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R
E
F
R
I
G
E
R
A
N
T
S
Friends
Friends
SO2                                         Journey of time
NH3
CH3Cl
CFCs
HCFCs
HFCs
HCs
Air
Water
CO2
NGR
NGR

  1850   1875   1900   1925   1950   1975    2000 2010
Myth: Refrigerant is always a gas

Refrigerants change their phase depending on the pressure and temperature in which they
operate.




 Dry ice is frozen carbon dioxide.

 Dry ice also has the very nice feature of sublimation -- as it breaks down, it turns directly into carbon
 dioxide gas rather than a liquid.
 The super-cold temperature and the sublimation feature make dry ice great for refrigeration.
Fact: Refrigerant can exist in liquid and solid als0
Myth: Refrigerants are always synthetic compounds

                                                        C
                                                        F
                                                       HC F C
                                                       F
                                                       C



Fact: Refrigerants can be organic, inorganic natural
Efforts
Efforts
Myth: Only CFCs, HCFCs have refrigerant numbers as R-xxxx

Numbering system begins from right                                                     Example .HCFC 22

First digit on the right     =   Number of fluorine atoms                          Number of F atoms       =2

Second digit from the right =    Number of hydrogen atoms plus one                 Number of H atoms + 1   =2

Third digit from the right   =    Number of carbon atoms minus one                 Number of C atoms – 1   =0
                                 (not used when equal to zero)


Zeotrope Mixture series starts with 4, example R410A, etc

Azeotrope Mixture series starts with 5, example R502, etc




Inorganic compounds
Inorganic compounds shall be assigned a number in the 700 series, identification numbers are formed by
adding the relative molecular mass of components to 700.
Examples:     R717 = ammonia (molecular mass 17), R718 = water (molecular mass 18)
                R744 = CO2 (molecular mass 44)

Fact: All refrigerants are has refrigerant number
Myth: All Refrigerants damage ozone layer

                                              Ozone
Refrigerant                                   depleting
compounds                                     Potential
containing                                    (ODP) is a
chlorine                                      factor
element will                                  indicating a
harm Ozone                                    substance’s
layer                                         relative
                                              ozone
                                              damaging
                                              power




Fact: Only CFCs, HCFCs do harm ozone layer.
Myth: All Refrigerants damage ozone layer

                                                                                                         Ozone
Refrigerant                                                                                              depleting
compounds                                                                                                Potential
containing                                                                                               (ODP) is a
chlorine                                                                                                 factor
element will                                                                                             indicating a
harm Ozone                                                                                               substance’s
layer                                                                                                    relative
                                                                                                         ozone
                                                                                                         damaging
                                                                                                         power


ODP value of                     H                                                                  Cl   HFCs
CFC-11 is 1.It                                                   Chlorine       O
                                     C        F                  monoxide           Cl        Chlorine   Hydro
is the
                                                                                              Radical    carbons
reference.                   F           Cl
For ex. a                                                                                                CO2,
substance                                                    O       O
                                                     Cl          O
                                                                                                         Ammonia,
with 2 ODP is    H
twice                C                            Chlorine   Ozone (O3)
                                                                                                         Air, water,
                         F                        Radical                                Oxygen
harmful of                                                                  O                            etc have
                                                                                    O    molecule
CFC11                    CHF2                                                             (O2)           zero ODP

Fact: Only CFCs, HCFCs do harm ozone layer.
Efforts
Efforts
Myth: Refrigerants are used only for cooling
                                                                         Heat Pumps
                                                                            are used for
                                                                        heating water and
                                                                        air in cold climates
                                                                           for comfort air
                                                                        conditioning. Heat
                                                                          pumps are also
                                                                        becoming popular
                                                                         for water heating
                                                                          applications for
                                                                            sanitary and
                                                                         kitchen purposes




Fact: Heating with refrigeration cycle is one of the energy efficient ways of heating
Myth: Refrigerants information is required only for some technical people




Fact: Awareness of refrigerants is very important as we live with them
Myth: Refrigerants information is required only for some technical people




   Refrigerants are no more just a Engineer’s subject, it is in everybody’s interest these days




Fact: Awareness of refrigerants is very important as we live with them
Myth: Refrigerants information is required only for some technical people




   Refrigerants are no more just a Engineer’s subject, it is in everybody’s interest these days




