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Properties of Lubricants
and
Lubrication
3/14/2014 1
Lubricant:
The substances which are used to decrease the force of friction
between the moving parts of machine in contact are known as
Lubricants and the process of decreasing the force of friction
between the moving parts of machine in contact is known as
Lubrication.
Composition of lubricating oils:
Lubricating oil fractions extracted from crude oil are a widely
varying mixture of straight and branched chain paraffinic,
napthenic aromatic hydrocarbons having boiling points ranging
from about 302o to 593oC. Some specialty lubricants may have
boiling point extremes of 177 and 815oC. The choice of grade of
lubricating oil base is determined by the expected use.
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FRICTION:
 When on surface of machinery moves over the another
surface, resistance to relative motion of the surfaces
arises. When we look at the solid surface it appears
smooth to naked eye , but this smooth surface shows
irregularities of projections and cavities when viewed
under high power microscope.
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4
When one such surface is placed over another, its
projections fall into the cavities of the other and get
interlocked .Due to this interlocking , there is
resistance to the relative motion of the surfaces.
This is called the frictional forces or frictional
resistance of friction. In due course of motion, the
old projections get broken and deformities arise.
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 So, FRICTION may be defined as the opposing force
that is set up between the surface of contact, when
one body moves over the surface of another body.
5
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EFFECT OF FRICTION:
The frictional forces oppose the relative motion between
the moving parts of a machine. Therefore extra energy
has to be spent to overcome the friction , which
increases expenses of energy .The friction between
the moving parts of machines also produces heat
which causes damage to the machinery. Thus friction
causes wear and tear of the moving parts of machinery
in contact and due to this cause, the machines lose
their efficiency and become useless.
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FUNCTIONS OF LUBRICANTS:
I. Lubricants avoid the damage of the moving parts of machines
by minimizing the production of heat.
II. Lubricants reduce the wear and tear of machinery by keeping
the moving parts of machines apart.
III. Lubricants reduce the maintenance and running cost of
machine.
IV. Lubricants act as the coolant because it reduces the
production of heat between the moving parts of machine in
contact.
V. Lubricants increases the efficiency of machine by reducing the
loss of energy.
VI. By using the lubricants, the relative motion of the moving parts
of machine becomes smooth and noise level of running
machine reduces.
VII. Lubricants also act as the corrosion preventers.
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VIII.Lubricants also act as a seal as in piston. Lubricant
used between piston and walls of the container (cylinder)
prevents the leakage of hot gases produced by the
internal combustion i.e.it act as seal.
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General capabilities expected from an engine lubricant:
- Dispersivity or capacity to disperse or suspend the deposits forming
contaminants
- Detergency or capacity to keep hot parts of an engine clean
- Thermal strength or capacity to withstand temperature changes
- Anti-oxidant or capacity to resist the action of oxygen
- Anti-wear or capacity to resist wear
- Anti-scuffing or capacity to preserve oil film even in the presence of high
pressures.
- Alkalinity reserve or capacity to neutralise acids formed during
combustion or other sources thereby preventing corrosive wear.
- Demulsibility or capacity to separate contaminants.
- Resistance to hydrolysis or capacity to withstand the action of water
which can affect additives Pumpability
- Centrifugibility and filterability or capacity to separate insoluble elements.
- Anti-rust, anti-corrosive and anti-foam are just some of the other
properties which protect the metalic object from wear down.
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NORMAL PROPERTIES REQUIRED ARE:
1. Adequate viscosity at working temperature so that the oil
spreads over the liner surface to provide a tough film which resists
the scrapper action of the piston rings.
2. The oil must provide an effective seal between the rings and
liner.
3. Only a soft deposit must be formed when the oil burns,
4.Alkalintiy level (total base number or TBN) must match the
acidity of the oil being burnt.
5. Detergent and dispersant properties are required in order to
hold deposits in suspension and thus keep surfaces clean.
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Classification of
Lubricants
Liquid
Lubricants
Eg.Mineral Oil,
Petroleum Oil,
Vegetable Oil etc
Semi Solid
Lubricants
Eg. Petroleum
jellies
Solid Lubricants
Eg. Graphite,
Molybdenum
Disulphide etc.
VISCOSITY:
• It’s a measure of a fluid’s resistance to flow.
• Viscosity of the lubricating oil determines its performance under
operating conditions.
• A low viscosity oil is thin and flows easily .
• A high viscosity oil is thick and flows slowly.
• As oil heats up it becomes less
viscous (Becomes thin)
• Too low viscosity of the liquid > Lubricant film cannot be maintained
between the moving surfaces > Excessive wear.
• Too high viscosity of the liquid > Excessive friction.
• Selected Lubricant must be proper viscous.
• Viscosity is usually expressed in centipoise or centistoke.
Viscosity Index :
• It is “Avg. decrease in viscosity of oil per degree rise in temp between
1000F & 2100F.”
• Viscosity of liquids decreases with increasing temperature.
• The rate at which viscosity of a lubricant changes with temperature is
measured by a scale called Viscosity Index.
• Silicones, polyglycol ethers, Diesters or triesters have high Viscosity Index.
Determination of Viscosity Index :
• First the viscosity of the oil under test is determined at 100°F & 210°F.
Let it be U and V respectively.
• Then viscosity of Pennsylvanian oil is determined. Let it be VH.
• Then viscosity of Gulf oil is determined. Let it be VL
viscosity Index = VL- U x 100
VL- VH
V.I. = 100 (Pennsylvanian oils.)
V.I. = Zero (Naphthanic-base gulf oils)
Higher the V.I, lesser is the variation of viscosity with change in
temperature.Thus, a good lubricating oil should possess high V.I.
Viscosity
Temp
100O 200
L
U
H
F
• Iodine number is the number of Gms equivalent of iodine to amount of ICl
absorbed by 100gm of oil.
• Each oil has its specific Iodine Number.
• So Iodine Number determines the extent of contamination of oil.
• Low Iodine Number is desirable in oils.
Some oils and their Iodine Numbers are given below :
Iodine Number Oil Example
>150 Drying oil Linseed oil, tung oil
100-150 Semidrying oil Castor oil , Soyabean oil
<100 Non-Drying oil Coconut oil, Olive oil
• Aniline point is the Min temp at which oil is miscible with equal amt of
aniline
• Aniline Point is a measure of aromatic content of the lubricating oil.
• Low Aniline Point oil have high aromatic content which attacks rubber
seals.
• Higher Aniline point means low %age of hydrocarbons (desirable).
• Thus Aniline Point is used as an indication of possible deterioration of
rubber sealing etc.
Determination of Aniline Point :
Aniline +
sample oil
(equal)
Heated in Test tube
Homogeneous
solution
Cooled
Cloudiness
The temperature at which separation of the two phases (Aniline + oil) takes place
is the Aniline Point.
• Emulsification is the property of lub oil to get mixed with water
easily.
• Emulsions can be oil in water emulsion or water in oil emulsion.
• A good lubricating oil should form such an emulsion with water
which breaks easily. This property is called demulsification.
• The time in seconds in which a given volume of oil and water
separates out in distinct layers is called steam demulsification
number.
• A good lubricating oil should have lower demulsification
number.
• Quicker the oil separates out from the emulsion formed, better
is the lubricating oil.
• In cutting oils the higher the emulsification number, better the
oil is. This is because the emulsion acts as a coolant as well as
a lubricant.
• Flash Point is the min temp at which the lubricant vaporizes that ignite
when a tiny flame is brought near.
• Fire Point is the Min temp at which the lubricant’s vapours burn constantly
for 5 seconds when tiny flame is brought near.
• Fire point = flashpoint+5°C to 400°C.
• Both should be higher than the max temp of country (for transportation)
• If flash point < 140°F = Flammable liquids
And if flash point > 140°F =Combustible liquids.
The flash and fire points are generally determined by
using Pensky-Marten’s apparatus.
•Oil under examination is filled in the oil cup up to the
mark and heated by the air bath by a burner.
•Stirrer is worked b/n tests at a rate of about 1 – 2
rev/sec.
•Heat is applied so as to raise the oil temp by about
5c/min.
•The temp at which distinct flash appeared in side the
oil cup is recorded as flashpoint.
•The heating is continued to record the fire point.
• Drop Point is the Temperature
at which grease passes from
the semi-solid to the liquid
state. So, it determines the
upper temp limit for the
applicability of grease.
Determination :
• Beaker is heated.
• Temperature is raised.
• Grease sample passes from a
semi-solid to a fluid state.
• Temp at which its first drop
falls from the opening is
recorded as drop-point.
• Cloud Point is the temp at which the lubricant becomes cloudy
or hazy when cooled.
• Pour Point is the temp at which the lubricant just ceases to flow
when cooled.
• Both indicates suitability of lubricant in cold conditions and thus
must be low.
• Pour point of wax can be lowered by dewaxing or adding
suitable pour point depressant.
• Pour point of an oil can be lowered by lowering the viscosity of
the oil which is achieved by removing the viscous constituent of
the oil.
• Lubricating oils used in capillary feed systems should have low
cloud points, otherwise impurities will clog the capillary.
• A high pour point leads to the solidification of the lubricant that
may cause jamming of the machine.
• Neutralization Point determines Acidity or Alkalinity of oil.
