO -
INORGANIC
COMPOUNDS NHAVA UK 1.160 4,972.52 4,286.65
11.12.
2014
293190
90
ORGANIC CHEMICALS -
DEQUEST 2060S 4 MUMBAI UK 0.002 2,989.60 14,94,800
22.09.
2014
293190
90
DEQUEST 2000 AMINO
TRIMETHYLENE
PHOSPHONIC ACID NHAVA UK 1.250 1,970.52 1,576.41
24.09.
2014
293190
90
DEQUEST 2000 L C
METHYLENE
PHOSPHONIC ACID NHAVA UK 0.540 1,827.09 3,383.50
20.11.
2014
293190
90
1685900 DEQUEST 2010
SFQ ELECTROPLATING
CHEMICAL NHAVA GERMANY 0.400 1,794.62 4,486.55
12.01.
2015
381230
90
DEQUEST 2060S
ANTIFOAMING AGENT NHAVA BELGIUM 0.290 1,480.11 5,103.82
08.10.
2014
293190
90
1685900 DEQUEST 2010
SFQ ELECTROPLATING
CHEMICAL NHAVA GERMANY 0.300 1,441.95 4,806.50
27.05.
2014
292910
90
DEQUEST 2010 1 -
HYDROXYETHYLIDENE
- 1 1 - DIPHOSPHONIC
ACID NHAVA UK 0.290 1,391.28 4,797.51
05.12.
2014
293190
90
DEQUEST 2010
SAMPLE HYDERABA ITALY 0.002 1,348.81 6,74,405.00
25.04.
2014
294200
90
DEQUEST 2060S
ANTIFOAMING AGENT NHAVA BELGIUM 0.205 1,181.05 5,761.21
26.02.
2015
293190
90 DEQUEST 2016D MUMBAI UK 0.025 959.50 38,380.00
12.01.
2015
293190
90
1685900 DEQUEST 2010
SFQ ELECTROPLATING
CHEMICAL NHAVA GERMANY 0.200 924.91 4,624.55
11.07.
2014
293190
90
DEQUEST 2006 25 KG
DRUM - 17961 MUMBAI UK 0.025 821.48 32,859.20
30.10.
2014
293190
90
DEQUEST 2010
SAMPLE HYDERABA UK 0.001 673.33 6,73,330.00
15
30.10.
2014
293190
90
DEQUEST 2010
SAMPLE HYDERABA UK 0.001 673.33 6,73,330.00
25.04.
2014
294200
90
DEQUEST 2060S
ANTIFOAMING AGENT NHAVA BELGIUM 0.085 491.33 5,780.35
16.09.
2014
292990
90
DEQUEST 2000
METHYLENEPHOSPHO
NIC ACID USE IN
PRINTING INDUSTRY NHAVA BELGIUM 0.200 475.27 2,376.35
18.07.
2014
292990
90
DEQUEST 2000
METHYLENEPHOSPHO
NIC ACID NHAVA BELGIUM 0.200 358.93 1,794.65
04.02.
2015
382490
22
DEQUEST 2006 25 LB
EXP - WATER
TREATMENT
CHEMICALS - 4DRUM CHENNAI
UNITED STATES
OF 0.045 258.87 5,752.66
20.11.
2014
340290
99
SP144982 DEQUEST
2047 1 BAGSAMPLE
NCV FOR RESEARCH
PURPOSE ONLY MUMBAI NETHERLANDS 0.027 213.43 7,904.81
20.11.
2014
340290
99
SP144768 DEQUEST
2016 1 BAGSAMPLE
NCV FOR RESEARCH
PURPOSE ONLY MUMBAI NETHERLANDS 0.027 205.77 7,621.11
18.12.
2014
293190
90
DEQUEST CHEMICALS
FOR WATER
MANAGEMENT N C V
SAMPLE 1BOTTLE MUMBAI THAILAND 0.001 105.04 1,05,040.00
31.05.
2014
340290
99
SAMPLES WASHING
COMPOUNDS 1 BAG
SP135217 DEQUEST
2047 SAMPLE - NCV - R
& D PURPOSES MUMBAI NETHERLANDS 0.027 65.73 2,434.44
31.05.
2014
340290
99
SAMPLES WASHING
COMPOUNDS 1 BAG
SP141188 DEQUEST
2016 SAMPLE - NCV - R
& D PURPOSES MUMBAI NETHERLANDS 0.027 65.73 2,434.44
11.04.
2014
340290
59
DEQUEST 2047
SAMPLE NOT FOR
SALE - LAUNDRY
WASHING POWDER
INGREDIENTS MUMBAI SOUTH AFRICA 0.003 30.23 10,076.66
19.12.
2014
293190
90
DEQUEST AZ - 24 - 6949
1 - HYDROXYL
ETHYLIDENE - 1 1
DIPHOSPHONIC ACID MUMBAI
UNITED STATES
OF 0.001 29.02 29,020.00
19.12.
