1
Sustainable phosphorus sources ready for the European market
Chris Thornton
European Sustainable
Phosphorus Platform
(ESPP)
info@phosphorusplatform.eu
www.phosphorusplatform.eu
@phosphorusfacts
2
Without mineral phosphate fertilisers
we could feed maybe 1/5th
of the current world population
Adapted from Dawson et al., Food Policy 2011:
http://www.sciencedirect.com/science/journal/03069192
Without mineral nitrogen fertilisers
we could support around 1/2
of world food production
Fertilizers Europe 2018, based on Erisman, Sutton et al.,
Nature Geoscience 2008 DOI: 10.1038/ngeo325
https://www.researchgate.net/publication/248828433_
How_a_century_of_ammonia_synthesis_changed_the_world
https://phosphorusalliance.org
3
200 – 260 million tonnes of
phosphate rock are mined annually
(17 - 24 Mt P)
95% of use is in agriculture:
- fertilisers
- animal feed
But phosphorus is also essential
(in much smaller quantities) for:
- fire safety
- electronics, batteries …
- water treatment
- chemicals and pharmaceuticals …
See ESPP Phosphorus Fact Sheet
www.phosphorusplatcorm.eu
4
3 July 2018
http://www.stockholmresilience.org
Baltic Sea
eutrophication,
source WWF
Eutrophication is a major environmental challenge:
• Phosphorus (P) = first cause of EU Water Framework Directive
(non-morphological) quality status failure
• 55% of rivers, 74% of lakes
exceed P level for good ecological status
• P discharge from sewage works
reduced by 70% 1987 - 1996
• 35% of EU surface waters bodies,
and 35% of EU groundwater areas
are impacted by ‘diffuse’ pollution
Sources: see “Phosphorus Fact Sheet”
on www.phosphorusplatform.eu
5
EU policies to address phosphorus:
from prevention to stewardship
• EU water policy
- Urban Waste Water Treatment Directive 1991/271
- Nitrates Directive 1991/676
- Water Framework Directive 2000/2000
- Groundwater Directive 2006/118
(P on monitoring list 2014)
• Common Agricultural Policy
- proposed FaST tool, 2019
• Critical Raw Materials list
- phosphate rock 2014
- white phosphorus (P4) 2017
• Circular Economy Package
- EU Fertilising Products Regulation, 2019
6
Why recycle phosphorus?
• Synergies
- reducing phosphorus losses to surface waters
- manure management / Nitrates Directive implementation
- reducing ammonia emissions
- improving sewage works operation
& biosolids management
- anaerobic digestion / renewable energy
- return of organic carbon to soil
- food waste
- water reuse
• Circular economy
- rural jobs
- reduce dependency on imports
- EU leadership in recycling
7
National legislation
• Switzerland 2016
- P-recycling obligation from sewage sludge
incineration ash and from animal by-products
- 2018 ordinance defines requirements
for recycled fertilisers
• Germany 2017
- P-recycling obligation from sewage
• Helcom 2017
- P-recycling strategy & reporting
• …
For details of Swiss and German legislation see ESPP Scope Newsletter n°129
http://www.phosphorusplatform.eu/scope129
and HELCOM see ESPP eNews n°9 http://www.phosphorusplatform.eu/eNews009
8
Recycling potential
• European Commission 1
STRUBIAS recycled products
could replace 25-40%
of EU mineral phosphate fertilisers
• European Commission 2
Phosphorus recycling could replace
30%
of EU mineral phosphate fertilisers
• i.e. market value of recycled
phosphates of c. 600 M€ 3
1 = JRC STRUBIAS draft « Market » report 20/12/2017
2 = IP/18/6161 http://europa.eu/rapid/press-release_IP-18-6161_en.htm
3 = ESPP estimate
P recycling potential in EU-27
[kton P/year] Total Recycled Potential
Sewage sludge 297 115 182
Biodegradable solid waste 130 38 92
Meat & bone meal 128 6 122
Total 427-555 153-160 274-396
Manure recycling = 1 736
Mineral fertiliser use = 1 448
Van Dijk et al. “Phosphorus flows and balances of the European Union Member States”, Science of
the Total Environment Volume 542, Part B, 15 January 2016, Pages 1078-1093
http://dx.doi.org/10.1016/j.scitotenv.2015.08.048
9
Recycling routes
today demonstrated /operational
• Manure / food industry by-products organic fertilisers
• Sewage biosolids  composting / digestion  agriculture
• Animal by-product incineration ash  fertiliser
• Sewage sludge incineration ash  technical phosphates
• Sewage sludge incineration ash  fertiliser industry
• Manure  biochar  fertiliser
• Struvite precipitation from sewage  fertiliser
• Wastewater  algae  organic fertilisers
COOPERL / Brittany farmers’ cooperatives. 400 000 t/y
manure processed to organic fertiliser product
