This is a presentation from the Water Industry Operators Association (WIOA) Conference in April 2018. It is based on a feasability study into sustainable odour control
Decoding Kotlin - Your guide to solving the mysterious in Kotlin.pptx
Ti02 ENM for wastewater odour control networks
1. Solar Odour Control
WIOA NSW Conference – April 2018
Duncan Reynolds
R&D Manager / Regional Marketing
2. Our Project Goal
Establish Proof of Concept and feasibility of
products/processes which:
• Perform the function of odour control for a wide
range of sewage gases
• Are cost-effective to the Utility/Council
3. Our Project Goal (cont)
• Can be sourced from within Australia
• Ideally be disposed of without landfilling (measured by Life
Cycle Assessment)
• Manufactured within Australia:
providing employment in the growing Advanced
Manufacturing sector
compliance with relevant statutory requirements
4. Our Project Goal (cont)
Titanium dioxide (Ti02)
Engineered Nano Materials
(ENMs) were chosen for further
investigation
5. Background Science
Figure 1:
An illustrative photocatalytic
oxidation process for
VOCs and chemical equation
OH + VOC + O2 nCO2 + mH2O
6. Engineering
Ideal onsite process conditions:
1. H2S levels < 15 ppm
2. Gas flowrates < 5 L/s
3. UV-A irradiation > 5 mW/cm2
4. Temperature between 60-80 ˚C
8. Engineering (cont)
Figure 2:
Sample photoreactor from an
EU-Funded pilot study
European Experiment:
• UV bulbs set on a timer
side-mounted to the unit
• Bulbs were activated
during non-daylight hours
(Portella, 2012).
11. SVSR Methylene Blue (MB) Experiment
When MB is contacted with irradiated TiO2, the hydroxyl
radicals generated lead to a reduction in the blue colour
12. SVSR Methylene Blue (MB) Experiment (cont)
(a) After 1 minute exposure (b) After 25 minutes exposure
Experiment:
Visually monitoring 2 samples using sunlight (Sydney, Nov 2017)
13. Sustainability and Life Cycle Assessment
Table 4. World Rankings of Australia’s Ti02 resources and
production as at December 2016
World
Ranking for
Resources
% of World
Resources
World
Ranking of
Production
% of World
Production
Rutile 1 50 1 42
Ilmenite 2 19 3 13
14. Conclusion and Areas for future research
SVSR’s preliminary research identified the following areas
requiring future research:
• Assessing non-photonic forms of activation energy
e.g. electrical current provided by DC photovoltaic panels
• Quantifying required change-out periods
15. Conclusion and Areas for future research (cont)
• Detailed Life Cycle Assessment, including trials for:
Manufacturing process
Better understanding their environmental fate eg in
biosolids or natural surface waters
Detailed characterisation of spent TiO2 ENMs to assess
their suitability for incineration and/or reuse
16. Conclusion and Areas for future research (cont)
Source: Brar, S. K. et al (2010)