Fact: Awareness of refrigerants is very important as we live with them
Myth: Air is not used as refrigerant


                                                               Air is used as working fluid in
                                                               aircraft air-conditioning
                                                               systems.
                                                               Air is taken from outside and
                                                               made to follow the refrigeration
                                                               cycle




Fact: Air is used as working refrigerant in aircraft systems
Myth: Air is not used as refrigerant




Air as refrigerant is becoming
popular among natural refrigerants
for refrigeration applications due to
its zero ODP and zero GWP




Fact: Air is used as working refrigerant in aircraft systems
Myth: All Refrigerants contribute to higher global warming effect
Global Warming
Potential (GWP) is
relative power of a
given pollutant to
cause global warming
over a given time
scale, factoring its
ability to trap the
sun’s heat and its
atmospheric life time.
GWP is measured
relative to carbon di
oxide which is given
GWP of 1




Fact: Refrigerants with zero, close to zero GWP are also available
Myth: Refrigerant mixtures can not be used
                                                      Below refrigerant mixtures are
                                                      popular in AC & R applications.


                                                      R410A =R125+R32
                                                      R407C=R32+R125+R134a
                                                      R404A=R125+R143a+R134a
                                                      R507=R125+R143a
                                                      It is important to check the
                                                      temperature glide

                                                      Temperature glide is
                                                      difference in phase change
                                                      temperatures of individual
                                                      members




Fact: Refrigerant mixtures are being used currently
Myth: All Refrigerants are covered under some legislation



                 Global Warming Potential (GWP)100a
               20.000




                4.000


                    R404A

                        R410A

                2.000   R407C
                        R134a           R22




Fact: Applicability of legislation depends on your location and country programme
Myth: All Refrigerants are covered under some legislation



                 Global Warming Potential (GWP)100a
               20.000




                4.000


                    R404A

                        R410A

                2.000   R407C
                        R134a           R22
                                                              Montreal
                                                              protocol




Fact: Applicability of legislation depends on your location and country programme
Myth: All Refrigerants are covered under some legislation



                 Global Warming Potential (GWP)100a
               20.000




                         protocol
                          Kyoto
                4.000


                    R404A

                        R410A

                2.000   R407C
                        R134a           R22
                                                              Montreal
                                                              protocol




Fact: Applicability of legislation depends on your location and country programme
Myth: All Refrigerants are covered under some legislation



                 Global Warming Potential (GWP)100a
               20.000




                         protocol
                          Kyoto
                4.000


                    R404A

                        R410A

                2.000   R407C




                                                F-Gas
                        R134a           R22
                                                              Montreal
                                                              protocol




Fact: Applicability of legislation depends on your location and country programme
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Disclaimer
The information provided in this file is based on my experience in the air conditioning and refrigeration Industry. Source of information is
internet