ww.phosphorusplatform.eu/scope122
Géotexia, Saint Gilles du Mené, Brittany. Methanisation of
70 000 t/y pig manure. French fertiliser homologation
obtained for digestate 2013
https://www.anses.fr/sites/default/files/documents/FERTIXIA
NK_FSIM_2013-0856_Ans.pdf
10
Veolia UK: fertilisers from wastes
Pro-Grow:
• 10 UK composting sites producing 200 000 t/year soil conditioners
from green & food wastes
• All grades have “product” status and PAS100 certified
Granulation factory at Livingstone, near Edinburgh
Capacity 20 000 t/y
Currently:
fertilisers from food industry by-product ashes
liming materials
micro-nutrient fertilisers
Under development: recycled fertilisers
11
EasyMining Sweden Ash2Phos®
• P-recovery from sewage sludge incineration ash & iron ore tailings
 CleanMAP® = technical grade MAP (mono ammonium phosphate)
 plus iron and aluminium salts & silica/cement by-product
• Pilot plant sewage sludge ash Helsingborg (2018) = up to 0,6t/h
• Pilot plant iron mining tailings, underway (25 kg/h)
• Full scale plant construction starting 2019
12
Yara : nitrogen recovery
from municipal waste, Oslo
• Ammonia stripping
in VEAS municipal waste anaerobic digester
650 000 t/y municipal waste
• 12-15% of input nitrogen recovered as ammonium nitrate
http://www.circulary.eu/project/yara-recovery/
13
Thames Water – Ostara Pearl®
• Slough municipal wastewater treatment plant, UK, since 2013
• 150 tonnes Crystal Green® fertiliser / year
• High quality slow release fertiliser
• Today also plants in Spain, Netherland.
• 18 plants operational worldwide
www.ostara.com and www.phosphorusplatform.eu/scope99
https://www.aljazeera.com/programmes/earthrise/2014/12/recyc
ling-phosphorus-2014121693225616272.html
14
Timac AGRO – Roullier Group:
specific maize starter fertiliser including struvite
• Fertiliser industry added-value for recycled nutrients
• Recovered struvite from industries
• Non-burning, enabling “ultra localisation” next to roots
• Micro-granulation
• Specific balanced formulation for maize nutrition
15
ICL fertilisers Amsterdam & Ludwigshaven
• Use of secondary materials
in fertiliser production:
- meat and bone meal ash
- struvite
• Objective: 100% by 2025
• Pilot testing successful
• Industrial installations
(storage, handling) planned
www.icl-group.com
16
Ecophos P-recycling from sewage sludge ash
• Pilot plant operational Varna, Bulgaria
• Production of DCP (Di Calcium Phosphate) for fertilisers, animal feed
• Dunkerque, France
• First line operational since 1/2018: 220 000 t/y DCP from low grade P-rock
• Second line in authorisation phase:
100 000 t/y of sewage sludge incineration ash
and other secondary raw materials
• Contract 60 000 t/y ash from Netherlands
(SNB – HVC Groep)
See SCOPE Newsletter 111 and www.ecophos.com
17
Suez Phosphogreen
• Struvite recovery from sewage
• Biological P removal sewage works
with anaerobic sludge digestion
- 2013, Aby wwtp, Aarhus, 84 000 p.e.
- 2015, Herning, Denmark, 150 000 p.e.
- 2017, Marselisborg, Denmark 200 000p.e.
• Advantages
- struvite sale: 250€ - 300€ /tonne
- reduced P-removal chemical costs
- avoidance of nuisance deposits
- reduced sludge volumes
- reduced energy consumption for biological N removal
https://www.suezwaterhandbook.com/degremont-R-
technologies/sludge-treatment/recovery/recycle-phosphorus-from-
effluent-to-produce-a-valuable-fertilizer-Phosphogreen
18
Why the EU Fertilising Products Regulation (FPR) is essential
- Open EU markets for recycled nutrient products
- European market for organic fertilisers, biostimulants …
- Open EU market for nutrient recycling technologies
- Continuation of markets for ‘national’ fertilisers
Challenges to address :
- Add STRUBIAS to FPR annexes (struvite, biochar, ashes)
= products already on the market
- Clarify Nitrates Directive status of recycled products
(DG ENVI ‘SafeManure’ project)
- Address consumer and food industry / supermarket
concerns about contaminants  European initiative?
- Cost of recycling: transfer tax from labour to resources
19
Sustainable phosphorus sources ready for the European market
Chris Thornton
European Sustainable
Phosphorus Platform
(ESPP)
info@phosphorusplatform.eu
www.phosphorusplatform.eu
@phosphorusfacts

Sustainable phosphorus sources ready for the European market - EU GreenWeek 2019 event Sustainable fertilisers: greener practices to be promoted by the upcoming Fertilising Products Regulation, 16 May 2019

  • 1.