• Acidity/Acid value/Acid number is mgs of KOH required to
neutralize acid in 1 gm of oil.
• Alkalinity/Base value/Base number is mgs of acid required
to neutralize all bases in 1 gm oil.
• As Neutralization Point of oil increases, age of oil
decreases.
• It’s the mgs of KOH required to saponify 1 gm of oil.
• Saponification is hydrolysis of an Easter with KOH to give
alcohol and Na/K salt of acid.
• Mineral oils do not react with KOH and are not saponifiable.
• Vegetable and animal oils have very high saponification
values.
Significance
• Saponification value helps us to ascertain whether the oil
under reference is mineral or vegetable oil or a
compounded oil.
• Each oil has its specific Soaponification Number.
Deviation from it indicates the extent of adulteration of oil.
ADDITIVES
Improvements in lubricating oil over the last twenty
years have come about almost entirely from the use
of additives.
These are added for three main reasons;
1.to protect the lubricant in service by limiting the
chemical change and deterioration
2.To protect the mechanism from harmful
combustion products and malfunctioning
lubricating oil
3.To improve existing physical properties and to
create new beneficial characteristics in the oil
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Typical additives are:
Barium, calcium, phosphorus, Sulphur, chlorine, zinc, oxidation
inhibitor-increases oil and machinery life, decreases sludge and
varnish on metal parts.
Corrosion inhibitor- protects against chemical attack of alloy
bearings and metal surfaces.
Antiwear improvers- protects rubbing surfaces operating with this
film boundary lubrication. One such antiwear ( and oxidation
inhibitor) chemical is Zinc dithiophosphate or ZDDP
Detergent- tend to neutralise the deposits before formation under
high temperature and pressure conditions, or as a result of using a
fuel with high sulphur content.
Dispersant- used to disperse or suspend the deposits forming
contaminants. Typical dispersants, such as polyesters and
benzlamides, are usually clean burning. The molecules have a
polar charge at one end which attracts and holds the deposits
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Alkaline agents- neutralizes acids, these form the TBN of the oil
and includes additives such as the above dispersants and
detergents. An excess of acid neutralizing alkalis are present in the
oil and these help to keep parts clean. Failure to keep an oil
alkaline can lead to damage to bearings due to acidic attack as
well as increased liner wear.
Rust inhibitors- protect to form the oxidation of metal component.
Pour point depressants- improves low temperature viscosity
Oiliness agent- reduces friction seizure point and wear rates
EP additives- increases film strength and load carrying capability
Antifoam agents- prevents stable bubble formation
Metal deactivators- prevent catalytic effects of metal
Antiseptic- bactericide.
Polymer Agents / Viscosity Improver - an additive that improves
the viscosity index of the oil. I.e. reduces the effect of temerpature
of the oil.
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LUB OIL ANALYSIS:
 Regular testing of crankcase lub oil is important to ensure that
deterioration has not taken place. The results of in service deterioration
could be a reduction in engine protection or actual attack on working
points by corrosive deposits. Oil samples are generally tested every 3 to
4 months depending on the system and experience. Shipboard testing is
taking a rising prominence to allow monitoring of oil condition between
testing.
 To ensure good representation, care should be taken where the sample
is drawn
 Correct
 Main supply line
 inlet or outlet from lub oil cooler
 Outlet from main lub oil pump
 Incorrect
 standpipes
 purifier outlet
 purifier direct sump suction
 Samples should be drawn over a period of several minutes
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Viscosity
 The viscosity is the most important property of the oil. Oil
of correct viscosity will provide optimum film strength with
minimum friction losses and leakage.
 The viscosity of a L.O. may fall due to fuel dilution if
running on gas oil, and rise if running on heavy f.o.
Viscosity may also increase due to heavy soot loading if
purifiers and filters not operating efficiently. Oil ageing
caused by oxidation and thermal degradation increases
viscosity.
 A simple shipboard test is the Mobil flow stick where
drops of new and used oil are placed in separate
channels on an inclined 'stick'. The rate the oil flows
down the stick is proportional to its viscosity.
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Water content
 Initially determined by 'crackle' test. The
presence of Na and Mg in a 4:1 ratio indicates
salt water contamination.
 Limits are laid down by the manufacturer, but as
a rule of thumb a limit of 0.2% should cause
investigation into source and remedial action at
0.5%
 Gross contamination can be remedied by placing
the charge in a separate tank and heating to
70oC and circulating through purifier.
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Spectrometry
 Indicates the presence of metal element composition and
identifies additive and contaminant levels.
 Zinc(Zn),Phosphorus(P)- are components of many oils
such as diesel engine oils, hydraulic oils and gear oils, to
enhance antiwear and over properties of the oil
 Calcium(Ca)- primarily a component of engine oils,
provides detergency,alkalinity and resistance to
oxidation. Residual fuel engine oils have higher Ca levels
 Nickel(Ni)- Bearings, Valves, gear plating, fuel derivative
 Barium(Ba)- Multi purpose additive, declining importance
 Magnessium(Mg)- as for Ca, may also be due to sea
water contamination if found in Ratio of 1:4 of Na
 Chromium(Cr)- Piston rings, hydraulic actuator cylinders
 Manganese(Mn)- Cylinder wear
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 Aluminium(Al)- generally comes from wearing piston skirts,
levels rise where new piston fitted to old engine. Typically
10ppm, but rises during bedding in. May also indicate the
presence of catylytic fines in residual fuels.
 Iron(Fe), Molybdenum(Mo), Chromium(Cr)- metals alloyed
for piston ring etc, a rise in level may indicate ring pack/liner
wear.
 Copper(Cu), Lead(Pb) , Tin(Sn), Silver(Ag) - soft metals
used in the overlay of shell bearings, and phosphor bronze
gears.Note that high copper content can also occur when
samples are drawn from copper pipes which have not been
flushed as well as gear wear.
 Silicon(Si)- Indicates poor air filtration, possible fuel derivative
 Sulphur(S)- May indicate the presence of clay based
(bentonite) greases
 Sodium(Na)- With Mg indicates the presence of sea water
contamination, possible coolant system and fuel derivative
 Vanadium(V)- Usually indicates the presence of fuel oil
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Alkalinity and acidity
 TBN-TOTAL BASE NUMBER- measure of alkaline additives available
for the neutralisation of acids from combustion products and oxidation.
Level governed by type of fuel.
 For crosshead engines the TBN will tend to rise due to contamination
by liner lubrication, it should not be allowed to raise more than twice
that of the new charge.
 As a guide, the TBN of fresh oil should be at least:
 10 x fuel sulphur content (%) for trunk piston engines
(10mgKOH/g)
 20 x fuel sulphur content (%) for cyl oil in x-head engines
(20mgKOH/g)
 A simple shipboard go,no-go test is available for measuring the TBN, it
involves the addition of an indicator and acid reagent to a 30ml
sample. The quantify of acid reagent added is determined by the
required level of TBN, for TBN2.5 0.5ml are added, for TBN20 4ml is
added. After three minutes the colour is checked against a chart
 Purple:Good level of TBN
 Green:Borderline
 Yellow:Low level of TBN
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 TAN-TOTAL ACID NUMBER-measure of organic acid and strong
acid content of oil. Where SAN is nil, the TAN represents the acidity
in the oil due to both the acids in the additives and the oxidation of
the hydrocarbons in the oil. The TAN of fresh oils varies with oil type,
and tends to climb with age. A high TAN may indicate that an oil
should be changed or freshened by top up. A high TAN may be
accompanied with increased viscosity.
 SAN-STRONG ACID NUMBER-indicates the presence of strong,
highly corrosive (inorganic) acids, usually formed from combustion
products. If SAN is not zero the oil should be changed immediately
 Oil cleanliness
 IC-INDEX OF COMBUSTION-measures soot loading of oil
 MD-MERIT OF DISPERSANCY-Ability of an oil to disperse
contaminants, such as soot, wear debris and water and thereby carry
them away from the critical areas. Measured by oil blot test and
should not be allowed to fall below 50
 DP-DEMERIT POINTS- combination of IC and MD: the lower the
value, the healthier is the condition of the oil
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Shipboard water content test
1. The flask is filled to mark 'A' with kerosene
2. A capsule of reagent (calcium hydride) is added.
Any water in the kerosene will react with the
calcium hydride and any gas vented off.
3. he container is topped to mark 'B' with sample oil
4. The screw valve and cap are closed.
5. The flask is inverted and shaken
6. After 2 minutes the screw valve is opened. The
hydrogen produced by the reaction between the
reagent and water exerts a pressure which forces
the kerosene through the open valve into the
graduated cylinder. The amount discharged is
proportional to the water content in the oil sample.
7. If the water content is greater than 1.5% then the
test should be repeated this time using a smaller
sample by filling only to mark 'C'.The second scale
on the graduated cylinder should then be used.
8. If water is detected its type, sea or fresh , should
then be determined by use of a special reagent the
water
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Types of Lubrication
Considering the nature of motion between moving or
sliding surfaces, there are different types of mechanisms
by which the lubrication is done. They are:
1. Hydrodynamic lubrication or thick film lubrication
2. Hydrostatic lubrication
3. Boundary lubrication or thin film lubrication
4. Extreme pressure lubrication
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1. Hydrodynamic Lubrication or Thick Film Lubrication
Hydrodynamic lubrication is said to exist when the
moving surfaces are separated by the pressure of a
continuous unbroken film or layer of lubrication. In this
type of lubrication, the load is taken completely by the oil
film.
