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SESSION 3:
Water Quality, Testing
and Treatment
Water Quality and Testing
 Drinking water standards
 Common contaminants
 Testing
 Why?
 When?
 What?
Drinking Water Quality
 Federal Safe Drinking Water Act, 1974 (SDWA):
 Establishes standards for surface and groundwater
sources used for drinking water.
 EPA sets standards based on whether a
contaminant:
1. Harms human health
2. Is known to occur in drinking water
3. Can be detected in drinking water
 TCEQ is required to enforce the SDWA
Water Quality Law and Policy
Texas Private Well Regulations
• Well location requirements
• Well construction
• No requirements for water
testing or maintenance
after construction
Water Supply Regulations
EPA – National Drinking
Water Standards
• Public water systems
• Primary Standards – Health
• Secondary Standards –
Nuisance
• Can be used as a guide for
your private well.
Secondary Standards
• Secondary standards, or SMCL
• Set for aesthetic considerations
 Taste
 Color
 Odor
• 15 contaminants
• Examples:
 Iron
 Sulfate
 TDS
EPA Drinking Water Standards
Primary Standards
• Maximum Contaminant
Level, or MCL
• Pose risks to human health
• Over 80 contaminants
• Examples:
 Nitrate
 E. coli
 Arsenic
 Organic chemicals and
pesticides
Summary of Screening Results
Number of samples screened: 11
Positives coliform: 5 (45%) Positives E. coli: 0
Nitrate average (ppm): 0.5 Range: 0 - 2
Salinity average (ppm TDS): 578 Range: 380 - 901
pH average: 8.1 Range: 7.8 – 8.4
Water Well Testing FAQs
How often should the well be tested?
• Annually for bacteria
• Every few years for general chemistry such as
nitrates and salts
• As frequently as needed for other contaminants of
concern
How much will it cost?
• Varies depending on analyses selected.
• Basic E. coli test should be less than $30
Private Well Testing
Drinking Water Testing:
• County Health Departments and River Authorities
• NELAC-certified labs on TCEQ website
 http://www.tceq.texas.gov/goto/certified_labs
 512-239-3754
Private Well Testing for E. coli and Other Concerns
Private Well Testing
Irrigation and Livestock:
Texas AgriLife Extension Service Soil, Water and Forage
Testing Laboratory at TAMU (http://soiltesting.tamu.edu/)
Private Well Testing
Private Well Testing
Fecal Bacteria
 Microscopic organisms
found in feces of humans
and other warm-blooded
animals
 Not all are harmful by
themselves
 Indicator organisms:
indicate presence of
pathogenic bacteria,
viruses, parasites
 E. coli is the most
commonly tested
Why Check for E. coli?
• Indicator bacteria
 Indicates disease risk from
other organisms that are
pathogenic
• Cost effective
• MCL (maximum contaminant
level) is 0 colonies/100 ml
• Test annually and each time
the well is opened or repaired
HUMANS
50 FT. MINIMUM
SEPARATION
100 FT. MINIMUM
SEPARATION
DRAIN/SPRAY FIELD
Sources of Bacteria
LIVESTOCK
• 150 FT. MINIMUM SEPARATION
• DOWN SLOPE FROM WELL
Sources of Bacteria
DOMESTIC
ANIMALS
150 FT. MINIMUM SEPARATION
FROM PENS, YARDS AND RUNS
Sources of Bacteria
Nitrate
• Methemoglobinemia (blue baby syndrome)
 Pregnant/ nursing women
 Infants
 Elderly/ suppressed immune systems
• Sources: natural sources, fertilizer, animal waste, sewage
Treatment: reverse osmosis, ion exchange, distillation
Nitrate
MCL = 10 ppm
Sources of Nitrates
HUMANS
50 FT. MINIMUM
SEPARATION
100 FT. MINIMUM
SEPARATION
DRAIN/SPRAY FIELD
FERTILIZER
Sources of Nitrates
STORAGE: 150 FT. MINIMUM SEPARATION
ANIMAL WASTE
Sources of Nitrates
• 150 FT. SEPARATION FOR PETS AND LIVESTOCK
• WILDLIFE: NO GUIDELINES
• Level of dissolved minerals,
including salts
• More than 500 ppm tastes
salty
• Sodium is often referred to as
a measure of salinity, most
common cause of high TDS in
Texas
Total Dissolved Solids (TDS)
.
