SlideShare a Scribd company logo
1 of 129
iju
N
( )NjiUp
m
H
ji
ij
i
i ,,2,1,
2
1 2
=+





= ∑∑ <
)1(
∑( )
2
1−NN
ijr

ijij rrr

−= iju
∫ −= ωβ dH
hN
TVQ NN )exp(
!
1
),( 3
∫ ∑ ∫ ∑< =
−−=
ji
N
i
NNi
ijNN drdp
m
p
u
hN
TVQ
1
33
2
3
})
2
exp(){exp(
!
1
),( ββ
( ) rdpdup
mhN
TVQ NN
ji
ij
i
iNN
332
3
2
1
exp
!
1
,






−





−= ∑∑∫ <
ββ )2(
∫∏∫ ∑ ==
−=−=
N
i
i
i
N
i
Ni
dp
m
p
dp
m
p
I
3
1
2
1
3
2
)
2
exp()
2
exp( ββ
∫ ∫
∞
−
=−=
0
223
2
)4())
2
exp((
2
Nm
p
N
dppedp
m
p
I πβ
β
23
)2( N
mkTI π=
( ) ( )TVZ
N
dru
N
TVQ NN
N
ji
ijNN ,
!
1
exp
!
1
, 3
3
3
λ
β
λ
=






−= ∑∫ <
)3(
( ) rNd
ji
ij
u
erNd
ji ij
uTVNZ 33exp, ∫ ∏
<
−
=∫ ∑
<
−=















 β
β )4(
mkT
h
π
λ
2
=
( )0iju =),( TVZN
ijf
(0)
( , ) N
NZ V T V=
(0)
3
( , )
!
N
N N
V
Q V T
N λ
=and )5(
.1−=
− iju
ij ef
β
)6(
( )0iju =
ijf( )TVZN ,
ijf iju
88
N
8=N
( )TVZN ,
[[ ]]1
2 6 8
3 5 7
4
( ) ( )
[ ] Nklijij
N
ji
ijN
rdrdfff
rdrdfTVZ
3
1
3
3
1
3
1
1,


∫ ∑ ∑
∫∏
+++=
+=
<
)7(
.8
3
1
3
6714128
3
1
3
6834 rdrdffftandrdrdfft BA  ∫∫ == )8(
]][[1
2 6 8
3 5 7
4
)9(
ijfijrr
[[ [[ [[[[ ]]]]]]]]3 5 8
42
1
[[ ]]76≡
2 ]][[ 5 ]][[ 7[[ ]][[ ]]3 4 6 8 ]][[1 ]][[≡
∫ ∫ ∫ ∫ ∫ ∫= 8
3
6
3
684
3
3
3
347
3
52
3
1
3
3 rdrdfrdrdfrdrdrdrdtA )10(
∫ ∫ ∫ ∫ ∫= 7
3
6
3
674
3
2
3
1
3
14128
3
5
3
3
3
rdrdfrdrdrdffrdrdrdtB
)11(
NNNN11NN
At
Bt
8Z
( ,.., , )λ β α
3 3
1( ... ) ... Nf f f d r d rα β λ∫ )12(
NN
55
l
l cluster−
l
5 cluster−
3 4 5
1 2
∫≡ 5
3
1
3
3425151412 .... rdrdfffff
)14(
( , )NZ V T = )13(N
1
l
l cluster−
( 1,2)l ≠l cluster−
3 cluster−
l cluster−
2 3
1
2 3
1
2 3
1
2 3
1
and )15(
)16(×= −
Vl
TVb ll )1(3
!
1
),(
λ
l cluster−
1122((
22
)(),(lim TbTVb l
V
l =
∞→
( )TVbl ,
l1r
( )1−lijf
r
1r
V
V
∫ +++= 3
3
2
3
1
3
2313122313231213126
)(
6
1
rdrdrdfffffffff
Vλ
[ ]∫∫ ∫∫+≈ 13
3
12
3
23131213
33
13126 12
3
6
1
rdrdfffVrdrdffV
Vλ
V
b 63
6
1
λ
= [ 2 3
1
2 3
1
2 3
1
2 3
1
]++ +
V
1
1 =b 1 ][ ∫= 1
31
rd
V
1= )17(
∫∫+= 13
3
12
3
2313126
2
2
6
1
2 rdrdfffb
λ
)19(
V2
1
32
λ
=b ][ 1 2
∫∫ ∫≈= 12
3
1232
3
1
3
123
2
1
V2
1
rdfrdrdf
λλ
)18(
∫ ∫
∞ ∞ −
−==
0 0
2
)(
3
2
3
)1(
2
)(
2
drredrrrf kT
ru
λ
π
λ
π
N
1mclaster−1
2mclaster−2
3mclaster−3
{ }lm
( ) { }∑=
/
, lN mSTVZ
N
{ }lmSclasterl −
),( TVZN
Nlm
N
l
l =∑=1
Nml ,.....,1,0= )20(
)21(
77
Nlm
N
l
l =∑=1
{ }lm
{ }lS m
l
l
m∑
{ }lm
11)NN
22
( ) ( ) ( )
.
!
!
!2!1
!
21
∏
=
l
mmm l
l
NN

)22(
{ }lS m
∏l
( clasterl − lm
) )23(
22
s{ms{mLL{{
( ).!/1∏l
lm
[∏l
( clasterl −
!
)
l
m
m
l
] )24(
3( 1)
( ! ) / !lml
l l
l
bl V mλ −
  ∏ )25(
)22()25(
( )
( )
.
!
1
!, 31
3
∑ ∏






















=
l
l
m l l
m
N
N
m
V
bNTVZ
λ
λ )26(
( ) ,333 1 Nlmm
l
l ll
λλλ == ∑
∏ )27(
( )
( )
.
!
1
,
1
3





















′
= ∏∑ =
N
L l
m
l
m
N
m
V
bTVQ
l
l
λ
∑}{ lmNlm
N
l
l =∑=1
)28(
NN00
( ) ,11
∏== ∑
l
mlllmN
zzz
( , )NQ V T
1
1
N
l
lm N
=
=∑
∑
∞
=
=℘
0
),(),,(
N
N
N
TVQzTVz
)26(}{ lm
}{ lm
)29(
)30(
( )
.
11
,exp
!
1
!
1
,,
1
3
1
3
1 0
3
0,, 1
3
1
21
∑
∏
∏ ∑
∑ ∏
∞
=
∞
=
∞
=
∞
=
∞
=
∞
=
=℘












=






















=






















=℘
l
l
l
l
l
l
l m l
m
l
l
mm l l
m
l
l
zbIn
V
V
zb
m
V
zb
m
V
zbTVz
l
l
λ
λ
λ
λ
)31(
)32(
zz
∞→Vif ∑
∞
=∞→
=





℘≡
1
3
1
ln
1
lim l
l
l
V
zb
VKT
P
λ
∑
∞
=∞→
=





∂
℘∂
≡
1
3
1
l
l
l
V
zb
z
Ln
V
z
V
N
Lim λ
)33(
)34(
zz343435353535zz3434Vv
N
=
( )la T
lalb
( )3
vλ
( )
13
1
−
∞
=






= ∑
l
l
l
v
Ta
KT
Pv λ
)1(
( )∑ ∑∑∑
∞
=
−∞
=
∞
=
∞
= 













=
1
1
111 l
l
n
n
nl
l
l
e
l
l
e zbnTazblzb )2(
,111 ≡= ba )3(
( )
( )∫
∞
−
−−=/−=
0
2/
322 .1
2
drreba KTru
λ
π
)4(
,
3
1
24
0 0
13
3
12
3
23131262
2
23 ∫∫
∞ ∞
−=−= rdrdfffbba
λ
)5(
,31820 432
3
24 =−+−= bbbba )6(
l-clasterl-claster
l-clusterl-cluster
l-clusterl-clusterLL33--clustercluster
1−lβ
3a
( ) ( ) ×
−
= −−
Vl ll 131
!1
1
λ
β
2 3
1
)2(
1
1 ≥
−
−= − l
l
l
a ll β )7(
)8(






=
=
∫∫
∫
∞ ∞
0 0
13
3
12
3
13126
3
3
2
3
1
3
23131262
2
1
2
1
rdrdffV
V
rdrdrdfff
V
λ
λ
β
∫∫
∞ ∞
−=
0 0
13
3
12
3
23131263
2
1
rdrdfff
V
a
λ
)2(
1
1 ≥
−
−= − l
l
l
a ll β
)7( .
23
3
2
β−=a (9)
9.49.4
))1010((
))1111((
1010
))1212((
))1313((
lb 1−lβ∞→V
{ }
∑ ∏ 





=
−
=lm
l
k k
k
l
m
l
l
b
1
1
2
!
)(1 β
{ }km
,...2,1,01
1
1
=−=∑
−
=
k
l
k
k mlkm
{ }
∏
∑
∑ −
+−
∑−=
−
−
l l
ll
l
m
m
l
m
lb
l
ml
l
l
k
!
)(
)!1(
)!2(
)1(
1/
1β
{ }lm
∑=
=−=−
l
l
ll mlml
2
,....2,1,01)1(
))11((
))22((
11 =a
2a
)(ru
)(ru
( )
( )∫
∞
−
−−=/−=
0
2/
322 .1
2
drreba KTru
λ
π