The basis of hydrodynamic lubrication is the formation of
an oil wedge. When the journal rotates, it creates an oil
taper or wedge between the two surfaces, and the
pressure build up with the oil film supports the load.
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Hydrodynamic lubrication depends on:
relative speed between the surfaces,
- oil viscosity,
- load, and
clearance between the moving or sliding surfaces.
In hydrodynamic lubrication the lube oil film thickness is greater
than outlet, pressure at the inlet increases quickly, remains fairly
steady having a maximum value a little to the outside of the
bearing center line, and then decreases quickly to zero at the
outlet.
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Application of hydrodynamic lubrication
Delicate instruments.
Scientific instruments.
Large plain bearings like pedestal bearings, main bearing of diesel
engines.
Fig: Hydrodynamic Lubrication
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Hydrodynamic Lubrication
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Elastohydrodynamic,
This is the type of lubrication used with rolling
element bearings. To clarify, the material of the
running surface deforms under high pressure as the
rolling element passes over it. The oil wedge forms
in this deformation.
(i) Deformation and increased viscosity with
pressure are involved
(ii) Frictional coefficient = 0.05
(iii) film thickness less than Hydrodynamic
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2. Hydrostatic Lubrication:
Hydrostatic lubrication is essentially a form of hydrodynamic
lubrication in which the metal surfaces are separated by a
complete film of oil, but instead of being self-generated, the
separating pressure is supplied by an external oil pump.
Hydrostatic lubrication depends on the inlet pressure of lube oil
and clearance between the metal surfaces, whereas
hydrodynamic lubrication it depends on the relative speed
between the surfaces, oil viscosity, load on the surfaces, and
clearance between the moving surfaces.
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Example: the cross head pin bearing or gudgeon pin bearing
in two stroke engines employs this hydrostatic lubrication
mechanism. In the cross head bearing, the load is very high
and the motion is not continuous as the bearing oscillation is
fairly short. Thus hydrodynamic lubrication cannot be
achieved. Under such conditions, hydrostatic lubrication offers
the advantage.
Hydrostatic Lubrication
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3. Boundary Lubrication or Thin Film Lubrication
Boundary lubrication exists when the operating condition are
such that it is not possible to establish a full fluid condition,
particularly at low relative speeds between the moving or
sliding surfaces.
The oil film thickness may be reduced to such a degree
that metal to metal contact occurs between the moving
urfaces. The oil film thickness is so small that oiliness
becomes predominant for boundary lubrication.
Boundary lubrication happens when,
A shaft starts moving from rest.
The speed is very low.
The load is very high.
Viscosity of the lubricant is too low.
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Examples for boundary lubrication:
Guide and guide shoe in two stroke engine.
Lubrication of the journal bearing in diesel engines (mainly during
starting and stopping of engine).
Piston rings and when cylinder liner is at TDC and BDC position
when the piston direction changes and if the relative speed is very
slow.
Boundary Lubrication
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 A thin lubricant should have high viscosity index,
good resistance to heat and oxidation, good
oiliness and low pour point.
44
Velocity
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4. Extreme Pressure Lubrication
When the moving or sliding surfaces are under very high pressure
and speed, a high local temperature is attained. Under such
condition, liquid lubricant fails to stick to the moving parts and may
decompose and even vaporize. To meet this extreme pressure
condition, special additives are added to the minerals oils. These are
called “extreme pressure lubrication.” These additives form on the
metal surfaces more durable films capable of withstanding high loads
and high temperature. Additives are organic compounds like chlorine
(as in chlorinated esters), sulphur (as in sulphurized oils), and
phosphorus (as in tricresyl phosphate).
The Extreme pressure Additives are the organic compounds
possessing the active radicals or groups such as chlorine, sulphur ,
phosphorus etc. These compounds react with metallic surfaces at
high temperature to form metallic chlorides.
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Extreme Pressure Lubrication
 sulphides or phosphides which can form surface layers
on the moving or sliding metallic surfaces and act as
good lubricants.
46
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Stresses on Lube oil
The main stresses experienced by Lube oils in diesel engines operating
on heavy fuel oils are expressed as follows
Acid Stress- Caused by sulphuric and oxidation acids. This leads to
increased corrosive wear, deposits, reduced Base Number and shorter oil
life.Rapid depletion of the BN is the clearest sign of oil stress
Thermal/Oxidative stress-This caused by elevated temperatures leading
to increased rates of thermal/oxidative breakdown of lubricant and fuel.
This leads to increased levels of deposits, sludges, corrosive wear of
bearing material, oil thickening and reduced oil life. In addition deposits
on the under crown side of the piston can lead to increased hot corosion
on the piston.
Asphaltene Stress-This caused by fuel contamination of the lube oil and
can lead to increased levels of deposits, sludges, lacquers, oil thickening
and reduced oil life. In addition deposits on the under crown side of the
piston can lead to increased hot corosion on the piston
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Various Factors of Lubricating Oil:
OXIDATION
- Oxidation degrades the lube oil producing sludges, varnishes and
resins. Presence of moisture, and some metals particularly copper
tend to act as a catalyst. Once oxidation starts, deterioration of the
properties of the oil is rapid.
- Oxidation reduces its effectiveness as a lubricant. Oxidation will
also cause deposits which can block passage ways and coat working
parts. The rate of oxidation will depend upon temperature, the
higher the temperature the more rapid the rate. Anti oxidants are
available which reduce the rate, also additional properties can be
achieved by the use of additives.
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-- Most of the chemicals found in an oil will react more or less with
oxygen, The effects of this oxidation is always undesirable. Hence, a
major objective of the refining process of a mineral oil is to remove
those hydrocarbons i.e. the aromatics, the small amount of
unsaturates together with molecules containing sulphur, oxygen and
nitrogen.
- The use of anti-oxidants make a slightly better balance although
there usefulness is limited.
- Tin based white metal is susceptible to hardening as an oxide layers
from on the surface. These tin oxides are a grey-black in appearance
and are extremely hard. There formation reduces the bearing
clearance as the oxide layer is thicker than the original white metal
material from which it formed. The oxide has a lower coefficient of
friction than the original white metal but it will cause problems if it
brakes up as fragments will become embedded edge on in the white
metal and can score the pin. .
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Emulsification
- This occurs due to water contamination; also, contamination with
grease, fatty oils, varnish, paint and rust preventers containing fatty
products can also promote emulsification.
- The presence of an emulsion can be detected by a general
cloudiness of the sample. Salt water emulsifies very easily and
should be avoided.
- Water entrained in the oil supplied to a journal bearing can lead
to loss of oil wedge, rub and failure.
Fresh water contamination whilst not in itself dangerous can lead
to rusting. The iron oxides catalyses the oil to form sludge's. The
additives in the oil can leach out to change the water into an
electrolyte.
- Salt water contamination is very serious as it causes tin oxide
corrosion, and also leads to electrochemical attack on the tin
matrix in the white metal. The sea water act as then electrolyte.
A major problem of water within a lub oil is where the mix enters a
bearing, here it is possible for the water to be adiabatically heated
causing it to flash off collapsing the oil wedge.
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THERMAL DEGRADATION:
Under high temperatures an oil is liable to thermal degradation
which causes discoloration and changes the viscosity. Additives
cannot change an oils susceptibility to this degradation.
RECHARGING
When recharging no more than 10 % of the working charge should
be topped up due to heavy sludgeing that can occur due to the
heavy precipitation of the sludge.
EP ADDITIVE OILS
Can assist in healing of damaged gear surfaces but should be used
as a temporary measure only due to risk of side effects.
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Contamination of Lube oil in Diesel Engine:
Water
Water from,
1.bilge's
2.Jackets
3.Sea via coolers
4.leaky seals or washing in purifiers
5.Condensation
Problems caused by water contamination,
Water leads to corrosion especially if there is sulphur
present due to fuel contamination
forms emulsions which are not capable of withstanding
high loads
removes water soluble additives when centrifuged out
leads to possible bacterial attack
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Fuel
May be heavy residual or light diesel/gas oil and can be sourced to
faulty to cylinder combustion or faulty seals on fuel p/ps.
Problems
- Increases viscosity for hfo, reduces viscosity for D.O.
- Reduces flashpoint
- Introduces impurities such as sulphur
- Dilutes lub oil when in large quantities.
Solid impurities
carbon from the cylinder combustion process, particularly of
importance with trunk piston engines but also for crosshead engines
with inefficient diaphragm. The carbon can lead to restrictions and
blockages of oil ways causing bearing failure. Straight mineral oils
hold 1% carbon in suspension, dispersant oils hold about 5%.
3/14/2014 53
Bacterial attack:
Certain bacteria will attack oil but water must be present. The
bacteria may exist in a dormant state in the oil but water is
required if they are to reproduce.. The bacteria digest the oil
causing breakdown emulsions to be formed, acidity
increases, dead bacteria block filters and corrosive films form
on working surfaces.
In summary their must be three essential conditions for
microbiological growth;
1. There must be a source of carbon- present in the oil
2. There must be some bacteria or fungal spores present-
these are almost universally present in the atmosphere.
