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NAME: RAJA ROSENANI BINTI RAJA ABDULLAH

CLASS: 5 ADIODA

SUBJECT: CHEMISTRY

TEACHER’S NAME:
BIL.                                    TOPICS                                    PAGES
 1.    SOAP AND DETERGENT
         a) Definition of soap and examples of soap
         b) History of soap manufacturing
         c) Preparation of soap through saponification
         d) Definition of detergent and examples of detergent
         e) Preparation of detergent
         f) The cleansing of soap and detergent
         g) Comparison of the effectiveness of cleansing action of soap and
            detergent in hard water
         h) The purpose of adding detergent additives
         i) Survey of soap and detergent used
 2.    FOOD ADDITIVES
         a) Purpose of using food additives
         b) Types, examples and functions of food additives
         c) Survey on additives in food
         d) Disadvantages of using food additives
 3.    MEDICINES
         a) Examples of traditional medicines, their sources and uses
         b) Types, functions and examples of modern medicines
         c) The possible side effects of using modern and traditional medicines
            including examples
         d) The correct usage of modern and traditional medicines
         e) Drug abuse
               i.   List of drugs that are normally abused
              ii.   Reasons why teenagers take drugs
             iii. The side effects of the drugs on health
             iv.    The impacts of drug abuse on our society
              v.    Ways to prevent the drug abuse
DEFINITION OF SOAP

  1. Soaps are sodium or potassium salts of long-chain fatty acids.
  2. The general formula of a soap can be written as RCOO-Na+ or RCOO-K+, where R is an
     alkyl group usually containing 12 or 18 carbon atoms. R can be saturated or unsaturated.

  SOAP                 FORMULA
  Sodium laurate       CH3(CH2)10COO-Na+
  Sodium palmitate     CH3(CH2)14COO-Na+
  Potassium stearate   CH3(CH2)16COO-K+
  Potassium oleate     CH3(CH2)7CH=
                       CH(CH2)7COO-K+
  Table 1.1 The formulae of some examples of soap



THE HISTORY OF SOAP MANUFACTURING




                               Large-scale commercial
                               soapmaking occured in
                                                                  Twenty years
                                 1791 when a French
                                                              later, Belgian chemist
                                   chemist, Nicholas
                                                                  Ernest Solvay
  In the past, soap was          Leblanc patented a
                                                             developed a process to
  made by mixing animal           process for making
                                                             further reduce the cost
  fats with alkaline wood        soda ash or sodium
                                                                of obtaining soda
  ashes.                            carbonate from
                                                              ash, thereby reducing
                                  common salt. The
                                                                 the cost of soap
                                process yeilding large
                                                                 manufacturing.
                                 quantities of quality
                                       soda ash.
SAPONIFICATION

  1. Boiling fats or oils with concentrated sodium hydroxide solution or concentrated
     potassium hydroxide solution to produce glycerol and the salts of fatty acids which are
     the soaps. The general equation for this reaction is :
            O                                        O
            II                                       II
          - - -                            -
      CH2 O C R                        CH2 OH       R-C-O-Na+
     I

            O                                       O
            II                                       II
     CH2-O- C-R + 3NaOH                CHOH       + R- C-O-Na+

             O                                        O
             II                                       II
         - - -
     CH2 O C R                         CH2OH         R-C-O-Na+
     Oil or fat   alkali             glycerol      soaps
     Where the three alkyl groups (R, R’ and R’’) can be the same or different group.
  2. The fats and oils are hydrolyses first to form glycerol and fatty acids. The acid then reacts
     with an alkali to form the corresponding sodium or potassium salts.
  3. The following equation shows how soap, sodium palmitate, is prepared.




                                                                               When concentrated
                                                                               potassium
                                                                               hydroxide is used
                                                                               instead of
  Potassium soaps                                                              concentrated
  are softer, milder                                                           sodium hydroxide
  than sodium                                                                  solution, potassium
  soaps and are                                                                soap, potassium
  usually used for                                                             palmitate is
  bathing.                                                                     formed.
DEFINITION OF DETERGENT

  1. Detergents are synthetic cleansing agents made from hydrocarbons obtained from
     petroleum fractions. Thus, detergents are petrochemicals.
  2. Detergents can be classified into three main types, depending on the charge on the
     detergent ion.
         a) Anionic detergents where the head of the detergent particle contains a negatively
            charged ion.                                                    Negatively
            Example: R – O – SO3-Na+ (Sodium alkyl sulphate)                charged ion



         b) Cationic detergents where the head of the detergent particle contains a positively
            charged ion.
                                                    Positively
            Example: R – N (CH3)3+BR-               charged ion


        c) Non ionic detergents
            Example: R – O – CH2CH2OH
      There are two types of anionic detergents :
        a) Detergent molecule with a benzene ring such as sodium alkylbenzene sulphonate.