−= 612
)()(4)(
rr
ru
σσ
ε
))33((
))44((
3344
+∞=)(ru 0rr <
σ6
0 2=rε−
σ<rσ>>r
0r
6
00 )/()( rruru −=
334411
))55((
))66((
))77((
10
<<





KT
u
.exp1
2 0
0 0
2
6
02
32






























−+= ∫ ∫
∞r
o
drr
r
r
KT
u
drra
λ
π
.1
3
2~ 0
3
3
0
2 





−−
KT
ur
a
λ
π
∫
∞
−+=
0
2600
33
3
0
2 ))((
2
3
2
r
drr
r
r
kT
ur
a
λ
π
λ
π
xex
+≈1
...)()()(
3
21
1
3
1
++== −
∞
=
∑ v
aa
v
Ta
kT
pv l
l
l
λλ
))(1(
3
2
1
3
0
3
3
0
vkT
ur
kT
pv λ
λ
π
−+=
))88((
aabb
))99((
))1010((
))1111((
1
3
0
3
0
2
0
3
0
)
3
2
1()
3
2
1()
3
2
( −
−≈+=+
v
r
v
kT
v
r
v
kT
v
ur
p
πππ
0
30
3
0
0
3
0
4})
2
(
3
4
{4
3
2
3
2
v
rr
b
ur
a
=≡=
=
π
π
π
( ) ,~
2
KTbv
v
a
P −−





+
aabb
l>2l>2
))1616) () (1515((
))1717((


 +∞=
=
)(
0)(
ru
ru
0rr <
0rr > 

 −=
=
1)(
0)(
rf
rf
0rr <
0rr >
3
0
3
3
0
2 4
3
2
λ
ν
λ
π
==
r
a
( )
( )∫
∞
−
−−=/−=
0
2/
322 .1
2
drreba KTru
λ
π
∫ +=
0
0
2
3
0
2
r
drr
λ
π
9.2.59.2.5
))1818((
1122
33
))11(-(-
))1919((
33
012 rr <
13
r
13
r
23r12r0rr >
,
3
1
24
0 0
13
3
12
3
23131262
2
23 ∫∫
∞ ∞
−=−= rdrdfffbba
λ
{ } ,
3
1
12
3
0
13
3
63
0
12
rdrda
r
r
∫=
∫′=
λ
2
1
3
12r 13r
23r
0r
013 rr <023
rr <
1s2s0
r
( ){ }
( )[ ]
∫
−
−−=∫′
2
12
2
0 2/
0
12
2/122
013
3
.22
rr
dyyryrrd π
0ry
12r120 rr −
dy
120 rr −
1s2s
.
1919( )( )
))2020((
.
164
3
3
4 3
1212
2
03
013
3






+−=∫′
rrr
rrd
π
{ } ,
3
1
12
3
0
13
3
63
0
12
rdrda
r
r
∫=
∫′=
λ
.
8
5
18
5 2
26
6
0
2
3 a
r
a ==
λ
π
““BoltzmanBoltzman” -1899” -1899MajumdarMajumdar “-1929“-1929
Ree_ HooverRee_ Hoover “-1964“-1964
Ree –HooverRee –Hoover
3
2
3
2
1
4 28695.0
1120
4
2(tan1377273
2
3
8960
1283
aaa =










−+
+=
−
π
π
5
26
4
25
)004.00386.0(
)003.01103.0(
aa
aa
±=
±=
6
27 0127.0 aa =
))11((
))22((
11N
V NZ0Z0Q
1
3
1 QZ λ=V
∞→V
( ) ( ) ( ) .
!
,
,,, 3
0 0
N
N N
NN
N
z
N
TVZ
zTVQTVz 





=≡℘ ∑ ∑
∞
=
∞
= λ
),( TVQN
( ) ( )
N
N
N
N
TVZ
TVQ 3
!
,
,
λ
≡








+





+





+==℘≡ ∑
∞
=

2
3
2
1
3
1
3
0 !2!1
1ln
1
)(
!
),(
ln
1
ln
1
λλλ
zZzZ
V
Z
N
TVZ
VVKT
P N
N
N
(3)
(4)
∑
∞
=
∞→ =℘=
1
3
1
)ln
1
(lim
l
l
lV zb
VkT
p
λ
3:Z
{ } [ ]...})
!1
()
!2
(2{
!2
1
!1
1
...)
!2!1
1ln(
1 22
3
1
6
2
3
12
3
2
3
1
+−+=+++ z
ZZ
z
Z
V
z
Z
z
Z
V λλλλλ
...)(
11 2
213
1
3
++== ∑
∞
=
zbzbzb
l
l
l
λλ
))55((
))66((
))77((
))88((
l
z
1l >
i
iz V≡1l >
1 1a =
,1
1
11 ≡= Z
V
b
( ),
!2
1 2
1232 ZZ
V
b −=
λ
( )3
112363 23
!3
1
ZZZZ
V
b +−=
λ
( ).61234
!4
1 4
1
2
12
2
213494 ZZZZZZZ
V
b −++−=
λ
66889.1.169.1.16
l-clusterl-cluster
11
22
l cluster−
lb
lZ
lb
∞→V
V
lZ
×= −
Vl
TVb ll )1(3
!
1
),(
λ
RushbrookeRushbrooke
9.1.299.1.29( )( )
))1212((
))1313((
×= − )1(3
!
1
ll
l
b
λ
l
VlZ
( )
( )
.
!
1
,
1
3





















′
= ∏∑ =
N
L l
m
l
m
N
m
V
bTVQ
l
l
λ
{ }
∑∏= 





=
l
l
m
M
l l
m
lM
M
m
bV
MZ
1
3
3
!
)/(
!
λ
λ
,...2,1,0
1
==∑=
l
M
l
l mMlm
{ }lm
9.2.79.2.7
))1414((
))1515((
))1616((
151516161414
3
1
λ
∑
∞
=
∞→
=





≡
1
3
1
2
1
l
l
l
V
zbIn
V
Lim
KT
P
λ
,
1
1−
−
−= ll
l
l
a βla
1−lβ
∑
∞
=
∞→
=





∂
∂
≡
1
3
121
l
e
V
zbl
z
In
V
z
Lim
v

λ
KT
P
3
λ
z
0→z
0→z
KT
P
v
1
∫=
z
z
dz
zvKT
zp
0
)(
1)(
))1717((
1515
))1818((
))1919((
Z<<1Z<<1
1717191920201616
))2121((
v
nx
3
3 λ
λ ==
∑
∞
=
=
1
)(
l
l
l zblzx
{ })(exp)( xxxz ϕ−=
0→x
x
( ) ( )
.
1
1
11
1
3
0 1
33
0
3












+
−=












−=






′−=
∑
∫ ∑∫
∞
=
∞
=
k
k
k
x
k
k
k
x
x
k
kx
dxxkxdxx
x
KT
xP
β
λ
β
λ
ϕ
λλ
17172121
))2222((
))2323((
x(zx(z((
))2424((
))2525((
β
∑
∞
=






+
−=
1 1
1
k
k
k x
k
k
KT
Pv
β
( ).1
1
11 >
−
−= − l
l
l
a lβ
lb
( ) ( )xfxxz /=
( ) ( ){ }
0
1
1
1
!
=
−
−∞
=






= ∑
ξ
ξ
ξ
j
j
j
j
j
f
d
d
j
z
zx
)!1( −j
1−j
ξ
{ } j
f )(ξ0=ξ
))2626((
1818
))2727((
))2828((
∏
∞
=1
)exp(
k
k
kj ξβ
( ) ( ){ } ( ),expexpexp
11
∏∑
∞
=
∞
=
=






==
k
k
k
k
k
k xxxxf ββϕ
( ) ( ) ×−= ∑
∞
=
!1
!1
j
j
z
zx
j
j
0=ξ 1−j
ξ
∑
∞
=
=
1
)(
l
l
l zblzx
( )
( )
( )
∏
∏ ∑
−
=
∞
= ≥
−
∑′=
















×=
1
1
2
1 0
1
2
,
!
1
!
1
j
k k
m
k
m
k m
km
k
m
kj
j
m
j
j
m
j
inoftcoefficienthe
j
b
k
k
k
k
k
β
ξ
β
ξ
{ }km
1
1
1
−=∑
−
=
jkm
j
k
k ,..2,1,0=km
BethBethUhlenbeckUhlenbecku(ru(r((
9.4.99.4.9
))11((
( ),
!2
1 2
1232 ZZ
V
b −=
λ
( ).
2
1 2
12322 ZZ
V
ab −=−=
λ
))22((
00
))33((
9.4.29.4.2
))44((
)0(
11 ZVZ ≡≡
( ) ( ) ( ) ( )
( ),
2
1 20
1
0
23
0
2
0
2 ZZ
V
ab −=−=
λ
( ) ( )
( )0
223
0
22
2
1
ZZ
V
bb −=−
λ
( ) ( ).,!, 3
TVQNTVZ N
N
N λ≡
( ) ( )
( ) ( )
( ).
0
22
ˆˆ
3
0
22
3
0
22
HH
eeTr
V
QQ
V
bb ββλλ −−
−≡−=−
))55((
))66((
))77((
))88((
PP2m2m
( ) ( ),,,ˆ
21212 rrErrH ααα ψψ =
( ) ( ).
2
ˆ
12
2
2
2
1
2
2 ru
m
H +∇+∇−=