3. There must be free water present.
3/14/2014 54
Two other factors which encourage the growth of bacteria:
1. A slight acidity in the water (pH 5 or 6) and
2. A slightly raised temperature (20 to 40oC) which can lead to
rapid growth.
Biocide additives are available but they are not always compatible
with other desired additives and can lead to large organic
blockages if treated in the machinery. The best solution is to avoid
the presence of water. If mild attack takes place the oil may be
heated in the renovating tank to above 90oC for 24hrs before being
returned to the sump via the centrifugal separator. For a severe
attack the only solution is complete replacement of the charge
followed by sterilization of the system. It may be noted that on
replenishment the bacteria may be present in a dormant state in
the new charge.
3/14/2014 55
56
LUBRICATION FEATURES OF A LARGE DIESEL ENGINE
• In some engines such as long and super long stroke engines, the
piston is not directly connected to the crank pin via a connecting
rod.
• The piston has a piston rod extending from the bottom of the
piston.
• The piston rod is then connected to the connecting rod at the
crosshead bearing.
• The crosshead bearing has a to and fro motion and therefore a
continuous hydrodynamic film cannot form.
• Therefore oil has to be pumped to the crosshead bearing at a
predetermined pressure in order to take the loads of compression
and combustion.
• The crosshead is connected to the crank pin via a connecting rod.
3/14/2014
57
Piston
Piston rod
Crank pin, bottom end
bearing (rotatory motion)
Journal, journal bearing
(rotatory motion)
Crosshead, crosshead
bearing (reciprocating)
Connecting rod
Piston rings
Oil pumped at
a certain
pressure
Web
Piston skirt
Stuffing box
Platform separating cylinder
from crank case
3/14/2014
Problems caused by stuffing box leakage oil entering
crankcase:
Low speed engines are particularly at risk from crankcase
lubricant contamination caused by cylinder oil drainage past the
piston rod gland and combustion products. This can lead to
severe damage of engine crankcase components and reduction
of life of oil which is normally expected to last the lifetime.
There has been a general increase in the viscosity and Base
number of crankcase oils over recent years particularly for
engines built since the early 1980's. Increased alkalinity, viscosity
and insolubles, fuel derived elements such as vanadium and oil
additive derived elements such as calcium, suggest that the
contamination is from the cylinder oil drainage.
Deterioration of the crankcase oil has led to the expensive
necessity of replacing up to 50% of the sump, this is particularly
of concern as it is often only a temporary measure.
3/14/2014 58
Four causes are put forward:
1. New crankcase oil contaminated with new cylinder oil-unlikely
2. Cylinder oil drainings being recycled and returned to the sump-very
likely as it is a common practice to purify oil leaking through the gland,
tests done on this purified oil found high amounts of insolubles.
3. Leakage past rod gland- very likely, high pressure scavenge air can
blow cylinder oil and dirt past the top scrapper ring and sealing rings
into the piston rod drain tank, and even possibly directly into the sump.
A problem that worsens with age and wear.
4. Leakage of exhaust valve lubrication system-unlikely
The most likely cause for contamination is leakage past the
piston rod. It is seen that maintenance of the stuffing box is of the
utmost importance. Tell tales and drainage lines should be proved free
and use of oil drained from the uppermost drain should not be allowed
even after purification due to the high level of contamination which can
destroy the properties of the oil in the sump.
3/14/2014 59
60
Cylinder liner lubrication
 The type of Cyl. Lub oil required will depend upon the cylinder
conditions and the engine design e.g crosshead or trunk piston.
However, the property requirements are basically the same but will
vary in degree depending upon the fuel and operating conditions.
 In some engines, lubricating oil in the cylinder is different from the oil
supplied to the other bearings.
 The cylinder oil contains additives to withstand the high temperatures
and contaminants from combustion products.
 The oil is slightly basic in nature to counter the acids formed from
combustion.
 Scraper rings spread the oil over the liner surface.
 Lub. oil is usually injected between the two scraper rings.
 Oil is injected at a predetermined period during the downward stroke.
 Before starting, oil is pumped into the liner by manual priming
methods.
 After starting, the oil pump is driven by the engine through a cam
shaft.
3/14/2014
CYLINDER LUB OIL PROPERTIES
 Normal properties required are:
1. adequate viscosity at working temperature so that the oil
spreads over the liner surface to provide a tough film which
resists the scraper action of the piston rings
2. the oil must provide an effective seal between the rings and
liner
3. only a soft deposit must be formed when the oil burns
4. alkalinity level (total base number or TBN) must match the
acidity of the oil being burnt
5. detergent and dispersant properties are required in order to hold
deposits in suspension and thus keep surfaces clean
 Behaviour depends upon the temperature of the liner, piston crown
and piston rings. TBN and detergency are closely linked. This can
have an adverse effect when running on lighter fuels with lower
sulphur content for any period of time. Coke deposits are can
increase.
3/14/2014 61
62
Compression rings
Scraper rings
Cylinder liner
Oil injection passage
Injection points
Cylinder oil
pump/lubricator
Handle
Camshaft
Piston
3/14/2014
63
Trunk type engine (no piston rod)-
Splash type lubrication
Piston rings
Web
Crank pin, bottom end
bearing (rotatory
motion)
Connecting rod
Gudgeon pin
Cylinder liner
Journal, journal bearing
(rotatory motion)
Web extension
Oil
Oil is picked up by the webs
while rotating, and splashed
onto the piston and liner
3/14/2014
64
Telescopic pipes (one
moves inside the
other)
Piston rod
Movement of crosshead
Movement of bearing
Connecting rod
Stationary pipe
Oil supply
CROSSHEAD
LUBRICATION
Crosshead
bearing
3/14/2014
65
Journal bearing
Journal
Bearing
The journal bearing may undergo hydrodynamic lubrication
or a combination of hydrodynamic and hydrostatic (externally
pressurized) lubrication.
The oil supply may be from any one or number of positions,
depending on the design.
Oil supply
3/14/2014
Distribution within a journal bearing
If the maximum radial clearance is Cr
then Cr = e + Hm
where e is the eccentricity between the shaft
and bearing centre line and Hm is the minimum
clearance (oil film thickness)
an eccentricity factor can be calculated from
n = e / Cr
Factors involved with the eccentricity factor n
are:
minimum oil film thickness,
- journal attitude angle,
 pressure distribution,
 peak pressure angle,
 friction,
 horsepower loss and
 oil flow through the loaded region.
The latter three determine the temperature of
the bearing which for high speed bearings can
be a limiting factor.
3/14/2014 66
67
Oil passage between bearings in a unit
Web
Journal
Crank pin
Oil passage
(drilled)
Connecting rod
Gudgeon pin
TRUNK TYPE ENGINE
3/14/2014
68
68
Lubrication system
• TG- Temperature gauge
• PG- Pressure gauge
ENGINE Shaft
Cooler
Storage tank Pump
Filter
Bearings
PG
PG
TG PG
TG
3/14/2014
69
Storage tank/sump
Engine sump
ENGINE Shaft Bearing
• The storage tank usually forms the bottom-most compartment of the engine.
• It is also sometimes known as the sump.
• Oil from the sump is usually transported to the bearings by an engine driven
pump or an independently electric motor driven pump that transports the oil to
the journal bearings.
• Through passages drilled in the crank shaft and webs, it is transported to the
crank pin.
• Usually a strainer is provided on the suction side of the pump to prevent large
contaminant particles from damaging the pump and bearings.
Pump
Connection for
filling the tank
strainer
3/14/2014
70
Oil cooler- tube and shell type
Oil in
Oil out
Water in Water out
TG
TG
TG
TG
• In this case, cooling water flows through the tubes.
• Oil flows in the shell around the tubes and passes the heat to the water.
• The in/out temperatures of the oil and water are to be monitored.
• Oil pressure is always kept above water pressure to prevent water
contamination of oil
• However, if there is a leak oil is lost and the sump level is therefore to be
monitored regularly
PG PG
PG
PG
3/14/2014
71
71
Engine lubrication system
• TG- Temperature gauge
• PG- Pressure gauge
ENGINE Shaft
Cooler
Storage tank Pump
Filter
Bearings
PG
PG
TG PG
TG
Some adverse situations:
•Oil inlet pressure to engine LOW
•Oil outlet temperature from engine HIGH
•Oil outlet temperature from cooler HIGH
3/14/2014
Properties ideal for bearings:
1. Soluble for high speed fluid film hydrodynamic
lubrication, hence, low viscosity with reduced oil film
friction.
2. moderate bearing loads
3. improved heat transfer behavior
4. corrosion protection
5. cooling
6. low friction
7. good low temperature viscosity
8. good high temperature viscosity
3/14/2014 72
PROPERTIES IDEAL FOR GEAR CASE:
• high film strength to prevent metal to metal contact.
Hence, high viscosity adhesive to resist sliding and
centrifugal forces
• corrosion protection
• cooling
• reduces friction
• good low tempo viscosity
• good high tempo viscosity The thicker the oil film the
greater the cushioning against shocks. Also less tendency
for pit formation by hydraulic action in cracks,
• sound damping properties with cushioning effects
• antifoam properties
3/14/2014 73
Turbine oil
 Compromise between above two requirements
1. Generally a good quality refined mineral oil derived
from paraffanic base stock used with various
additives including EP additives for highly loaded
gearing.