                                                                Where R represents a long
                                                                hydrocarbon chain.




     We can represent the detergent ion, alkylbenzene sulphonate ion, more simply as :




         b) Detergent molecule without a benzene ring such as sodium alkyl sulphate.
            We can represent the detergent ion, alkyl sulphate ion as:

                    R – OSO3-
PREPARATION OF DETERGENT

                        1. Production of lauryl hydrogen sulphate
           CH₃(CH₂)₉CH₂OH + H₂SO₄            CH₃(CH₂)₉CH₂OSO₃H + H₂O

                   Lauryl alcohol                    Lauryl hydrogen sulphate




                    2. neutralization of lauryl hydrogen sulphate
        CH₃(CH₂)₉CH₂OSO₃H + NaOH              CH₃(CH₂)₉CH₂OSO₃Na + H₂O

            Lauryl hydrogen sulphate                Sodium lauryl sulphate




                                       DETERGENT

THE CLEANSING ACTION OF SOAP AND DETERGENT
THE EFFECTIVENESS OF CLEANSING ACTION OF SOAP AND DETERGENT

Condition          Soap                      Detergent
Hard water         Form an insoluble         Detergent is effective
(contain calcium   precipitate = soap scum   cleaner. Form soluble
& magnesium        (formation of soap scum   substances = calcium or
ion)               causes wastage of soap)   magnesium salts (do
                                             not form scum)
Soft water (do not Soap is effective         Detergent is effective
contain calcium & cleaner.                   cleaner.
magnesium ion)
Acidic water       Form insoluble long-      Detergent is effective
(contain hydrogen chain fatty acids          cleaner. Form soluble
ion)               (reduces the amount of    substances (Do not
                   soap used for cleaning)   form scum)
Environment        Soap is biodegradable     Soap is non-
                                             biodegradable
Biological enzymes
                Biological enzymes in detergents can break down fat and
              protein molecules in food stains. The fatty acids, glycerol and
              amino acids produced are soluble in water and are removed
                                     during washing.



   Stabilisers                                                              Perfumes
The functions of                                                           Perfumes are
 stabilizers is to                                                        added to make
  prevents the                                                             clothes smell
  formation of                                                            fresh and clean
      foam
                                     ADDITIVES AND
                                      FUNCTIONS

                                                                           Whitening /
    Drying agents ; Sodium                                               bleaching agents
     sulphate and sodium                                                     : sodium
            silicate                                                        perborate
      Anhydrous sodium                                                       Bleaches
    sulphate and sodium                                                     (bleaching
    silicate (Na2S2O3) are                                               agents) remove
   used as drying agents to                                               coloured stains
        ensure that the                                                    by oxidation
   detergent in powdered                                                  process. When
    firm is always in a dry                                               coloured stanis
           condition.                                                    are oxidized, the
                                                                            colour will
                                                                             disappear
Preservatives:
                            to inhibit or
                            prevent the
                              growth of
                           moulds, yeast
                          and bacteria that
   Thickeners                spoil foods
  Thickeners are
    substances
which, when added                              Stabilisers and
       to the                                   thickeners: to
mixture, increase its                            improve the
 viscosity without                             texture of foods
   substantially
modifying its other
    properties.

