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Industrial Hygiene
Airborne Hazard
The Bhopal Disaster
By,
Abirami V.Veeramani
Kong Wanying
Mohd Yusri Hafizi
Nivashini Krishna Kumar
Siti Saidatul
Occurrence 3rd December 1984
Place of
occurrence
Bhopal, Madhya Pradesh, India.
Company Union Carbide Corporation.
Chemical Methyl Isocyanate (40 tons)
People Affected > 500,000
People Died (+-) 40,000
What Happened 45 tons of methyl Isocyanate (MIC)
escaped from two underground
storage tanks at The Union Carbide
Pesticide Plant.
What Happened ?
To The Human
Health
• A Nitrogen line was connected to the tank to transfer the product by
inert pressurization of the headspace.
• The tank was fitted with a pressure relief valve and rupture disc. The
vent line from the valve exhausted into a scrubbing tower filled with
caustic soda (NaOH). This would neutralize the MIC to form Sodium
isocyanate. Any residual gas from the scrubber was sent to a 30 m tall
flare stack where it would be burned off.
• There was an external coiled jacket on the vessel through which
coolant (freon / chloroform) was re-circulated. This was to keep the
vessel contents at 0 C and thus prevent any adverse exothermic
reactions occurring.
• Tanks were not to be filled above the 50 % mark so that in the event
of dangerous chemical reactions occurring, solvents could be pumped in
to quench the reactions.
ANTICIPATION
Hazards in any large scale in any chemical processing industry can be classified into
the following categories ;-
Monitor
for IDLH
General
onsite
Monitoring
Perimeter
Monitoring
Periodic
Monitoring
Characterize the
site
Uses variety of
medium to
collect sample
Detect contaminants
that might escape
from the site
Keep update on
change over
time
INHALATION Face mask/face shield
EYE Goggle/face shield
SKIN Rubber hand
glove/safety
shoes/body
overclothing
Bhopal Disaster 1984- Methyl Isocyanate

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Bhopal Disaster 1984- Methyl Isocyanate

  • 1. Industrial Hygiene Airborne Hazard The Bhopal Disaster By, Abirami V.Veeramani Kong Wanying Mohd Yusri Hafizi Nivashini Krishna Kumar Siti Saidatul
  • 2. Occurrence 3rd December 1984 Place of occurrence Bhopal, Madhya Pradesh, India. Company Union Carbide Corporation. Chemical Methyl Isocyanate (40 tons) People Affected > 500,000 People Died (+-) 40,000 What Happened 45 tons of methyl Isocyanate (MIC) escaped from two underground storage tanks at The Union Carbide Pesticide Plant. What Happened ?
  • 3.
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10. • A Nitrogen line was connected to the tank to transfer the product by inert pressurization of the headspace. • The tank was fitted with a pressure relief valve and rupture disc. The vent line from the valve exhausted into a scrubbing tower filled with caustic soda (NaOH). This would neutralize the MIC to form Sodium isocyanate. Any residual gas from the scrubber was sent to a 30 m tall flare stack where it would be burned off. • There was an external coiled jacket on the vessel through which coolant (freon / chloroform) was re-circulated. This was to keep the vessel contents at 0 C and thus prevent any adverse exothermic reactions occurring. • Tanks were not to be filled above the 50 % mark so that in the event of dangerous chemical reactions occurring, solvents could be pumped in to quench the reactions.
  • 11.
  • 12. ANTICIPATION Hazards in any large scale in any chemical processing industry can be classified into the following categories ;-
  • 13.
  • 14.
  • 15.
  • 16.
  • 17.
  • 18.
  • 19.
  • 20.
  • 21.
  • 22. Monitor for IDLH General onsite Monitoring Perimeter Monitoring Periodic Monitoring Characterize the site Uses variety of medium to collect sample Detect contaminants that might escape from the site Keep update on change over time
  • 23.
  • 24.
  • 25.
  • 26.
  • 27.
  • 28.
  • 29.
  • 30.
  • 31. INHALATION Face mask/face shield EYE Goggle/face shield SKIN Rubber hand glove/safety shoes/body overclothing