2. Anti-foaming properties important
3/14/2014 74

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Properties of Lubricats and Lubrication-Edit.pptx

  • 2. Lubricant: The substances which are used to decrease the force of friction between the moving parts of machine in contact are known as Lubricants and the process of decreasing the force of friction between the moving parts of machine in contact is known as Lubrication. Composition of lubricating oils: Lubricating oil fractions extracted from crude oil are a widely varying mixture of straight and branched chain paraffinic, napthenic aromatic hydrocarbons having boiling points ranging from about 302o to 593oC. Some specialty lubricants may have boiling point extremes of 177 and 815oC. The choice of grade of lubricating oil base is determined by the expected use. 3/14/2014 2
  • 3. FRICTION:  When on surface of machinery moves over the another surface, resistance to relative motion of the surfaces arises. When we look at the solid surface it appears smooth to naked eye , but this smooth surface shows irregularities of projections and cavities when viewed under high power microscope. 3/14/2014
  • 4. 4 When one such surface is placed over another, its projections fall into the cavities of the other and get interlocked .Due to this interlocking , there is resistance to the relative motion of the surfaces. This is called the frictional forces or frictional resistance of friction. In due course of motion, the old projections get broken and deformities arise. 3/14/2014
  • 5.  So, FRICTION may be defined as the opposing force that is set up between the surface of contact, when one body moves over the surface of another body. 5 3/14/2014
  • 6. EFFECT OF FRICTION: The frictional forces oppose the relative motion between the moving parts of a machine. Therefore extra energy has to be spent to overcome the friction , which increases expenses of energy .The friction between the moving parts of machines also produces heat which causes damage to the machinery. Thus friction causes wear and tear of the moving parts of machinery in contact and due to this cause, the machines lose their efficiency and become useless. 3/14/2014 6
  • 7. FUNCTIONS OF LUBRICANTS: I. Lubricants avoid the damage of the moving parts of machines by minimizing the production of heat. II. Lubricants reduce the wear and tear of machinery by keeping the moving parts of machines apart. III. Lubricants reduce the maintenance and running cost of machine. IV. Lubricants act as the coolant because it reduces the production of heat between the moving parts of machine in contact. V. Lubricants increases the efficiency of machine by reducing the loss of energy. VI. By using the lubricants, the relative motion of the moving parts of machine becomes smooth and noise level of running machine reduces. VII. Lubricants also act as the corrosion preventers. 3/14/2014
  • 8. VIII.Lubricants also act as a seal as in piston. Lubricant used between piston and walls of the container (cylinder) prevents the leakage of hot gases produced by the internal combustion i.e.it act as seal. 3/14/2014 8
  • 9. General capabilities expected from an engine lubricant: - Dispersivity or capacity to disperse or suspend the deposits forming contaminants - Detergency or capacity to keep hot parts of an engine clean - Thermal strength or capacity to withstand temperature changes - Anti-oxidant or capacity to resist the action of oxygen - Anti-wear or capacity to resist wear - Anti-scuffing or capacity to preserve oil film even in the presence of high pressures. - Alkalinity reserve or capacity to neutralise acids formed during combustion or other sources thereby preventing corrosive wear. - Demulsibility or capacity to separate contaminants. - Resistance to hydrolysis or capacity to withstand the action of water which can affect additives Pumpability - Centrifugibility and filterability or capacity to separate insoluble elements. - Anti-rust, anti-corrosive and anti-foam are just some of the other properties which protect the metalic object from wear down. 3/14/2014 9
  • 10. NORMAL PROPERTIES REQUIRED ARE: 1. Adequate viscosity at working temperature so that the oil spreads over the liner surface to provide a tough film which resists the scrapper action of the piston rings. 2. The oil must provide an effective seal between the rings and liner. 3. Only a soft deposit must be formed when the oil burns, 4.Alkalintiy level (total base number or TBN) must match the acidity of the oil being burnt. 5. Detergent and dispersant properties are required in order to hold deposits in suspension and thus keep surfaces clean. 3/14/2014 10
  • 11. Classification of Lubricants Liquid Lubricants Eg.Mineral Oil, Petroleum Oil, Vegetable Oil etc Semi Solid Lubricants Eg. Petroleum jellies Solid Lubricants Eg. Graphite, Molybdenum Disulphide etc.
  • 12. VISCOSITY: • It’s a measure of a fluid’s resistance to flow. • Viscosity of the lubricating oil determines its performance under operating conditions. • A low viscosity oil is thin and flows easily . • A high viscosity oil is thick and flows slowly. • As oil heats up it becomes less viscous (Becomes thin) • Too low viscosity of the liquid > Lubricant film cannot be maintained between the moving surfaces > Excessive wear. • Too high viscosity of the liquid > Excessive friction. • Selected Lubricant must be proper viscous. • Viscosity is usually expressed in centipoise or centistoke.
  • 13. Viscosity Index : • It is “Avg. decrease in viscosity of oil per degree rise in temp between 1000F & 2100F.” • Viscosity of liquids decreases with increasing temperature. • The rate at which viscosity of a lubricant changes with temperature is measured by a scale called Viscosity Index. • Silicones, polyglycol ethers, Diesters or triesters have high Viscosity Index. Determination of Viscosity Index : • First the viscosity of the oil under test is determined at 100°F & 210°F. Let it be U and V respectively. • Then viscosity of Pennsylvanian oil is determined. Let it be VH. • Then viscosity of Gulf oil is determined. Let it be VL viscosity Index = VL- U x 100 VL- VH V.I. = 100 (Pennsylvanian oils.) V.I. = Zero (Naphthanic-base gulf oils) Higher the V.I, lesser is the variation of viscosity with change in temperature.Thus, a good lubricating oil should possess high V.I. Viscosity Temp 100O 200 L U H F
  • 14. • Iodine number is the number of Gms equivalent of iodine to amount of ICl absorbed by 100gm of oil. • Each oil has its specific Iodine Number. • So Iodine Number determines the extent of contamination of oil. • Low Iodine Number is desirable in oils. Some oils and their Iodine Numbers are given below : Iodine Number Oil Example >150 Drying oil Linseed oil, tung oil 100-150 Semidrying oil Castor oil , Soyabean oil <100 Non-Drying oil Coconut oil, Olive oil
  • 15. • Aniline point is the Min temp at which oil is miscible with equal amt of aniline • Aniline Point is a measure of aromatic content of the lubricating oil. • Low Aniline Point oil have high aromatic content which attacks rubber seals. • Higher Aniline point means low %age of hydrocarbons (desirable). • Thus Aniline Point is used as an indication of possible deterioration of rubber sealing etc. Determination of Aniline Point : Aniline + sample oil (equal) Heated in Test tube Homogeneous solution Cooled Cloudiness The temperature at which separation of the two phases (Aniline + oil) takes place is the Aniline Point.
  • 16. • Emulsification is the property of lub oil to get mixed with water easily. • Emulsions can be oil in water emulsion or water in oil emulsion. • A good lubricating oil should form such an emulsion with water which breaks easily. This property is called demulsification. • The time in seconds in which a given volume of oil and water separates out in distinct layers is called steam demulsification number. • A good lubricating oil should have lower demulsification number. • Quicker the oil separates out from the emulsion formed, better is the lubricating oil. • In cutting oils the higher the emulsification number, better the oil is. This is because the emulsion acts as a coolant as well as a lubricant.
  • 17. • Flash Point is the min temp at which the lubricant vaporizes that ignite when a tiny flame is brought near. • Fire Point is the Min temp at which the lubricant’s vapours burn constantly for 5 seconds when tiny flame is brought near. • Fire point = flashpoint+5°C to 400°C. • Both should be higher than the max temp of country (for transportation) • If flash point < 140°F = Flammable liquids And if flash point > 140°F =Combustible liquids. The flash and fire points are generally determined by using Pensky-Marten’s apparatus. •Oil under examination is filled in the oil cup up to the mark and heated by the air bath by a burner. •Stirrer is worked b/n tests at a rate of about 1 – 2 rev/sec. •Heat is applied so as to raise the oil temp by about 5c/min. •The temp at which distinct flash appeared in side the oil cup is recorded as flashpoint. •The heating is continued to record the fire point.
  • 18. • Drop Point is the Temperature at which grease passes from the semi-solid to the liquid state. So, it determines the upper temp limit for the applicability of grease. Determination : • Beaker is heated. • Temperature is raised. • Grease sample passes from a semi-solid to a fluid state. • Temp at which its first drop falls from the opening is recorded as drop-point.
  • 19. • Cloud Point is the temp at which the lubricant becomes cloudy or hazy when cooled. • Pour Point is the temp at which the lubricant just ceases to flow when cooled. • Both indicates suitability of lubricant in cold conditions and thus must be low. • Pour point of wax can be lowered by dewaxing or adding suitable pour point depressant. • Pour point of an oil can be lowered by lowering the viscosity of the oil which is achieved by removing the viscous constituent of the oil. • Lubricating oils used in capillary feed systems should have low cloud points, otherwise impurities will clog the capillary. • A high pour point leads to the solidification of the lubricant that may cause jamming of the machine.