( ) ( ) ( ) ( )
( ),
1
,
/.
2/1
re
V
rRrR n
RPi
nj
j
ψψψψα






==

( )
.
22
2
n
j
m
P
E εα +=
ε
jjnnPP
))99((
))1010((
44
))1111((
m
2
1
ε
( ) ( ) ( ),
2
1
2
2
2
rrru
m
nnnr ψεψ =












+∇






−

( ) ,13
2
=∫ rdrnψ
∑
−
−
−
∑
−
=
∑
−
−
−
=−


















n
nene
j
mjP
e
V
n
E
e
E
e
V
bb
)0(4/23
)0(3
22
)0(
βεβεβλ
α
β
αβλ
α
))1212((
( )( )
3
2/1
8
λ
V
=
( )
3
2
3
2
1
2
0
4/
3
4/ )2(8
4~ 22
h
mkTV
dPPe
h
V
e mPmP
j
j π
πββ
=− ∫∑
∞
−−
mkT
h
π
λ
2
=
3
1
λ
1111
))1313((
))1414((
))1515((
)0(
nε
( ) ( )
{ }.8
0
2/10
22 ∑ −−
−=−
n
nn
eebb βεβε
( )
( ),/
2
1
2
222
0


pk
m
k
m
P
n ==






=ε
)()0(
kg
nε
( ),/
22


pk
m
k
n ==ε
1313
))1616((
))1717((
)(kg
( )
( ) ( )
( ){ }dkkgkgeebb
B
mkB 0
0
/2/12/10
22
22
88 −+=− ∑ ∫
∞
−− ββε
∑
)(rχ
),( ϕθY
( )
( )
( ).,, ϕθ
χ
ψ ml
kl
klmklm Y
r
r
Ar =
))1818((
rr
))1919((
))2020((
)()( rr ψψ =−
)()( rr ψψ −=−l
( ) ,00 =Rklχ
0R
( )rklχ
( ) ( ) ,
2
sin






+−∝ k
l
krr lkl η
π
χ
( ) ,2,1,0,
2
==+− nnk
l
kR lo πη
π
u(ru(r((kknnn+1n+1
))2121((
)(klη
l
)(kglk∆
( ) ,π
η
=∆






+ k
dk
kd
R l
o
ππη
π
η
π
nnk
l
kRkk
l
Rkk ll −+=






+−−






∆++−∆+ )1()(
2
)(
2
)( 00
π
ηη
=∆






∆
−∆+
+ k
k
kkk
R ll )()(
0
dk
kd l )(η
))2222((
kkmmkk
))2323((l
)12( +l
l)12( +l
{ }lll −− ),...,1(,
)(kg
( ) ( ) ( ) ( ) .12
1






∂
∂
++∑′=
′
∑=
k
k
Rlkgkg l
o
l
l
l
η
π
( ) ( ) ,
1212






∂
∂
+
+
=
∆
+
=
k
k
R
l
k
l
kg l
ol
η
π
=∆kkgl )(
))2424((
))2525((
1616( )(( )(
))2626((
u(ru(r((
∑ /
,...4,2,0=l
,...5,3,1=l
)(klη
( )
( ) ( ).120
+
′
∑= l
R
kg
l
o
π
( ) ( )
( ) ( ) ( ).12
10
k
k
lkgkg l
l ∂
∂
+
′
∑=−
η
π
( )
( ) ( )
( ){ }dkkgkgeebb
B
mkB 0
0
/2/12/10
22
22
88 −+=− ∑ ∫
∞
−− ββε
( )
( ) ( ) dk
k
k
elebb lmk
lB
B
∂
∂
+∑′+=− ∫∑
∞
−− η
π
ββε
0
/
2/1
2/10
22
22
12
8
8 
)(klη
))2727((
5.5.255.5.25( )(( )(
))2828((
)0(
22 bb −2b
)0(
2b
( ) ( )
2/5
0
2
0
2
2
1
±=−= ab
( ) ( ) ( )
( ) ( ) ( )






−≡−= 20
1
0
2
3
20
1
0
23
0
2
2
1
2
1
QQ
V
ZZ
V
b
λ
λ
)0(
2Q
( )
.
2
1
2
1
2
1
2
1
2/5
2
3
1
32/5
2
3
3
0
2 ±=














−














±





=
λλλ
λ VVV
V
b












±





=
V
V
TVQ
3
2/3
2
3
)0(
2
2
1
1
2
1
),(
λ
λ
9.1.189.1.185.5.285.5.28( )(( )(
))2929((
)]/2exp(1ln[ 32
3 λπ rkTu −±−=
( ) ( )
( )
.
2
12
1
2
2/5
0
2/2
3
2
0
/
3
0
2
22
±=±=
−=
∫
∫
∞
−
∞
−
drre
drreb
r
KTrus
λπ
λ
π
λ
π
)(ru
))3030((
))3131((
o
o
rrfor
rrforru
>=
<+∞=
0
)(
)(
)(
tan)( 1
ol
ol
l
krn
krj
k −
=η
)(klη
( )rχ0rr =
)(xjl)(xnl
))3232((
))3333((
))3434((
{ } 00
1
0 )tan(tan)( krkrk −=−= −
η
,....
cos3sin)3(
)(,
cossin
)(,
sin
)( 3
2
2210
x
xxxx
xj
x
xxx
xj
x
x
xj
−−
=
−
==
( ) ,...
sin3cos)3(
,
sincos
)(,
cos
)( 3
2
2210
x
xxxx
xn
x
xxx
xn
x
x
xn
+−
−=
+
−=−=
{ })(tan
)tan(1
)tan(
tan)( 0
1
0
00
001
1 krkr
krkr
krkr
k −−
−−=






+
−
−=η
....
5
)(
3
)( 5
0
3
0
−+=
krkr
[ ]
[ ] 





−
−−=






−+
−−
−= −−
2
0
01
02
000
2
0001
2
)(3
)(3
tan
)(3/)tan()(31
)(3/)(3)tan(
tan)(
kr
kr
kr
krkrkr
krkrkr
kη
...
45
)( 3
0
+−=
kr
11
22
2626
))3535((
l0)0( =lη
dkkkelbb l
k
l
)()12(
8
0
2
22/1
)0(
22
22
η
π
λ β
∫∑
∞
−
+
′
=− 
2,0=l1=l
)(....
3
10
2
5
0
21
0)0(
22 Bose
rr
bb −





−





−=−
λ
π
λ
)(....186
5
02
2
0
Fermi
rr
−





+





−=
λ
π
λ
π
))11((
( ).
2
ˆ 2
1
2
ij
ji
i
N
i
N ru
m
h
H
<=
∑+∇∑−=
))22((
11......NN
∑ −−
=≡
α
ββ αEH
N eeTrTVQ N
)(),(
ˆ
{ }∑ ∫
−
=
α
α
β
α ψψ
V
NH
rdNeN N 3ˆ*
),....,1(),....,1(
αψ
Nrr ...1
))33((
))44((
NW
∧
{ }∑ −
′′>≡′′<
α
α
β
α ψψλ ),...,1(),...,1(!,...,1ˆ,...,1 *ˆ3
NeNNNWN NHN
N
{ } αβ
α
αα ψψλ EN
eNNN −
∑ ′′= ),...,1(),...,1(! *3
NW
∧
),...,1( NWN
{ } αβ
α
αα ψψλ EN
N eNNNNW −
∑= ),...,1(),...,1(!),...,1( *3
22
))55((
9.1.39.1.39.4.29.4.2
))9.1.39.1.3((
))9.4.29.4.2((
)( NWTr
∧
)(
!
1
),...,1(
!
1
),( 3
3
3 NN
N
V
NNN WTr
N
rdNW
N
TVQ
λλ
== ∫
NZrdNW N
N
3
),...,1(
( ) ( ){ }NNN drrdrrrr ++ ,...,,,...... 111
( ) ( )3
3 3
1 1
, exp ,
! !
N
N ijN N N
i j
Q V T u d r Z V T
N N
β
λ λ<
 
= − = 
 
∑∫
( ) ( ).,!, 3
TVQNTVZ N
N
N λ≡
33
))66((
5.3.165.3.16
66
))77((
rr ,′
}∑


>=′< −−′
P
mprpirpi
ee
V
e
V
W 2//).(/).(3
1
2
11
11
1ˆ1 β
λ 
{ }mprrip
e
h
pVd
V
2//).(
3
33
2
11 βλ −−′
+∞
∞−
∫∫∫= 
22
11 /)( λπ rr
e −′−
=
∞→T0→λ
rr ′,
11 rr

