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1000 0569/2011 /027( 02) 0433 50                    A cta P etro log ica Sinica 岩石 学报




                                                                                                                                           *




夏琼霞             郑永飞
X I Q iongX ia and ZHENG Y ongF e i
  A

                                                ,                                             ,         230026
CAS K ey L abora tory of C rust M an tleM a terials and Env ironm en ts S ch ool of Earth and Space S cien ces U niversity of S cience and T echnology of Ch ina,
                                                                      ,                                      ,
  H ef ei 230026, Ch ina
2010 11 10 收稿, 2011 01 06 改回



X ia QX and Zheng YF 2011 The composition and ch e ical zon ing in garnet from h igh to u ltrah igh pressure m etam orph ic
                                                      m
rock s A cta Petrolog ica S in ica, 27( 2) : 433- 450


Abstrac t      G arne t is comm on in eclog ite and gne iss of high pressure ( HP ) to u ltrah igh pressure ( UH P) m eta orph ic or ig in It can
                                                                                                                          m
be we ll preserved during subduc tion zone m eta orphism fo r its h igh re frac to riness and low so lubility in flu id and m e lt The che ica l
                                                  m                                                                                        m
composition and m ineral inc lusions preserv ed in garnet can be used to constra in the P T cond itions, m eta orph ic evo lution, and fluid
                                                                                                                  m
action T he che ica l composition o f garne t is re lated to m any factors such as who le rock co pos ition, P T conditions g arnet fo r ing
                 m                                                       ,                          m                          ,            m
m eta o rph ic reactions and the asse blag e of coex isting m inerals T hus the m ajor e le ents trace e lem ents, oxygen iso topes m inera l
     m                                 m                                                   m     ,                                   ,
inc lusions and the ir re lations in garnet should all be taken into accoun t when it is used to constra in the me ta orphic P T evo lu tion in
                                                                                                                      m
UHP m etamo rph ic rocks In add ition, in situ analyses o fU Pb isotopes and trace e lements in accesso ry m inera ls such as zircon and /o r
m onazite inc lusions in garne t can place a direct constra int on the ti e o f m eta orphic garne t grow th T hrough study ing the history of
                                                                        m            m
ga rnet gro th dur ing subduc tion zone m eta orphism, it can not on ly prov ide pe tro log ic and geochem ica l ev idence for the processes to
           w                                   m
produce garne t bear ing m eta o rph ic ro cks but also g ive c lues to the orig in o f garnet T hese a re ve ry i portant to the che ica l
                              m              ,                                                                   m                   m
dyna ics o f subduction zone m eta o rph ism
    m                              m
K ey word s      G arnet H P /UHP m etamo rph is O r ig in; Chem ical zon ing Inclusions
                        ;                        m;                           ;

               在俯冲带 变质过程中, 石榴石是高压 超高压变质榴 辉岩和片麻 岩的常见 变质矿物                                                                       由于 石榴石具 有难熔 和流体
中的低溶解能力的特点, 通常可以很好地保存下来, 并且能够保留复杂的化学成 分环带, 以及不同 类型的矿 物或流体包 裹体,
为解释石榴石寄主岩石经历的 变质演化历史提供了重要信息                                                        石榴子石的主微 量元素成分 受控于很多 因素, 如全岩成 分 变
质的温压条件 控制石榴子石形成的相关变质反应 与石 榴子石 共生的 矿物种 类和成 分等                                                                               因此, 在 利用石榴 石探讨 超高压
变质的演化历史时, 对石榴石进行系统 的主要 元素 微 量元素 氧 同位 素以 及矿物 包裹 体分析, 以 及相 互间的 成因 关系                                                                                                  同
时, 对石榴石中的锆石或独居石包裹体并进行原位 U Pb定 年和微 量元素分 析, 可以为 变质石 榴石的 形成时代 提供直 接的时
间制约         深入研究超高压变质岩中石榴 石的生长阶段, 不仅可以 为含石 榴石寄 主岩石 的变质 过程提 供岩石学 和地球 化学证
据, 而且对于理解石榴石的形成机制 生长规律及其变质化学动力学过程具有重要的科学意义
               石榴石; 高压 /超 高压变质; 成因机制; 环带; 包裹体
                            P578 947




   *                  973        ( 2009CB825004 )                                  ( 40921002 41003014 )               .
                        :         ,    , 1979       ,     ,                 , E m ai:l qxxia ustc. edu cn
                                                                                           @          .
434                                                                                                         A cta P etro log ica Sinica 岩石学报              2011, 27( 2)




     1 X ray                     Austroalpine         W lz                               ( 12F03)
 ( a) ( d)         12F03                          X                      ; ( e)        ( c)                                          (    G aid ies et a l , 2008)
                                                                                                                                                         .
 F ig 1 X ray m aps of a prog rade garnet porphy roblast of m etape lite 12F 03 from the W lz Comp lex in A ustroa lp ine basem ent
     .
 ( a) ( d) X ray m aps of a gar et porphyrob last from samp le 12F03 Th e locat ion of the com positional prof ile A B as illu strated in ( c) is show n in ( e)
                              n                                     ;
 ( m od ified after G aid ies e t al. , 2008)


                                                                                              ( Spear
                                                                                                    ,     1993 M enard and Spear
                                                                                                             ;                 ,               1993;    G a id ies et al ,
                                                                                                                                                                       .
                                                                                              2006)           ,
1 引言                                                                                                                                       ,

                                 S                               ,                                                                                                   ( Spear
                                                                                              and Se lverstone 1983; M enard and Spear 1993; A yres and
                                                                                                             ,                       ,

     ,                                                                       ,                V ance 1997 Ca rsw e ll et al. ,
                                                                                                   ,    ;                            1997,      2000;     Enam , 1998;
                                                                                                                                                               i
                                                                                              Cooke et al. , 2000; E scuder V iruete et al , 2000 K ing et al ,
                                                                                                                                         .      ;           .
                                     ,                               ,
                                     ( Loo is et al. , 1985; Chakrabo rty
                                          m                                                   2004; K onrad Schm o lke et al. , 2006, 2008a ),

and G angu ly 1992 V ielzeuf et al , 2007),
             ,   ;               .                                                                           ( L asaga and Jiang 1995; V ance 1995 G angu ly
                                                                                                                                ,            ,   ;

                            ,                                                                 et al. ,   1996; G r iffin et al. , 1996;    Perchuck et al. ,         1999;

         ( O Br ien 1997; K ing et al. ,
                  ,                              2004; K onrad Schm olke et                   Po llington and Bax ter 2010),
                                                                                                                    ,

al , 2006 Tong et al , 2007; Caddick et al. , 2010)
 .      ;          .                                                                                                      (H o lliste r 1966; Loom is and N i ick,
                                                                                                                                      ,                     m