                        PURPOSES OF FOOD
                         PRESERVATIVES



    Colouring
     agents: to                                  Flavouring
     restore the                                  agents: to
    colour or to                                enhance the
    enhance the                                 taste of food
   natural colour

                          Antioxidants: to
                         prevent spoilage of
                             food due to
                            oxidation by
                               oxygen
TYPES, EXAMPLES AND FUNCTIONS OF FOOD ADDITIVES

TYPES         EXAMPLES                     FUNCTIONS
Preservatives sodium nitrite, sodium            to inhibit or prevent the growth of moulds,
              benzoate                          yeast and bacteria that spoil food
Stabilizer    gelatin and acacia gum            to improve the texture of foods
Thickener     gelatin and acacia gum            Thickeners are substances which, when
                                                added to the mixture, increase its viscosity
                                                without substantially modifying its other
                                                properties.
Flavouring     Monosodium                       to enhance the taste of food
agents         glutamate(MSG), aspartame
Dye            azo compounds, triphenyl           added to food to replace colors lost during
               compounds                          preparation, or to make food look more
                                                  attractive.
Antioxidants   ascorbic acid                      to prevent spoilage of food due to
                                                  oxidation by oxygen
Effects on health

       Allergy: MSG
       Carcinogenic: NaNO₂
       Brain damage: MSG
       Hyperactivity: sodium benzoate
       leukemia: Aspartame

Effects on environment

       A
       B
       C
       D

My advice:


       Avoiding the different types of food additives can help improve many health problems.
       Have a better understanding about preservatives in food and what they can do to you.
       If you are on the road to improving your health, enjoy looking after yourself, to keep you
       looking younger, you need to be familiar with some of the preservatives to avoid.
Traditional medicines

           Derived from plants and animals




      Plant          Local name                            Uses
Aloe vera         Lidah buaya          Sap used to relieved pain from burns
Betel             Sireh                Leaves relieved sore eyes
Bitter gourd      Peria                Fruit used to cure diabetes
Coconut           Kelapa               Young coconut water reduces fever
Garlic            Bawang putih         Reduces infection and hypertension
Ginger            Halia                Reduces inflammation and improves blood
                                       circulation and digestion
Ginseng           Ginseng              Roots maintain good health
Hibiscus          Bunga Raya           Leaves relieves headache and hair loss
Turmeric          Kunyit               Cures pimples




Sea cucumber (gamat)
• To treat Japanese encephalitis
  and hole in the heart
Centipede
• To treat lockjaw and convulsions

Ant
• To treat hepatitis B
PICTURES
TYPES              EXAMPLES                      FUNCTIONS
ANALGESICS             Paracetamol                   reduces fever, relieves flu
                       Aspirin                       symptoms and relieves pain
                       Codeine                       but it does not reduce
                                                     inflammation
                                                     Aspirin is used for relief,
                                                     particularly where there is
                                                     inflammation involved, such as
                                                     arthritic pain and dental pain.
                                                     used in headache tables and
                                                     cough medicines but cause
                                                     drowsiness
ANTIBOITICS               Penicillin                 treat diseases, caused by
                          Streptomycin               bacteria, such as pneumonia,
                                                     gonorrhea and syphilis
                                                     treat tuberculosis, whooping
                                                     cough and some forms of
                                                     pneumonia.
PSYCOTHERAPEUTIC      1. Stimulant                   to reduce fatigue
                   Methylphenidate,                  to reduce tension and anxiety
                   Dextroamphetamine,                to treat psychiatric illness
                   Amphetamine
                      2. Antipsychotics
                   Barbiturates, Tranquilisers
                      3. Antidepressants
                   Chlorpromazine,
                   Haloperidol, Clozapine
Modern medicine

       Example                        Side effects
Methylphenidate,              High dose or excessive use of stimulants over long periods of
dextroamphetamine,            time can lead to anxiety, hallucinations, severe depression, or
amphetamine                   physical and psychological dependence.
Tranquilisers                 Tranquilisers cause drowsiness, poor coordinationor
                              lightheadadness. Overdose of these drugs can lead to
                              respiratory difficulties, sleeplessness, coma and even death
Barbiturates                  Barbiturates cause addition. People who rely on barbiturates to
                              fight against insomnia sometimes kill themselves accidentally by
                              taking an overdose
Aspirin                       Can cause bleeding in the stomach because aspirin is
                              vey acidic. Can cause allergic reactions, skin rashes and
                              asthmatic attacks
Paracetamol                   Liver damage
Codeine                       Addiction, depression and nausea.
Morphine                      Addiction

Traditional medicine

          Example                                         Side effect
Quinine                       Hearing loss
Kava-kava                     liver damage