Salinity Tolerance - Plants
PPM
0 - 175 Excellent, no risk to plants
175 – 525 Good, not for sensitive plants
525 – 1,400 Permissible, not for low salt
tolerant plants
1,400 – 2,100 Doubtful, damage to high salt
tolerant plants
>2,100 Unsuitable
Resources
Dr. Guy Fipps
http://twon.tamu.edu/fact-sheets/
.
Salinity Tolerance - Animals
PPM
0 - 3,000 O.K. for all livestock
3,000 – 4,999 Satisfactory, may result in temporary
refusal/diarrhea; poor quality for poultry
4,999 - 6,999 Reasonably safe, not for pregnant/
lactating animals
6,999 - 10,000 Risky to young, pregnant/lactating animals
or animals under heat stress
>10,000 Unsuitable for all livestock
Iron and Manganese
• Nuisance –unpleasant taste,
odor, and color
• Secondary MCL:
 Iron = 0.3 ppm
 Manganese = .05 ppm
• Stains- Iron (reddish brown)
Manganese (brownish black)
on concrete, laundry, and
plumbing fixtures
Iron and Manganese Treatment
Treatment depends on type and
concentration
• Initially clear, but particles form
and settle out
• Water from tap has solid
particles or has a tint
• Iron/manganese bacteria-
reddish or black slime in toilet
or faucets.
Treatment: Phosphate injection, water softener, oxidizing filter, aeration/filtration,
shock treatment and filtration
Hydrogen Sulfide
• Colorless gas with a “rotten egg” odor
• Formed by sulfur- and sulfate-reducing bacteria that can occur
naturally in groundwater
• Shallow or poorly constructed wells
• Wells drilled in shale, sandstone, near coal or oil fields
Hydrogen Sulfide (H2S) Treatment
• If the smell is only from the hot water faucet, problem likely is in
the water heater
 Ensure the water heater is set according to manufacturer’s
recommendation – often 140o will help. Careful of scalding.
 Problem might be caused by a chemical reaction with the
magnesium control rod (anode)
o Can be removed or replaced with an aluminum or zinc rod.
 Consider a tankless heater.
• If the smell is coming from both hot and cold faucets, but only
from water treated by a water softener and not in the untreated
water, problem likely is sulfur bacteria in the water softener.
 Hire a water treatment specialist to clean the water softener.
Hydrogen Sulfide (H2S) Treatment
• If the smell is strong when the water in both the hot and cold faucets
is first turned on, and becomes weaker or goes away after the water
has run for a while, or if the smell varies over time, the problem is
likely sulfur bacteria in the well or plumbing system.
 If from sulfur-reducing bacteria, shock chlorination may treat;
could follow with a UV filter OR manganese greensand filter (up
to 10 ppm) or continuous chlorination system (6 to 75 ppm)
• If the smell is strong when you first turn on the water in both the hot
and cold faucets and is more or less constant and persists with use,
the problem likely is H2S in the groundwater that supplies the well.
 A whole house carbon filter may remove enough (GAC up to 1
ppm and Catalytic C “more” depending on DO).