                                         ,                                                    1982; Cyg an and Lasaga 1982; Cherno ff and Car lson, 1997;
                                                                                                                     ,
                                                                                              O B rien, 1999; Spea r and D anie, 2001)
                                                                                                                               l

                                             ,
                                 ,                                                                                               ,

( V ance and O N ions 1990; W ang et al ,
                    ,                 .                  1992;           Park inson,
2000; Compagnon i and H iraji a 2001 Carswe ll et al. , 2003
                            m,     ;                       ;
D av is andW h itney 2006; Cutts et al. , 2010)
                    ,
                                                                                              2 石榴石的主要元素环带
             ,
                                ( K onrad Schm olke et al. , 2007) ,                          2 1
夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因                                                                                                                                                                                              435


      ,            X                                                                                                                                                             ,                            Ca
                                 (       1)                                                                                                        ,
              PT                  ( Spear et a1 , 1984; Enam , 1998) ,
                                                             i                                                                               , H er ann and G reen ( 2001 )
                                                                                                                                                  m                                                            H er ann
                                                                                                                                                                                                                  m
                                                                                            ( L asage,       ( 2002)              K2 O Ca M gO A l2 O 3 SiO2 H 2 O ( KCM ASH )
                                                                                                                                         O
l983;     Spea r and P arr ish,                      1996;       A yres and V ance,                 1997;                                                           ,                                Ca
Carlson and Schwarze 1997; O B rien, 1997; G anguly et al ,
                    ,                                   .                                                                                                                                   , A uzanneau et al.
2000; K ohn, 2004; Spear 2004; Stor and Spear 2005
                       ,          m         ,    ;                                                           ( 2006)                              H er
                                                                                                                                                     mann and G reen ( 2001)
      , 2003 2005)
           ,                                 ,                                                                            Na                           ,                                                                     ,
                       P T                                                           ( Spea r et al ,
                                                                                                  .                                                                                                       ,
1984; Spear 1993; Carswe ll et al. , 2000 K ing et al. , 2004;
          ,                             ;                                                                                                                               ,
K onrad Schm o lke et al. , 2006)                                                                            (                                                                         )
  ,                        Mn                                     ,                                                            ( 2009)
      ,                                  ,                                                                                               ,                 TH ERMO CA LC                                           P T
              ( D ee r et al. , 1982; Spear 1993)
                                          ,                                      H o llister ( 1966,             ,                                                          I                                  (X Grs )
1969)                                                                                      Mn                         ,               P T                       2 4~ 2 6G Pa                    570 ~ 585 ;
                   Leake ( 1967)                                 Mn                                                                               II                                             ,                 PT
                                                                 Mn                                 Fe                    1 9~ 2 4GP a                 530~ 570                         ,
                                                                                                                      ,                            Ca
                                                                           ,                                                                                                                ,
          ,                  Mg                                       , Mn                           ,                                                                                                                       ,
Ca                                                                         ( Spear et al. ,         1984;                                                           Mn
Enam , 1998; G hent 1998; Carswe ll et al. ,
     i            ,                                                                  2000 Zhang et
                                                                                        ;                             ;           ,                                                              ,
al , 2005a)
 .                                                                     ,                   Ca                                  Mn                                           ,
                                                        ( H er ann and G reen,
                                                             m                                      2001;    ( K ohn 2003)
                                                                                                                   ,                               ,
H er ann, 2002)
   m                         Carsw ell et al. ( 2000)                                                                      Mn                                                                         ( > 650               ),
                                                                                                ,                                        ,                              Fe M n M g
                                                                                                                 ,                                                              ( T racy 1982)
                                                                                                                                                                                        ,
                                 ,                                             Ca                                          ,                                ,
                   ,       F e /M g                                                                                  Mn                                                              ( A nderson and O li p io
                                                                                                                                                                                                        m ,
( 2005)                                                                                         ,            1977; W oodsw orth 1977; Y ardley
                                                                                                                              ,               ,                                      1977; D empster 1985;
                                                                                                                                                                                                   ,
                                                      M gO                             , M nO                Carlson and Schwarze,                         1997 C arlson
                                                                                                                                                              ;        ,                2002 )        Ca rlson and
                   , CaO                                                   ,                                 Schw arze ( 1997)                    Car lson ( 2002)                              T ex is                L lano
      ,                           10~ 50 m                                       ,                           U p lift                                                                                                   ,
                                             ,                                                                                                                                   ,                             Mn
                                 ,
                                     ,                                                                               0 5~ 1mm                      , Mn
               ,                                                                 ,                                                                                                           Mn
                                                                                                                 ,                                                                                                 ,
                             ,                                                                                                                                    Mn
                                                                                       P T                                                    ,                                                                              ,
  ,                                                                                    (                 ,                                                          600 ~ 750
2005)                                                                                                        ( Spear 1991; Car lson and Schw arze 1997 Carlson, 2002 )
                                                                                                                   ,                             ,   ;
               ,                                 ,                              CaO                                                                                             ,
                                                             ,                                                                                     /                            ( O Br ien 1997 A renas et
                                                                                                                                                                                         ,    ;
  ,                     CaO                                                                                  al , 1997 )
                                                                                                              .                                    /                                        ( R einecke
                                                                                                                                                                                                      ,                1998;
                       ( G a idies et al. , 2006)                              , A uzanneau et al.           Co pagnon i and H iraji a 2001)
                                                                                                               m                   m ,                                          W ang and L iou ( 1991)
( 2006)
436                                                                                                                                A cta P etro log ica Sinica 岩石学报                      2011, 27( 2)


                                                      ,
                                                               ,
                 ( > 800            )
                                    ,
                                ,
                                                 ,                               ,
          850~ 900 ,
     ,
                           ,                                                             ( Chen e t a1 ,
1998)             , Zhang et a l ( 2005b)
                               .                                                                                           2                           T o nshend D a
                                                                                                                                                          w          m
                                                          ,                                                      ,    Mn
                                                                                     (                       Fe/                                                                      (         1mm ) ,
Mg           )                                                                           ,                                                       3!                                   (     W h itn ey and
> 900            4 1~ 4 5G Pa                                                                            ,            S eaton, 2010)
                                                      900                                ,                            F ig 2
                                                                                                                          .         EBSD photom icrog raph to show M n zon ing and
                                                                                                     ,                structure o f a po lycrystal g arnet fro the T ownshend D a
                                                                                                                                                              m                  m
                                                                                 ,                                    samp le d istinct garne t cry sta ls
                                                                                                                      Each i age represents a d ifferent slice ( separated by 1mm ) of th e sam e
                                                                                                                           m
                                                                                                                 ,    cluster both s lices contain garnet 3
                                                                                                                            ;                              ,     the on ly garnet common to both
                                                                                                                      slices ( mod if ied afterW h itn ey and Seaton 2010 )
                                                                                                                                                                    ,
                                                               ( O B rien, 1997)


