course material

1. Synthesis of carbon nanotube membranes from plastics waste for
brackish water treatment: Towards nanotechnological recycling
Synthesis of carbon nanotube membranes from plastics waste for brackish water treatment:
Towards nanotechnological recyclingCategory : Bold Essays WritingSynthesis of carbon
nanotube membranes from plastics waste for brackish water treatment: Towards
nanotechnological recycling Paper details:need answer to the above question based on my
CV and research proposal.1. Title: Synthesis of carbon nanotube membranes from plastics
waste for brackish water treatment: Towards nanotechnological recycling 2. Aims The
water scarcity problem in Australia is being exacerbated by urban growth and, in many
regions, by increasingly erratic rainfall patterns due to climate change. Australians rely
heavily on groundwater sources, with around 4 million people dependent partially or
totally on groundwater for domestic water supply. Treating the brackish groundwater may
be a viable community water supply option in regional and remote communities in
Australia [1]. Conventional desalination methods are energy and operationally intensive,
whereas adsorption-based techniques, although simpler to use, have limited capacity to
remove salts [2]. Carbon nanotubes (CNTs) have attracted growing attention as a new
material for preparing membranes that may overcome these problems [3,4]. Tip-
functionalized nonpolar interior home of carbon nanotubes (CNTs) provides strong
invitation to polar water molecules and rejects salts and pollutants. Most of current
synthesis methods of CNTs rely on expensive carbon precursors, including such highly pure
gases as acetylene, ethane, ethylene and methane [5]. In the pursuit of getting an
economical precursor, this research will use waste plastic, especially polythenes of
thickness of less than 50 µm that are creating environmental disposal problems. This
attempt will not only solve the problem of disposal of waste plastic but also convert the
waste (plastic) to wealth (CNTs membranes). CNTs membranes can remove salt as well as
organic and metal contaminants. The specific aims of this proposed project are: Aim 1. to
convert waste plastic bags into well-organised carbon nanotubes (CNTs) membranes by a
metal-free chemical vapour deposition (CVD) approach using nanoporous anodic alumina
membranes (NAAMs); Aim 2. comprehensive structural and chemical characterization of
CNTs-NAAMs and liberated CNTs; Aim 3. to study the efficiency of CNTs membranes for
removing salt, microbes and other organic contaminants from brackish water and monitor
the quality of filtered water. 3. Approach 3.1 Fabrication of CNTs-NAAMs Polyethylene bags