  • 20. • Neutralization Point determines Acidity or Alkalinity of oil. • Acidity/Acid value/Acid number is mgs of KOH required to neutralize acid in 1 gm of oil. • Alkalinity/Base value/Base number is mgs of acid required to neutralize all bases in 1 gm oil. • As Neutralization Point of oil increases, age of oil decreases.
  • 21. • It’s the mgs of KOH required to saponify 1 gm of oil. • Saponification is hydrolysis of an Easter with KOH to give alcohol and Na/K salt of acid. • Mineral oils do not react with KOH and are not saponifiable. • Vegetable and animal oils have very high saponification values. Significance • Saponification value helps us to ascertain whether the oil under reference is mineral or vegetable oil or a compounded oil. • Each oil has its specific Soaponification Number. Deviation from it indicates the extent of adulteration of oil.
  • 22. ADDITIVES Improvements in lubricating oil over the last twenty years have come about almost entirely from the use of additives. These are added for three main reasons; 1.to protect the lubricant in service by limiting the chemical change and deterioration 2.To protect the mechanism from harmful combustion products and malfunctioning lubricating oil 3.To improve existing physical properties and to create new beneficial characteristics in the oil 3/14/2014 22
  • 23. Typical additives are: Barium, calcium, phosphorus, Sulphur, chlorine, zinc, oxidation inhibitor-increases oil and machinery life, decreases sludge and varnish on metal parts. Corrosion inhibitor- protects against chemical attack of alloy bearings and metal surfaces. Antiwear improvers- protects rubbing surfaces operating with this film boundary lubrication. One such antiwear ( and oxidation inhibitor) chemical is Zinc dithiophosphate or ZDDP Detergent- tend to neutralise the deposits before formation under high temperature and pressure conditions, or as a result of using a fuel with high sulphur content. Dispersant- used to disperse or suspend the deposits forming contaminants. Typical dispersants, such as polyesters and benzlamides, are usually clean burning. The molecules have a polar charge at one end which attracts and holds the deposits 3/14/2014 23
  • 24. Alkaline agents- neutralizes acids, these form the TBN of the oil and includes additives such as the above dispersants and detergents. An excess of acid neutralizing alkalis are present in the oil and these help to keep parts clean. Failure to keep an oil alkaline can lead to damage to bearings due to acidic attack as well as increased liner wear. Rust inhibitors- protect to form the oxidation of metal component. Pour point depressants- improves low temperature viscosity Oiliness agent- reduces friction seizure point and wear rates EP additives- increases film strength and load carrying capability Antifoam agents- prevents stable bubble formation Metal deactivators- prevent catalytic effects of metal Antiseptic- bactericide. Polymer Agents / Viscosity Improver - an additive that improves the viscosity index of the oil. I.e. reduces the effect of temerpature of the oil. 3/14/2014 24
  • 26. LUB OIL ANALYSIS:  Regular testing of crankcase lub oil is important to ensure that deterioration has not taken place. The results of in service deterioration could be a reduction in engine protection or actual attack on working points by corrosive deposits. Oil samples are generally tested every 3 to 4 months depending on the system and experience. Shipboard testing is taking a rising prominence to allow monitoring of oil condition between testing.  To ensure good representation, care should be taken where the sample is drawn  Correct  Main supply line  inlet or outlet from lub oil cooler  Outlet from main lub oil pump  Incorrect  standpipes  purifier outlet  purifier direct sump suction  Samples should be drawn over a period of several minutes 3/14/2014 26
  • 27. Viscosity  The viscosity is the most important property of the oil. Oil of correct viscosity will provide optimum film strength with minimum friction losses and leakage.  The viscosity of a L.O. may fall due to fuel dilution if running on gas oil, and rise if running on heavy f.o. Viscosity may also increase due to heavy soot loading if purifiers and filters not operating efficiently. Oil ageing caused by oxidation and thermal degradation increases viscosity.  A simple shipboard test is the Mobil flow stick where drops of new and used oil are placed in separate channels on an inclined 'stick'. The rate the oil flows down the stick is proportional to its viscosity. 3/14/2014 27
  • 28. Water content  Initially determined by 'crackle' test. The presence of Na and Mg in a 4:1 ratio indicates salt water contamination.  Limits are laid down by the manufacturer, but as a rule of thumb a limit of 0.2% should cause investigation into source and remedial action at 0.5%  Gross contamination can be remedied by placing the charge in a separate tank and heating to 70oC and circulating through purifier. 3/14/2014 28
  • 29. Spectrometry  Indicates the presence of metal element composition and identifies additive and contaminant levels.  Zinc(Zn),Phosphorus(P)- are components of many oils such as diesel engine oils, hydraulic oils and gear oils, to enhance antiwear and over properties of the oil  Calcium(Ca)- primarily a component of engine oils, provides detergency,alkalinity and resistance to oxidation. Residual fuel engine oils have higher Ca levels  Nickel(Ni)- Bearings, Valves, gear plating, fuel derivative  Barium(Ba)- Multi purpose additive, declining importance  Magnessium(Mg)- as for Ca, may also be due to sea water contamination if found in Ratio of 1:4 of Na  Chromium(Cr)- Piston rings, hydraulic actuator cylinders  Manganese(Mn)- Cylinder wear 3/14/2014 29
  • 30.  Aluminium(Al)- generally comes from wearing piston skirts, levels rise where new piston fitted to old engine. Typically 10ppm, but rises during bedding in. May also indicate the presence of catylytic fines in residual fuels.  Iron(Fe), Molybdenum(Mo), Chromium(Cr)- metals alloyed for piston ring etc, a rise in level may indicate ring pack/liner wear.  Copper(Cu), Lead(Pb) , Tin(Sn), Silver(Ag) - soft metals used in the overlay of shell bearings, and phosphor bronze gears.Note that high copper content can also occur when samples are drawn from copper pipes which have not been flushed as well as gear wear.  Silicon(Si)- Indicates poor air filtration, possible fuel derivative  Sulphur(S)- May indicate the presence of clay based (bentonite) greases  Sodium(Na)- With Mg indicates the presence of sea water contamination, possible coolant system and fuel derivative  Vanadium(V)- Usually indicates the presence of fuel oil 3/14/2014 30
  • 31. Alkalinity and acidity  TBN-TOTAL BASE NUMBER- measure of alkaline additives available for the neutralisation of acids from combustion products and oxidation. Level governed by type of fuel.  For crosshead engines the TBN will tend to rise due to contamination by liner lubrication, it should not be allowed to raise more than twice that of the new charge.  As a guide, the TBN of fresh oil should be at least:  10 x fuel sulphur content (%) for trunk piston engines (10mgKOH/g)  20 x fuel sulphur content (%) for cyl oil in x-head engines (20mgKOH/g)  A simple shipboard go,no-go test is available for measuring the TBN, it involves the addition of an indicator and acid reagent to a 30ml sample. The quantify of acid reagent added is determined by the required level of TBN, for TBN2.5 0.5ml are added, for TBN20 4ml is added. After three minutes the colour is checked against a chart  Purple:Good level of TBN  Green:Borderline  Yellow:Low level of TBN 3/14/2014 31
  • 32.  TAN-TOTAL ACID NUMBER-measure of organic acid and strong acid content of oil. Where SAN is nil, the TAN represents the acidity in the oil due to both the acids in the additives and the oxidation of the hydrocarbons in the oil. The TAN of fresh oils varies with oil type, and tends to climb with age. A high TAN may indicate that an oil should be changed or freshened by top up. A high TAN may be accompanied with increased viscosity.  SAN-STRONG ACID NUMBER-indicates the presence of strong, highly corrosive (inorganic) acids, usually formed from combustion products. If SAN is not zero the oil should be changed immediately  Oil cleanliness  IC-INDEX OF COMBUSTION-measures soot loading of oil  MD-MERIT OF DISPERSANCY-Ability of an oil to disperse contaminants, such as soot, wear debris and water and thereby carry them away from the critical areas. Measured by oil blot test and should not be allowed to fall below 50  DP-DEMERIT POINTS- combination of IC and MD: the lower the value, the healthier is the condition of the oil 3/14/2014 32
  • 33. Shipboard water content test 1. The flask is filled to mark 'A' with kerosene 2. A capsule of reagent (calcium hydride) is added. Any water in the kerosene will react with the calcium hydride and any gas vented off. 3. he container is topped to mark 'B' with sample oil 4. The screw valve and cap are closed. 5. The flask is inverted and shaken 6. After 2 minutes the screw valve is opened. The hydrogen produced by the reaction between the reagent and water exerts a pressure which forces the kerosene through the open valve into the graduated cylinder. The amount discharged is proportional to the water content in the oil sample. 7. If the water content is greater than 1.5% then the test should be repeated this time using a smaller sample by filling only to mark 'C'.The second scale on the graduated cylinder should then be used. 8. If water is detected its type, sea or fresh , should then be determined by use of a special reagent the water 3/14/2014 33
  • 34. Types of Lubrication Considering the nature of motion between moving or sliding surfaces, there are different types of mechanisms by which the lubrication is done. They are: 1. Hydrodynamic lubrication or thick film lubrication 2. Hydrostatic lubrication 3. Boundary lubrication or thin film lubrication 4. Extreme pressure lubrication 3/14/2014 34