                                        ( EBSD )
                  ( D anie l and Spear 1998; Sp iess et a l , 2001;
                                     ,                    .
W h itney et al. , 2008; W hitney and Seaton,                                        2010)                       ,
W h itney and Seaton ( 2010)
                       3                                  Mn                 (           2),
                                                                     ,
Fe M n M g                                           Ca
                                                                                                             ,
                                                                         ,
                                            (W h itney and Seaton 2010)
                                                                ,

                                                                                                                           3                               K 92 12B                                   ,
                                            F allM ounta in
                   ,
                                                                                                                                                                      ,                      G rt1 + G rt2,
                       ( Spea r et al. , 1990; Spear and K ohn, 1996;
                                                                                                                      G rt4    G rt5 (   K ohn et a l , 1997)
                                                                                                                                                    .
K ohn et al. , 1997 P yle and Spear 1999, 2000 )
                  ;               ,
                                                                                             (                        F ig 3 E lectron m icroprobe trave rse ac ross garnet from sa ple
                                                                                                                          .                                                        m

         )                              (        3)                                                  ,                K 92 12B, show ing mu ltiple stag es of ga rnet gro th
                                                                                                                                                                         w
                                                          18                                                          V ert ical l ines separate areas correspond ing to G rt1 + G rt2, G rt4,            and
                   ,                                           O             ,
                                                                                                                      G rt5 ( modif ied afterK ohn e t al. , 1997)
                                                                                                 ,
                                                                         ( G rt1 + G rt2 )
                                                                                                                     1995)                                                                    ( Py le and
                                    (                               ),
                                                                                                                     Spear 1999)
                                                                                                                         ,               G rt3                                ,
Ch l+ Q tz= G rt1 + H 2 O, B t+ Sil1 + Q tz= G rt2 + M s                                                 ,
                                                                                                                     Bt+ S il1 3 + P l+ Q tz= G rt3 + K fs+ m elt
                                                                                                                                                                ,
         Mn Fe M g                                                 (Ca                                   )
                                                                                                                                ,
G rt1 + G rt2                                ,                     Mn Fe M g
                               ( Spear et al , 1990, 1995)
                                           .                                             G rt1                                                        Cr                          ,
                                                                                                                                                                          ,               M us+ P l+ Q tz
                                            ( G rt2 ),                                   ( Spear et al ,
                                                                                                     .
                                                                                                                                           (M s+ P l+ Q tz= S il3 + m elt ∀ K fs)
夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因                                                                                                                                437




     4 X ray                                        VCA 7079                2                                       (    D ah lqu ist et al. , 2007)
 F ig 4 X ray co positiona lm aps and spessa rtine inve rse be ll shaped zon ing pro files in t o ga rnets fro gran ite VCA 7079 ( after
     .          m                                                                             w               m
 D ah lqu ist et al , 2007)
                  .
 A bb reviations CZ= cen tral zon e I Z= in ter ed iate composit ional zone; M R Z= m argin al ri zone
               :                  ; C         m                                                 m


                                       ,                                    Cr                               ( annuli)                        ,
                  ,                           ,                                                                18
                                                                                                                    O            ,
                                 Cr                     ( Spear and K ohn,                                    Ca             G rt5        ,
1996; K ohn et al. , 1997 Spear et al , 1999)
                        ;           .                                                               ,
                                  ,
                           ,           K fs+ G rt2 3 + (                )        = Bt
+ S il4 + P l+ Q tz                                 ( R eNTR, R e trog rade
                                                                                        2 2
N e t transfer R eactions)                 G rt3,                                Mn
                                                                                                                             ,
                  ,
                                                                                          ( L eake 1967; M ann ing 1983 D eer et a l , 1992),
                                                                                                  ,               ,   ;            .
                       ,                            [ S il1 4 + (            )
                                                                                                                                     ( L eake 1967 A llan and
                                                                                                                                             ,   ;
 ∀ K fs= M s+ P l+ Q tz],
                      G rt4,           B t+ S il1 4 + Q tz + P l= G rt4 +               C la rke 1981; M ille r and Stoddard,
                                                                                               ,                                      1981;   du Bray,   1988;

M s G rt4                             Mn                            ,                   H og an, 1996; K ebede et al , 2001 D ahlquist et al. , 2007)
                                                                                                                   .      ;
                                                             ( Spea r et al ,
                                                                          .                                              ,
1990)     G rt3                (M n            )          G rt4                  (M n   ( du B ray 1988; V illa ros et al. , 2009) ,
                                                                                                  ,
            ),                        Mn                 ! ( hum p) ( Spear                         ,
et a l , 1990; K ohn et a l , 1997 )
     .                    .                                                                          ,
438                                                                                                                        A cta P etro log ica Sinica 岩石学报                                2011, 27( 2)