2. will be washed, air-dried and shreIDed into small pieces. In the proposed project, we will
use nonporous anodic alumina membranes (NAAMs) as template for CNTs synthesis to
avoid the production of poisonous contaminants due to the use of metal catalysts. NAAMs
will be produced by the two-step anodization procedure [6,7]. Then the small plastic pieces
and NAAMs will be put into the pyrolysis zone and the deposition zone of the chemical
vapour deposition (CVD) reactor, respectively, to start the carbon decomposition process.
Argon (Ar) gas will be used to ensure the absence of oxygen during the CNTs synthesis
process. The temperature and time conditions will be optimized for obtaining maximum
yield through CVD. After the completion of CNTs production, the CVD will be cooled at room
temperature and CNTs -NAAMs will be collected and placed in inert conditions. After that
the Al2O3 matrix will be dissolved by using solvents such as hydrofluoric acid (HF). Then
we will shift the CNTs to ethanol for centrifugation. Structural and chemical
characterizations of the prepared CNTs-NAAMs and liberated CNTs will be conducted with
scanning electron microscope, transmission electron microscopy, X-ray photoelectron
spectroscopy, X-rays diffraction, and Raman spectroscopy using the facilities at AIIM
according to an ongoing collaboration between Dr Faisal Hai (supervisor, CME) and Prof
Will Price (AIIM). 3.2 Filtration process Filtration process will become cost-effective if the
utilized pressure for water flow is low. In the proposed project, we will utilize filtration
employing only the native pressure of the water column in CNTs-NAAMs. The schematic
diagram of the working principle of the CNT- NAAMs filtration setup is shown in Figure 1.
The CNTs are nearly in contact with each other. The arrows depict flow of water through
the CNTs. The water used here will be the brackish water from nearby sources. Then the
filtered water will be analyzed for different water quality parameters such as salt
concentration, microbes and other organic contaminants. A pilot system will be constructed
to assess the performance of the developed system in remote areas. This will be conducted
in collaboration with Prof Price (AIIM), who has recently successfully conducted an on-site
trial of reverse osmosis desalination of brackish coal seam gas produced water at
Gloucester, NSW. Strategic alignment with host unit: This research will be supervised by Dr
Faisal Hai at the School of Civil, Mining and Environmental Engineering (CME) in
collaboration with Prof Price (AIIM). Dr Hai’ s collaboration with Prof Price strategically
focuses on novel membrane processes for water/wastewater treatment. With a well-
established capacity for membrane synthesis, membrane processes development and high
precision trace organic analysis, Dr Hai’ s lab is well placed to support the proposed
innovative research. Project alignment with UOW priority research areas: The proposed
project builds on the strategic research direction and the multidisciplinary research
environment of UOW and will be carried out at the School of CME. Expected outcomes:
Transforming waste materials through ‘ nanotechnological recycling’ will provide a
potential solution for minimizing the environmental pollution at the same time producing
clean drinking water. Moreover, the carbon nanotube-based membranes may lead to next-
generation rechargeable, point-of-use potable water purification appliances with superior
desalination, disinfection and filtration properties. The proposed research aIDresses issues
from ARC research priorities. Consequently, this will provide excellent opportunities for
ARC and industry funded projects given the current significant interest in water recycling

3. by all stakeholders of the Australian water industry as well as in other countries. References
1. Works, NSW Public, A. N. Z. E. C. C. Australia, M. F. Microfiltration, P. V. Photovoltaic, U. F.
Ultrafiltration, U. V. Ultraviolet, and VWS&T. Veolia Water Solutions. “ Brackish
groundwater: a viable community water supply option?.” The National Water Commission,
Australian Government, Canberra (2011): 1-81. 2. Al-Ahmad, M., FA Abdul Aleem, A. Mutiri,
and A. Ubaisy. “ Biofuoling in RO membrane systems Part 1: Fundamentals and control.”
Desalination 132, no. 1 (2000): 173-179. 3. Das, Rasel, Md Eaqub Ali, Sharifah Bee Abd
Hamid, Seeram Ramakrishna, and Zaira Zaman Chowdhury. “ Carbon nanotube membranes
for water purification: a bright future in water desalination.” Desalination 336 (2014): 97-
109. 4. Wang, Haitao, Hanyu Ma, Wen Zheng, Dingding An, and Chongzheng Na.
“ Multifunctional and Recollectable Carbon Nanotube Ponytails for Water Purification.” ACS
applied materials & interfaces 6, no. 12 (2014): 9426-9434. 5. Shajahan, Md, Y. H. Mo, AKM
Fazle Kibria, M. J. Kim, and K. S. Nahm. “ High growth of SWNTs and MWNTs from C2H2
decomposition over Co– Mo/MgO catalysts.” Carbon 42, no. 11 (2004): 2245-2253. 6.
Altalhi, Tariq, Tushar Kumeria, Abel Santos, and Dusan Losic. “ Synthesis of well-organised
carbon nanotube membranes from non-degradable plastic bags with tuneable molecular
transport: Towards nanotechnological recycling.” Carbon 63 (2013): 423-433. 7. Nielsch,
Kornelius, Jinsub Choi, Kathrin Schwirn, Ralf B. Wehrspohn, and Ulrich Gösele. “ Self-
ordering regimes of porous alumina: the 10 porosity rule.” Nano letters 2, no. 7 (2002):
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