 Aeration tank, early-style pressure tank bladder (up to 2 ppm)
Hydrogen Sulfide (H2S) Treatment
What to Test for: Nearby Land Use
Problem Type Symptoms Recommended Test
Leaking fuel tank Hydrocarbon scan, VOCs
Landfills TDS, pH, heavy metals
Gas or oil drilling
TDS, chloride, sodium, barium, lead,
pH, corrosivity, strontium
Coal mining
TDS, iron, sulfate, pH, corrosivity,
manganese, aluminum
Septic system failure Fecal coliform/E. coli , nitrate
Intensive agricultural use
Total coliform, nitrate, pesticide
scan, pH, TDS
If suspect or observe
What to Test for: Nuisance Problems
Problem Type Symptoms Recommended Test
Red or brown Iron
Black Manganese
Reddish-brown slime Iron bacteria
White deposits, soap scum Hardness
Rotten egg Hydrogen sulfide
Metallic pH, iron, zinc, copper, lead
Salty TDS, chloride, sodium
Septic, musty, earthy Coliform bacteria, iron, methane
Gasoline or oil Hydrocarbon scan, VOCs
Soapy Surfactants, detergents
Brown, yellow, reddish Iron
Cloudy Turbidity, suspended solids
Black Manganese
Stains on Fixtures or
Plumbing
Odor or Taste
Appearance of water
What to test for: Health Concerns
Problem Type Symptoms Recommended Test
Gastrointestinal illness
coliform bacteria,
sulfates, Giardia
Water supplies used for infants less
than six months old, pregnant or
nursing women, or elderly with
genetically impaired enzyme system
Nitrates
Family member on recommended
low-sodium diet Sodium
Dicoloration of children's teeth Fluoride
Uses or
Symptoms
Questions?
Water Treatment Options
Water Treatment Options
• Particle and microfiltration
• Activated carbon filter
• Reverse osmosis
• Distillation
• Ion exchange – water
softening
• Disinfection
• Continuous chlorination
• Ultraviolet light
Water Treatment
• Test your well
• Locate contamination source if
possible
• Check well construction
• Inspect septic system
• Eliminate source of
contamination
• Consider drilling new well
Point of Entry (POE)
Treats water as it enters a
home, whole house
Point of use (POU)
Installed at the faucet
Licensed Water Treatment Specialists
www.tceq.state.tx.us/
Licensed Water Treatment Specialists
www.tceq.state.tx.us/
www2.tceq.texas.gov/lic_dpa/index.cfm
Licensed Water Treatment Specialists
Licensed Water Treatment Specialists
www2.tceq.texas.gov/lic_dpa/index.cfm
Licensed Water Treatment Specialists
• Fecal coliform/E. coli bacteria
 Indicator bacteria
 Indicates risk from other disease-causing organisms
 E. coli from human and animal digestive systems
• Iron, manganese, and sulfur-reducing bacteria
 Nuisance bacteria, not a health risk
Bacteria
Shock Chlorination
• Method of disinfecting a water well
• Not a long term solution – does not address source
• Should be done anytime well system is “opened”
• Recommended to contact a licensed well driller
• If homeowner does it, make sure to follow correct procedure
Treating Bacteria
Shock Chlorination of Stored Water
• Check to see if storage tank is the source
• Determine the correct amount of chlorine
Treating Bacteria
Continuous Chlorination
• Requires “contact time”
• Professionally installed
Treating Bacteria
• Disinfection by-products
Ultraviolet systems (UV)
• Disrupts bacteria life cycle
• More effective than chlorine
• Low cost to operate
• Easy to maintain
• No taste or odor
Treating Bacteria
• Filtration
 Several types of filters
 Remove suspended solids
 Filters are made to remove specific particles sizes
 Can be used prior to other water treatments
Filtration
Filtration
Media Filters
 Used for suspended solids
 Often used prior to other water treatment devices
 Requires back
flushing
 Point-of-Entry
Cartridges
 Primarily used
for suspended
solids
 Sized by pore
space and flow
rate
Filtration
 Replace filters to avoid clogging
 Size by targeted contaminant
Activated Carbon Filters
• Coal or charcoal surface absorbs contaminants
• Processed to make large surface area available for adsorption
or chemical reaction
• Replace carbon regularly
• Point-of-use
• Most common
May treat:
― Chlorine
― Color
― Lead
― Radon
― Taste and odor
Reverse Osmosis (RO)
• Effective for a variety of
contaminants
• Pressure forces water
through a membrane
• Point-of-use
• Could overwhelm septic
Problem
Pollutants
Aluminum, Arsenic, Asbestos, Barium, Cadmium, Chloride,
Chlorine, Chromium, Copper, Fluoride, Iron, Hardness, Lead,
Magnesium, Manganese, Mercury, Nitrate, Radium, Radon,
Silver, Sodium, Sulfate, Endrin, Heptachlor, Lindane
Ion Exchange – Water Softener
Water softeners
• Calcium and magnesium ions exchanged with
sodium or potassium
• Can remove some dissolved metals
• Will not remove particles, pathogens, organic
chemicals
• Works best if water has been pre-filtered
Resources on specific water quality issues available
through: twon.tamu.edu and agrilifebookstore.org
Questions?