( D ah lqu ist et al. , 2007)                       ,                                                                    du Bray ( 1988)                      ,
                                      ,                                (                 )                                 M iller and Stoddard ( 1981)                         ,           Mn
                                          (H abler et al. , 2007)                             ,                                             ,                                                    M n /( F e
                                                                               ,                              + M g) # 0 04                 , du Bray ( 1988)                 A rab ian Sh ie ld
                                                                                                                                                                      ,
                                                                                                              M n /( F e+ M g ) # 0 04
                                                                                                                                     ,                                                       ,
         ,                                         ,                                          ( L eake,                                                                   D ah lqu ist et al. ( 2007)
1967; du Bray 1988; D ah lqu ist et a , 2007; V illaros et al ,
             ,                                              .                                                                                                     P e n R osado
2009) (      4)                                                                                                     ,                                                                              ,
                                                                     , M n /( Fe+ M g )
                   ,                                                           Mn
Fe     Mg                    ,                                                 Mn                             2 3
                                  ,                                                               ,                                                                                 (                    )
                                                         ,                     Mn            Fe                 ,                                                                                  ,
                                                                  Y ard ley ( 1977)                   Spear                                     ( C lechenko and V a lley 2003; D zigge l
                                                                                                                                                                         ,
( 1993)        ,                             ,                                                                et al , 2009)
                                                                                                                  .                                                                     ,
                       T < 640 ∀ 30                 ,                      Mn                                                          PT                                    ( G arcia Casco et al ,
                                                                                                                                                                                                 .
                       ( Y ard ley,         1977; M ann ing,                   1983 H arr ison,
                                                                                  ;                           2002),
1988);                           T > 700               ,Mn                                                    ( Jam tve it and A nderson, 1992)
              ,
                                                                                   ,                          ( O rto leva et al. , 1987)
                                   ( D ay et al. , 1992)                            Setouch i                                                                                           ,
                                                        ( K ano and Y ash i a
                                                                          m,                          1976;                                               ,                         ( Y ardley et al ,
                                                                                                                                                                                                   .
K aw abata and T akafu j, 2005)
                        i                                                                                     1991; Cro e et al. , 2001; C lechenko and V alley 2003; Sm ith
                                                                                                                       w                                       ,
                   D ay et al ( 1992)
                            .                                                                                 et al , 2004)
                                                                                                                  .                                      ( D zigge l et al. , 2009) (                    5)
                                      ,       K ano and Y ash i a ( 1976)
                                                              m                                                                         ,
                                                 K aw abata and T akafuji ( 2005)                                                       ,
                                                                                                                                                ( Ja tv eit et al. , 1993; Cro e et al ,
                                                                                                                                                    m                         w      .
                                                                                                              2001; C lechenko and V alley 2003)
                                                                                                                                          ,
                                                                           ,                                                   ,
                                                                                                              ( K a abata and T akafu j, 2005)
                                                                                                                   w                   i
                                                              ,
< 500~ 700M P a                                         ( G reen and R ing ood 1968;
                                                                          w ,
G reen 1972 1992)
     ,    ,
                                                                                                              3 石榴石的微量元素环带
                                                                       ( Pa ti o Douce and                                                                        ,
Johnson,     1991;          Skjerlie and Johnston,                     1993;           V ie lzeuf and
M onte,l 1994)                                                                                                ( H ickm ott et al. ,          1987
                                                                                                                                                ;       H ickmo tt and Sh i izu,
                                                                                                                                                                          m                            1990;
Mn           ( M iller et al. ,              1981
                                                ;            C lem ens and W al,l 1981,                       H ickm ott and Spear 1992; L anzirott, 1995; Spear and K ohn,
                                                                                                                                 ,                 i
1982),                 S                                                   P T fH 2O                          1996; Cherno ff and Ca rlson 1999)
                                                                                                                                         ,
       Mn               ,                                200~ 600 Pa ( C lemens and
                                                                M                                                                                   ,                       Mn
W a l, 1988)
     l                 S                            Mn                                                                                 ,
                                      ,          Strathbog ie                                                                      ,                                                                    ,
                                   ( C rd) +                       ( Bt)                 ( Phillips et
al , 1981), V io let T own
 .                                                                                                                             ,
( Crd) +                     ( O px )                    ( C lemens and W a l, 1984)
                                                                             l                                                ( H ickm ott et al. ,       1987 H ickmo tt and Sh i izu,
                                                                                                                                                             ;                   m
G reen ( 1977)               ,                                                                            ,   1990; H ickm o tt and Spear
                                                                                                                                        ,               1992;         Spear and K ohn,                 1996;
               Mn                                                                                             Cherno ff and C arlson 1999; O ta end i et al. , 2002 K on rad
                                                                                                                                   ,           m                  ;
夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因                                                                                                                                      439




       5        N a ib ia
                   m          N avachab                                                                   Mn         Ca       X                (       D zigge l et
 al. , 2009)
 F ig 5 The oscillatory zoning profiles and X ray composition maps o fM n and Ca in the garnet from the N avachab go ld depo sit in
     .
 N a ibia ( m od ified afte r D z iggel et al. , 2009)
    m


Schmo lke et al. , 2008a)       H ickm ott                                     K ohn, 1996); ( 4)                                  ,
                                                                 ,                                               ( H ickmo tt and Sh i izu, 1990); ( 5)
                                                                                                                                     m
                                                                ( H ickmo tt                                             ( H ickm ott et al. , 1987; X iao et
and Spear 1992),
        ,                                                                      al , 2002); ( 6)
                                                                                .
( H ickm ott and Sh i izu, 1990 ), P T
                    m                                       ( H ickm ott et                                                       ( Schwandt et al , 1996);
                                                                                                                                                 .
al , 1987; H ickm ott and Spear 1992) ,
 .                            ,                                                ( 7)                                                                      ( Cherno ff
( H ickm ott et al. , 1992 H erv ig and Peacock, 1989)
                         ;                                                     and Carlson, 1999)                ,
                                                                                 ,                                                                              ( Jun
  ,                                                                            and H ellenbrand, 2006 K onrad Schmo lke et al. , 2008a b)
                                                                                                    ;                                 ,
( H ickm ott et al. ,   1987 O B rien, 1997; K on rad Schmo lke et
                           ;
al , 2008a b)
 .        ,                 , Sm N d     Lu H f                           Sm                  ( Y ang and R ivers 2002)
                                                                                                                ,                                  ,
      Lu                         ,                                                                                   ,
                                                                ( L apen et                           ,
al , 2003; K y lander C lark et al. , 2007 Cheng et al. , 2008,
 .                                       ;                                                        ,                                    ! ( H ickmo tt et al ,
                                                                                                                                                          .
2009a b, 2010, 2011)
     ,                                                     ( HREE )            1987; Spear et al. , 1990; K ohn et al. , 1997; Py le and Spear
                                                                                                                                             ,
      Y                 ( H ickm ott et al , 1987 Bea et al. , 1994;
                                         .      ;                              1999)          ,                                                             ,
H er ann,
   m           2002
                  ;     O tamend i et al ,
                                       .          2002;     R ubatto and                                                                   ,
H er ann 2003 2007) ,
   m ,      ,                                                              ,                                                           ,
                 ,          (M REE)               (HR EE)       Y                !(    6)
                                     ( H ickmo tt and Shi izu 1990;
                                                        m ,
Lanziro tt, 1995; Chernoff and Car lson, 1999 O ta end iet al ,
          i                                 ;     m         .                                         ( L anzirott,i 1995; Spea r and K ohn, 1996;
2002)                                                       ,    : ( 1)        Py le and Spea r 1999; Chernoff and Carlson, 1999; Py le et al ,
                                                                                              ,                                             .
                            ( L anz irott,i 1995); ( 2 )                       2001; Y ang and R ivers 2002),
                                                                                                     ,
                              ( O ta endi et al , 2002); ( 3)
                                    m         .                                                                ( Chernoff and Carlson, 1999)                       ,
                                 ( H ickmo tt et al. , 1987; Spea r and                           P icuris                                         Yb Y P Ti
440                                                                                                               A cta P etro log ica Sinica 岩石学报               2011, 27( 2)