  • 35. 1. Hydrodynamic Lubrication or Thick Film Lubrication Hydrodynamic lubrication is said to exist when the moving surfaces are separated by the pressure of a continuous unbroken film or layer of lubrication. In this type of lubrication, the load is taken completely by the oil film. The basis of hydrodynamic lubrication is the formation of an oil wedge. When the journal rotates, it creates an oil taper or wedge between the two surfaces, and the pressure build up with the oil film supports the load. 3/14/2014 35
  • 36. Hydrodynamic lubrication depends on: relative speed between the surfaces, - oil viscosity, - load, and clearance between the moving or sliding surfaces. In hydrodynamic lubrication the lube oil film thickness is greater than outlet, pressure at the inlet increases quickly, remains fairly steady having a maximum value a little to the outside of the bearing center line, and then decreases quickly to zero at the outlet. 3/14/2014 36
  • 37. Application of hydrodynamic lubrication Delicate instruments. Scientific instruments. Large plain bearings like pedestal bearings, main bearing of diesel engines. Fig: Hydrodynamic Lubrication 3/14/2014 37
  • 39. Elastohydrodynamic, This is the type of lubrication used with rolling element bearings. To clarify, the material of the running surface deforms under high pressure as the rolling element passes over it. The oil wedge forms in this deformation. (i) Deformation and increased viscosity with pressure are involved (ii) Frictional coefficient = 0.05 (iii) film thickness less than Hydrodynamic 3/14/2014 39
  • 40. 2. Hydrostatic Lubrication: Hydrostatic lubrication is essentially a form of hydrodynamic lubrication in which the metal surfaces are separated by a complete film of oil, but instead of being self-generated, the separating pressure is supplied by an external oil pump. Hydrostatic lubrication depends on the inlet pressure of lube oil and clearance between the metal surfaces, whereas hydrodynamic lubrication it depends on the relative speed between the surfaces, oil viscosity, load on the surfaces, and clearance between the moving surfaces. 3/14/2014 40
  • 41. Example: the cross head pin bearing or gudgeon pin bearing in two stroke engines employs this hydrostatic lubrication mechanism. In the cross head bearing, the load is very high and the motion is not continuous as the bearing oscillation is fairly short. Thus hydrodynamic lubrication cannot be achieved. Under such conditions, hydrostatic lubrication offers the advantage. Hydrostatic Lubrication 3/14/2014 41
  • 42. 3. Boundary Lubrication or Thin Film Lubrication Boundary lubrication exists when the operating condition are such that it is not possible to establish a full fluid condition, particularly at low relative speeds between the moving or sliding surfaces. The oil film thickness may be reduced to such a degree that metal to metal contact occurs between the moving urfaces. The oil film thickness is so small that oiliness becomes predominant for boundary lubrication. Boundary lubrication happens when, A shaft starts moving from rest. The speed is very low. The load is very high. Viscosity of the lubricant is too low. 3/14/2014 42
  • 43. Examples for boundary lubrication: Guide and guide shoe in two stroke engine. Lubrication of the journal bearing in diesel engines (mainly during starting and stopping of engine). Piston rings and when cylinder liner is at TDC and BDC position when the piston direction changes and if the relative speed is very slow. Boundary Lubrication 3/14/2014 43
  • 44.  A thin lubricant should have high viscosity index, good resistance to heat and oxidation, good oiliness and low pour point. 44 Velocity 3/14/2014
  • 45. 4. Extreme Pressure Lubrication When the moving or sliding surfaces are under very high pressure and speed, a high local temperature is attained. Under such condition, liquid lubricant fails to stick to the moving parts and may decompose and even vaporize. To meet this extreme pressure condition, special additives are added to the minerals oils. These are called “extreme pressure lubrication.” These additives form on the metal surfaces more durable films capable of withstanding high loads and high temperature. Additives are organic compounds like chlorine (as in chlorinated esters), sulphur (as in sulphurized oils), and phosphorus (as in tricresyl phosphate). The Extreme pressure Additives are the organic compounds possessing the active radicals or groups such as chlorine, sulphur , phosphorus etc. These compounds react with metallic surfaces at high temperature to form metallic chlorides. 3/14/2014 45
  • 46. Extreme Pressure Lubrication  sulphides or phosphides which can form surface layers on the moving or sliding metallic surfaces and act as good lubricants. 46 3/14/2014
  • 47. Stresses on Lube oil The main stresses experienced by Lube oils in diesel engines operating on heavy fuel oils are expressed as follows Acid Stress- Caused by sulphuric and oxidation acids. This leads to increased corrosive wear, deposits, reduced Base Number and shorter oil life.Rapid depletion of the BN is the clearest sign of oil stress Thermal/Oxidative stress-This caused by elevated temperatures leading to increased rates of thermal/oxidative breakdown of lubricant and fuel. This leads to increased levels of deposits, sludges, corrosive wear of bearing material, oil thickening and reduced oil life. In addition deposits on the under crown side of the piston can lead to increased hot corosion on the piston. Asphaltene Stress-This caused by fuel contamination of the lube oil and can lead to increased levels of deposits, sludges, lacquers, oil thickening and reduced oil life. In addition deposits on the under crown side of the piston can lead to increased hot corosion on the piston 3/14/2014 47
  • 48. Various Factors of Lubricating Oil: OXIDATION - Oxidation degrades the lube oil producing sludges, varnishes and resins. Presence of moisture, and some metals particularly copper tend to act as a catalyst. Once oxidation starts, deterioration of the properties of the oil is rapid. - Oxidation reduces its effectiveness as a lubricant. Oxidation will also cause deposits which can block passage ways and coat working parts. The rate of oxidation will depend upon temperature, the higher the temperature the more rapid the rate. Anti oxidants are available which reduce the rate, also additional properties can be achieved by the use of additives. 3/14/2014 48
  • 49. -- Most of the chemicals found in an oil will react more or less with oxygen, The effects of this oxidation is always undesirable. Hence, a major objective of the refining process of a mineral oil is to remove those hydrocarbons i.e. the aromatics, the small amount of unsaturates together with molecules containing sulphur, oxygen and nitrogen. - The use of anti-oxidants make a slightly better balance although there usefulness is limited. - Tin based white metal is susceptible to hardening as an oxide layers from on the surface. These tin oxides are a grey-black in appearance and are extremely hard. There formation reduces the bearing clearance as the oxide layer is thicker than the original white metal material from which it formed. The oxide has a lower coefficient of friction than the original white metal but it will cause problems if it brakes up as fragments will become embedded edge on in the white metal and can score the pin. . 3/14/2014 49
  • 50. Emulsification - This occurs due to water contamination; also, contamination with grease, fatty oils, varnish, paint and rust preventers containing fatty products can also promote emulsification. - The presence of an emulsion can be detected by a general cloudiness of the sample. Salt water emulsifies very easily and should be avoided. - Water entrained in the oil supplied to a journal bearing can lead to loss of oil wedge, rub and failure. Fresh water contamination whilst not in itself dangerous can lead to rusting. The iron oxides catalyses the oil to form sludge's. The additives in the oil can leach out to change the water into an electrolyte. - Salt water contamination is very serious as it causes tin oxide corrosion, and also leads to electrochemical attack on the tin matrix in the white metal. The sea water act as then electrolyte. A major problem of water within a lub oil is where the mix enters a bearing, here it is possible for the water to be adiabatically heated causing it to flash off collapsing the oil wedge. 3/14/2014 50
  • 51. THERMAL DEGRADATION: Under high temperatures an oil is liable to thermal degradation which causes discoloration and changes the viscosity. Additives cannot change an oils susceptibility to this degradation. RECHARGING When recharging no more than 10 % of the working charge should be topped up due to heavy sludgeing that can occur due to the heavy precipitation of the sludge. EP ADDITIVE OILS Can assist in healing of damaged gear surfaces but should be used as a temporary measure only due to risk of side effects. 3/14/2014 51
  • 52. Contamination of Lube oil in Diesel Engine: Water Water from, 1.bilge's 2.Jackets 3.Sea via coolers 4.leaky seals or washing in purifiers 5.Condensation Problems caused by water contamination, Water leads to corrosion especially if there is sulphur present due to fuel contamination forms emulsions which are not capable of withstanding high loads removes water soluble additives when centrifuged out leads to possible bacterial attack 3/14/2014 52
  • 53. Fuel May be heavy residual or light diesel/gas oil and can be sourced to faulty to cylinder combustion or faulty seals on fuel p/ps. Problems - Increases viscosity for hfo, reduces viscosity for D.O. - Reduces flashpoint - Introduces impurities such as sulphur - Dilutes lub oil when in large quantities. Solid impurities carbon from the cylinder combustion process, particularly of importance with trunk piston engines but also for crosshead engines with inefficient diaphragm. The carbon can lead to restrictions and blockages of oil ways causing bearing failure. Straight mineral oils hold 1% carbon in suspension, dispersant oils hold about 5%. 3/14/2014 53
  • 54. Bacterial attack: Certain bacteria will attack oil but water must be present. The bacteria may exist in a dormant state in the oil but water is required if they are to reproduce.. The bacteria digest the oil causing breakdown emulsions to be formed, acidity increases, dead bacteria block filters and corrosive films form on working surfaces. In summary their must be three essential conditions for microbiological growth; 1. There must be a source of carbon- present in the oil 2. There must be some bacteria or fungal spores present- these are almost universally present in the atmosphere. 3. There must be free water present. 3/14/2014 54
