2. Occurrence 3rd December 1984
Place of
occurrence
Bhopal, Madhya Pradesh, India.
Company Union Carbide Corporation.
Chemical Methyl Isocyanate (40 tons)
People Affected > 500,000
People Died (+-) 40,000
What Happened 45 tons of methyl Isocyanate (MIC)
escaped from two underground
storage tanks at The Union Carbide
Pesticide Plant.
What Happened ?
10. • A Nitrogen line was connected to the tank to transfer the product by
inert pressurization of the headspace.
• The tank was fitted with a pressure relief valve and rupture disc. The
vent line from the valve exhausted into a scrubbing tower filled with
caustic soda (NaOH). This would neutralize the MIC to form Sodium
isocyanate. Any residual gas from the scrubber was sent to a 30 m tall
flare stack where it would be burned off.
• There was an external coiled jacket on the vessel through which
coolant (freon / chloroform) was re-circulated. This was to keep the
vessel contents at 0 C and thus prevent any adverse exothermic
reactions occurring.
• Tanks were not to be filled above the 50 % mark so that in the event
of dangerous chemical reactions occurring, solvents could be pumped in
to quench the reactions.
11.
12. ANTICIPATION
Hazards in any large scale in any chemical processing industry can be classified into
the following categories ;-