       6
                                 (     Y ang and R ivers 2002)
                                                       ,
 F ig 6 A schem atic diag ra show ing the va riation o f ga rnet
     .                      m
 com patible and                inco pa tible e le en ts formed by ga rnet
                                    m             m
 resorp tion and subsequent reg row th ( m od ified a fter Y ang and
 R ivers 2002)
       ,


Sc                                           ,                       Ca
               ,                                                      ,
                                                 ;                                                     7                              V erpenesse t                            714 3
               ,                                                                                                                            4                                  ( a),
      ( Chernoff and Carlson, 1999)                                                                            4                                       ( b) (            K onrad
                            ,                                                                     Schm olke et al , 2008a)
                                                                                                                .
     ( Chernoff and C arlson 1997, 1999)
                           ,                                                                      F ig 7
                                                                                                      .        R EE zon ing profiles o f g arnet fo r sa ple 714 3 fro
                                                                                                                                                        m             m
                            ,                                         ,                           V erpenesset ( a) and four d ifferen tR EE pa tterns co rrespond to
                                                                                                  four stag es o f garnet grow th ( b ) ( mod ified afte r K onrad
                                  ,                                        (           P Ca       Schm olke et al , 2008a)
                                                                                                                .
      REE          )                                 ,                                   ,
                                                                   , LREE                                               HREE                              ,
  ,                                                                   ; M REE                                       !             REE                                      ( Zone
           ,                                             ; HREE                    ,          2),              HREE                         M REE                                  ,
                                                 ( Y ang and R ivers 2002)
                                                                   ,                          HREE M REE                                                  ,
                                                     ,                                                                                                        , Ep
                                                                                                                           ,                                  ,
       K onrad Schm o lke et al. ( 2008a)                                                     (                ) Amp+ Ep∃ G rt( 2) ( G rs           ) + Cpx ( 1) + K y+ Q tz
                                                                                         ,    + H 2O                    REE                         M REE           ,      HREE
                       ,                                                                              LREE                               ( Z one 3),
       ,                                                                       ,                                    ,                                                      ,
                                                               (    7)                                     (            ) Amp + Cpx ( 1) ∃ G rt( 3) + Cpx ( 2 ) + Q tz+
REE                                          ( Zone 1),                            HREE       H 2O                   REE                          M REE           , HREE
M REE              ,                     HREE                             , MR EE                                                    ( Zone 4),
               ,                                                               ,                  ,                                           Ky,                       Cpx( 2) +
                           Chl+ Ep+ Q tz∃ (              A l ) G rt( 1) + (
                                                           m                             )    K y∃ G rt( 4) + Cpx ( 3) + Q tz
Amp+ H 2 O,                           HREE                                                                                 ( SI S)
                                                                                                                              M
夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因                                                                                                                                                                                                              441


      ( LA ICP M S)                                                                                               ,                                 ,
                                                       (                        ),                                     M REE HREE                                                                                            TTG
                                                                                                            ( B ea
et al , 1996; G r iffin et al. , 1996, 1999; Egg in, 2003; Rusk et
    .                                                                                                                                               ( Z hang et al , 2009, 2010)
                                                                                                                                                                 .
al , 2004; Luguet et al. , 2005 R ighter et al. , 2005;
 .                            ;
  , 2005 2006)
       ,
                                             Sass i et al. ( 2000)                                    SI S
                                                                                                       M               4 石榴石的氧同位素环带
                                        , HREE                                                    ,                                                                                                                          20             90
                                                           Jahn et al. ( 2003 2005)
                                                                            ,                                                             ( Chamber la in and Conrad 1991, 1993; Y oung and
                                                                                                                                                                   ,
                                                           LA I M S
                                                              CP                          ,                            R um ble 1993; Ja tve it and H erv ig 1994),
                                                                                                                               ,        m                   ,                                                           K ohn et al.
                                                                                                                  ,    ( 1993)
                                                                                                          X iao et                                                               T ie rra de l F uego
al ( 2001 2002)
 .      ,                                                                                                                                       ,                                        18
                                                                                                                                                                                              O                      5∋ ,
                     LA ICPM S                                          ,                                                                                                   75
                                                                                         ( 2004)                                                                                                  ( K ohn et al. , 1993)
LA I M S
   CP                                                                                                                    ,                                            ,
                     Ce                                                                                                                         ,
                        ( 2006)                                                     ( CCSD )                           ( Chamber la in and Conrad, 1991, 1993; Y oung and Rum ble,
                            ,                                                                             M REE        1993; Ja tve it and H erv ig 1994; K ohn and V a lley 1994; V an
                                                                                                                               m                   ,                        ,
                        M REE               HREE                                                                       H aren et al. , 1996 Crowe et al. , 2001; Ske lton et al. , 2002;
                                                                                                                                          ;
       ,                                 Sm                Lu                        ( H aur i et al ,
                                                                                                   .                   M a rtin et al , 2006)
                                                                                                                                    .                                     K ohn et al. ( 1997)
1994),                           ,                                                                                                                                                       ,
                        ,            HREE                                       MR EE                                    ,                                                       ,
( H ickm ott et al. ,                1987
                                        ;        H ickm o tt and Sh i izu,
                                                                    m                                      1990;                                                                                  X iao et al. ( 2002)
Schwandt et al. , 1996)                                     CCSD                                                                                        /
                                M REE                               ,                    ( 2006)                                      ,                     5 8 ( 5 2mm                                                       18
                                                                                                                                                                                                                                   O
                                            HREE                                                                             ( 8 9∋ ~ 9 3∋ ),                                        (                                  )
                                                                                                                                 18
  ,                                     HREE ( K le in et al , 2000),
                                                           .                                                                          O                           ( 6 8∋ ~ 7 4∋ ) ,
                                                                        ( K osler 2001 ),
                                                                                ,                                                                                                                                       ,
                                                                                                                                                                                                            18
                                                                    HREE                                                                                                                                         O
                ,                                                               ,                                        ,
                                                                                                                                                                                                                                   18
HREE                             ,                                                                                                                                    /                                 ,                               O
                                                                                                                                                                                                                        18
                                                                                                                  ,                             ,                                                                            O,
                                                                                                                                           18
                     HREE                    ,                                                                                                  O                           , X iao et al. ( 2002 )
                                                                                                                                                             18
                                                       !: ( 1)                                                                                                    O
                                                            M REE HREE                                                                                                       ,
( Rubatto 2002; W h itehouse and P latt 2003); ( 2)
         ,                            ,                                                               Lu H f
                                            176
                                                     L u /177 H f                                         176
                                                                                                                H f/
177
  Hf           ( Zheng et al. , 2005 W u et al. , 2006)
                                   ;
                                                                                                                       5 石榴石中的矿物包裹体研究
                            ,
           ( X ia et al , 2009, 2010; Zheng 2009a Chen et al ,
                      .                    ,     ;         .                                                                                                                                  (
2010),                                                                               (                                       )                                                   ,
                            )                                                                 (
                                                 )              ,                                                                                   (                                        , 2004)
             HREE                                                   ,                    900                                                                      ,
               DZr/ Grt % 1,            850                             DZ r/G rt # 5( R ubatto and
H er ann, 2007)
   m                                    & 850                               ,                         /
442                                                                                                                                                A cta P etro log ica Sinica 岩石学报                          2011, 27( 2)


