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CCPS
    An AIChE Industry
                             Process Safety Beacon                                     Messages for
                                                                                       Manufacturing
                                                                                        Personnel
    Technology Alliance
                                              January 2002


 Explosions
 Every year, hundreds of equipment
 items are damaged in an explosion.
 These events are often described in
 familiar terms:

 ? a flammable vapor, air and an
 ?
   ignition source generate
   pressure,
 ? which ruptures
 ?
   piping/buildings/equipment (like
   these column trays),
 ? leading to property damage,
 ?
   downtime, lost business and, in
   some cases, serious injury or
   death to personnel in the
                                              There are many ways to prevent explosions - this message
   immediate area.
                                              will BRIEFLY discuss one : How much flammable material
                                              is needed to generate an explosion? The short answer is - in
                                              most cases, LESS THAN YOU MIGHT THINK!

     Most flammable materials have a flammable range, a concentration of the flammable
     material in air, which will support combustion. If the concentration of the substance is
     above or below these “flammable limits”, combustion will not occur. Please recognize that
     these values depend upon a number of variables, including the material itself, the pressure,
     and the oxygen concentration.


Let’s go take a fairly simple example – PROPANE, a material         In a typical manufacturing site,
many of us have in our home B-B-Q grills. How much propane          flammable materials are
is needed to fill a 2-car garage (say 20’ by 20’ by 10’) to its     handled in hundreds or
lower flammable limit? Propane’s flammable limits in ambient        thousands of gallons. It is
conditions are between 2.3% and 9.5% (by volume) in air (ref:       obvious that careful control is
SAX, 9th edition). SO….                                             needed for these materials.
     -garage volume = 20 * 20 * 10 = 4000 ft3                       Very small quantities, even
     -lower explosive limit amount = 2.3% * 4000 ft3 = 92 ft3       those involved with valve
      of propane vapor                                              leakage, can generate events
     -which is equivalent to about 3 gallons of liquid –            which have very severe
Answer: NOT MUCH!                                                   consequences!

     {PSID Members see Incident *327}

AIChE © 2002. All rights reserved. Reproduction for non-commercial, educational purposes is encouraged.
However, reproduction for the purpose of resale by anyone other than CCPS is strictly prohibited.
                                                          Contact us at ccps@aiche.org or 212-591-7319

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Explosions!

  • 1. CCPS An AIChE Industry Process Safety Beacon Messages for Manufacturing Personnel Technology Alliance January 2002 Explosions Every year, hundreds of equipment items are damaged in an explosion. These events are often described in familiar terms: ? a flammable vapor, air and an ? ignition source generate pressure, ? which ruptures ? piping/buildings/equipment (like these column trays), ? leading to property damage, ? downtime, lost business and, in some cases, serious injury or death to personnel in the There are many ways to prevent explosions - this message immediate area. will BRIEFLY discuss one : How much flammable material is needed to generate an explosion? The short answer is - in most cases, LESS THAN YOU MIGHT THINK! Most flammable materials have a flammable range, a concentration of the flammable material in air, which will support combustion. If the concentration of the substance is above or below these “flammable limits”, combustion will not occur. Please recognize that these values depend upon a number of variables, including the material itself, the pressure, and the oxygen concentration. Let’s go take a fairly simple example – PROPANE, a material In a typical manufacturing site, many of us have in our home B-B-Q grills. How much propane flammable materials are is needed to fill a 2-car garage (say 20’ by 20’ by 10’) to its handled in hundreds or lower flammable limit? Propane’s flammable limits in ambient thousands of gallons. It is conditions are between 2.3% and 9.5% (by volume) in air (ref: obvious that careful control is SAX, 9th edition). SO…. needed for these materials. -garage volume = 20 * 20 * 10 = 4000 ft3 Very small quantities, even -lower explosive limit amount = 2.3% * 4000 ft3 = 92 ft3 those involved with valve of propane vapor leakage, can generate events -which is equivalent to about 3 gallons of liquid – which have very severe Answer: NOT MUCH! consequences! {PSID Members see Incident *327} AIChE © 2002. All rights reserved. Reproduction for non-commercial, educational purposes is encouraged. However, reproduction for the purpose of resale by anyone other than CCPS is strictly prohibited. Contact us at ccps@aiche.org or 212-591-7319