2014
293190
90
DEQUEST 2000 AZ - 95 -
5706 AMINO TRI
METHYLENE
PHOSPHONIC ACID MUMBAI
UNITED STATES
OF 0.001 27.88 27,880.00
16
Indian export of all phosphonates for water treatment application
Annual export
Portwise export
2013-2014 2014-2015
Qty in MT 18223 27314
0
5000
10000
15000
20000
25000
30000
Qty in MT
NHAVA SHEVA
SEA
96%
MUMBAI AIR
1%
BANGALORE AIR
3%
17
Countrywise export
Productwise export
In MT
Product 2013-2014 2014-2015
HEDP 10233 18594
DTPMPA 6983 7785
ATMP 893 736
HMDTMP 83 158
EDTMP 35 41
Total 18228 27314
NETHERLANDS
23%
UNITED STATES
OF AMERICA
11%
ITALY
11%
JAPAN
7%
SPAIN
7%
BELGIUM
5%
EGYPT
6%
UNITED KINGDOM
5%
OTHERS
25%
18
Brandwise export
Aquapharm 85%
Excel and others
15%
19
CHAPTER IV
INDIAN DEMAND SUPPLY SCENARIO – PERIOD 2015
Indian demand
Indian demand supply scenario
In tonnes
Period Indianproduction Indiandomestic
demand
Exportdemand Gap in supply
2015 40000 20700 27300 8000
Productwise demand pattern
HEDP 60%
DTPMP 30%
ATMP 5%
OTHERS 5%
Indian demand for organophosphonate in water treatment sector 20700 tonnes
20
CHAPTER V
GLOBAL SCENARIO – PERIOD 2015
Global Market for chelating agent
Global Market for organophosphonates
Source:TransparencyMarket Research,USA
Dow Chemical Company
Dionex Corporation
Global demandforchelatingagent 1.02 milliontonnes
Global marketvalue forchelatingagent USD 4 billion
Global demandforoganophosphonatecompounds 0.26 milliontonnes
(Forall applicationsectors aschelatingagentincludinghousehold,textile andpulp&paper)
21
Global manufacturers and their organophosphonate range of products
Italmatch ChemicalsSpA, Belgium
Phosphonate family
Aminophosphonates: Six familiesof aminophosphonates DEQUEST® 2000, 2040, 2050,
2060, 2080, 2090
Nonaminophosphonates Two non-aminophosphonates DEQUEST® 2010 and 7000.
Groupingof phosphonates
These productsare classified accordingtoa fourdigitproductcode describedhereafter.
The firstthree digitsdesignate the series,groupingthe DEQUEST® gradesbelongingtothe same
chemical structure,i.e.:
DEQUEST® 200X series Basedon Aminotri (methylene-phosphonicacid) orATMP.
DEQUEST® 201X series Basedon 1-Hydroxyethylidene 1,1-DiphosphonicacidorHEDP
DEQUEST® 204X series Basedon Ethylenediaminetetra(methylene phosphonicacid) or
EDTMP.
DEQUEST® 205X series Basedon Hexamethylenediaminetetra (methylenephosphonic
acid) or HMDTMP
DEQUEST® 206X series Basedon Diethylenetriaminepenta(methylene phosphonic
acid) or DETPMP
DEQUEST® 208X series Basedon a proprietarypolyaminophosphonicacidpreparation.
DEQUEST® 209X series Basedon Bishexamethylenetriaminephosphonate
DEQUEST® 700x series Basedon Phosphonobutane tricarboxylicacid (PBTC).
Product type classification
The fourthnumber(x) indicatesthe producttype,using the followingconvention:
0 - Acidsolution
1 - Solidacid
4 - Potassiumsalt
6 - Sodiumsalt
7 - Calciumsalt
As an example,DEQUEST® 2066 standsfor the aqueous solutionof the sodiumsaltof Diethylene-
triamine penta(methylenephosphonicacid)
22
Product range, specificationand itsspecificusage - 200X, 201X, 600X, 700X series
23
24
Product range, specificationand itsspecificusage - 204X, 205X, 206X, 406X series
25
Product range, specificationand itsspecificusage - 204X, 205X, 206X, 406X series
26
Product range, specificationand itsspecificusage - 208X, 209X series
Special Dequestphosphonatesgrade
A numberof special DEQUEST® phosphonates gradesare availablewhichhave beendevelopedfor
specificapplications.These include the following
Special grade
product
Specific feature Application
DEQUEST® 2000 LC A lowchloride grade of DEQUEST®
2000
Specificallydevelopedforapplications
inwhichchloridescouldcause
corrosionof stainlesssteelas
hydrogenperoxide stabilizer
DEQUEST® 2000 EG A purifiedgrade of DEQUEST® 2000. Electronicsapplications
DEQUEST® 2000 LA, A lowammoniagrade of DEQUEST®
2000
Specificallydevelopedforhigh pH
applicationsinwhichammoniagases
cause smell problems.