THE CORRECT USAGE OF OF MODERN AND TRADITIONAL MEDICINE

1. Self-medication
        Do not prescribe medicines for yourself (self-medication) or for other people. Discuss
        with your doctor and listen to him concerning the medicine to be taken.
2. Follow the instructions given
        Follow the instructions given by your doctor or pharmacist concerning the dosage and
        method of taking the medicine.
3. Medicines for adult and children
        Medicines for adult should not be given to children and vice versa.
4. Side effects
        Visit the doctor immediately if there are symptoms of allergy or other effects of the
        drugs.
5. Expiry date
        Like foods, medicines also have expiry date. Do not take medicines after their expiry
        dates.
List the drugs that are normally abused.
        Ecstasy
        Morphine
        Ice
        Nicotine

Give reasons why teenagers take drugs
       Stress
       Poverty
       Influenced by peers

The side effects of the drugs on health
       Ecstasy can cause depression and anxiety
       Morphine can cause addiction
        Ice can cause stroke and injuries to the liver and kidneys
       Nicotine can cause addiction

The impact of drug abuse to the society
      The increase of drug addict in the society
      Lead to grey society
      Increase of crime rate in the society

Ways to prevent drug abuse
       Use the correct amount of dosage
       Use the drug for the correct purpose

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Chem f5 (print,label)