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Water Quality, Testing and Treatment Trinity River Authority July 2021.pdf

  • 1. SESSION 3: Water Quality, Testing and Treatment
  • 2. Water Quality and Testing  Drinking water standards  Common contaminants  Testing  Why?  When?  What?
  • 3. Drinking Water Quality  Federal Safe Drinking Water Act, 1974 (SDWA):  Establishes standards for surface and groundwater sources used for drinking water.  EPA sets standards based on whether a contaminant: 1. Harms human health 2. Is known to occur in drinking water 3. Can be detected in drinking water  TCEQ is required to enforce the SDWA Water Quality Law and Policy
  • 4. Texas Private Well Regulations • Well location requirements • Well construction • No requirements for water testing or maintenance after construction Water Supply Regulations EPA – National Drinking Water Standards • Public water systems • Primary Standards – Health • Secondary Standards – Nuisance • Can be used as a guide for your private well.
  • 5. Secondary Standards • Secondary standards, or SMCL • Set for aesthetic considerations  Taste  Color  Odor • 15 contaminants • Examples:  Iron  Sulfate  TDS EPA Drinking Water Standards Primary Standards • Maximum Contaminant Level, or MCL • Pose risks to human health • Over 80 contaminants • Examples:  Nitrate  E. coli  Arsenic  Organic chemicals and pesticides
  • 6. Summary of Screening Results Number of samples screened: 11 Positives coliform: 5 (45%) Positives E. coli: 0 Nitrate average (ppm): 0.5 Range: 0 - 2 Salinity average (ppm TDS): 578 Range: 380 - 901 pH average: 8.1 Range: 7.8 – 8.4
  • 7. Water Well Testing FAQs How often should the well be tested? • Annually for bacteria • Every few years for general chemistry such as nitrates and salts • As frequently as needed for other contaminants of concern How much will it cost? • Varies depending on analyses selected. • Basic E. coli test should be less than $30
  • 8. Private Well Testing Drinking Water Testing: • County Health Departments and River Authorities • NELAC-certified labs on TCEQ website  http://www.tceq.texas.gov/goto/certified_labs  512-239-3754
  • 9. Private Well Testing for E. coli and Other Concerns
  • 10. Private Well Testing Irrigation and Livestock: Texas AgriLife Extension Service Soil, Water and Forage Testing Laboratory at TAMU (http://soiltesting.tamu.edu/)
  • 13. Fecal Bacteria  Microscopic organisms found in feces of humans and other warm-blooded animals  Not all are harmful by themselves  Indicator organisms: indicate presence of pathogenic bacteria, viruses, parasites  E. coli is the most commonly tested
  • 14. Why Check for E. coli? • Indicator bacteria  Indicates disease risk from other organisms that are pathogenic • Cost effective • MCL (maximum contaminant level) is 0 colonies/100 ml • Test annually and each time the well is opened or repaired
  • 15. HUMANS 50 FT. MINIMUM SEPARATION 100 FT. MINIMUM SEPARATION DRAIN/SPRAY FIELD Sources of Bacteria
  • 16. LIVESTOCK • 150 FT. MINIMUM SEPARATION • DOWN SLOPE FROM WELL Sources of Bacteria
  • 17. DOMESTIC ANIMALS 150 FT. MINIMUM SEPARATION FROM PENS, YARDS AND RUNS Sources of Bacteria
  • 18. Nitrate • Methemoglobinemia (blue baby syndrome)  Pregnant/ nursing women  Infants  Elderly/ suppressed immune systems • Sources: natural sources, fertilizer, animal waste, sewage Treatment: reverse osmosis, ion exchange, distillation
  • 20. Sources of Nitrates HUMANS 50 FT. MINIMUM SEPARATION 100 FT. MINIMUM SEPARATION DRAIN/SPRAY FIELD
  • 21. FERTILIZER Sources of Nitrates STORAGE: 150 FT. MINIMUM SEPARATION
  • 22. ANIMAL WASTE Sources of Nitrates • 150 FT. SEPARATION FOR PETS AND LIVESTOCK • WILDLIFE: NO GUIDELINES
  • 23. • Level of dissolved minerals, including salts • More than 500 ppm tastes salty • Sodium is often referred to as a measure of salinity, most common cause of high TDS in Texas Total Dissolved Solids (TDS)
  • 24. . Salinity Tolerance - Plants PPM 0 - 175 Excellent, no risk to plants 175 – 525 Good, not for sensitive plants 525 – 1,400 Permissible, not for low salt tolerant plants 1,400 – 2,100 Doubtful, damage to high salt tolerant plants >2,100 Unsuitable