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Refrigerants

  • 4. SO2 Journey of time NH3 CH3Cl CFCs HCFCs HFCs HCs Air Water CO2 NGR NGR 1850 1875 1900 1925 1950 1975 2000 2010
  • 5. Myth: Refrigerant is always a gas Refrigerants change their phase depending on the pressure and temperature in which they operate. Dry ice is frozen carbon dioxide. Dry ice also has the very nice feature of sublimation -- as it breaks down, it turns directly into carbon dioxide gas rather than a liquid. The super-cold temperature and the sublimation feature make dry ice great for refrigeration. Fact: Refrigerant can exist in liquid and solid als0
  • 6. Myth: Refrigerants are always synthetic compounds C F HC F C F C Fact: Refrigerants can be organic, inorganic natural
  • 9. Myth: Only CFCs, HCFCs have refrigerant numbers as R-xxxx Numbering system begins from right Example .HCFC 22 First digit on the right = Number of fluorine atoms Number of F atoms =2 Second digit from the right = Number of hydrogen atoms plus one Number of H atoms + 1 =2 Third digit from the right = Number of carbon atoms minus one Number of C atoms – 1 =0 (not used when equal to zero) Zeotrope Mixture series starts with 4, example R410A, etc Azeotrope Mixture series starts with 5, example R502, etc Inorganic compounds Inorganic compounds shall be assigned a number in the 700 series, identification numbers are formed by adding the relative molecular mass of components to 700. Examples: R717 = ammonia (molecular mass 17), R718 = water (molecular mass 18) R744 = CO2 (molecular mass 44) Fact: All refrigerants are has refrigerant number
  • 10. Myth: All Refrigerants damage ozone layer Ozone Refrigerant depleting compounds Potential containing (ODP) is a chlorine factor element will indicating a harm Ozone substance’s layer relative ozone damaging power Fact: Only CFCs, HCFCs do harm ozone layer.
  • 11. Myth: All Refrigerants damage ozone layer Ozone Refrigerant depleting compounds Potential containing (ODP) is a chlorine factor element will indicating a harm Ozone substance’s layer relative ozone damaging power ODP value of H Cl HFCs CFC-11 is 1.It Chlorine O C F monoxide Cl Chlorine Hydro is the Radical carbons reference. F Cl For ex. a CO2, substance O O Cl O Ammonia, with 2 ODP is H twice C Chlorine Ozone (O3) Air, water, F Radical Oxygen harmful of O etc have O molecule CFC11 CHF2 (O2) zero ODP Fact: Only CFCs, HCFCs do harm ozone layer.
  • 14. Myth: Refrigerants are used only for cooling Heat Pumps are used for heating water and air in cold climates for comfort air conditioning. Heat pumps are also becoming popular for water heating applications for sanitary and kitchen purposes Fact: Heating with refrigeration cycle is one of the energy efficient ways of heating
  • 15. Myth: Refrigerants information is required only for some technical people Fact: Awareness of refrigerants is very important as we live with them
  • 16. Myth: Refrigerants information is required only for some technical people Refrigerants are no more just a Engineer’s subject, it is in everybody’s interest these days Fact: Awareness of refrigerants is very important as we live with them
  • 17. Myth: Refrigerants information is required only for some technical people Refrigerants are no more just a Engineer’s subject, it is in everybody’s interest these days Fact: Awareness of refrigerants is very important as we live with them
  • 18. Myth: Air is not used as refrigerant Air is used as working fluid in aircraft air-conditioning systems. Air is taken from outside and made to follow the refrigeration cycle Fact: Air is used as working refrigerant in aircraft systems
  • 19. Myth: Air is not used as refrigerant Air as refrigerant is becoming popular among natural refrigerants for refrigeration applications due to its zero ODP and zero GWP Fact: Air is used as working refrigerant in aircraft systems
  • 20. Myth: All Refrigerants contribute to higher global warming effect Global Warming Potential (GWP) is relative power of a given pollutant to cause global warming over a given time scale, factoring its ability to trap the sun’s heat and its atmospheric life time. GWP is measured relative to carbon di oxide which is given GWP of 1 Fact: Refrigerants with zero, close to zero GWP are also available
  • 21. Myth: Refrigerant mixtures can not be used Below refrigerant mixtures are popular in AC & R applications. R410A =R125+R32 R407C=R32+R125+R134a R404A=R125+R143a+R134a R507=R125+R143a It is important to check the temperature glide Temperature glide is difference in phase change temperatures of individual members Fact: Refrigerant mixtures are being used currently
  • 22. Myth: All Refrigerants are covered under some legislation Global Warming Potential (GWP)100a 20.000 4.000 R404A R410A 2.000 R407C R134a R22 Fact: Applicability of legislation depends on your location and country programme
  • 23. Myth: All Refrigerants are covered under some legislation Global Warming Potential (GWP)100a 20.000 4.000 R404A R410A 2.000 R407C R134a R22 Montreal protocol Fact: Applicability of legislation depends on your location and country programme
  • 24. Myth: All Refrigerants are covered under some legislation Global Warming Potential (GWP)100a 20.000 protocol Kyoto 4.000 R404A R410A 2.000 R407C R134a R22 Montreal protocol Fact: Applicability of legislation depends on your location and country programme
  • 25. Myth: All Refrigerants are covered under some legislation Global Warming Potential (GWP)100a 20.000 protocol Kyoto 4.000 R404A R410A 2.000 R407C F-Gas R134a R22 Montreal protocol Fact: Applicability of legislation depends on your location and country programme
  • 26. Reddy cific han a Mo ia P – As an ager t Ltd gM s Pv keti n strie l.com Mar s Indu gma i Da nfos d die@ ha n.re 0712 o 4557 l: m e mai 9 1 99 P h: + Disclaimer The information provided in this file is based on my experience in the air conditioning and refrigeration Industry. Source of information is internet