  • 1. NAME: RAJA ROSENANI BINTI RAJA ABDULLAH CLASS: 5 ADIODA SUBJECT: CHEMISTRY TEACHER’S NAME:
  • 2. BIL. TOPICS PAGES 1. SOAP AND DETERGENT a) Definition of soap and examples of soap b) History of soap manufacturing c) Preparation of soap through saponification d) Definition of detergent and examples of detergent e) Preparation of detergent f) The cleansing of soap and detergent g) Comparison of the effectiveness of cleansing action of soap and detergent in hard water h) The purpose of adding detergent additives i) Survey of soap and detergent used 2. FOOD ADDITIVES a) Purpose of using food additives b) Types, examples and functions of food additives c) Survey on additives in food d) Disadvantages of using food additives 3. MEDICINES a) Examples of traditional medicines, their sources and uses b) Types, functions and examples of modern medicines c) The possible side effects of using modern and traditional medicines including examples d) The correct usage of modern and traditional medicines e) Drug abuse i. List of drugs that are normally abused ii. Reasons why teenagers take drugs iii. The side effects of the drugs on health iv. The impacts of drug abuse on our society v. Ways to prevent the drug abuse
  • 3.
  • 4. DEFINITION OF SOAP 1. Soaps are sodium or potassium salts of long-chain fatty acids. 2. The general formula of a soap can be written as RCOO-Na+ or RCOO-K+, where R is an alkyl group usually containing 12 or 18 carbon atoms. R can be saturated or unsaturated. SOAP FORMULA Sodium laurate CH3(CH2)10COO-Na+ Sodium palmitate CH3(CH2)14COO-Na+ Potassium stearate CH3(CH2)16COO-K+ Potassium oleate CH3(CH2)7CH= CH(CH2)7COO-K+ Table 1.1 The formulae of some examples of soap THE HISTORY OF SOAP MANUFACTURING Large-scale commercial soapmaking occured in Twenty years 1791 when a French later, Belgian chemist chemist, Nicholas Ernest Solvay In the past, soap was Leblanc patented a developed a process to made by mixing animal process for making further reduce the cost fats with alkaline wood soda ash or sodium of obtaining soda ashes. carbonate from ash, thereby reducing common salt. The the cost of soap process yeilding large manufacturing. quantities of quality soda ash.
  • 5. SAPONIFICATION 1. Boiling fats or oils with concentrated sodium hydroxide solution or concentrated potassium hydroxide solution to produce glycerol and the salts of fatty acids which are the soaps. The general equation for this reaction is : O O II II - - - - CH2 O C R CH2 OH R-C-O-Na+ I O O II II CH2-O- C-R + 3NaOH CHOH + R- C-O-Na+ O O II II - - - CH2 O C R CH2OH R-C-O-Na+ Oil or fat alkali glycerol soaps Where the three alkyl groups (R, R’ and R’’) can be the same or different group. 2. The fats and oils are hydrolyses first to form glycerol and fatty acids. The acid then reacts with an alkali to form the corresponding sodium or potassium salts. 3. The following equation shows how soap, sodium palmitate, is prepared. When concentrated potassium hydroxide is used instead of Potassium soaps concentrated are softer, milder sodium hydroxide than sodium solution, potassium soaps and are soap, potassium usually used for palmitate is bathing. formed.
  • 6. DEFINITION OF DETERGENT 1. Detergents are synthetic cleansing agents made from hydrocarbons obtained from petroleum fractions. Thus, detergents are petrochemicals. 2. Detergents can be classified into three main types, depending on the charge on the detergent ion. a) Anionic detergents where the head of the detergent particle contains a negatively charged ion. Negatively Example: R – O – SO3-Na+ (Sodium alkyl sulphate) charged ion b) Cationic detergents where the head of the detergent particle contains a positively charged ion. Positively Example: R – N (CH3)3+BR- charged ion c) Non ionic detergents Example: R – O – CH2CH2OH There are two types of anionic detergents : a) Detergent molecule with a benzene ring such as sodium alkylbenzene sulphonate. Where R represents a long hydrocarbon chain. We can represent the detergent ion, alkylbenzene sulphonate ion, more simply as : b) Detergent molecule without a benzene ring such as sodium alkyl sulphate. We can represent the detergent ion, alkyl sulphate ion as: R – OSO3-
  • 7. PREPARATION OF DETERGENT 1. Production of lauryl hydrogen sulphate CH₃(CH₂)₉CH₂OH + H₂SO₄ CH₃(CH₂)₉CH₂OSO₃H + H₂O Lauryl alcohol Lauryl hydrogen sulphate 2. neutralization of lauryl hydrogen sulphate CH₃(CH₂)₉CH₂OSO₃H + NaOH CH₃(CH₂)₉CH₂OSO₃Na + H₂O Lauryl hydrogen sulphate Sodium lauryl sulphate DETERGENT THE CLEANSING ACTION OF SOAP AND DETERGENT
  • 8. THE EFFECTIVENESS OF CLEANSING ACTION OF SOAP AND DETERGENT Condition Soap Detergent Hard water Form an insoluble Detergent is effective (contain calcium precipitate = soap scum cleaner. Form soluble & magnesium (formation of soap scum substances = calcium or ion) causes wastage of soap) magnesium salts (do not form scum) Soft water (do not Soap is effective Detergent is effective contain calcium & cleaner. cleaner. magnesium ion) Acidic water Form insoluble long- Detergent is effective (contain hydrogen chain fatty acids cleaner. Form soluble ion) (reduces the amount of substances (Do not soap used for cleaning) form scum) Environment Soap is biodegradable Soap is non- biodegradable
  • 9. Biological enzymes Biological enzymes in detergents can break down fat and protein molecules in food stains. The fatty acids, glycerol and amino acids produced are soluble in water and are removed during washing. Stabilisers Perfumes The functions of Perfumes are stabilizers is to added to make prevents the clothes smell formation of fresh and clean foam ADDITIVES AND FUNCTIONS Whitening / Drying agents ; Sodium bleaching agents sulphate and sodium : sodium silicate perborate Anhydrous sodium Bleaches sulphate and sodium (bleaching silicate (Na2S2O3) are agents) remove used as drying agents to coloured stains ensure that the by oxidation detergent in powdered process. When firm is always in a dry coloured stanis condition. are oxidized, the colour will disappear