−′
11ˆ1 1 >=< W
( ) ( ){ }
1
2
exp .kU r V i k r
−
=

55
))88((
ψ
),...,1( N
N
W
),...,1( N
3
3
31 1
1
),(
λλ
V
rdTVQ
V
== ∫
),...,1( NWN{ }αψ
AABBAABB
11λλ
22řř
))99((
AABB
1122AABB
Nrr ,....,1
)()(),...,( 1 BBAANN rWrWrrW ≈
ji rr ,
ijr
ijr
NWAW
BW
AB rr
ijr λ?
ijr r%?
))1010((
1111((
2=N
v
∞→12r
1)2()1()2,1( 112 ≡→ WWW
∞→12r
)2,1(2w
)2,1(2w
)2()1( 11 ww
)2()1( 11 ww)2,1(2U
( ) 02,12 →U
( ) ( ) ( ) ( )212,12,1 1122 WWWU −≡
))1212((
))1313((
))1414((
)2,1(2Uijf
lUˆ
>′>=<′< 1ˆ11ˆ1 11 UW
>′′<+>′><′>=<′′< 2,1ˆ2,12ˆ21ˆ12,1ˆ2,1 2112 UUUW
>′><′><′>=<′′′< 3ˆ32ˆ21ˆ13,2,1ˆ3,2,1 1113 UUUW
>′′><′<+ 3,2ˆ3,21ˆ1 21 UU
>′′><′<+ 3,1ˆ3,12ˆ2 21 UU
>′′><′<+ 2,1ˆ2,13ˆ3 21 UU
>′′′<+ 3,2,1ˆ3,2,1 3U
))1515((
))1616((
lUˆl
[ ][ ] 






′
= ∑∑ P fatorsmfactorsmm
N UUUU
l
NW ....)()....()().....( 2211
),...,1(
21
)(
∑{ }lm
,....2,1,0;
1
==∑=
l
N
l
l mNlm
1717((
))1818((
))1919((
∑p
{ }lm,1ˆ11ˆ1 11 WU ′=′
,2ˆ21ˆ12,1ˆ2,12,1ˆ2,1 1122 WWWU ′′−′′=′′
3,2,1ˆ3,2,13,2,1ˆ3,2,1 33 WU ′′′=′′′
3,2ˆ3,21ˆ1 21 WW ′′′−
3,1ˆ3,12ˆ2 21 WW ′′′−
2,1ˆ2,13ˆ3 21 WW ′′′−
1 1 1
ˆ ˆ ˆ2 1 1 2 2 3 3 ,W W W′ ′ ′+
11
))2020((
2218181919∑l
lm
( ) ( ) ,!11
1
−∑−
−∑
ll
m
mll
W
( )lUl ,....,1
NWˆ
( )l,.....1
12 ,,....., WWWl
))2121((
))2222((
1616--11--99
( )l,.....1
( ) rriflU ijl
~,0~,...,1 λ>>−
lb
( ) ( ) ( )∫−
= ;1,...,1
!
1
, 3
13
rdU
Vl
TVb l
lll
λ
lU
ijr
( ) ( )3 1
1
,
!
l l
b V T
l Vλ −
= × l cluster−
2121
551515
))55((
))1515((
( )TVbl ,
V∞→V
( )Tbl
( )lUl ,....,1
)(
!
1
),...,1(
!
1
),( 3
3
3 NN
N
V
NNN WTr
N
rdNW
N
TVQ
λλ
== ∫
[ ][ ] 






′
= ∑∑ P fatorsmfactorsmm
N UUUU
l
NW ....)()....()().....( 2211
),...,1(
21
)(
))2323((
))2424((
( ).!/1∏l
lm
( ) ( ) ( )
.
!
!
!2!1
!
21
∏
=
l
mmm l
l
NN

( )
( )
[ ][ ]






∑∑′= ∫ .........
!
1
, 2211
3
3
UUUUrd
N
TNQ p
m
N
NN
lλ
( )
( ) ( )
[ ]
{ }
[ ]
( )
[ ]
{ }
[ ]
( ){ }
1 2
1 2
3
1 1 2 23
1 2
3
1 23
1
3
3
1
1 !
, ... ... ...
! 1! 2! ... ! !...
1 !
...
! ! !
1 !
! ! !
l
l
l
l
l
l
N
N m mN
m
N lm
m m
mlN
m l l
N
ml
lmlN
m l l
N
Q V T d r U U U U
N m m
N
d r U U
N l m
N
d rU
N l m
ι
ι
ι
λ
λ
λ
=
=
=
∑
=
 
 =   
  
∑ ∫
∑ ∏ ∫
∑ ∏ ∫
))2525((
))2626((
lU
( )
( )
( )( ) 










∏∑′= −
=
!/
1
, 13
1
1
3 l
ml
N
lm
NN mVbTVQ
l
l
λ
λ
( )
;
!
1
31
1 





















∏∑′=
− l
mN
km m
V
b
l
l λ
( ) .333 Nlmml
l
lll
λλλ ==∏ ∑
( ) ( ) ( )∫−
= ;1,...,1
!
1
, 3
13
rdU
Vl
TVb l
lll
λ
( ) ,11
∏== ∑
l
mlllmN
zzz
( )
.
11
,exp
!
1
!
1
,,
1
3
1
3
1 0
3
0,, 1
3
1
21
∑
∏
∏ ∑
∑ ∏
∞
=
∞
=
∞
=
∞
=
∞
=
∞
=
=℘












=






















=






















=℘
l
l
l
l
l
l
l m l
m
l
l
mm l l
m
l
l
zbIn
V
V
zb
m
V
zb
m
V
zbTVz
l
l
λ
λ
λ
λ
( ) ( )∑
∞
=
=℘
0
,,,
N
N
N
TVQzTVz
l
l
l
V
zbLn
VKT
P
Lim ∑
∞
=∞→
=





℘=
1
3
11
λ
3
1
1 l
l
V l
N z Ln
lb z
V V zLim λ
∞
→∞ =
∂ ℘ 
= = ÷
∂ 
∑
25252525--11--99
))2727((
55--99
lb
.
111
1
3
1
3
l
l
l
l
l
l
zblandzb
KT
P ∞
=
∞
=
∑=∑=
λυλ
lUnW( )ln ≤
n( )ln ≤
lb2=l
1.71.71.81.8((
2727--55--99
lb
( ) ( ) ,1 2/510 −−
±= l
lb
2≥l
( )0
lb
YangYangleelee
U
U
lU
))9.6.19.6.1((
))9.6.29.6.2((
( )
2
2
1
1
ˆ .
2
N
N ij
i i j
h
H u r
m = <
= − ∑∇ + ∑
( ) ( ) ( ){ }ˆ* 31 1
, 1,..., 1,..., .
! !
i NE H N
N i i
i i
V
Q V T e N e N d r
N N
β β
ψ ψ− −
= ∑ = ∑ ∫
9.6.3a9.6.3a
9.6.4a9.6.4a
((9.6.5a9.6.5a))
NWˆ
( ) ( ){ }3 *ˆ1,..., 1,..., 1,..., 1,..., ,iEN
N i i
i
N W N N N e β
λ ψ ψ −
′ ′ ′ ′= ∑
( ) ( ) ( ){ }3 *
1,..., 1,..., 1,..., .iEN
N i i
i
W N N N e β
λ ψ ψ −
= ∑
( ) ( ) ( )∫ == .ˆ
!
1
,...,1
!
1
, 3
3
3 NN
N
NNN WTr
N
rdNW
N
TVQ
λλ
U
9.6.129.6.129.6.169.6.169.6.179.6.179.6.209.6.20
))9.6.279.6.27((
9.6.229.6.22aa))
WU
,
111
1
3
1
3
l
l
l
l
l
l
zblandzb
KT
P ∞
=
∞
=
∑=∑=
λυλ
( ) ( ) .ˆ1
!
1
131