                                                             ,                                                                (             Na K A l S i                   ),
                                                                                       ( X iao et al. ,             2000,         ,                                ,
2001, 2002 Franz et al , 2001;
         ;           .                                                       Scambe llur i and Philippo t
                                                                                                        ,                     ( Scambellur i and Philippo t 2001;
                                                                                                                                                          ,                                            , 2009)
2001; T ouret 2001; Fu et al , 2001, 2002 2003a b; Fan et
            ,              .            ,      ,
al ,
 .           2002,        2003,           2005;         Shen et al. ,                     2003
                                                                                             ;            T ou ret and                                         ,
Co pagnon,i 2003;
  m                                                  , 2005 2006;
                                                          ,                                               , 2005
                                                                                                               ;
         , 2005, 2006; Zhang et al. , 2005b, 2006 2007, 2008)
                                                ,                                                                                     ( Parkinson, 2000; K a abata and T akafuj,i 2005 Cutts et
                                                                                                                                                            w                        ;
                                                                                                                  ( Zheng,    al , 2010)
                                                                                                                               .                        K awabata and T akafuji ( 2005)
2008; Zheng et al. , 2009a ),                                                                                                 Setouch i                                                                  ,
                                                                                                               ( Zheng,                                                                                                      ,
2009a b; Zheng et a l , 2009b, 2011)
     ,              .                                                                                                                                                      ;
                                                                                                      ,                                                                ,                                              P ark inson
        ( O kay et al. , 1989; W ang et al , 1989 1992 )
                                         .      ,                                                                             ( 2000)             K okche tav                                                     ,
( Xu et al. , 1992)                                                  ,
                  ( > 100km ),                                                                ,                                                            ,                                                                 (
                                                                                                                              8):                                                                ( T ype 1 );
    ,                                                            (                    +                   +               )                                                              ,                            ,
( Okay et al. , 1989) ,                                                                                                                            ,
                                                                     ,                                                        ( T ype 2) ;                                                                   +
         ,                                                                                                                                  ,                              ( Type 3);
                                                                                                  ,           W ang and                                        ,                         ,                                 ( T ype
L iou ( 1991)                                                                                                                 4);
                                                         ,                                                                    T ype 1                          ,
                                                                                                                                      (T = 380~ 580 , P < 1 0G Pa);                                3
                                      ( Ferrando et al , 2005; M a lasp ina et al ,
                                                     .                          .                                                                              ,
2006;                        , 2009)                     Ferrando et al. ( 2005)                                              ( P ~ 2 6G Pa T ~ 600
                                                                                                                                           ,                           )                                 ,            K okche tav
                                                                                                                                                                                                                           W ang
                                                ,                                     +                   +               ∀   et al ( 1992)
                                                                                                                                  .
                  ∀ Zn                    ∀                  ∀                        ∀           ∀                   ∀           ,                                                          ,
                         ∀                      M a laspina et al. ( 2006)
                                                                                                                                                                                ,
                                                                                 (                ),                                        ,
                       10% ~ 20%                                                 80% ~ 90%                                    400               1 2~ 1 5GP a
(                  +              ∀                 ∀                    ∀                )                                            ,                                             ,
                                                                                                              ,                                    ,                                                              600 ,
                                                                 /                                                                         2 0~ 2 2GP a
                                      Saxon ian E rzg eb irge                                                                                      ,
                       (Hw ang et al , 2001 Stockhert et al. , 2001)
                                   .      ;                                                                                             Cutts et al. ( 2010)                                        M oine Superg roup
                         K okchetav                                                                                       ,                                                                                               LA I
                                                                                                                                                                                                                             CP
                                                                                     (Hw ang et al. , 2003)                   MS            U Pb           ,
                   ,                                                                                                                                       U Pb                     825 ~ 780M a,
                                      /                                                                       ( Ph ilippot                                 ;                                             U Pb                724
and Se lverstone,                 1991;             Ph ilippot
                                                             ,                   1993;        Ph ilippot et al ,
                                                                                                             .                ∀ 6M a,                              SI S
                                                                                                                                                                    M               U Pb               725 ∀ 4M a            ,
1995; Zhang et al. , 2008 M posko s et al. , 2009 ),
                        ;                                                                                                                                                                ;
                                              (H ura i et al. , 2010)                                                                      U Pb                464 ∀ 3 a
                                                                                                                                                                     M ,                                                   462 ∀
                                                                             ,                                                2M a                                                   SI S
                                                                                                                                                                                      M                 463 ∀ 4M a
              ,                                                              ,                                                    ,                                                          ,
夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因                                                                                                                                            443




     8 K ulet                                                ,
                                                                      (       Park inson, 2000 )
 F ig 8
     .         Sketch of garnet po rphyrob last in K ulet wh itesch ist ( N 307 ),                 show ing co rre lation betw een inc lusion asse lages and
                                                                                                                                                  mb
 prograde co pos itiona l zona tion
            m
 N ote rad ial fractu ring around sil ica inclusions in them an tle reg ion U pp er right in set show s com pos itional l ine p rofile of th eG rt and low er right in set
                                                                                                                                                 ,                       ,
 system atic d istribu tion of s ilica inclus ion types Q tz and / or C oe in the G rt ( after Park inson, 2000 )


