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Chapter 11
Chemical Reactions and Equations
Word Equations
• Recall that word equations can
describe chemical reactions.
• Reactants are written to the left of
the arrow and products are written to
the right of the arrow.
• Recall how to name and write
formulas from your flowchart.
• A skeleton equation is the formulas
of the reactants and products
without the amounts included.
Balancing Chemical
Equations
• Skeleton equations
do not require
amounts but in order
to use actual
equations in
chemistry, a balanced
equation with
amounts must be
written.
Law of Conservation of
Mass
• Chemical reactions must obey
the Law of Conservation of Mass.
• Reactants must equal the
products in amount and mass.
• A balanced chemical equation
compares the amounts of
reactants to products.
An Example….
• We need two wheels to make a toy
car.
• They are sold only in twos.
• Each toy car has one car body (Cb)
and 4 wheels are necessary. (W4)
• What would be our balanced
chemical equation for the toy car?
Building a Toy Car
Building a Tricycle….
• Again, we need one trike body (Tb)
but a tricycle has 3 wheels (W3) and
the wheels only come in packages
of two. (W2)
• How many orders of each tricycle
should be make so there are no
leftover parts?
• Write a balanced “chemical”
equation.
Building Tricycle
Tips and Tricks…

• If there is a polyatomic ion on
both sides of the equation,
keep it together and balance it
as one atom.
• Balance the more complicated
compounds first.
• The elements that are by
themselves should be
balanced last.
• Sometimes it is helpful to
create a chart below the
equation to keep track of the
numbers.
• If you have a word equation,
write the skeleton equation
first, then balance.
LET’S PRACTICE!

• Balance the equations.
• AgNO3 + H2S Ag2S + HNO3
• Zn(OH)2 + H3PO4 Zn3(PO4)2 +
H2 O
• Iron(III) chloride + calcium
hydroxide iron(III) hydroxide +
ANSWERS

• Balance the equations.
• 2AgNO3 + H2S Ag2S + 2HNO3
• 3Zn(OH)2 + 2H3PO4 Zn3(PO4)2 +
6H2O
• 2FeCl3 + 3Ca(OH)2 2Fe(OH)3 +
3CaCl2
Vocabulary Cards

• Skeleton equation
• Reactants
• Products
• Law of Conservation of
Mass
SUM IT UP!
• Write the
balanced
chemical
equation for the
following word
equation.
• Hydrogen + sulfur
 hydrogen
sulfide
Types of Chemical
Reactions
• There are 5 general types of
reactions.
• Occasionally, a reaction may fit
equally into two categories.
• Identification is useful to help
determine and predict the products.
Combination Reactions
• It is also called a synthesis reaction.
• Two or more substances combine to
create a single new substance.
• Mg + O2  MgO
• K + Cl2  KCl
• Balance these equations!
Decomposition Reactions
• A single compound breaks down into
two or more simpler products.
• HgO  Hg + O2
• H2O H2 + O2
• Balance these equations!
Single-Replacement Reaction
• One element replaces a second element
in a compound.
• Requires the activity series to determine
if the reaction will occur.
• The element that is higher up on the
series will replace any lower elements.
• A halogen (group 7) can replace any
other halogen providing that it is higher
up on the periodic table.
• If a reaction doesn’t occur, write NR for
no reaction.
Single-Replacement
Reactions
• K + H2O  KOH + H2
• Zn + Cu(NO3)2  Cu + Zn(NO3)2
• Br2 + NaI  NaBr + I2
• Br2 + NaCl  NR
• Balance these equations!
Double-Replacement
Reactions
• Sometimes when two solutions are
mixed, nothing happens.
• Other times, the ions in the two solutions
react.
• In these types of reactions, the two metal
(positive) cations switch places with each
other.
• Occasionally, a precipitate will form or a
gas will be generated.
• Sometimes, both products are aqueous
so you won’t see anything different
Double-Replacement
Reactions
• Na2S + Cd(NO3)2  CdS + NaNO3
• NaCN + H2SO4  HCN + Na2SO4
• Ca(OH)2 + HCl  CaCl2 + H2O
• Balance these equations!
Combustion Reactions
• This is a chemical change that takes
place when a compound (usually a
hydrocarbon) reacts with oxygen
(O2) and produces carbon dioxide,
water and usually energy in the form
of heat and/or light.
• C8H18 + O2  CO2 + H2O
• When balancing, these numbers are
usually high.
Vocabulary Cards
• Combination/Synthesis
Reaction
• Decomposition Reaction
• Single-Replacement
Reaction
• Double-Replacement
Reaction
• Combustion Reaction
SUM IT UP
Write the balanced
chemical reaction
for the
decomposition of
aluminum oxide.
Combination or synthesis
reaction
Single- Replacement
Reaction
Decomposition
Reaction
Double- Replacement
Reaction
Combination or
Synthesis Reaction
Single- Replacement
Reaction
Double-Replacement
Reaction
Decomposition
Reaction
Double Replacement reaction
Reaction in Aqueous
Solution