=
∞→− l
vl
UTr
V
Lim
l
b
λ
9.6.39.6.3))9.6.3a9.6.3a((
))11((
))22((
S
( )EB.
A( )DF.
S
NW
A
NW
αψiψ
W
NWNPNWN N
P
S
N ,...,1ˆ,...,1,...,1ˆ,...,1 ′′′∑=′′
′
( )[ ]
,,...,1ˆ,...,11,..,1ˆ,...,1 NWNPNWN N
P
P
A
N ′′′−∑=′′ ′
′
p′!N1,...,rrN
′′
p′
[ ]p′
( ) ( ) ( ) ( )1,2,32,3,13,1,23,2,1 ′′′′′′′′′=′′′′ ororp
( ) ( ) ( ) ( )2,1,33,2,11,3,23,2,1 ′′′′′′′′′=′′′′ ororp
p′
p′
22((1111
))33((
))44((
))55((
( ){ },111ˆ1
22
11 /
1
/
1
λπ rrAS
eWW −′−
=′=′
,2,1ˆ1,22,1ˆ2,12,1ˆ2,1 22
/
2 WWW AS
′′±′′=′′
3,2,1ˆ3,1,23,2,1ˆ3,2,13,2,1ˆ3,2,1 33
/
3 WWW AS
′′′±′′′=′′′
3,2,1ˆ2,3,13,2,1ˆ1,3,2 33 WW ′′′±′′′+
.3,2,1ˆ1,2,33,2,1ˆ2,1,3 33 WW ′′′±′′′+
))9.6.129.6.12((
9.6.139.6.13((
9.6.149.6.14((
>′>=<′< 1ˆ11ˆ1 11 UW
>′′<+>′><′>=<′′< 2,1ˆ2,12ˆ21ˆ12,1ˆ2,1 2112 UUUW
>′><′><′>=<′′′< 3ˆ32ˆ21ˆ13,2,1ˆ3,2,1 1113 UUUW
>′′><′<+ 3,2ˆ3,21ˆ1 21 UU
>′′><′<+ 3,1ˆ3,12ˆ2 21 UU
>′′><′<+ 2,1ˆ2,13ˆ3 21 UU
>′′′<+ 3,2,1ˆ3,2,1 3U
9.6.179.6.17((
9.6.189.6.18((
9.6.199.6.19((
,1ˆ11ˆ1 11 WU ′=′
,2ˆ21ˆ12,1ˆ2,12,1ˆ2,1 1122 WWWU ′′−′′=′′
3,2,1ˆ3,2,13,2,1ˆ3,2,1 33 WU ′′′=′′′
3,2ˆ3,21ˆ1 21 WW ′′′−
3,1ˆ3,12ˆ2 21 WW ′′′−
2,1ˆ2,13ˆ3 21 WW ′′′−
,3ˆ32ˆ21ˆ12 121 WWW ′′′+




















−′−
=′=′
2/
2
121
1
ˆ11
1
ˆ1
λπ rr
eUA
S
U
( )[ ] 3,2,1
3
ˆ3,2,113,2,1/
3
ˆ3,2,1
,2
1
ˆ11
1
ˆ22,1
2
ˆ1,22,1
2
ˆ2,12,1
/
2
ˆ2,1
UPP
P
ASU
UUUU
AS
U
′′′′′
∑
′
±=′′′
′′±′′±′′=′′
,3
1
ˆ22
1
ˆ11
1
ˆ3
3
1
ˆ12
1
ˆ31
1
ˆ2
3,2
2
ˆ1,23,2
2
ˆ2,11
1
ˆ3
3,2
2
ˆ3,13,2
2
ˆ1,31
1
ˆ2
UUU
UUU
termsofsetssimilartwo
UUU
UUU
′′′+
′′′+
+
′′±′′′+
′′±′′′+












(6)
(7)
(8)
.....
))99((
))1010((
s
lUA
lU( )lnUn ≤
l( )1,2,...,lαm
α
,2,1,0,
1
==∑
=
α
α
αα ml
l
m
( )( ){ } ( )( ){ } ( ){ } ,
321
 
groupsm
ghi
groupsm
efcd
groupsm
ba
abc ,,....,
11
22
))1111((
( )[ ]
{ }[
{ }
{ } ],ˆ
ˆˆ
ˆˆ1
3
22
11



×′′′×
′′′′×
′′±∑′ ′
′
efUIHG
efUFEcdUDC
bUBaUA
P
P
1111
77
[ ],...,, CBA ′′′p′[ ]l′′′ ,..,2,1
[ ]p′
lUl A
S
l ,..,1ˆ,..,1 ′′
2=l( ){ }12 12 =m0=αm
( )( ){ }21
21 =m
l
0=αm
77..
( )1,2,..,l
6688
44
2211 11 UU

′′
11 rr =′
22 rr =′
2r 1r
3=l( ){ }123
( ){ } ( ){ }231
( ){ } ( ){ }132( ){ } ( ){ }123
))1212((
lUB
NW
lU
NNN TH Ω+= ˆ

NN T

Ωˆ
NW
( ) ,ˆexp3 



−=
N
HN
N
W βλβ
))1313((
))1414((
( )
( ),
1
,
1
2
2
2
exp3ˆexp30
∏
=
⋅
∏
=
∇=−=




























N
i
iw
N
i imN
TN
N
W
β
β
λβλβ

( ) .2
2
2
exp3,








∇≡⋅
im
iw
β
λβ
( )1;βW
11 1W

′
11 1U

′
( )
( )β0
NWN
( )βNW
NΩ

( ) ( )
( )ββ 0
NN WW →
0→ΩN

0→β
∞=Ω N
NΩ
( ) ( ) ( ) ( )
( ) ( ) ( )
+
′′Ω−′′−′Ω−′−∫ ′′∫ ′+
′Ω−′−∫+=






























′
















































ββββββ ββ β
ββββ βββ
0
ˆ
0
ˆ
0
00
0
ˆ
0
0
0
N
W
NN
W
NN
Wdd
N
W
NN
Wd
N
W
N
W
1515
))1616((
∞=Ω
∧
N
≡)(1 βW
1
1′
ββ =
0=β ≡ ),1;(βw
≡)(2 βW
1
1′
2
2′
+
1
1′
2
2′
+
1
1′
2
2′
β′
β ′′
β′
)1;(βw= )2;(βw )2;()1;()ˆ)(2;()1;({ 12
0
βββββββ
β
′′Ω−′−′−′+ ∫ wwwwd
)}2;()1;()ˆ)(2;(
)1;()ˆ)(2;()1;({
12
12
0 0
ββββ
ββββββββ
β β
′′′′Ω−′′−′
′′−′Ω−′−′−′′′+ ∫ ∫
′
www
wwwdd
....+
))1717((
))1818((
=)(3 βW
1
1′
2
2′
3
3′
+
1
1′
2
2′
3
3′
+
1
1′
2
2′
3
3′
+ +
1
1′
2
2′
3
3′
1
1′
2
2′
3
3′
....++ +
)1;(βw= )2;(βw )3;(βw
)3;()}]2;()1;()ˆ)(2;()1;({[ 12
0
ββββββββ
β
wwwwwd ′′Ω−′−′−′+ ∫
Two similar terms
Terms of higher order
1515
))1919((
1616181812121414
=NW βN
))2020((
))2121((
))2222((
=)(βlU
=)(2 βU
1
1′
2
2′
β′ +
1′
1 2
2′
β ′′ ....+
....++=)(3 βU + + ....+
lβ
17172121
))2323((
))2424((
))2525((
l
l
















∇








∇−−=
−=
2
2
2
2
1
2
2
6
)0(
222
2
exp
2
exp)ˆexp(
)()()(
m
h
m
h
H
WWU
ββ
βλ
βββ
)2,1;(βB
)
2
ˆexp(
12
ˆ6)(
212
ˆ)2,1;( HWB βλββ −Ω−=Ω−≡
)(2)2
2
2
1
(
2
2)(2)2,1;( β
β
β
β U
m
hU
B ∇+∇−
∂
∂
=
))2626((
00
)(2 βW
12
∧
Ω−
β
=Ω−≡ )(ˆ)2,1;( 212 ββ WB +
1
1′
2
2′
+
1
1′
2
2′
1
1′
2
2′
....+
=
1
1′
2
2′
2020
))2828((
00
))2929((
2525
β′
β′ β ′′
B
β
∫ ′′−′−′=
β
βββββββ
0
)}2,1;()2;()1;({)(2 BwwdU
)(2)2
2
2
1
(
2
2)(2)2,1;( β
β
β
β U
m
hU
B ∇+∇−
∂
∂
=
1
1′
2
2′
β′
2222
))3030((
1
1′
2
2′
3
3′
β′
β ′′
1
1′
2
2′
3
3′
β ′′
β′
, , ....etc
and
2′
1
1′
2 3
3′
, ....etc
.
(31)
.
2
)}1;()3,2;()2,1;(
0 0
)3;()2;()1;({
)}3;()2,1;()3,2;(
0 0
)3;()2;()1;()(3
Binordershigherofterms
Borderoftermsotherfour
wBB
wwWdd
wBB
wwwddU
+
+
′′×′′′′−′×
′
′′−′−′−′′′+
′′×′′′′−′×
∫ ∫
′
′−′−′′−′′′=
∫ ∫