    1 Sustainable phosphorus sourcesready for the European market Chris Thornton European Sustainable Phosphorus Platform (ESPP) info@phosphorusplatform.eu www.phosphorusplatform.eu @phosphorusfacts
  • 2.
    2 Without mineral phosphatefertilisers we could feed maybe 1/5th of the current world population Adapted from Dawson et al., Food Policy 2011: http://www.sciencedirect.com/science/journal/03069192 Without mineral nitrogen fertilisers we could support around 1/2 of world food production Fertilizers Europe 2018, based on Erisman, Sutton et al., Nature Geoscience 2008 DOI: 10.1038/ngeo325 https://www.researchgate.net/publication/248828433_ How_a_century_of_ammonia_synthesis_changed_the_world https://phosphorusalliance.org
  • 3.
    3 200 – 260million tonnes of phosphate rock are mined annually (17 - 24 Mt P) 95% of use is in agriculture: - fertilisers - animal feed But phosphorus is also essential (in much smaller quantities) for: - fire safety - electronics, batteries … - water treatment - chemicals and pharmaceuticals … See ESPP Phosphorus Fact Sheet www.phosphorusplatcorm.eu
  • 4.
    4 3 July 2018 http://www.stockholmresilience.org BalticSea eutrophication, source WWF Eutrophication is a major environmental challenge: • Phosphorus (P) = first cause of EU Water Framework Directive (non-morphological) quality status failure • 55% of rivers, 74% of lakes exceed P level for good ecological status • P discharge from sewage works reduced by 70% 1987 - 1996 • 35% of EU surface waters bodies, and 35% of EU groundwater areas are impacted by ‘diffuse’ pollution Sources: see “Phosphorus Fact Sheet” on www.phosphorusplatform.eu
  • 5.
    5 EU policies toaddress phosphorus: from prevention to stewardship • EU water policy - Urban Waste Water Treatment Directive 1991/271 - Nitrates Directive 1991/676 - Water Framework Directive 2000/2000 - Groundwater Directive 2006/118 (P on monitoring list 2014) • Common Agricultural Policy - proposed FaST tool, 2019 • Critical Raw Materials list - phosphate rock 2014 - white phosphorus (P4) 2017 • Circular Economy Package - EU Fertilising Products Regulation, 2019
  • 6.
    6 Why recycle phosphorus? •Synergies - reducing phosphorus losses to surface waters - manure management / Nitrates Directive implementation - reducing ammonia emissions - improving sewage works operation & biosolids management - anaerobic digestion / renewable energy - return of organic carbon to soil - food waste - water reuse • Circular economy - rural jobs - reduce dependency on imports - EU leadership in recycling
  • 7.
    7 National legislation • Switzerland2016 - P-recycling obligation from sewage sludge incineration ash and from animal by-products - 2018 ordinance defines requirements for recycled fertilisers • Germany 2017 - P-recycling obligation from sewage • Helcom 2017 - P-recycling strategy & reporting • … For details of Swiss and German legislation see ESPP Scope Newsletter n°129 http://www.phosphorusplatform.eu/scope129 and HELCOM see ESPP eNews n°9 http://www.phosphorusplatform.eu/eNews009
  • 8.
    8 Recycling potential • EuropeanCommission 1 STRUBIAS recycled products could replace 25-40% of EU mineral phosphate fertilisers • European Commission 2 Phosphorus recycling could replace 30% of EU mineral phosphate fertilisers • i.e. market value of recycled phosphates of c. 600 M€ 3 1 = JRC STRUBIAS draft « Market » report 20/12/2017 2 = IP/18/6161 http://europa.eu/rapid/press-release_IP-18-6161_en.htm 3 = ESPP estimate P recycling potential in EU-27 [kton P/year] Total Recycled Potential Sewage sludge 297 115 182 Biodegradable solid waste 130 38 92 Meat & bone meal 128 6 122 Total 427-555 153-160 274-396 Manure recycling = 1 736 Mineral fertiliser use = 1 448 Van Dijk et al. “Phosphorus flows and balances of the European Union Member States”, Science of the Total Environment Volume 542, Part B, 15 January 2016, Pages 1078-1093 http://dx.doi.org/10.1016/j.scitotenv.2015.08.048
  • 9.
