When is a product more soluble in an organic solvent then in an aqueous solution. When is a product more soluble in an organic solvent then in an aqueous solution. Solution Organic compounds are generally non polar and water is a polar solvent. As \"like dissolves like\", so polar products can dissolve in polar solvents(aqueous solution) and non-polar product can dissolve in non-polar solvents(organic sollvent). Polar products rarely dissolve in non-polar solvents and vice versa. .