Which is a polar molecule? C 5 H 10 C 3 H 6 HF Br 2 Solution H-F is a polar molecule because there is a huge polarity difference between H and F as H is an electropositive atom where as F is the most electronegative atom, when they combine together to form HF as a molecule a dipole moment is there which makes it polar. Rest all the molecules are either diatomic where there is no net dipole moment or hydrocarbons which are almost non polar. .