27
Zschimmer& Schwarz MohsdorfGmbH & Co.KG,USA
Name Chemical Name CommonName(s) Form Cas #
CublenK60 1-Hydroxyethane 1,1-DiphosphonicAcid HEDP acid form Liquid 2809-
21-4
CublenK8514GR 1-Hydroxyethane 1,1-
DiphosphonicTetrasodiumSalt
Na4HEDP Granules 3794-
83-0
CublenAP1 Aminotris (methylene phosphonic
acid) lowchloride content
ATMP acid form
(low chloride)
Liquid 6419-
19-9
CublenAP5 Aminotris (methylene phosphonicacid) ATMP acid form Liquid 6419-
19-9
CublenA4015 Aminotris (methylene phosphonic
acid) PentasodiumSalt
Na5ATMP Liquid 2235-
43-0
CublenE34135P Ethylenediamine tetra(methylene
phosphonicacid) CalciumSodiumSalt
Ca.Na-EDTMP Granules 85480-
89-3
CublenD5012 Diethylenetriaminepenta(methylene
phosphonicacid) DisodiumSalt
Na2DTPMP Liquid 22042-
96-2
CublenD3217 Diethylenetriaminepenta(methylene
phosphonicacid) SeptasodiumSalt
Na7DTPMP Liquid 22042-
96-2
CublenD3217N Diethylenetriaminepenta(methylene
phosphonicacid) SeptasodiumSalt
Na7DTPMP (low
chloride)
Liquid 22042-
96-2
CublenR60 Hydroxyethylaminobis (methylene
phosphonicacid)
HEMPA acid form Liquid 5995-
42-6
CublenP50 2-Phosphonobutane-1,2,4-tricarboxylic
Acid
PBTC acidform Liquid 37971-
36-1
CublenDNC450 Diethylenetriaminepenta
(methylene phosphonicacid)
DTPMP acid form Liquid 15827-
60-8
Kemira
Trade name Product description Solid % pH Application
KemGuard
8001
Organophosphonate
& polymer
functionality
34 4-5 Scalesof calciumto very
severe conditions;effectivein
hightemperatures;effective
for barium;highlycalcium
tolerant;effective for
stabilizationof dissolvediron
KemGuard
8010
Organophosphonate
functionality
50 4–5 Calciumcarbonate & sulfate
scale control;effectivein
severe conditions;effectivein
hightemperatures;effective

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Market profile on phophonates water treatment industry july 2015

  • 1. 1 MARKET PROFILE ON ORGANOPHOSPHONATES
  • 2. 2 MARKET PROFILE ON ORGANOPHOSPHONATES CHAPTER I PRODUCT OVERVIEW.........................................................................................................4 General details ...............................................................................................................................4 Use of organo phosphonatesin boiler water treatment ....................................................................5 Use of organo phosphonatesin cooling water treatment..................................................................6 Advantages of organophosphonates over polyphosphates................................................................7 Choice of organophosphonate:........................................................................................................7 CHAPTER II INDIAN PRODUCTION........................................................................................................8 Indian manufacturers of organo phosphonic acids and phosphonate salts .........................................8 Aquapharm Chemical Company Pvt. Ltd. ......................................................................................8 Excel Industries Ltd......................................................................................................................8 Other suppliers...............................................................................................................................9 Indian supply of organophosphonates for water treatment application .............................................9 CHAPTER III INDIAN TRADE DETAILS...................................................................................................10 Indian import of phosphonates for use in water treatment .............................................................10 Annual import...........................................................................................................................10 Productwise import – Period 2014-2015.....................................................................................11 Portwise import – Period 2014-2015 ..........................................................................................11 Countrywise import...................................................................................................................11 Import details of Dequest (phosphonates) for water treatment application..................................12 Indian export of all phosphonates for water treatment application..................................................16 Annual export...........................................................................................................................16 Portwise export.........................................................................................................................16 Countrywise export...................................................................................................................17 Productwise export ...................................................................................................................17 Brandwise export......................................................................................................................18
  • 3. 3 CHAPTER IV INDIAN DEMAND SUPPLY SCENARIO – PERIOD 2015 ........................................................19 Indian demand .............................................................................................................................19 Indian demand supply scenario......................................................................................................19 Productwise demand pattern ........................................................................................................19 CHAPTER V GLOBAL SCENARIO – PERIOD 2015...................................................................................20 Global Market for chelating agent..................................................................................................20 Global Market for organophosphonates.........................................................................................20 Global manufacturers and their organophosphonate range of products...........................................21 Italmatch Chemicals SpA, Belgium..............................................................................................21 Zschimmer& Schwarz Mohsdorf GmbH & Co.KG, USA .................................................................27 Kemira......................................................................................................................................27
  • 4. 4 CHAPTER I PRODUCT OVERVIEW General details Phosphonicacidsare organicderivativesof phosphonicacid of the formR-PO3H2. Commonlyusedwatertreatmentchemicals inIndiaare givenbelow. The introduction of an amine group into the molecule increases the metal binding abilities of the phosphonate.The stabilityof the metal complexesincreaseswithincreasingnumberof phosphonic acid groups. Phosphonates are highly water soluble, non-volatile and highly sorptive chemicals. The other phosphonate used to a much lesser extent are,  Hexamethylene diamine tetramethylene phosphoric acid (HMDTMP)  Ethylene diamine tetramethylene phosphoric acid (EDTMP) The keypropertiesof Organophosphonatesare:  Thresholdeffectandcrystal distortion.  HydrolyticStability.  Sequestrationcharacteristics.  Deflocculation.  Chlorine stability