  • 26. . Salinity Tolerance - Animals PPM 0 - 3,000 O.K. for all livestock 3,000 – 4,999 Satisfactory, may result in temporary refusal/diarrhea; poor quality for poultry 4,999 - 6,999 Reasonably safe, not for pregnant/ lactating animals 6,999 - 10,000 Risky to young, pregnant/lactating animals or animals under heat stress >10,000 Unsuitable for all livestock
  • 27. Iron and Manganese • Nuisance –unpleasant taste, odor, and color • Secondary MCL:  Iron = 0.3 ppm  Manganese = .05 ppm • Stains- Iron (reddish brown) Manganese (brownish black) on concrete, laundry, and plumbing fixtures
  • 28. Iron and Manganese Treatment Treatment depends on type and concentration • Initially clear, but particles form and settle out • Water from tap has solid particles or has a tint • Iron/manganese bacteria- reddish or black slime in toilet or faucets. Treatment: Phosphate injection, water softener, oxidizing filter, aeration/filtration, shock treatment and filtration
  • 29. Hydrogen Sulfide • Colorless gas with a “rotten egg” odor • Formed by sulfur- and sulfate-reducing bacteria that can occur naturally in groundwater • Shallow or poorly constructed wells • Wells drilled in shale, sandstone, near coal or oil fields
  • 30. Hydrogen Sulfide (H2S) Treatment • If the smell is only from the hot water faucet, problem likely is in the water heater  Ensure the water heater is set according to manufacturer’s recommendation – often 140o will help. Careful of scalding.  Problem might be caused by a chemical reaction with the magnesium control rod (anode) o Can be removed or replaced with an aluminum or zinc rod.  Consider a tankless heater. • If the smell is coming from both hot and cold faucets, but only from water treated by a water softener and not in the untreated water, problem likely is sulfur bacteria in the water softener.  Hire a water treatment specialist to clean the water softener.
  • 31. Hydrogen Sulfide (H2S) Treatment • If the smell is strong when the water in both the hot and cold faucets is first turned on, and becomes weaker or goes away after the water has run for a while, or if the smell varies over time, the problem is likely sulfur bacteria in the well or plumbing system.  If from sulfur-reducing bacteria, shock chlorination may treat; could follow with a UV filter OR manganese greensand filter (up to 10 ppm) or continuous chlorination system (6 to 75 ppm) • If the smell is strong when you first turn on the water in both the hot and cold faucets and is more or less constant and persists with use, the problem likely is H2S in the groundwater that supplies the well.  A whole house carbon filter may remove enough (GAC up to 1 ppm and Catalytic C “more” depending on DO).  Aeration tank, early-style pressure tank bladder (up to 2 ppm)
  • 33. What to Test for: Nearby Land Use Problem Type Symptoms Recommended Test Leaking fuel tank Hydrocarbon scan, VOCs Landfills TDS, pH, heavy metals Gas or oil drilling TDS, chloride, sodium, barium, lead, pH, corrosivity, strontium Coal mining TDS, iron, sulfate, pH, corrosivity, manganese, aluminum Septic system failure Fecal coliform/E. coli , nitrate Intensive agricultural use Total coliform, nitrate, pesticide scan, pH, TDS If suspect or observe
  • 34. What to Test for: Nuisance Problems Problem Type Symptoms Recommended Test Red or brown Iron Black Manganese Reddish-brown slime Iron bacteria White deposits, soap scum Hardness Rotten egg Hydrogen sulfide Metallic pH, iron, zinc, copper, lead Salty TDS, chloride, sodium Septic, musty, earthy Coliform bacteria, iron, methane Gasoline or oil Hydrocarbon scan, VOCs Soapy Surfactants, detergents Brown, yellow, reddish Iron Cloudy Turbidity, suspended solids Black Manganese Stains on Fixtures or Plumbing Odor or Taste Appearance of water
  • 35. What to test for: Health Concerns Problem Type Symptoms Recommended Test Gastrointestinal illness coliform bacteria, sulfates, Giardia Water supplies used for infants less than six months old, pregnant or nursing women, or elderly with genetically impaired enzyme system Nitrates Family member on recommended low-sodium diet Sodium Dicoloration of children's teeth Fluoride Uses or Symptoms
  • 36.