• Your world is water-based.
• Most reactions take place in water.
• Most equations can show the reactions between
compounds but do not show how the compounds
behave when dissolved in water.
• They actually separate into the various ions when in
aqueous solution.
• You can use these ions to write a complete ionic
equation.
• If the ion remains unchanged on both sides of the
equation, it is called a spectator ion.
• The spectator ion doesn’t participate in the reaction
directly and can be cancelled out.
• The resulting equation is called the net ionic equation.
• Remember, the resulting equation must be balanced.
Net Ionic Equations
• A net ionic equation shows only
those particles involved in the
reaction and is balanced with
respect to both mass and charge.
• Pb (s) + 2Ag+ (aq)  2Ag (s) + Pb +2 (aq)
• There are 2 Ag on both sides and +2
on both sides.
Solubility
• Soluble means it can dissolve in
water or be aqueous.
• There are rules to determine if
something is soluble or not.
• Page. 344 table 11.3 has the rules.
• If something is soluble write (aq).
• If it isn’t soluble or is insoluble, it is
solid or (s).
• Check the table for the rules.
LET’S PRACTICE!
• Balance this equation.

• Ca+2 + OH- + H+ + PO4-3  Ca+2
+ PO4-3 + H2O
Answers
• Balance this equation.

• Ca+2 + 2OH- + 2H+ + PO4-3 
Ca+2 + PO4-3 + 2H2O
• First balance the charges,
then balance the numbers of
the types of atoms.
• Both sides must have an
equal charge.
LET’S PRACTICE!
• Write the complete
and net ionic
equations for:
• Sodium hydroxide
(aq) and
phosphoric acid
(aq) makes calcium
phosphate and
water.
• Don’t forget to use
your solubility rules.
Answers

• Write the complete and net ionic equations
for:
• Sodium hydroxide and phosphoric acid
makes calcium phosphate and water.
• 3Ca(OH)2 (aq) + 2H3PO4 (aq)  Ca3(PO4)2 (s) +
6H2O (l)
• 3Ca +2 + 6OH- + 6H+ + 2PO4-3  3Ca+2 +
2PO4-3 + 6H2O
• 6OH- + 6H+  6H2O
• Reduce
• OH- + H+  H2O
Vocabulary Cards

• Aqueous
• Spectator ion
• Complete ionic equations
• Net ionic equations
• Solubility
SCIENCE SWAG
• Create your own
visual
representation of
the 5 types of
chemical reactions
we have studied.
• Put them on a
poster.
• Due one week from
today.
POST IT UP
Write a balanced net ionic equation for
Lead(II) nitrate (aq) reacting with sulfuric
acid (aq). Hint: It’s a double replacement
reaction.
I S!
TH
OT
IG

IN
EE
DH
EL
P!
Excessive Cuteness!