          U Pb         ,


                           ,                         ,                                     6 结语
                      : ( 1)                                                      ,
                                  ( K awabata and T akafuj,i 2005); ( 2)
                                          ,                               ,                                                                          ,
                                      ,
                           ( O kay et al. ,   1989 W ang et al. , 1989,
                                                 ;
1992; Parkinson, 2000); ( 3)                                                                                        ,
     ,                                                   +                                            ,
      ( van R oer und and D rury 1998 Y e et al. , 2000;
                m               ,   ;
  , 2002; Song et a l , 2004) ,
                    .
                                               ,
           ,                                                     ,                                    ,
                                      ,                                                                                     ,
                                                                                                                        ,
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  • 1. 1000 0569/2011 /027( 02) 0433 50 A cta P etro log ica Sinica 岩石 学报 * 夏琼霞 郑永飞 X I Q iongX ia and ZHENG Y ongF e i A , , 230026 CAS K ey L abora tory of C rust M an tleM a terials and Env ironm en ts S ch ool of Earth and Space S cien ces U niversity of S cience and T echnology of Ch ina, , , H ef ei 230026, Ch ina 2010 11 10 收稿, 2011 01 06 改回 X ia QX and Zheng YF 2011 The composition and ch e ical zon ing in garnet from h igh to u ltrah igh pressure m etam orph ic m rock s A cta Petrolog ica S in ica, 27( 2) : 433- 450 Abstrac t G arne t is comm on in eclog ite and gne iss of high pressure ( HP ) to u ltrah igh pressure ( UH P) m eta orph ic or ig in It can m be we ll preserved during subduc tion zone m eta orphism fo r its h igh re frac to riness and low so lubility in flu id and m e lt The che ica l m m composition and m ineral inc lusions preserv ed in garnet can be used to constra in the P T cond itions, m eta orph ic evo lution, and fluid m action T he che ica l composition o f garne t is re lated to m any factors such as who le rock co pos ition, P T conditions g arnet fo r ing m , m , m m eta o rph ic reactions and the asse blag e of coex isting m inerals T hus the m ajor e le ents trace e lem ents, oxygen iso topes m inera l m m m , , inc lusions and the ir re lations in garnet should all be taken into accoun t when it is used to constra in the me ta orphic P T evo lu tion in m UHP m etamo rph ic rocks In add ition, in situ analyses o fU Pb isotopes and trace e lements in accesso ry m inera ls such as zircon and /o r m onazite inc lusions in garne t can place a direct constra int on the ti e o f m eta orphic garne t grow th T hrough study ing the history of m m ga rnet gro th dur ing subduc tion zone m eta orphism, it can not on ly prov ide pe tro log ic and geochem ica l ev idence for the processes to w m produce garne t bear ing m eta o rph ic ro cks but also g ive c lues to the orig in o f garnet T hese a re ve ry i portant to the che ica l m , m m dyna ics o f subduction zone m eta o rph ism m m K ey word s G arnet H P /UHP m etamo rph is O r ig in; Chem ical zon ing Inclusions ; m; ; 在俯冲带 变质过程中, 石榴石是高压 超高压变质榴 辉岩和片麻 岩的常见 变质矿物 由于 石榴石具 有难熔 和流体 中的低溶解能力的特点, 通常可以很好地保存下来, 并且能够保留复杂的化学成 分环带, 以及不同 类型的矿 物或流体包 裹体, 为解释石榴石寄主岩石经历的 变质演化历史提供了重要信息 石榴子石的主微 量元素成分 受控于很多 因素, 如全岩成 分 变 质的温压条件 控制石榴子石形成的相关变质反应 与石 榴子石 共生的 矿物种 类和成 分等 因此, 在 利用石榴 石探讨 超高压 变质的演化历史时, 对石榴石进行系统 的主要 元素 微 量元素 氧 同位 素以 及矿物 包裹 体分析, 以 及相 互间的 成因 关系 同 时, 对石榴石中的锆石或独居石包裹体并进行原位 U Pb定 年和微 量元素分 析, 可以为 变质石 榴石的 形成时代 提供直 接的时 间制约 深入研究超高压变质岩中石榴 石的生长阶段, 不仅可以 为含石 榴石寄 主岩石 的变质 过程提 供岩石学 和地球 化学证 据, 而且对于理解石榴石的形成机制 生长规律及其变质化学动力学过程具有重要的科学意义 石榴石; 高压 /超 高压变质; 成因机制; 环带; 包裹体 P578 947 * 973 ( 2009CB825004 ) ( 40921002 41003014 ) . : , , 1979 , , , E m ai:l qxxia ustc. edu cn @ .
  • 2. 434 A cta P etro log ica Sinica 岩石学报 2011, 27( 2) 1 X ray Austroalpine W lz ( 12F03) ( a) ( d) 12F03 X ; ( e) ( c) ( G aid ies et a l , 2008) . F ig 1 X ray m aps of a prog rade garnet porphy roblast of m etape lite 12F 03 from the W lz Comp lex in A ustroa lp ine basem ent . ( a) ( d) X ray m aps of a gar et porphyrob last from samp le 12F03 Th e locat ion of the com positional prof ile A B as illu strated in ( c) is show n in ( e) n ; ( m od ified after G aid ies e t al. , 2008) ( Spear , 1993 M enard and Spear ; , 1993; G a id ies et al , . 2006) , 1 引言 , S , ( Spear and Se lverstone 1983; M enard and Spear 1993; A yres and , , , , V ance 1997 Ca rsw e ll et al. , , ; 1997, 2000; Enam , 1998; i Cooke et al. , 2000; E scuder V iruete et al , 2000 K ing et al , . ; . , , ( Loo is et al. , 1985; Chakrabo rty m 2004; K onrad Schm o lke et al. , 2006, 2008a ), and G angu ly 1992 V ielzeuf et al , 2007), , ; . ( L asaga and Jiang 1995; V ance 1995 G angu ly , , ; , et al. , 1996; G r iffin et al. , 1996; Perchuck et al. , 1999; ( O Br ien 1997; K ing et al. , , 2004; K onrad Schm olke et Po llington and Bax ter 2010), , al , 2006 Tong et al , 2007; Caddick et al. , 2010) . ; . (H o lliste r 1966; Loom is and N i ick, , m , 1982; Cyg an and Lasaga 1982; Cherno ff and Car lson, 1997; , O B rien, 1999; Spea r and D anie, 2001) l , , , ( V ance and O N ions 1990; W ang et al , , . 1992; Park inson, 2000; Compagnon i and H iraji a 2001 Carswe ll et al. , 2003 m, ; ; D av is andW h itney 2006; Cutts et al. , 2010) , 2 石榴石的主要元素环带 , ( K onrad Schm olke et al. , 2007) , 2 1