  • 5. 5 Use of organo phosphonates in boiler water treatment In the operation of steam boiler, the major problems are faced due to scaling and on account of corrosion. In the process of making steam in a steam boiler, the steam which leaves the boiler is almost pure water. The water remaining in the boiler becomes more concentrated with the impurities. After reaching a certain concentration and due to the inverse solubilities of some of these impurities they come out of solution and begin to adhere to the hot heat exchange surfaces such as the boiler tubes. This causes loss of efficiency, corrosion and mechanical failure. As a solution to this condition, some of the impuritiescanbe removedmechanicallybefore enteringthe boiler. In most cases a certain percentage of the impurities are removed mechanically followed by the addition of chemicals whose properties result in the elimination or reduction of deposits caused by the remaining impurities. The impuritiesthatare mainconcernsina steamboilerare hardness (Ca and Mg) and iron which enters the boiler via the make-up water as calcium and magnesium bicarbonate. These compounds are quite soluble. The problembeginsasheatisaddedto the boiler andmuch of the calcium becomes calcium carbonate. Calciumcarbonate issparinglysolubleandwill precipitate. Magnesium will also form sparingly soluble compounds such as magnesium silicate and magnesium hydroxide. Iron enteringthe boiler as iron bicarbonate with the make-up water or as corrosion products from the condensate,feedwaterorboileritself isespecially troublesome. Because the iron compounds formed underboilerconditionsare soinsolubleitisimperative thattheybe dealtwith.Itis also speculated that iron hampers the dispersing ability of polymers by deactivating their functional groups. The two main chemical methods of dealing with hardness and iron in boilers are to intentionally precipitate the impuritiesinsome formwhichis lesstroublesome thanthe untreatedspecies or to keep the impuritiesinsolutionordispersedsothatprecipitationanddepositsare not formed. In fact, usually a dynamic combination of sequestration and dispersion takes place.
  • 6. 6 Use of organo phosphonates in cooling watertreatment In the case of cooling water systems, biofouling is the major problem. The problems arise due to reverse solubilityof calciumcarbonate and the instability of calcium bicarbonate. Calcium bicarbonate breaks down to form calcium carbonate, which precipitates easily and forms scales. Phosphonatesact asscale inhibitorsby adsorbingontospecificcrystal nuclei surfacesof insolublesalts, thuspoisoningfurthercrystal growth.Theyusuallycontainmultiplephosphonate groups(R-PO3H2,R¼ organicchain) most commonlyfoundintheirdeprotonatedform, due tothe particularpHrange of operation. Organophosphonates,insubstoichiometricamountspreventorretardthe precipitationof scale forming salts.Phosphonate interfere with the nucleation of the hardness crystal causing much higher levels of hardnesstostay insolutionthanwouldbe possible with untreated water. The inhibitor is adsorbed on the surface of scale forming crystals during the process of crystallization. This retards the growth of crystalsand whentheyare formedtheyare highlydistortedpreventingorderlylattice type growth. This changes the adherence characteristics of the scales formed leading to a soft sludge rather than an adherent scale, which is easily dispersed by the movement of water. Suspended particles and dirt in cooling water generally have a negative surface charge. Anionic polymers increase this negative surface charge and keep the particles separated. Cationic dispersant when used should be carefully controlled, since the positive charge might be expected to co2 agulate the negatively charged particles, leading to the formation of dense particles. Addition of cationic dispersants also involves greater expense since a higher dosage is required as the charge on the suspended particles would neutralize before sufficient positive charge was built up to keep them separated. Organophosphonates exhibit good molecules stability towards chlorine, which is commonly used as a biocide incoolingwatersystem.Incase where greatermoleculesstabilitytochlorine is desired. HEDP is preferable to ATMP since it contains nitrogen and therefore chlorine demand for the formation of chloramines is totally absent.
  • 7. 7 Advantages of organophosphonates over polyphosphates Reductionin sludge formation: Polyphosphates,whenusedascorrosioninhibitor,give rise toexcessive orthophosphate sludgeswhereasOrganophosphonateswith zincgive good corrosionprotectionwithout leading to any sludge formation. Optimum usage level: Due to the sequestering ability of phosphonate, the zinc ions are present in a complexed form limiting the rate of reaction of zinc with hydroxyl ions. Therefore, optimum concentrationof zinc hydroxide allows the formation of a thin hydroxide film at the surface giving the desired corrosion resistance. Superior sequestering ability of heavy metals: The sequestering ability of phosphonate enables it to control heavymatter(Fe,Cu& Zn) depositsandthiscontrol isfar superior to other traditional chelants. Phosphonate also help to disperse suspended particles.Phosphonate provide excellent control of hydrated ferric oxide deposits which are formed as a result of corrosion. They adsorb on the particle surfaces and reduce the attractive forces between individual iron particles. Higher stabilityand resistant to hydrolysis: Phosphonatesdonot hydrolyse easily like Polyphosphates and are useful to avoid Calcium precipitation even in alkaline waters. The carbon to phosphorus to oxygen(CPO) bondinginOrganophosphonatesismore resistant to hydrolysis or cleavage than the COP bond in phosphate esters and the OP bond in polyphosphates. Organophosphonates are extremely stable to hydrolysis as compared to polyphosphates at elevated temperature and extremes in pH for extended periods of time. Choice of organophosphonate: From the two most commonly used phosphonate for cooling water treatment HEDP is preferred to ATMP for the following reasons: ATMP is more corrosive toCu coolingsystemsinvolving Cu or Cu alloys, are therefore very sensitive to ATMP. WithATMP one would thenhave to use CucorrosioninhibitorslikeThiazolesandTrizoles making the treatment more expensive. HEDP has betterstabilitytochlorine thanthe Nitrogencontaining ATMP.Nitrogencontainingcompound have a tendency to form chloramines. Though, when complexed with Zinc, ATMP exhibits stability towardschlorine it should be used with caution in chlorinated cooling water systems especially when continuous chlorination is used. The addition of Zinc to ATMP to a certain extent inhibits the dissolution of copper. In the presence of ATMP, however,the powerfuloxidizing potentialof chlorine promotes the dissolution of copper, when chlorine is used as a biocide.
