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VSEP Brine Recovery
Orica Watercare – Tom Williams
June 2010
What is VSEP?

• Vibrating Separation
  Membrane System
• Conventional
  Polymeric
  Membranes
• Oscillating to create
  shear at the surface
How does VSEP work?

• Membrane filter is mounted on a
  resonating mechanical drive

•    A 20 hp drive motor spins an
    eccentric lobe. This drives a large
    steel mass at the bottom of the
    unit.
• Once speed increases to a specific
  rate, the whole system resonates
    at a given harmonic frequency.
• The result is 2cm peak to peak
  displacement at a rate of about
  50hz.
Introduction to VSEP




System Operation:
The system operates automatically via PLC controls and automated valves. The feed pump initiates at
system start up and spins up to speed. The modulating control valve on the concentrate outlets
throttles flow and applies back pressure in the system. Once pressure reaches 30 psi, the VSEP drive
motor to engages and spins up to the frequency setpoint where the filter pack will vibrate.
Introduction to VSEP
Introduction to VSEP
VSEP
Components:
Membrane units
are modular
and can be
used in parallel
or in series.
VSEP Brine Recovery
•   City of St Cloud - USA
•   Piloted June – Nov 2009
•   18 MLD plant
•   MIEX regen system uses
    55kg/ML of NaCl
•   Produces 1000litre/ML of waste
    brine at 1100bv
•   Brine concentration 300g/l
•   waste brine recycling can
    reduce overall salt consumption
    by around 49%                          A Six-Module VSEP System
                                             Six-

•   the amount of salt discharged
    to sewer can be reduced by
    over 70%
St Cloud Pilot Plant
Summary of Trial Results
 Run   Recovery   Feed            Permeate                         Concentration
 (*)   %
                                  Variable          % removed
                  DOC     SO4     DOC        SO4    DOC     SO4    DOC      SO4
                  mg/L    mg/L    mg/L       mg/L                  mg/L     mg/L
 2     70         2760    3400    49         290    98.2    91.5   11800    12000
 2     80                         78         500    97.2    85.3   17247    19733
 2     83                         46         1600   98.3    52.9   18000    17000
 3     67         4060    3500    54         280    98.7    92     12047    16880
 3     85                         70         1400   98.3    60     21147    23360
 4     71         3330    4300    72         333    97.8    92.2   13747
 4     80                         10         550    99.7    87.2   17647
 5     72         3397    5150    33         112    99      97.8   13947    23300
 8-1   75                         9          170
 8-2              22.5    222     0.5        50     97.8    77.5

*Each batch run was 1000 litres of waste brine with the unit operating at 350psi
and average flux rate of 40.2 gfd.
Conclusions
• The test results show that over 97% of the TOC was
  rejected by the NF membrane at waste recovery rates from
  67 to 85%.
• Photos of the samples show that increasing the recovery rate
  from 70 to 85% resulted in an increasing yellow-brown colour
  of the permeate.
• Sulphate proved to be the limiting constituent in determining
  the optimum recovery rate. Around 85-95% removal of
  sulphate was achieved up to a recovery rate of 80% which
  achieved the target permeate concentration of less than
  1000 mg/L. When the recovery rate was increased above
  80% the sulphate removal quickly reduced to 53-60%
  resulting in concentrations in the range of 1400-1600 mg/L.
Increasing % Recovery Photo

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Vsepweb

  • 1. VSEP Brine Recovery Orica Watercare – Tom Williams June 2010
  • 2. What is VSEP? • Vibrating Separation Membrane System • Conventional Polymeric Membranes • Oscillating to create shear at the surface
  • 3. How does VSEP work? • Membrane filter is mounted on a resonating mechanical drive • A 20 hp drive motor spins an eccentric lobe. This drives a large steel mass at the bottom of the unit. • Once speed increases to a specific rate, the whole system resonates at a given harmonic frequency. • The result is 2cm peak to peak displacement at a rate of about 50hz.
  • 4. Introduction to VSEP System Operation: The system operates automatically via PLC controls and automated valves. The feed pump initiates at system start up and spins up to speed. The modulating control valve on the concentrate outlets throttles flow and applies back pressure in the system. Once pressure reaches 30 psi, the VSEP drive motor to engages and spins up to the frequency setpoint where the filter pack will vibrate.
  • 6. Introduction to VSEP VSEP Components: Membrane units are modular and can be used in parallel or in series.
  • 7. VSEP Brine Recovery • City of St Cloud - USA • Piloted June – Nov 2009 • 18 MLD plant • MIEX regen system uses 55kg/ML of NaCl • Produces 1000litre/ML of waste brine at 1100bv • Brine concentration 300g/l • waste brine recycling can reduce overall salt consumption by around 49% A Six-Module VSEP System Six- • the amount of salt discharged to sewer can be reduced by over 70%
  • 9. Summary of Trial Results Run Recovery Feed Permeate Concentration (*) % Variable % removed DOC SO4 DOC SO4 DOC SO4 DOC SO4 mg/L mg/L mg/L mg/L mg/L mg/L 2 70 2760 3400 49 290 98.2 91.5 11800 12000 2 80 78 500 97.2 85.3 17247 19733 2 83 46 1600 98.3 52.9 18000 17000 3 67 4060 3500 54 280 98.7 92 12047 16880 3 85 70 1400 98.3 60 21147 23360 4 71 3330 4300 72 333 97.8 92.2 13747 4 80 10 550 99.7 87.2 17647 5 72 3397 5150 33 112 99 97.8 13947 23300 8-1 75 9 170 8-2 22.5 222 0.5 50 97.8 77.5 *Each batch run was 1000 litres of waste brine with the unit operating at 350psi and average flux rate of 40.2 gfd.
  • 10. Conclusions • The test results show that over 97% of the TOC was rejected by the NF membrane at waste recovery rates from 67 to 85%. • Photos of the samples show that increasing the recovery rate from 70 to 85% resulted in an increasing yellow-brown colour of the permeate. • Sulphate proved to be the limiting constituent in determining the optimum recovery rate. Around 85-95% removal of sulphate was achieved up to a recovery rate of 80% which achieved the target permeate concentration of less than 1000 mg/L. When the recovery rate was increased above 80% the sulphate removal quickly reduced to 53-60% resulting in concentrations in the range of 1400-1600 mg/L.