ββββ
β β
ββββββββ
ββββ
β β
βββββββββ
3 ( )U β
:‫یییی‬ ‫ییییییی‬ ‫یییی‬ ‫یی‬ ‫یییی‬:‫یییی‬ ‫ییییییی‬ ‫یییی‬ ‫یی‬ ‫یییی‬
13.7.913.7.9.(.(
))11((
>′<>′><′>=<′′′< NWNWWN
N
WN
1
ˆ...2
1
ˆ21
1
ˆ1,...,2,1ˆ,...,2,1
1 NW W
∧ )
N
17.6.917.6.919.6.919.6.9
))22((
))44((
2
/2
1111 )({1ˆ11ˆ1 λπ rreWU −′=>′>=<′< −
0...ˆˆˆ
432 ==== UUU
)2,1;(βB
lb
otherwise
lforUTr
Vll
b
0
11)ˆ(
)1(!
1
131
=
==
−
=
λ
7.7.97.7.98.7.98.7.9
))55((
))66((
))77((
AS
lU
/∧
1>l
2 1 11,2 1,2 2 1 1 2 ,SIA
U U U′ ′ ′ ′= ±
) ) )
/
3 1 1 1 11,2 ,3 1,2,3 2 1 3 2 1 1 3S A
U U U U U′ ′ ′ ′ ′ ′ ′=
) ) ) ) )
1 1 13 1 1 2 2 3 ,U U U′ ′ ′+
) ) )
l
( )[ ]
/
1 11,..., 1,..., 1 1 2 ...
S A
p
l
p
l U l A U B U
∧ ∧ ∧′
′
 
′ ′ ′ ′= ±  
 
∑
))88((
))99((
6.6.96.6.9
))1010((
( ) ( ) rdlUlUUll l
V
l 3
111
1
1...2111!1 ∫ 





−±−=
∧∧∧
−
( ) ( )
l
l
UTrl 





±−=
∧
−
1
1
1!1
×−=
∧
)!1()( /
lUTr AS
l
,ˆ 2/
,
3
11
2
mp
pp epWppUp β
δλ −
′
∧
=′=′
pp ′,δ
( )
( )
1
/
1
3 1
1
( )
l
S A l
l l
b Tr U
l Vλ
−
∧
−
±
=
))1111((
111199
))1212((
28.6.928.6.9((
∫∑
∞
−−
∧
→=





0
22/
3
32/3
1
22 4
dppe
h
V
eUTr mpl
p
lmpll
l
ββ π
λλ
( )
1/ 5/ 2
1 /
lS A
lb l
−
= ±
:‫ییی‬ ‫ییی‬ ‫یییییییی‬:‫ییی‬ ‫ییی‬ ‫یییییییی‬
30.5.930.5.9
))1313((
9.5.79.5.79.5.89.5.81313
))1414((
0r
)(2 βW
( ) ( ){ }6 *
2
ˆ1 , 2 1, 2 1 ,2 1,2 E
a a
a
W e αβ
λ ψ ψ −
′ ′ ′ ′= ∑
( ) ( ) ( )2 22
. / 1 . / 2 /3 / 4 3/ 2
,
1 1
2p r P R m R Ri p m
p
e e e e
v v
λβ
λ
′− − −− 
− 
 
∑ h h
%
))1515((
))1616((
))1717((
( ) ( ){ } mk
ml
klmklm errdk /
, 0
* 22
3 hβ
λ −
∞
∑∫ Ψ′Ψ
)(
→
rklmψ
r
( ) ( )
( ) ,
2
,,
2/1
r
r
Yr kl
mlklm
χ
π
ϕθ





=Ψ
( ) ( ) ( ),,,
3*
kkrdrr mmllklmmlk −′=ΨΨ ′′′′′
∫ δδδ
))1818((
))1919((
1515
))2020((
( ) ( ),cos
4
12
,
1
, θ
π
ϕθ l
l
m
ml P
l
Y
+
=′′∑−−
( ) ( )rrrr ′′= /.cosθ
( ) ( ) ( ) ( ){ } .cos12
2 0
/*
2
3
22
∑ ∫ 





′+
′
∞
−
l
mk
klkll errdkPl
rr
hβ
χχθ
π
λ
14142020
2121
9.7.239.7.23
))2222((
( ){ }22
21212
32/1
2 2/exp
2
2,1ˆ2,1 λπ
π
λ
rrrr
rr
W −−′+′−
′
=′′
( ) ( ) ( ) ( ){ } .cos12
0
/* 22
∑ ∫ 





′+×
∞
−
l
mk
klkll errdkpl hβ
χχθ
( ) ( ){ } ( ) ( ){ }( )0**
rrrr klklklkl χχχχ ′−′
{ })()( *
rr klkl χχ ′
2U
2222
::
2
0






λ
r
)()0( sorl =
0, rrr >′
( ) ( ) ( ) ( ){ }krrkkrkrkrrk sinsinsinsin 00
′−−−′
( ) ( ){ }02coscos
2
1
krkrrkkrrk −+′−+′=
( ) ( ){ }krrk sinsin0 ′− ( ) ( ){ }.coscos
2
1
krrkkrrk −′−+′=
{ })()( rr klkl χχ ′
2121l0=l
( ){ } { }
2 2
1/2 3
2 2 /
2 1 2 1 22
0
2
1,2 1,2 exp / 2 ... k m
U r r r r dk e
rr
βλ
π λ
π
∞
−
′ ′ ′ ′= − + − −
′ ∫
h
)
( ){ }22
2121
2
2/exp
2
λπ
π
λ
rrrr
rr
−−′+′−
′
=
( ) } ( ){ }{
( ){ } ( ){ }
2 2 2
0
2 22 2
exp / 2 exp 2 2/ 2 ,
exp / 2 exp / 2
or r r r r r r r
r r r r otherwise
π λ π λ
π λ π λ
 ′ ′ ′− + − − + − 〉

×
′ ′− + − − −

))2525((
9.7.79.7.7
))2626((
2424
))2727((
.2,12,1
2
1
2
3
1
3
1
3
232 rdrdrdU
V
b
s
s
∫∫
∧
=
λ
s
b2
[ ] 1
3
2
3
221132 2,1ˆ1,22,1ˆ2,12ˆ11ˆ2
2
1
rdrdUUUU
V
bs
∫∫ ++=
λ
R r
{ }
22 200
2 2 2
0
2 ( )2 2
(0) 2 2
2 2 2 2
0
0
1 1 1
4 1 4
2
2
rr rr r
r
b b e e r dr e r dr
r r
r
ππ π
λ λ λ
π π
πλ
λ
∞ −
− − −    
− = − + −  ÷  ÷ ÷     
 
= −  ÷
 
∫ ∫
))2828((
9.7.299.7.299.7.319.7.31
))2929((
{ }{ }211
'
.... UUU∑
s
iUs
b2
( ) ( ){ } ,ˆˆˆ 21
121
nn
UUUTr
UhlenbeckBeth−
{ } { } { } { } { }' ' '
1 1 1 1 2 1 1 2 2... ... ... ...s
lU U U U U U U U U U= + + +∑ ∑ ∑
88
))3030((
( ) [ ]{ }[ ]∑ ∑〈
′′+′′− ii nn
nn
l
UjiUIJiiUJIUTrl
2
21
, 1221
ˆ,ˆ,,ˆ,ˆ!2
1n2n02 ≥n 01 ≥n221 −=+ lnn
)(
∧
s
lUTr
),.......,1( l′′)!2( −l
)(
∧
s
lUTr
ij
),.......,1( l
2
)1( −ll
))3131((
))3232((
))3333((
10109.109.10((((
3333
[ ]{ } ..ˆ2,1ˆ,2,1ˆ,ˆ!
2
1 21
1221
2,1 







′′+′′
′






∑ nn
nn
UUIJUJIUrTl
2 2
1
1, 1
/ 23
1 1 1
ˆ k m
k kk U k e β
λ δ −
′′ = h
( )
{ } ( ), 1 2
6
2
1 2 2 1 2 02 2 2
ˆ, , 0
2 i i
E E
k k k k
ro
k k U k k e e r
k k
β βλ
δ
π
′− −
+ +
′ ′ = − +
′−
))3434((
))3535((
313132323333
))3636((
33333535
2121
2
1
2
1
kkkkkk ′−′=′−=
( ) ( ).
22
2
2
2
1
2
2
2
2
1
2
kk
m
Ekk
m
E ′+′=′+=
hh
.ˆˆ
2,121,22,1221 kkUkkkkUkk +
))3737((
1 2 1 1
1,2 1,2
6 2
, 02 2 2
lim 0
E E
k k k k
k k
ro e e
r
k k
β β
λ
δ
π
′− −
′ ′+ +′ →
 −  
+   ÷−   
( ) ( )
( )1 2, 1 2
1,2 1,2
2 2 2 28
1 2 1 2 20
03 2 2
lim 0
4 k
E
k k k k
k
k k k kr e
r
k k
β
λ
δ
π →
−
′ ′+ +′
 ′ ′+ − + 
= + 
′−  
( )
8 2
2 2 20
1 2 03
exp ( )
2 2
r
k k o r
m
λ
β
π
 
= − − + + 
 
h
s
lb
))3838((
3838
))3939((
( )
3 3 3
1, 2 1 1 1 2 1 1 23 1
1 ˆlim ,..., , ,..., ...
!
s
llv
r r r U r r r d rd r d r
l Vλ −→∞ ∫
( )
3 3
2 1 1 2 1 23 1
1 ˆ0, ,..., 0, ,..., ...
!
s
ll
r r U r r d r d r
l λ −
= ∫
( )
( )
3 3
1 1 133 1
1
,..., ,..., ... ,
! 2
s
l l l ll
k k u k k d k d k
l λ π− ∫
s s
l lU U
)
( ) ( ) 6
2
3
1
32
2
2
,
2
1
16
0
5
2
1exp
2
1exp
32 21
h
pdpd
m
p
n
m
p
n
r
nn 





