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Solar Odour Control
WIOA NSW Conference – April 2018
Duncan Reynolds
R&D Manager / Regional Marketing
Our Project Goal
Establish Proof of Concept and feasibility of
products/processes which:
• Perform the function of odour control for a wide
range of sewage gases
• Are cost-effective to the Utility/Council
Our Project Goal (cont)
• Can be sourced from within Australia
• Ideally be disposed of without landfilling (measured by Life
Cycle Assessment)
• Manufactured within Australia:
 providing employment in the growing Advanced
Manufacturing sector
 compliance with relevant statutory requirements
Our Project Goal (cont)
Titanium dioxide (Ti02)
Engineered Nano Materials
(ENMs) were chosen for further
investigation
Background Science
Figure 1:
An illustrative photocatalytic
oxidation process for
VOCs and chemical equation
OH + VOC + O2  nCO2 + mH2O
Engineering
Ideal onsite process conditions:
1. H2S levels < 15 ppm
2. Gas flowrates < 5 L/s
3. UV-A irradiation > 5 mW/cm2
4. Temperature between 60-80 ˚C
Engineering (cont)
5. Humidity < 20% RH
6. Ph > 9
7. Borosilicate glass, UV transmissible reactor cover
8. Periodic backwashing with mildly alkaline fluids
Engineering (cont)
Figure 2:
Sample photoreactor from an
EU-Funded pilot study
European Experiment:
• UV bulbs set on a timer
side-mounted to the unit
• Bulbs were activated
during non-daylight hours
(Portella, 2012).
Commercial Applications
Different particle sizes
for different
applications eg liquid
and gas-phase
applications
LEFT RIGHT
Commercial Applications (cont)
LEFT RIGHT
SVSR Methylene Blue (MB) Experiment
When MB is contacted with irradiated TiO2, the hydroxyl
radicals generated lead to a reduction in the blue colour
SVSR Methylene Blue (MB) Experiment (cont)
(a) After 1 minute exposure (b) After 25 minutes exposure
Experiment:
Visually monitoring 2 samples using sunlight (Sydney, Nov 2017)
Sustainability and Life Cycle Assessment
Table 4. World Rankings of Australia’s Ti02 resources and
production as at December 2016
World
Ranking for
Resources
% of World
Resources
World
Ranking of
Production
% of World
Production
Rutile 1 50 1 42
Ilmenite 2 19 3 13
Conclusion and Areas for future research
SVSR’s preliminary research identified the following areas
requiring future research:
• Assessing non-photonic forms of activation energy
e.g. electrical current provided by DC photovoltaic panels
• Quantifying required change-out periods
Conclusion and Areas for future research (cont)
• Detailed Life Cycle Assessment, including trials for:
 Manufacturing process
 Better understanding their environmental fate eg in
biosolids or natural surface waters
 Detailed characterisation of spent TiO2 ENMs to assess
their suitability for incineration and/or reuse
Conclusion and Areas for future research (cont)
Source: Brar, S. K. et al (2010)
Any Questions?
Duncan Reynolds
R&D Manager / Regional Marketing
Duncan@svsr.com.au

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Ti02 ENM for wastewater odour control networks

  • 1. Solar Odour Control WIOA NSW Conference – April 2018 Duncan Reynolds R&D Manager / Regional Marketing
  • 2. Our Project Goal Establish Proof of Concept and feasibility of products/processes which: • Perform the function of odour control for a wide range of sewage gases • Are cost-effective to the Utility/Council
  • 3. Our Project Goal (cont) • Can be sourced from within Australia • Ideally be disposed of without landfilling (measured by Life Cycle Assessment) • Manufactured within Australia:  providing employment in the growing Advanced Manufacturing sector  compliance with relevant statutory requirements
  • 4. Our Project Goal (cont) Titanium dioxide (Ti02) Engineered Nano Materials (ENMs) were chosen for further investigation
  • 5. Background Science Figure 1: An illustrative photocatalytic oxidation process for VOCs and chemical equation OH + VOC + O2  nCO2 + mH2O
  • 6. Engineering Ideal onsite process conditions: 1. H2S levels < 15 ppm 2. Gas flowrates < 5 L/s 3. UV-A irradiation > 5 mW/cm2 4. Temperature between 60-80 ˚C
  • 7. Engineering (cont) 5. Humidity < 20% RH 6. Ph > 9 7. Borosilicate glass, UV transmissible reactor cover 8. Periodic backwashing with mildly alkaline fluids
  • 8. Engineering (cont) Figure 2: Sample photoreactor from an EU-Funded pilot study European Experiment: • UV bulbs set on a timer side-mounted to the unit • Bulbs were activated during non-daylight hours (Portella, 2012).
  • 9. Commercial Applications Different particle sizes for different applications eg liquid and gas-phase applications LEFT RIGHT
  • 11. SVSR Methylene Blue (MB) Experiment When MB is contacted with irradiated TiO2, the hydroxyl radicals generated lead to a reduction in the blue colour
  • 12. SVSR Methylene Blue (MB) Experiment (cont) (a) After 1 minute exposure (b) After 25 minutes exposure Experiment: Visually monitoring 2 samples using sunlight (Sydney, Nov 2017)
  • 13. Sustainability and Life Cycle Assessment Table 4. World Rankings of Australia’s Ti02 resources and production as at December 2016 World Ranking for Resources % of World Resources World Ranking of Production % of World Production Rutile 1 50 1 42 Ilmenite 2 19 3 13
  • 14. Conclusion and Areas for future research SVSR’s preliminary research identified the following areas requiring future research: • Assessing non-photonic forms of activation energy e.g. electrical current provided by DC photovoltaic panels • Quantifying required change-out periods
  • 15. Conclusion and Areas for future research (cont) • Detailed Life Cycle Assessment, including trials for:  Manufacturing process  Better understanding their environmental fate eg in biosolids or natural surface waters  Detailed characterisation of spent TiO2 ENMs to assess their suitability for incineration and/or reuse
  • 16. Conclusion and Areas for future research (cont) Source: Brar, S. K. et al (2010)
  • 17. Any Questions? Duncan Reynolds R&D Manager / Regional Marketing Duncan@svsr.com.au