  • 8. 8 CHAPTER II INDIAN PRODUCTION Indian manufacturers of organo phosphonic acids and phosphonate salts Name of the organization Location Brand name Excel IndustriesLtd., Lote Parshuram Unit Codex Aquapharm Chemical Co. P. Ltd., Pune Aquacid Aquapharm Chemical Company Pvt. Ltd. Year of establishment 1977 Share holders Mangwani familyandDesai family Market share of organophosphonatechemicalinIndia 35% Brand name of organophosphonates Aquacid Excel IndustriesLtd Year of incorporation 1960 Productrange Industrial chemicals,specialitychemicals,bio-fertilisersandbio- remediationtechnologies Brand name of organophosphonate Codex, Sequacel and Dispercel. End user industries served Coolingwatertreatment,boilerwatertreatment,soapsanddetergents, textile processing, bottle washing, industrial and institutional cleaners, deflocculation of slurries, antiscalant formulations for oilfields, sea water evaporators, reverse osmosis & sugar processing.
  • 9. 9 Other suppliers It isreportedthatmost of the playersimportthe productor source fromthe local supplierand formulate indifferentconcentrationaspercustomer’srequirement. Name of the organization Location Brand name Satyajit Chemicals Pvt. Ltd., Mumbai Aquasoft Acuro Organics Ltd., . Noida Chemicals New Delhi Acurotex Neelam Chemicals, Jaipur - Chemtex SpecialtyChemicals, WestBengal - Manhar Specialities, Gujarat - AVA Chemicals, Mumbai - Indian supply of organophosphonates for water treatment application Indian production of organophosphonates Around 40000 tonnes per annum
  • 10. 10 CHAPTER III INDIAN TRADE DETAILS Indian import of phosphonates for use in water treatment Annual import 2013-2014 2014-2015 Qty in MT 8190.85 7958.04 7800 7850 7900 7950 8000 8050 8100 8150 8200 8250 Qty in MT
  • 11. 11 Productwise import – Period2014-2015 Portwise import – Period2014-2015 Countrywise import Entire quantitygetsimportedfromChinaandlessthan1% fromSingapore andUK HEDP 75% ATMP AND OTHERS 25% NHAVA 97% CALCUTTA 2% CHENNAI 1% Total import 7958 MT
  • 12. 12 Import detailsof Dequest(phosphonates) forwater treatment application Period April 2013 to March 2014 Date ITC code Product Indian Port Country Qty in MT Value in USD Pricein USD per MT 24.05.2013 29319090 DEQUEST 2046 NHAVA UK 0.27 968 3585 21.06.2013 29319090 DEQUEST 2060S SAMPLE QTY 0 600 KSG 1 BOTTLE NCV MUMBAI UK 0.001 617 616640 12.08.2013 29319090 DEQUEST D2066 NHAVA UK 1.08 5236 4848 24.08.2013 29319090 DEQUEST 2006 MUMBAI UK 0.025 809 32362 04.09.2013 29319090 DEQUEST 2010 290K DNN OTHER ORGANO - INORGANIC COMPOUNDS NHAVA UK 2.32 9890 4263 12.09.2013 29319090 DEQUEST 2010 SAMPLE 1 200 KGS HYDERABA UK 2 808 404 16.09.2013 29319090 DEQUEST 2010 SAMPLE MUMBAI UK 0.001 32 31510 20.09.2013 29319090 DEQUEST 206OS DIETHYLENETRIAMINE PENTA NHAVA UK 0.29 2153 7425 27.09.2013 29319090 DEQUEST 2010 SAMPLE 2 BOTTLE HYDERABA UK 0.001 808 808000 09.10.2013 29319090 FOC ITEM - DEQUEST 2010 - 50 GRMS ORGANIC CHEMICALS BANGALOR SINGAP ORE 0.001 3 3330 01.11.2013 29319090 17967 DEQUEST 2010 MUMBAI UK 0.025 848 33936 10.12.2013 29319090 DEQUEST D2066 NHAVA UK 1.08 5236 4848 19.12.2013 29319090 DEQUEST 2006 MUMBAI UK 0.025 814 32572 19.12.2013 29319090 DEQUEST 2010 SAMPLE 6 X 0 6 KG BOTTLE HYDERABA UK 0.004 2020 504995 21.12.2013 29319090 DEQUEST 2046 MUMBAI UK 0.05 278 5555 24.12.2013 29319090 CHEMICAL DEQUEST 2016D MUMBAI UK 0.025 950 38014 24.12.2013 29319090 CHEMICALS DEQUEST 2047 MUMBAI UK 0.025 1125 45016 06.01.2014 29319090 ORGANIC CHEMICALS - DEQUEST 2060S 2 BOTTLE MUMBAI UK 0.001 1667 1666500 07.02.2014 29319090 DEQUEST 2046 NHAVA UK 0.27 889 3293 25.03.2014 29319090 DEQUEST 2046 MUMBAI UK 0.27 1663 6161 26.03.2014 29319090 DEQUEST 2046 NHAVA UK 0.27 931 3448 31.03.2014 29319090 DEQUEST 2010 - NHAVA GERMA 0.5 2320 4639