  • 10.
  • 11.
  • 12. Preservatives: to inhibit or prevent the growth of moulds, yeast and bacteria that Thickeners spoil foods Thickeners are substances which, when added Stabilisers and to the thickeners: to mixture, increase its improve the viscosity without texture of foods substantially modifying its other properties. PURPOSES OF FOOD PRESERVATIVES Colouring agents: to Flavouring restore the agents: to colour or to enhance the enhance the taste of food natural colour Antioxidants: to prevent spoilage of food due to oxidation by oxygen
  • 13. TYPES, EXAMPLES AND FUNCTIONS OF FOOD ADDITIVES TYPES EXAMPLES FUNCTIONS Preservatives sodium nitrite, sodium to inhibit or prevent the growth of moulds, benzoate yeast and bacteria that spoil food Stabilizer gelatin and acacia gum to improve the texture of foods Thickener gelatin and acacia gum Thickeners are substances which, when added to the mixture, increase its viscosity without substantially modifying its other properties. Flavouring Monosodium to enhance the taste of food agents glutamate(MSG), aspartame Dye azo compounds, triphenyl added to food to replace colors lost during compounds preparation, or to make food look more attractive. Antioxidants ascorbic acid to prevent spoilage of food due to oxidation by oxygen
  • 14.
  • 15. Effects on health Allergy: MSG Carcinogenic: NaNO₂ Brain damage: MSG Hyperactivity: sodium benzoate leukemia: Aspartame Effects on environment A B C D My advice: Avoiding the different types of food additives can help improve many health problems. Have a better understanding about preservatives in food and what they can do to you. If you are on the road to improving your health, enjoy looking after yourself, to keep you looking younger, you need to be familiar with some of the preservatives to avoid.
  • 16.
  • 17. Traditional medicines Derived from plants and animals Plant Local name Uses Aloe vera Lidah buaya Sap used to relieved pain from burns Betel Sireh Leaves relieved sore eyes Bitter gourd Peria Fruit used to cure diabetes Coconut Kelapa Young coconut water reduces fever Garlic Bawang putih Reduces infection and hypertension Ginger Halia Reduces inflammation and improves blood circulation and digestion Ginseng Ginseng Roots maintain good health Hibiscus Bunga Raya Leaves relieves headache and hair loss Turmeric Kunyit Cures pimples Sea cucumber (gamat) • To treat Japanese encephalitis and hole in the heart Centipede • To treat lockjaw and convulsions Ant • To treat hepatitis B
  • 19. TYPES EXAMPLES FUNCTIONS ANALGESICS Paracetamol reduces fever, relieves flu Aspirin symptoms and relieves pain Codeine but it does not reduce inflammation Aspirin is used for relief, particularly where there is inflammation involved, such as arthritic pain and dental pain. used in headache tables and cough medicines but cause drowsiness ANTIBOITICS Penicillin treat diseases, caused by Streptomycin bacteria, such as pneumonia, gonorrhea and syphilis treat tuberculosis, whooping cough and some forms of pneumonia. PSYCOTHERAPEUTIC 1. Stimulant to reduce fatigue Methylphenidate, to reduce tension and anxiety Dextroamphetamine, to treat psychiatric illness Amphetamine 2. Antipsychotics Barbiturates, Tranquilisers 3. Antidepressants Chlorpromazine, Haloperidol, Clozapine
  • 20. Modern medicine Example Side effects Methylphenidate, High dose or excessive use of stimulants over long periods of dextroamphetamine, time can lead to anxiety, hallucinations, severe depression, or amphetamine physical and psychological dependence. Tranquilisers Tranquilisers cause drowsiness, poor coordinationor lightheadadness. Overdose of these drugs can lead to respiratory difficulties, sleeplessness, coma and even death Barbiturates Barbiturates cause addition. People who rely on barbiturates to fight against insomnia sometimes kill themselves accidentally by taking an overdose Aspirin Can cause bleeding in the stomach because aspirin is vey acidic. Can cause allergic reactions, skin rashes and asthmatic attacks Paracetamol Liver damage Codeine Addiction, depression and nausea. Morphine Addiction Traditional medicine Example Side effect Quinine Hearing loss Kava-kava liver damage THE CORRECT USAGE OF OF MODERN AND TRADITIONAL MEDICINE 1. Self-medication Do not prescribe medicines for yourself (self-medication) or for other people. Discuss with your doctor and listen to him concerning the medicine to be taken. 2. Follow the instructions given Follow the instructions given by your doctor or pharmacist concerning the dosage and method of taking the medicine. 3. Medicines for adult and children Medicines for adult should not be given to children and vice versa. 4. Side effects Visit the doctor immediately if there are symptoms of allergy or other effects of the drugs. 5. Expiry date Like foods, medicines also have expiry date. Do not take medicines after their expiry dates.
  • 21. List the drugs that are normally abused. Ecstasy Morphine Ice Nicotine Give reasons why teenagers take drugs Stress Poverty Influenced by peers The side effects of the drugs on health Ecstasy can cause depression and anxiety Morphine can cause addiction Ice can cause stroke and injuries to the liver and kidneys Nicotine can cause addiction The impact of drug abuse to the society The increase of drug addict in the society Lead to grey society Increase of crime rate in the society Ways to prevent drug abuse Use the correct amount of dosage Use the drug for the correct purpose