  • 55. Two other factors which encourage the growth of bacteria: 1. A slight acidity in the water (pH 5 or 6) and 2. A slightly raised temperature (20 to 40oC) which can lead to rapid growth. Biocide additives are available but they are not always compatible with other desired additives and can lead to large organic blockages if treated in the machinery. The best solution is to avoid the presence of water. If mild attack takes place the oil may be heated in the renovating tank to above 90oC for 24hrs before being returned to the sump via the centrifugal separator. For a severe attack the only solution is complete replacement of the charge followed by sterilization of the system. It may be noted that on replenishment the bacteria may be present in a dormant state in the new charge. 3/14/2014 55
  • 56. 56 LUBRICATION FEATURES OF A LARGE DIESEL ENGINE • In some engines such as long and super long stroke engines, the piston is not directly connected to the crank pin via a connecting rod. • The piston has a piston rod extending from the bottom of the piston. • The piston rod is then connected to the connecting rod at the crosshead bearing. • The crosshead bearing has a to and fro motion and therefore a continuous hydrodynamic film cannot form. • Therefore oil has to be pumped to the crosshead bearing at a predetermined pressure in order to take the loads of compression and combustion. • The crosshead is connected to the crank pin via a connecting rod. 3/14/2014
  • 57. 57 Piston Piston rod Crank pin, bottom end bearing (rotatory motion) Journal, journal bearing (rotatory motion) Crosshead, crosshead bearing (reciprocating) Connecting rod Piston rings Oil pumped at a certain pressure Web Piston skirt Stuffing box Platform separating cylinder from crank case 3/14/2014
  • 58. Problems caused by stuffing box leakage oil entering crankcase: Low speed engines are particularly at risk from crankcase lubricant contamination caused by cylinder oil drainage past the piston rod gland and combustion products. This can lead to severe damage of engine crankcase components and reduction of life of oil which is normally expected to last the lifetime. There has been a general increase in the viscosity and Base number of crankcase oils over recent years particularly for engines built since the early 1980's. Increased alkalinity, viscosity and insolubles, fuel derived elements such as vanadium and oil additive derived elements such as calcium, suggest that the contamination is from the cylinder oil drainage. Deterioration of the crankcase oil has led to the expensive necessity of replacing up to 50% of the sump, this is particularly of concern as it is often only a temporary measure. 3/14/2014 58
  • 59. Four causes are put forward: 1. New crankcase oil contaminated with new cylinder oil-unlikely 2. Cylinder oil drainings being recycled and returned to the sump-very likely as it is a common practice to purify oil leaking through the gland, tests done on this purified oil found high amounts of insolubles. 3. Leakage past rod gland- very likely, high pressure scavenge air can blow cylinder oil and dirt past the top scrapper ring and sealing rings into the piston rod drain tank, and even possibly directly into the sump. A problem that worsens with age and wear. 4. Leakage of exhaust valve lubrication system-unlikely The most likely cause for contamination is leakage past the piston rod. It is seen that maintenance of the stuffing box is of the utmost importance. Tell tales and drainage lines should be proved free and use of oil drained from the uppermost drain should not be allowed even after purification due to the high level of contamination which can destroy the properties of the oil in the sump. 3/14/2014 59
  • 60. 60 Cylinder liner lubrication  The type of Cyl. Lub oil required will depend upon the cylinder conditions and the engine design e.g crosshead or trunk piston. However, the property requirements are basically the same but will vary in degree depending upon the fuel and operating conditions.  In some engines, lubricating oil in the cylinder is different from the oil supplied to the other bearings.  The cylinder oil contains additives to withstand the high temperatures and contaminants from combustion products.  The oil is slightly basic in nature to counter the acids formed from combustion.  Scraper rings spread the oil over the liner surface.  Lub. oil is usually injected between the two scraper rings.  Oil is injected at a predetermined period during the downward stroke.  Before starting, oil is pumped into the liner by manual priming methods.  After starting, the oil pump is driven by the engine through a cam shaft. 3/14/2014
  • 61. CYLINDER LUB OIL PROPERTIES  Normal properties required are: 1. adequate viscosity at working temperature so that the oil spreads over the liner surface to provide a tough film which resists the scraper action of the piston rings 2. the oil must provide an effective seal between the rings and liner 3. only a soft deposit must be formed when the oil burns 4. alkalinity level (total base number or TBN) must match the acidity of the oil being burnt 5. detergent and dispersant properties are required in order to hold deposits in suspension and thus keep surfaces clean  Behaviour depends upon the temperature of the liner, piston crown and piston rings. TBN and detergency are closely linked. This can have an adverse effect when running on lighter fuels with lower sulphur content for any period of time. Coke deposits are can increase. 3/14/2014 61
  • 62. 62 Compression rings Scraper rings Cylinder liner Oil injection passage Injection points Cylinder oil pump/lubricator Handle Camshaft Piston 3/14/2014
  • 63. 63 Trunk type engine (no piston rod)- Splash type lubrication Piston rings Web Crank pin, bottom end bearing (rotatory motion) Connecting rod Gudgeon pin Cylinder liner Journal, journal bearing (rotatory motion) Web extension Oil Oil is picked up by the webs while rotating, and splashed onto the piston and liner 3/14/2014
  • 64. 64 Telescopic pipes (one moves inside the other) Piston rod Movement of crosshead Movement of bearing Connecting rod Stationary pipe Oil supply CROSSHEAD LUBRICATION Crosshead bearing 3/14/2014
  • 65. 65 Journal bearing Journal Bearing The journal bearing may undergo hydrodynamic lubrication or a combination of hydrodynamic and hydrostatic (externally pressurized) lubrication. The oil supply may be from any one or number of positions, depending on the design. Oil supply 3/14/2014
  • 66. Distribution within a journal bearing If the maximum radial clearance is Cr then Cr = e + Hm where e is the eccentricity between the shaft and bearing centre line and Hm is the minimum clearance (oil film thickness) an eccentricity factor can be calculated from n = e / Cr Factors involved with the eccentricity factor n are: minimum oil film thickness, - journal attitude angle,  pressure distribution,  peak pressure angle,  friction,  horsepower loss and  oil flow through the loaded region. The latter three determine the temperature of the bearing which for high speed bearings can be a limiting factor. 3/14/2014 66
  • 67. 67 Oil passage between bearings in a unit Web Journal Crank pin Oil passage (drilled) Connecting rod Gudgeon pin TRUNK TYPE ENGINE 3/14/2014
  • 68. 68 68 Lubrication system • TG- Temperature gauge • PG- Pressure gauge ENGINE Shaft Cooler Storage tank Pump Filter Bearings PG PG TG PG TG 3/14/2014
  • 69. 69 Storage tank/sump Engine sump ENGINE Shaft Bearing • The storage tank usually forms the bottom-most compartment of the engine. • It is also sometimes known as the sump. • Oil from the sump is usually transported to the bearings by an engine driven pump or an independently electric motor driven pump that transports the oil to the journal bearings. • Through passages drilled in the crank shaft and webs, it is transported to the crank pin. • Usually a strainer is provided on the suction side of the pump to prevent large contaminant particles from damaging the pump and bearings. Pump Connection for filling the tank strainer 3/14/2014
  • 70. 70 Oil cooler- tube and shell type Oil in Oil out Water in Water out TG TG TG TG • In this case, cooling water flows through the tubes. • Oil flows in the shell around the tubes and passes the heat to the water. • The in/out temperatures of the oil and water are to be monitored. • Oil pressure is always kept above water pressure to prevent water contamination of oil • However, if there is a leak oil is lost and the sump level is therefore to be monitored regularly PG PG PG PG 3/14/2014
  • 71. 71 71 Engine lubrication system • TG- Temperature gauge • PG- Pressure gauge ENGINE Shaft Cooler Storage tank Pump Filter Bearings PG PG TG PG TG Some adverse situations: •Oil inlet pressure to engine LOW •Oil outlet temperature from engine HIGH •Oil outlet temperature from cooler HIGH 3/14/2014
  • 72. Properties ideal for bearings: 1. Soluble for high speed fluid film hydrodynamic lubrication, hence, low viscosity with reduced oil film friction. 2. moderate bearing loads 3. improved heat transfer behavior 4. corrosion protection 5. cooling 6. low friction 7. good low temperature viscosity 8. good high temperature viscosity 3/14/2014 72
  • 73. PROPERTIES IDEAL FOR GEAR CASE: • high film strength to prevent metal to metal contact. Hence, high viscosity adhesive to resist sliding and centrifugal forces • corrosion protection • cooling • reduces friction • good low tempo viscosity • good high tempo viscosity The thicker the oil film the greater the cushioning against shocks. Also less tendency for pit formation by hydraulic action in cracks, • sound damping properties with cushioning effects • antifoam properties 3/14/2014 73
  • 74. Turbine oil  Compromise between above two requirements 1. Generally a good quality refined mineral oil derived from paraffanic base stock used with various additives including EP additives for highly loaded gearing. 2. Anti-foaming properties important 3/14/2014 74