  • 13. 13 1665490 ELECTROPLATING CHEMICALS NY 07.09.2013 34029099 1 BAG 25 KG SP102548 DEQUEST DQ 2047 G FOR R & D MUMBAI NETHER LANDS 1 89 89 07.09.2013 34029099 1 BAG 25 KG SP133543 DEQUEST 2016DG EHDP FOR R & D MUMBAI NETHER LANDS 1 89 89 26.10.2013 34029099 SP135217 DEQUEST DQ2047 G 1 BAG R & D MUMBAI NETHER LANDS 1 133 133 14.10.2013 38119000 AMINO TRIS TRADE NAME DEQUEST SAMPLE FOR TESTING PURPOSES DELHI AIR SOUTH AFRICA 0.004 16 3975 30.08.2013 38123090 DEQUEST 2060S ANTIFOAMING AGENT NHAVA BELGIU M 0.29 1630 5619 13.02.2014 38249021 DEQUEST 2010 ELECTROPLATING PREPARATION DELHI AIR GERMA NY 0.5 2628 5256 06.01.2014 38249090 M - 02580 DEQUEST SAMPLE FOR R & D & TESTING PURPOSE DELHI AIR SOUTH AFRICA 0.005 13 2656
  • 14. 14 Period April 2014 to March 2015 I.E DATE ITC CODE PRODUCT INDIAN PORT COUNTRY QTY IN MT VALUE US$ PRICE US$ 27.11. 2014 293190 90 DEQUEST 2066 NHAVA UK 3.240 11,453.40 3,535.00 12.05. 2014 293190 90 DEQUEST 2066 NHAVA UK 2.160 7,962.84 3,686.50 10.12. 2014 293190 90 DEQUEST D2066 USE IN PRINTING INDUSTRY MUMBAI UK 1.080 7,690.14 7,120.50 12.11. 2014 291619 90 DEQUEST 2010 DQ D2010 1 PLT STC 4 DRUMS CHENNAI SINGAPORE 1.160 5,678.22 4,895.01 19.11. 2014 291619 90 DEQUEST 2010 DQ D2010 1 PLT STC 4 DRUMS CHENNAI SINGAPORE 1.160 5,678.22 4,895.01 04.02. 2015 293190 90 DEQUEST D2066 USE IN PRINTING INDUSTRY NHAVA UK 1.080 5,235.84 4,848.00 06.05. 2014 293190 90 DEQUEST D2066 CLEAR AMBER SOLUTION NHAVA UK 1.080 5,231.54 4,844.01 23.09. 2014 293190 90 DEQUEST 2010 290K DNN OTHER ORGANO - INORGANIC COMPOUNDS NHAVA UK 1.160 4,972.52 4,286.65 11.12. 2014 293190 90 ORGANIC CHEMICALS - DEQUEST 2060S 4 MUMBAI UK 0.002 2,989.60 14,94,800 22.09. 2014 293190 90 DEQUEST 2000 AMINO TRIMETHYLENE PHOSPHONIC ACID NHAVA UK 1.250 1,970.52 1,576.41 24.09. 2014 293190 90 DEQUEST 2000 L C METHYLENE PHOSPHONIC ACID NHAVA UK 0.540 1,827.09 3,383.50 20.11. 2014 293190 90 1685900 DEQUEST 2010 SFQ ELECTROPLATING CHEMICAL NHAVA GERMANY 0.400 1,794.62 4,486.55 12.01. 2015 381230 90 DEQUEST 2060S ANTIFOAMING AGENT NHAVA BELGIUM 0.290 1,480.11 5,103.82 08.10. 2014 293190 90 1685900 DEQUEST 2010 SFQ ELECTROPLATING CHEMICAL NHAVA GERMANY 0.300 1,441.95 4,806.50 27.05. 2014 292910 90 DEQUEST 2010 1 - HYDROXYETHYLIDENE - 1 1 - DIPHOSPHONIC ACID NHAVA UK 0.290 1,391.28 4,797.51 05.12. 2014 293190 90 DEQUEST 2010 SAMPLE HYDERABA ITALY 0.002 1,348.81 6,74,405.00 25.04. 2014 294200 90 DEQUEST 2060S ANTIFOAMING AGENT NHAVA BELGIUM 0.205 1,181.05 5,761.21 26.02. 2015 293190 90 DEQUEST 2016D MUMBAI UK 0.025 959.50 38,380.00 12.01. 2015 293190 90 1685900 DEQUEST 2010 SFQ ELECTROPLATING CHEMICAL NHAVA GERMANY 0.200 924.91 4,624.55 11.07. 2014 293190 90 DEQUEST 2006 25 KG DRUM - 17961 MUMBAI UK 0.025 821.48 32,859.20 30.10. 2014 293190 90 DEQUEST 2010 SAMPLE HYDERABA UK 0.001 673.33 6,73,330.00