+−
′






+−−= ∫∫ ∑ ββ
π
λ
( ) ( ) 12/exp
1
12/exp
11
2
2
12
1
16
−− −−
mpzmpz ββh
( ) ( )
2
2/33
3
2
0
21
2
3
8
12/exp
41






=





−∫
∞
−
zg
mpz
dpp
λ
π
β
π
h
( ) ( ) ( )
( )






+−





−
′





 −






∫∫∑ +
−
2
2
2
1
22
1
2
1
,
3
3
0
8
313
2
exp
2
exp
2
!
2
1
8!
1
21
21
kk
mm
k
n
r
l
l nn
nn
l
hh β
βλ
π
λ
πλ
2
3
1
3
2
2
2
2
2
exp kdkd
m
k
n 





−×
h
β
40
( ){ }2
2/3
02
zg
r
λ
−
( ) ( ){ } ,
2
2
02
2/3
0
2/5
3






+−=≡∑ λλ
λ r
Ozg
r
zg
kT
p
zb
l
ls
l
41
42
Clustering model for complex fluids

More Related Content

What's hot (8)

Communication systems solution manual 5th edition
Communication systems solution manual 5th editionCommunication systems solution manual 5th edition
Communication systems solution manual 5th edition
 
Capitulo 5 Soluciones Purcell 9na Edicion
Capitulo 5 Soluciones Purcell 9na EdicionCapitulo 5 Soluciones Purcell 9na Edicion
Capitulo 5 Soluciones Purcell 9na Edicion
 
Clase 16 dsp
Clase 16 dspClase 16 dsp
Clase 16 dsp
 
Clase 15 dsp
Clase 15 dspClase 15 dsp
Clase 15 dsp
 
Capitulo 7 Soluciones Purcell 9na Edicion
Capitulo 7 Soluciones Purcell 9na EdicionCapitulo 7 Soluciones Purcell 9na Edicion
Capitulo 7 Soluciones Purcell 9na Edicion
 
Capitulo 4 Soluciones Purcell 9na Edicion
Capitulo 4 Soluciones Purcell 9na EdicionCapitulo 4 Soluciones Purcell 9na Edicion
Capitulo 4 Soluciones Purcell 9na Edicion
 
solucionario de purcell 2
solucionario de purcell 2solucionario de purcell 2
solucionario de purcell 2
 
Qhttnew
QhttnewQhttnew
Qhttnew
 

Similar to Clustering model for complex fluids

El text.life science6.matsubayashi191120
El text.life science6.matsubayashi191120El text.life science6.matsubayashi191120
El text.life science6.matsubayashi191120RCCSRENKEI
 
ゲーム理論 BASIC 演習81 -交換経済における交渉解2-
ゲーム理論 BASIC 演習81 -交換経済における交渉解2-ゲーム理論 BASIC 演習81 -交換経済における交渉解2-
ゲーム理論 BASIC 演習81 -交換経済における交渉解2-ssusere0a682
 
Magnet Design - Hollow Cylindrical Conductor
Magnet Design - Hollow Cylindrical ConductorMagnet Design - Hollow Cylindrical Conductor
Magnet Design - Hollow Cylindrical ConductorPei-Che Chang
 
13200836 solution-manual-process-dynamics-and-control-donald-r-coughanowr-130...
13200836 solution-manual-process-dynamics-and-control-donald-r-coughanowr-130...13200836 solution-manual-process-dynamics-and-control-donald-r-coughanowr-130...
13200836 solution-manual-process-dynamics-and-control-donald-r-coughanowr-130...nutkoon
 
Formulario cálculo
Formulario cálculoFormulario cálculo
Formulario cálculoMan50035
 
NITheP UKZN Seminar: Prof. Alexander Gorokhov (Samara State University, Russi...
NITheP UKZN Seminar: Prof. Alexander Gorokhov (Samara State University, Russi...NITheP UKZN Seminar: Prof. Alexander Gorokhov (Samara State University, Russi...
NITheP UKZN Seminar: Prof. Alexander Gorokhov (Samara State University, Russi...Rene Kotze
 
Calculo
CalculoCalculo
CalculoJu Lio
 
Formulario derivadas e integrales
Formulario derivadas e integralesFormulario derivadas e integrales
Formulario derivadas e integralesGeovanny Jiménez
 
ゲーム理論 BASIC 演習82 -交換経済における交渉解3-
ゲーム理論 BASIC 演習82 -交換経済における交渉解3-ゲーム理論 BASIC 演習82 -交換経済における交渉解3-
ゲーム理論 BASIC 演習82 -交換経済における交渉解3-ssusere0a682
 

Similar to Clustering model for complex fluids (20)

Sk7 ph
Sk7 phSk7 ph
Sk7 ph
 
Sk7 ph
Sk7 phSk7 ph
Sk7 ph
 
El text.life science6.matsubayashi191120
El text.life science6.matsubayashi191120El text.life science6.matsubayashi191120
El text.life science6.matsubayashi191120
 
ゲーム理論 BASIC 演習81 -交換経済における交渉解2-
ゲーム理論 BASIC 演習81 -交換経済における交渉解2-ゲーム理論 BASIC 演習81 -交換経済における交渉解2-
ゲーム理論 BASIC 演習81 -交換経済における交渉解2-
 
Magnet Design - Hollow Cylindrical Conductor
Magnet Design - Hollow Cylindrical ConductorMagnet Design - Hollow Cylindrical Conductor
Magnet Design - Hollow Cylindrical Conductor
 
13200836 solution-manual-process-dynamics-and-control-donald-r-coughanowr-130...
13200836 solution-manual-process-dynamics-and-control-donald-r-coughanowr-130...13200836 solution-manual-process-dynamics-and-control-donald-r-coughanowr-130...
13200836 solution-manual-process-dynamics-and-control-donald-r-coughanowr-130...
 
Formulario calculo
Formulario calculoFormulario calculo
Formulario calculo
 
Formulario cálculo
Formulario cálculoFormulario cálculo
Formulario cálculo
 
NITheP UKZN Seminar: Prof. Alexander Gorokhov (Samara State University, Russi...
NITheP UKZN Seminar: Prof. Alexander Gorokhov (Samara State University, Russi...NITheP UKZN Seminar: Prof. Alexander Gorokhov (Samara State University, Russi...
NITheP UKZN Seminar: Prof. Alexander Gorokhov (Samara State University, Russi...
 
Formulario
FormularioFormulario
Formulario
 
Formulario calculo
Formulario calculoFormulario calculo
Formulario calculo
 
Formulas de calculo
Formulas de calculoFormulas de calculo
Formulas de calculo
 
Calculo
CalculoCalculo
Calculo
 
Calculo
CalculoCalculo
Calculo
 
Tablas calculo
Tablas calculoTablas calculo
Tablas calculo
 
Formulario
FormularioFormulario
Formulario
 
Formulario derivadas e integrales
Formulario derivadas e integralesFormulario derivadas e integrales
Formulario derivadas e integrales
 
ゲーム理論 BASIC 演習82 -交換経済における交渉解3-
ゲーム理論 BASIC 演習82 -交換経済における交渉解3-ゲーム理論 BASIC 演習82 -交換経済における交渉解3-
ゲーム理論 BASIC 演習82 -交換経済における交渉解3-
 
Taller 1 parcial 3
Taller 1 parcial 3Taller 1 parcial 3
Taller 1 parcial 3
 
Laplace
LaplaceLaplace
Laplace
 

Recently uploaded

OSVC_Meta-Data based Simulation Automation to overcome Verification Challenge...
OSVC_Meta-Data based Simulation Automation to overcome Verification Challenge...OSVC_Meta-Data based Simulation Automation to overcome Verification Challenge...
OSVC_Meta-Data based Simulation Automation to overcome Verification Challenge...Soham Mondal
 
HARMONY IN THE HUMAN BEING - Unit-II UHV-2
HARMONY IN THE HUMAN BEING - Unit-II UHV-2HARMONY IN THE HUMAN BEING - Unit-II UHV-2
HARMONY IN THE HUMAN BEING - Unit-II UHV-2RajaP95
 
Gfe Mayur Vihar Call Girls Service WhatsApp -> 9999965857 Available 24x7 ^ De...
Gfe Mayur Vihar Call Girls Service WhatsApp -> 9999965857 Available 24x7 ^ De...Gfe Mayur Vihar Call Girls Service WhatsApp -> 9999965857 Available 24x7 ^ De...
Gfe Mayur Vihar Call Girls Service WhatsApp -> 9999965857 Available 24x7 ^ De...srsj9000
 