  • 39. Water Treatment Options • Particle and microfiltration • Activated carbon filter • Reverse osmosis • Distillation • Ion exchange – water softening • Disinfection • Continuous chlorination • Ultraviolet light
  • 40. Water Treatment • Test your well • Locate contamination source if possible • Check well construction • Inspect septic system • Eliminate source of contamination • Consider drilling new well Point of Entry (POE) Treats water as it enters a home, whole house Point of use (POU) Installed at the faucet
  • 41. Licensed Water Treatment Specialists www.tceq.state.tx.us/
  • 42. Licensed Water Treatment Specialists www.tceq.state.tx.us/ www2.tceq.texas.gov/lic_dpa/index.cfm
  • 44. Licensed Water Treatment Specialists www2.tceq.texas.gov/lic_dpa/index.cfm
  • 46. • Fecal coliform/E. coli bacteria  Indicator bacteria  Indicates risk from other disease-causing organisms  E. coli from human and animal digestive systems • Iron, manganese, and sulfur-reducing bacteria  Nuisance bacteria, not a health risk Bacteria
  • 47. Shock Chlorination • Method of disinfecting a water well • Not a long term solution – does not address source • Should be done anytime well system is “opened” • Recommended to contact a licensed well driller • If homeowner does it, make sure to follow correct procedure Treating Bacteria
  • 48. Shock Chlorination of Stored Water • Check to see if storage tank is the source • Determine the correct amount of chlorine Treating Bacteria
  • 49. Continuous Chlorination • Requires “contact time” • Professionally installed Treating Bacteria • Disinfection by-products
  • 50. Ultraviolet systems (UV) • Disrupts bacteria life cycle • More effective than chlorine • Low cost to operate • Easy to maintain • No taste or odor Treating Bacteria
  • 51. • Filtration  Several types of filters  Remove suspended solids  Filters are made to remove specific particles sizes  Can be used prior to other water treatments Filtration
  • 52. Filtration Media Filters  Used for suspended solids  Often used prior to other water treatment devices  Requires back flushing  Point-of-Entry
  • 53. Cartridges  Primarily used for suspended solids  Sized by pore space and flow rate Filtration  Replace filters to avoid clogging  Size by targeted contaminant
  • 54. Activated Carbon Filters • Coal or charcoal surface absorbs contaminants • Processed to make large surface area available for adsorption or chemical reaction • Replace carbon regularly • Point-of-use • Most common May treat: ― Chlorine ― Color ― Lead ― Radon ― Taste and odor
  • 55. Reverse Osmosis (RO) • Effective for a variety of contaminants • Pressure forces water through a membrane • Point-of-use • Could overwhelm septic Problem Pollutants Aluminum, Arsenic, Asbestos, Barium, Cadmium, Chloride, Chlorine, Chromium, Copper, Fluoride, Iron, Hardness, Lead, Magnesium, Manganese, Mercury, Nitrate, Radium, Radon, Silver, Sodium, Sulfate, Endrin, Heptachlor, Lindane
  • 56. Ion Exchange – Water Softener Water softeners • Calcium and magnesium ions exchanged with sodium or potassium • Can remove some dissolved metals • Will not remove particles, pathogens, organic chemicals • Works best if water has been pre-filtered
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  • 59.
  • 60. Resources on specific water quality issues available through: twon.tamu.edu and agrilifebookstore.org