  • 15. 15 30.10. 2014 293190 90 DEQUEST 2010 SAMPLE HYDERABA UK 0.001 673.33 6,73,330.00 25.04. 2014 294200 90 DEQUEST 2060S ANTIFOAMING AGENT NHAVA BELGIUM 0.085 491.33 5,780.35 16.09. 2014 292990 90 DEQUEST 2000 METHYLENEPHOSPHO NIC ACID USE IN PRINTING INDUSTRY NHAVA BELGIUM 0.200 475.27 2,376.35 18.07. 2014 292990 90 DEQUEST 2000 METHYLENEPHOSPHO NIC ACID NHAVA BELGIUM 0.200 358.93 1,794.65 04.02. 2015 382490 22 DEQUEST 2006 25 LB EXP - WATER TREATMENT CHEMICALS - 4DRUM CHENNAI UNITED STATES OF 0.045 258.87 5,752.66 20.11. 2014 340290 99 SP144982 DEQUEST 2047 1 BAGSAMPLE NCV FOR RESEARCH PURPOSE ONLY MUMBAI NETHERLANDS 0.027 213.43 7,904.81 20.11. 2014 340290 99 SP144768 DEQUEST 2016 1 BAGSAMPLE NCV FOR RESEARCH PURPOSE ONLY MUMBAI NETHERLANDS 0.027 205.77 7,621.11 18.12. 2014 293190 90 DEQUEST CHEMICALS FOR WATER MANAGEMENT N C V SAMPLE 1BOTTLE MUMBAI THAILAND 0.001 105.04 1,05,040.00 31.05. 2014 340290 99 SAMPLES WASHING COMPOUNDS 1 BAG SP135217 DEQUEST 2047 SAMPLE - NCV - R & D PURPOSES MUMBAI NETHERLANDS 0.027 65.73 2,434.44 31.05. 2014 340290 99 SAMPLES WASHING COMPOUNDS 1 BAG SP141188 DEQUEST 2016 SAMPLE - NCV - R & D PURPOSES MUMBAI NETHERLANDS 0.027 65.73 2,434.44 11.04. 2014 340290 59 DEQUEST 2047 SAMPLE NOT FOR SALE - LAUNDRY WASHING POWDER INGREDIENTS MUMBAI SOUTH AFRICA 0.003 30.23 10,076.66 19.12. 2014 293190 90 DEQUEST AZ - 24 - 6949 1 - HYDROXYL ETHYLIDENE - 1 1 DIPHOSPHONIC ACID MUMBAI UNITED STATES OF 0.001 29.02 29,020.00 19.12. 2014 293190 90 DEQUEST 2000 AZ - 95 - 5706 AMINO TRI METHYLENE PHOSPHONIC ACID MUMBAI UNITED STATES OF 0.001 27.88 27,880.00
  • 16. 16 Indian export of all phosphonates for water treatment application Annual export Portwise export 2013-2014 2014-2015 Qty in MT 18223 27314 0 5000 10000 15000 20000 25000 30000 Qty in MT NHAVA SHEVA SEA 96% MUMBAI AIR 1% BANGALORE AIR 3%
  • 17. 17 Countrywise export Productwise export In MT Product 2013-2014 2014-2015 HEDP 10233 18594 DTPMPA 6983 7785 ATMP 893 736 HMDTMP 83 158 EDTMP 35 41 Total 18228 27314 NETHERLANDS 23% UNITED STATES OF AMERICA 11% ITALY 11% JAPAN 7% SPAIN 7% BELGIUM 5% EGYPT 6% UNITED KINGDOM 5% OTHERS 25%
  • 19. 19 CHAPTER IV INDIAN DEMAND SUPPLY SCENARIO – PERIOD 2015 Indian demand Indian demand supply scenario In tonnes Period Indianproduction Indiandomestic demand Exportdemand Gap in supply 2015 40000 20700 27300 8000 Productwise demand pattern HEDP 60% DTPMP 30% ATMP 5% OTHERS 5% Indian demand for organophosphonate in water treatment sector 20700 tonnes
  • 20. 20 CHAPTER V GLOBAL SCENARIO – PERIOD 2015 Global Market for chelating agent Global Market for organophosphonates Source:TransparencyMarket Research,USA Dow Chemical Company Dionex Corporation Global demandforchelatingagent 1.02 milliontonnes Global marketvalue forchelatingagent USD 4 billion Global demandforoganophosphonatecompounds 0.26 milliontonnes (Forall applicationsectors aschelatingagentincludinghousehold,textile andpulp&paper)
  • 21. 21 Global manufacturers and their organophosphonate range of products Italmatch ChemicalsSpA, Belgium Phosphonate family Aminophosphonates: Six familiesof aminophosphonates DEQUEST® 2000, 2040, 2050, 2060, 2080, 2090 Nonaminophosphonates Two non-aminophosphonates DEQUEST® 2010 and 7000. Groupingof phosphonates These productsare classified accordingtoa fourdigitproductcode describedhereafter. The firstthree digitsdesignate the series,groupingthe DEQUEST® gradesbelongingtothe same chemical structure,i.e.: DEQUEST® 200X series Basedon Aminotri (methylene-phosphonicacid) orATMP. DEQUEST® 201X series Basedon 1-Hydroxyethylidene 1,1-DiphosphonicacidorHEDP DEQUEST® 204X series Basedon Ethylenediaminetetra(methylene