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Chapter 11 notes

  • 2. Word Equations • Recall that word equations can describe chemical reactions. • Reactants are written to the left of the arrow and products are written to the right of the arrow. • Recall how to name and write formulas from your flowchart. • A skeleton equation is the formulas of the reactants and products without the amounts included.
  • 3. Balancing Chemical Equations • Skeleton equations do not require amounts but in order to use actual equations in chemistry, a balanced equation with amounts must be written.
  • 4. Law of Conservation of Mass • Chemical reactions must obey the Law of Conservation of Mass. • Reactants must equal the products in amount and mass. • A balanced chemical equation compares the amounts of reactants to products.
  • 5.
  • 6.
  • 7. An Example…. • We need two wheels to make a toy car. • They are sold only in twos. • Each toy car has one car body (Cb) and 4 wheels are necessary. (W4) • What would be our balanced chemical equation for the toy car?
  • 9. Building a Tricycle…. • Again, we need one trike body (Tb) but a tricycle has 3 wheels (W3) and the wheels only come in packages of two. (W2) • How many orders of each tricycle should be make so there are no leftover parts? • Write a balanced “chemical” equation.
  • 11.
  • 12. Tips and Tricks… • If there is a polyatomic ion on both sides of the equation, keep it together and balance it as one atom. • Balance the more complicated compounds first. • The elements that are by themselves should be balanced last. • Sometimes it is helpful to create a chart below the equation to keep track of the numbers. • If you have a word equation, write the skeleton equation first, then balance.
  • 13. LET’S PRACTICE! • Balance the equations. • AgNO3 + H2S Ag2S + HNO3 • Zn(OH)2 + H3PO4 Zn3(PO4)2 + H2 O • Iron(III) chloride + calcium hydroxide iron(III) hydroxide +
  • 14. ANSWERS • Balance the equations. • 2AgNO3 + H2S Ag2S + 2HNO3 • 3Zn(OH)2 + 2H3PO4 Zn3(PO4)2 + 6H2O • 2FeCl3 + 3Ca(OH)2 2Fe(OH)3 + 3CaCl2
  • 15.
  • 16. Vocabulary Cards • Skeleton equation • Reactants • Products • Law of Conservation of Mass
  • 17. SUM IT UP! • Write the balanced chemical equation for the following word equation. • Hydrogen + sulfur  hydrogen sulfide
  • 18. Types of Chemical Reactions • There are 5 general types of reactions. • Occasionally, a reaction may fit equally into two categories. • Identification is useful to help determine and predict the products.
  • 19. Combination Reactions • It is also called a synthesis reaction. • Two or more substances combine to create a single new substance. • Mg + O2  MgO • K + Cl2  KCl • Balance these equations!
  • 20.
  • 21. Decomposition Reactions • A single compound breaks down into two or more simpler products. • HgO  Hg + O2 • H2O H2 + O2 • Balance these equations!
  • 22.
  • 23. Single-Replacement Reaction • One element replaces a second element in a compound. • Requires the activity series to determine if the reaction will occur. • The element that is higher up on the series will replace any lower elements. • A halogen (group 7) can replace any other halogen providing that it is higher up on the periodic table. • If a reaction doesn’t occur, write NR for no reaction.
  • 24. Single-Replacement Reactions • K + H2O  KOH + H2 • Zn + Cu(NO3)2  Cu + Zn(NO3)2 • Br2 + NaI  NaBr + I2 • Br2 + NaCl  NR • Balance these equations!
  • 25.
  • 26. Double-Replacement Reactions • Sometimes when two solutions are mixed, nothing happens. • Other times, the ions in the two solutions react. • In these types of reactions, the two metal (positive) cations switch places with each other. • Occasionally, a precipitate will form or a gas will be generated. • Sometimes, both products are aqueous so you won’t see anything different
  • 27. Double-Replacement Reactions • Na2S + Cd(NO3)2  CdS + NaNO3 • NaCN + H2SO4  HCN + Na2SO4 • Ca(OH)2 + HCl  CaCl2 + H2O • Balance these equations!
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  • 31. Combustion Reactions • This is a chemical change that takes place when a compound (usually a hydrocarbon) reacts with oxygen (O2) and produces carbon dioxide, water and usually energy in the form of heat and/or light. • C8H18 + O2  CO2 + H2O • When balancing, these numbers are usually high.
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  • 33. Vocabulary Cards • Combination/Synthesis Reaction • Decomposition Reaction • Single-Replacement Reaction • Double-Replacement Reaction • Combustion Reaction
  • 34. SUM IT UP Write the balanced chemical reaction for the decomposition of aluminum oxide.
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  • 45. Reaction in Aqueous Solution • Your world is water-based. • Most reactions take place in water. • Most equations can show the reactions between compounds but do not show how the compounds behave when dissolved in water. • They actually separate into the various ions when in aqueous solution. • You can use these ions to write a complete ionic equation. • If the ion remains unchanged on both sides of the equation, it is called a spectator ion. • The spectator ion doesn’t participate in the reaction directly and can be cancelled out. • The resulting equation is called the net ionic equation. • Remember, the resulting equation must be balanced.
  • 46. Net Ionic Equations • A net ionic equation shows only those particles involved in the reaction and is balanced with respect to both mass and charge. • Pb (s) + 2Ag+ (aq)  2Ag (s) + Pb +2 (aq) • There are 2 Ag on both sides and +2 on both sides.
  • 47. Solubility • Soluble means it can dissolve in water or be aqueous. • There are rules to determine if something is soluble or not. • Page. 344 table 11.3 has the rules. • If something is soluble write (aq). • If it isn’t soluble or is insoluble, it is solid or (s). • Check the table for the rules.
  • 48. LET’S PRACTICE! • Balance this equation. • Ca+2 + OH- + H+ + PO4-3  Ca+2 + PO4-3 + H2O
  • 49. Answers • Balance this equation. • Ca+2 + 2OH- + 2H+ + PO4-3  Ca+2 + PO4-3 + 2H2O • First balance the charges, then balance the numbers of the types of atoms. • Both sides must have an equal charge.
  • 50. LET’S PRACTICE! • Write the complete and net ionic equations for: • Sodium hydroxide (aq) and phosphoric acid (aq) makes calcium phosphate and water. • Don’t forget to use your solubility rules.
  • 51. Answers • Write the complete and net ionic equations for: • Sodium hydroxide and phosphoric acid makes calcium phosphate and water. • 3Ca(OH)2 (aq) + 2H3PO4 (aq)  Ca3(PO4)2 (s) + 6H2O (l) • 3Ca +2 + 6OH- + 6H+ + 2PO4-3  3Ca+2 + 2PO4-3 + 6H2O • 6OH- + 6H+  6H2O • Reduce • OH- + H+  H2O
  • 52. Vocabulary Cards • Aqueous • Spectator ion • Complete ionic equations • Net ionic equations • Solubility
  • 53. SCIENCE SWAG • Create your own visual representation of the 5 types of chemical reactions we have studied. • Put them on a poster. • Due one week from today.
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  • 55. POST IT UP Write a balanced net ionic equation for Lead(II) nitrate (aq) reacting with sulfuric acid (aq). Hint: It’s a double replacement reaction. I S! TH OT IG IN EE DH EL P!