    9 Recycling routes today demonstrated/operational • Manure / food industry by-products organic fertilisers • Sewage biosolids  composting / digestion  agriculture • Animal by-product incineration ash  fertiliser • Sewage sludge incineration ash  technical phosphates • Sewage sludge incineration ash  fertiliser industry • Manure  biochar  fertiliser • Struvite precipitation from sewage  fertiliser • Wastewater  algae  organic fertilisers COOPERL / Brittany farmers’ cooperatives. 400 000 t/y manure processed to organic fertiliser product ww.phosphorusplatform.eu/scope122 Géotexia, Saint Gilles du Mené, Brittany. Methanisation of 70 000 t/y pig manure. French fertiliser homologation obtained for digestate 2013 https://www.anses.fr/sites/default/files/documents/FERTIXIA NK_FSIM_2013-0856_Ans.pdf
  • 10.
    10 Veolia UK: fertilisersfrom wastes Pro-Grow: • 10 UK composting sites producing 200 000 t/year soil conditioners from green & food wastes • All grades have “product” status and PAS100 certified Granulation factory at Livingstone, near Edinburgh Capacity 20 000 t/y Currently: fertilisers from food industry by-product ashes liming materials micro-nutrient fertilisers Under development: recycled fertilisers
  • 11.
    11 EasyMining Sweden Ash2Phos® •P-recovery from sewage sludge incineration ash & iron ore tailings  CleanMAP® = technical grade MAP (mono ammonium phosphate)  plus iron and aluminium salts & silica/cement by-product • Pilot plant sewage sludge ash Helsingborg (2018) = up to 0,6t/h • Pilot plant iron mining tailings, underway (25 kg/h) • Full scale plant construction starting 2019
  • 12.
    12 Yara : nitrogenrecovery from municipal waste, Oslo • Ammonia stripping in VEAS municipal waste anaerobic digester 650 000 t/y municipal waste • 12-15% of input nitrogen recovered as ammonium nitrate http://www.circulary.eu/project/yara-recovery/
  • 13.
    13 Thames Water –Ostara Pearl® • Slough municipal wastewater treatment plant, UK, since 2013 • 150 tonnes Crystal Green® fertiliser / year • High quality slow release fertiliser • Today also plants in Spain, Netherland. • 18 plants operational worldwide www.ostara.com and www.phosphorusplatform.eu/scope99 https://www.aljazeera.com/programmes/earthrise/2014/12/recyc ling-phosphorus-2014121693225616272.html
  • 14.
    14 Timac AGRO –Roullier Group: specific maize starter fertiliser including struvite • Fertiliser industry added-value for recycled nutrients • Recovered struvite from industries • Non-burning, enabling “ultra localisation” next to roots • Micro-granulation • Specific balanced formulation for maize nutrition
  • 15.
    15 ICL fertilisers Amsterdam& Ludwigshaven • Use of secondary materials in fertiliser production: - meat and bone meal ash - struvite • Objective: 100% by 2025 • Pilot testing successful • Industrial installations (storage, handling) planned www.icl-group.com
  • 16.
    16 Ecophos P-recycling fromsewage sludge ash • Pilot plant operational Varna, Bulgaria • Production of DCP (Di Calcium Phosphate) for fertilisers, animal feed • Dunkerque, France • First line operational since 1/2018: 220 000 t/y DCP from low grade P-rock • Second line in authorisation phase: 100 000 t/y of sewage sludge incineration ash and other secondary raw materials • Contract 60 000 t/y ash from Netherlands (SNB – HVC Groep) See SCOPE Newsletter 111 and www.ecophos.com
  • 17.
    17 Suez Phosphogreen • Struviterecovery from sewage • Biological P removal sewage works with anaerobic sludge digestion - 2013, Aby wwtp, Aarhus, 84 000 p.e. - 2015, Herning, Denmark, 150 000 p.e. - 2017, Marselisborg, Denmark 200 000p.e. • Advantages - struvite sale: 250€ - 300€ /tonne - reduced P-removal chemical costs - avoidance of nuisance deposits - reduced sludge volumes - reduced energy consumption for biological N removal https://www.suezwaterhandbook.com/degremont-R- technologies/sludge-treatment/recovery/recycle-phosphorus-from- effluent-to-produce-a-valuable-fertilizer-Phosphogreen
  • 18.
    18 Why the EUFertilising Products Regulation (FPR) is essential - Open EU markets for recycled nutrient products - European market for organic fertilisers, biostimulants … - Open EU market for nutrient recycling technologies - Continuation of markets for ‘national’ fertilisers Challenges to address : - Add STRUBIAS to FPR annexes (struvite, biochar, ashes) = products already on the market - Clarify Nitrates Directive status of recycled products (DG ENVI ‘SafeManure’ project) - Address consumer and food industry / supermarket concerns about contaminants  European initiative? - Cost of recycling: transfer tax from labour to resources
  • 19.
    19 Sustainable phosphorus sourcesready for the European market Chris Thornton European Sustainable Phosphorus Platform (ESPP) info@phosphorusplatform.eu www.phosphorusplatform.eu @phosphorusfacts