phosphonicacid) or EDTMP. DEQUEST® 205X series Basedon Hexamethylenediaminetetra (methylenephosphonic acid) or HMDTMP DEQUEST® 206X series Basedon Diethylenetriaminepenta(methylene phosphonic acid) or DETPMP DEQUEST® 208X series Basedon a proprietarypolyaminophosphonicacidpreparation. DEQUEST® 209X series Basedon Bishexamethylenetriaminephosphonate DEQUEST® 700x series Basedon Phosphonobutane tricarboxylicacid (PBTC). Product type classification The fourthnumber(x) indicatesthe producttype,using the followingconvention: 0 - Acidsolution 1 - Solidacid 4 - Potassiumsalt 6 - Sodiumsalt 7 - Calciumsalt As an example,DEQUEST® 2066 standsfor the aqueous solutionof the sodiumsaltof Diethylene- triamine penta(methylenephosphonicacid)
  • 22. 22 Product range, specificationand itsspecificusage - 200X, 201X, 600X, 700X series
  • 23. 23
  • 24. 24 Product range, specificationand itsspecificusage - 204X, 205X, 206X, 406X series
  • 25. 25 Product range, specificationand itsspecificusage - 204X, 205X, 206X, 406X series
  • 26. 26 Product range, specificationand itsspecificusage - 208X, 209X series Special Dequestphosphonatesgrade A numberof special DEQUEST® phosphonates gradesare availablewhichhave beendevelopedfor specificapplications.These include the following Special grade product Specific feature Application DEQUEST® 2000 LC A lowchloride grade of DEQUEST® 2000 Specificallydevelopedforapplications inwhichchloridescouldcause corrosionof stainlesssteelas hydrogenperoxide stabilizer DEQUEST® 2000 EG A purifiedgrade of DEQUEST® 2000. Electronicsapplications DEQUEST® 2000 LA, A lowammoniagrade of DEQUEST® 2000 Specificallydevelopedforhigh pH applicationsinwhichammoniagases cause smell problems.
  • 27. 27 Zschimmer& Schwarz MohsdorfGmbH & Co.KG,USA Name Chemical Name CommonName(s) Form Cas # CublenK60 1-Hydroxyethane 1,1-DiphosphonicAcid HEDP acid form Liquid 2809- 21-4 CublenK8514GR 1-Hydroxyethane 1,1- DiphosphonicTetrasodiumSalt Na4HEDP Granules 3794- 83-0 CublenAP1 Aminotris (methylene phosphonic acid) lowchloride content ATMP acid form (low chloride) Liquid 6419- 19-9 CublenAP5 Aminotris (methylene phosphonicacid) ATMP acid form Liquid 6419- 19-9 CublenA4015 Aminotris (methylene phosphonic acid) PentasodiumSalt Na5ATMP Liquid 2235- 43-0 CublenE34135P Ethylenediamine tetra(methylene phosphonicacid) CalciumSodiumSalt Ca.Na-EDTMP Granules 85480- 89-3 CublenD5012 Diethylenetriaminepenta(methylene phosphonicacid) DisodiumSalt Na2DTPMP Liquid 22042- 96-2 CublenD3217 Diethylenetriaminepenta(methylene phosphonicacid) SeptasodiumSalt Na7DTPMP Liquid 22042- 96-2 CublenD3217N Diethylenetriaminepenta(methylene phosphonicacid) SeptasodiumSalt Na7DTPMP (low chloride) Liquid 22042- 96-2 CublenR60 Hydroxyethylaminobis (methylene phosphonicacid) HEMPA acid form Liquid 5995- 42-6 CublenP50 2-Phosphonobutane-1,2,4-tricarboxylic Acid PBTC acidform Liquid 37971- 36-1 CublenDNC450 Diethylenetriaminepenta (methylene phosphonicacid) DTPMP acid form Liquid 15827- 60-8 Kemira Trade name Product description Solid % pH Application KemGuard 8001 Organophosphonate & polymer functionality 34 4-5 Scalesof calciumto very severe conditions;effectivein hightemperatures;effective for barium;highlycalcium tolerant;effective for stabilizationof dissolvediron KemGuard 8010 Organophosphonate functionality 50 4–5 Calciumcarbonate & sulfate scale control;effectivein severe conditions;effectivein hightemperatures;effective