College Call Girls Nashik Nehal 7001305949 Independent Escort Service Nashik
College Call Girls Nashik Nehal 7001305949 Independent Escort Service NashikCollege Call Girls Nashik Nehal 7001305949 Independent Escort Service Nashik
College Call Girls Nashik Nehal 7001305949 Independent Escort Service NashikCall Girls in Nagpur High Profile
 
IVE Industry Focused Event - Defence Sector 2024
IVE Industry Focused Event - Defence Sector 2024IVE Industry Focused Event - Defence Sector 2024
IVE Industry Focused Event - Defence Sector 2024Mark Billinghurst
 
VICTOR MAESTRE RAMIREZ - Planetary Defender on NASA's Double Asteroid Redirec...
VICTOR MAESTRE RAMIREZ - Planetary Defender on NASA's Double Asteroid Redirec...VICTOR MAESTRE RAMIREZ - Planetary Defender on NASA's Double Asteroid Redirec...
VICTOR MAESTRE RAMIREZ - Planetary Defender on NASA's Double Asteroid Redirec...VICTOR MAESTRE RAMIREZ
 
Heart Disease Prediction using machine learning.pptx
Heart Disease Prediction using machine learning.pptxHeart Disease Prediction using machine learning.pptx
Heart Disease Prediction using machine learning.pptxPoojaBan
 
Model Call Girl in Narela Delhi reach out to us at 🔝8264348440🔝
Model Call Girl in Narela Delhi reach out to us at 🔝8264348440🔝Model Call Girl in Narela Delhi reach out to us at 🔝8264348440🔝
Model Call Girl in Narela Delhi reach out to us at 🔝8264348440🔝soniya singh
 
Decoding Kotlin - Your guide to solving the mysterious in Kotlin.pptx
Decoding Kotlin - Your guide to solving the mysterious in Kotlin.pptxDecoding Kotlin - Your guide to solving the mysterious in Kotlin.pptx
Decoding Kotlin - Your guide to solving the mysterious in Kotlin.pptxJoão Esperancinha
 
Past, Present and Future of Generative AI
Past, Present and Future of Generative AIPast, Present and Future of Generative AI
Past, Present and Future of Generative AIabhishek36461
 
power system scada applications and uses
power system scada applications and usespower system scada applications and uses
power system scada applications and usesDevarapalliHaritha
 
Artificial-Intelligence-in-Electronics (K).pptx
Artificial-Intelligence-in-Electronics (K).pptxArtificial-Intelligence-in-Electronics (K).pptx
Artificial-Intelligence-in-Electronics (K).pptxbritheesh05
 
Sachpazis Costas: Geotechnical Engineering: A student's Perspective Introduction
Sachpazis Costas: Geotechnical Engineering: A student's Perspective IntroductionSachpazis Costas: Geotechnical Engineering: A student's Perspective Introduction
Sachpazis Costas: Geotechnical Engineering: A student's Perspective IntroductionDr.Costas Sachpazis
 
Internship report on mechanical engineering
Internship report on mechanical engineeringInternship report on mechanical engineering
Internship report on mechanical engineeringmalavadedarshan25
 
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130Suhani Kapoor
 
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur EscortsHigh Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escortsranjana rawat
 
Current Transformer Drawing and GTP for MSETCL
Current Transformer Drawing and GTP for MSETCLCurrent Transformer Drawing and GTP for MSETCL
Current Transformer Drawing and GTP for MSETCLDeelipZope
 
Architect Hassan Khalil Portfolio for 2024
Architect Hassan Khalil Portfolio for 2024Architect Hassan Khalil Portfolio for 2024
Architect Hassan Khalil Portfolio for 2024hassan khalil
 

Recently uploaded (20)

OSVC_Meta-Data based Simulation Automation to overcome Verification Challenge...
OSVC_Meta-Data based Simulation Automation to overcome Verification Challenge...OSVC_Meta-Data based Simulation Automation to overcome Verification Challenge...
OSVC_Meta-Data based Simulation Automation to overcome Verification Challenge...
 
HARMONY IN THE HUMAN BEING - Unit-II UHV-2
HARMONY IN THE HUMAN BEING - Unit-II UHV-2HARMONY IN THE HUMAN BEING - Unit-II UHV-2
HARMONY IN THE HUMAN BEING - Unit-II UHV-2
 
Gfe Mayur Vihar Call Girls Service WhatsApp -> 9999965857 Available 24x7 ^ De...
Gfe Mayur Vihar Call Girls Service WhatsApp -> 9999965857 Available 24x7 ^ De...Gfe Mayur Vihar Call Girls Service WhatsApp -> 9999965857 Available 24x7 ^ De...
Gfe Mayur Vihar Call Girls Service WhatsApp -> 9999965857 Available 24x7 ^ De...
 
College Call Girls Nashik Nehal 7001305949 Independent Escort Service Nashik
College Call Girls Nashik Nehal 7001305949 Independent Escort Service NashikCollege Call Girls Nashik Nehal 7001305949 Independent Escort Service Nashik
College Call Girls Nashik Nehal 7001305949 Independent Escort Service Nashik
 
IVE Industry Focused Event - Defence Sector 2024
IVE Industry Focused Event - Defence Sector 2024IVE Industry Focused Event - Defence Sector 2024
IVE Industry Focused Event - Defence Sector 2024
 
VICTOR MAESTRE RAMIREZ - Planetary Defender on NASA's Double Asteroid Redirec...
VICTOR MAESTRE RAMIREZ - Planetary Defender on NASA's Double Asteroid Redirec...VICTOR MAESTRE RAMIREZ - Planetary Defender on NASA's Double Asteroid Redirec...
VICTOR MAESTRE RAMIREZ - Planetary Defender on NASA's Double Asteroid Redirec...
 
Heart Disease Prediction using machine learning.pptx
Heart Disease Prediction using machine learning.pptxHeart Disease Prediction using machine learning.pptx
Heart Disease Prediction using machine learning.pptx
 
Model Call Girl in Narela Delhi reach out to us at 🔝8264348440🔝
Model Call Girl in Narela Delhi reach out to us at 🔝8264348440🔝Model Call Girl in Narela Delhi reach out to us at 🔝8264348440🔝
Model Call Girl in Narela Delhi reach out to us at 🔝8264348440🔝
 
Decoding Kotlin - Your guide to solving the mysterious in Kotlin.pptx
Decoding Kotlin - Your guide to solving the mysterious in Kotlin.pptxDecoding Kotlin - Your guide to solving the mysterious in Kotlin.pptx
Decoding Kotlin - Your guide to solving the mysterious in Kotlin.pptx
 
Past, Present and Future of Generative AI
Past, Present and Future of Generative AIPast, Present and Future of Generative AI
Past, Present and Future of Generative AI
 
power system scada applications and uses
power system scada applications and usespower system scada applications and uses
power system scada applications and uses
 
Artificial-Intelligence-in-Electronics (K).pptx
Artificial-Intelligence-in-Electronics (K).pptxArtificial-Intelligence-in-Electronics (K).pptx
Artificial-Intelligence-in-Electronics (K).pptx
 
Sachpazis Costas: Geotechnical Engineering: A student's Perspective Introduction
Sachpazis Costas: Geotechnical Engineering: A student's Perspective IntroductionSachpazis Costas: Geotechnical Engineering: A student's Perspective Introduction
Sachpazis Costas: Geotechnical Engineering: A student's Perspective Introduction
 
🔝9953056974🔝!!-YOUNG call girls in Rajendra Nagar Escort rvice Shot 2000 nigh...
🔝9953056974🔝!!-YOUNG call girls in Rajendra Nagar Escort rvice Shot 2000 nigh...🔝9953056974🔝!!-YOUNG call girls in Rajendra Nagar Escort rvice Shot 2000 nigh...
🔝9953056974🔝!!-YOUNG call girls in Rajendra Nagar Escort rvice Shot 2000 nigh...
 
young call girls in Rajiv Chowk🔝 9953056974 🔝 Delhi escort Service
young call girls in Rajiv Chowk🔝 9953056974 🔝 Delhi escort Serviceyoung call girls in Rajiv Chowk🔝 9953056974 🔝 Delhi escort Service
young call girls in Rajiv Chowk🔝 9953056974 🔝 Delhi escort Service
 
Internship report on mechanical engineering
Internship report on mechanical engineeringInternship report on mechanical engineering
Internship report on mechanical engineering
 
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
VIP Call Girls Service Hitech City Hyderabad Call +91-8250192130
 
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur EscortsHigh Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
High Profile Call Girls Nagpur Isha Call 7001035870 Meet With Nagpur Escorts
 
Current Transformer Drawing and GTP for MSETCL
Current Transformer Drawing and GTP for MSETCLCurrent Transformer Drawing and GTP for MSETCL
Current Transformer Drawing and GTP for MSETCL
 
Architect Hassan Khalil Portfolio for 2024
Architect Hassan Khalil Portfolio for 2024Architect Hassan Khalil Portfolio for 2024
Architect Hassan Khalil Portfolio for 2024
 

Clustering model for complex fluids