  • 3. 夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因 435 , X , Ca ( 1) , PT ( Spear et a1 , 1984; Enam , 1998) , i , H er ann and G reen ( 2001 ) m H er ann m ( L asage, ( 2002) K2 O Ca M gO A l2 O 3 SiO2 H 2 O ( KCM ASH ) O l983; Spea r and P arr ish, 1996; A yres and V ance, 1997; , Ca Carlson and Schwarze 1997; O B rien, 1997; G anguly et al , , . , A uzanneau et al. 2000; K ohn, 2004; Spear 2004; Stor and Spear 2005 , m , ; ( 2006) H er mann and G reen ( 2001) , 2003 2005) , , Na , , P T ( Spea r et al , . , 1984; Spear 1993; Carswe ll et al. , 2000 K ing et al. , 2004; , ; , K onrad Schm o lke et al. , 2006) ( ) , Mn , ( 2009) , , , TH ERMO CA LC P T ( D ee r et al. , 1982; Spear 1993) , H o llister ( 1966, , I (X Grs ) 1969) Mn , P T 2 4~ 2 6G Pa 570 ~ 585 ; Leake ( 1967) Mn II , PT Mn Fe 1 9~ 2 4GP a 530~ 570 , , Ca , , , Mg , Mn , , Ca ( Spear et al. , 1984; Mn Enam , 1998; G hent 1998; Carswe ll et al. , i , 2000 Zhang et ; ; , , al , 2005a) . , Ca Mn , ( H er ann and G reen, m 2001; ( K ohn 2003) , , H er ann, 2002) m Carsw ell et al. ( 2000) Mn ( > 650 ), , , Fe M n M g , ( T racy 1982) , , Ca , , , F e /M g Mn ( A nderson and O li p io m , ( 2005) , 1977; W oodsw orth 1977; Y ardley , , 1977; D empster 1985; , M gO , M nO Carlson and Schwarze, 1997 C arlson ; , 2002 ) Ca rlson and , CaO , Schw arze ( 1997) Car lson ( 2002) T ex is L lano , 10~ 50 m , U p lift , , , Mn , , 0 5~ 1mm , Mn , , Mn , , , Mn P T , , , ( , 600 ~ 750 2005) ( Spear 1991; Car lson and Schw arze 1997 Carlson, 2002 ) , , ; , , CaO , , / ( O Br ien 1997 A renas et , ; , CaO al , 1997 ) . / ( R einecke , 1998; ( G a idies et al. , 2006) , A uzanneau et al. Co pagnon i and H iraji a 2001) m m , W ang and L iou ( 1991) ( 2006)
  • 4. 436 A cta P etro log ica Sinica 岩石学报 2011, 27( 2) , , ( > 800 ) , , , , 850~ 900 , , , ( Chen e t a1 , 1998) , Zhang et a l ( 2005b) . 2 T o nshend D a w m , , Mn ( Fe/ ( 1mm ) , Mg ) , 3! ( W h itn ey and > 900 4 1~ 4 5G Pa , S eaton, 2010) 900 , F ig 2 . EBSD photom icrog raph to show M n zon ing and , structure o f a po lycrystal g arnet fro the T ownshend D a m m , samp le d istinct garne t cry sta ls Each i age represents a d ifferent slice ( separated by 1mm ) of th e sam e m , cluster both s lices contain garnet 3 ; , the on ly garnet common to both slices ( mod if ied afterW h itn ey and Seaton 2010 ) , ( O B rien, 1997) ( EBSD ) ( D anie l and Spear 1998; Sp iess et a l , 2001; , . W h itney et al. , 2008; W hitney and Seaton, 2010) , W h itney and Seaton ( 2010) 3 Mn ( 2), , Fe M n M g Ca , , (W h itney and Seaton 2010) , 3 K 92 12B , F allM ounta in , , G rt1 + G rt2, ( Spea r et al. , 1990; Spear and K ohn, 1996; G rt4 G rt5 ( K ohn et a l , 1997) . K ohn et al. , 1997 P yle and Spear 1999, 2000 ) ; , ( F ig 3 E lectron m icroprobe trave rse ac ross garnet from sa ple . m ) ( 3) , K 92 12B, show ing mu ltiple stag es of ga rnet gro th w 18 V ert ical l ines separate areas correspond ing to G rt1 + G rt2, G rt4, and , O , G rt5 ( modif ied afterK ohn e t al. , 1997) , ( G rt1 + G rt2 ) 1995) ( Py le and ( ), Spear 1999) , G rt3 , Ch l+ Q tz= G rt1 + H 2 O, B t+ Sil1 + Q tz= G rt2 + M s , Bt+ S il1 3 + P l+ Q tz= G rt3 + K fs+ m elt , Mn Fe M g (Ca ) , G rt1 + G rt2 , Mn Fe M g ( Spear et al , 1990, 1995) . G rt1 Cr , , M us+ P l+ Q tz ( G rt2 ), ( Spear et al , . (M s+ P l+ Q tz= S il3 + m elt ∀ K fs)
  • 5. 夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因 437 4 X ray VCA 7079 2 ( D ah lqu ist et al. , 2007) F ig 4 X ray co positiona lm aps and spessa rtine inve rse be ll shaped zon ing pro files in t o ga rnets fro gran ite VCA 7079 ( after . m w m D ah lqu ist et al , 2007) . A bb reviations CZ= cen tral zon e I Z= in ter ed iate composit ional zone; M R Z= m argin al ri zone : ; C m m , Cr ( annuli) , , , 18 O , Cr ( Spear and K ohn, Ca G rt5 , 1996; K ohn et al. , 1997 Spear et al , 1999) ; . , , , K fs+ G rt2 3 + ( ) = Bt + S il4 + P l+ Q tz ( R eNTR, R e trog rade 2 2 N e t transfer R eactions) G rt3, Mn , , ( L eake 1967; M ann ing 1983 D eer et a l , 1992), , , ; . , [ S il1 4 + ( ) ( L eake 1967 A llan and , ; ∀ K fs= M s+ P l+ Q tz], G rt4, B t+ S il1 4 + Q tz + P l= G rt4 + C la rke 1981; M ille r and Stoddard, , 1981; du Bray, 1988; M s G rt4 Mn , H og an, 1996; K ebede et al , 2001 D ahlquist et al. , 2007) . ; ( Spea r et al , . , 1990) G rt3 (M n ) G rt4 (M n ( du B ray 1988; V illa ros et al. , 2009) , , ), Mn ! ( hum p) ( Spear , et a l , 1990; K ohn et a l , 1997 ) . . ,
  • 6. 438 A cta P etro log ica Sinica 岩石学报 2011, 27( 2) ( D ah lqu ist et al. , 2007) , du Bray ( 1988) , , ( ) M iller and Stoddard ( 1981) , Mn (H abler et al. , 2007) , , M n /( F e , + M g) # 0 04 , du Bray ( 1988) A rab ian Sh ie ld , M n /( F e+ M g ) # 0 04 , , , , ( L eake, D ah lqu ist et al. ( 2007) 1967; du Bray 1988; D ah lqu ist et a , 2007; V illaros et al , , . P e n R osado 2009) ( 4) , , , M n /( Fe+ M g ) , Mn Fe Mg , Mn 2 3 , , ( ) , Mn Fe , , Y ard ley ( 1977) Spear ( C lechenko and V a lley 2003; D zigge l , ( 1993) , , et al , 2009) . , T < 640 ∀ 30 , Mn PT ( G arcia Casco et al , . ( Y ard ley, 1977; M ann ing, 1983 H arr ison, ; 2002), 1988); T > 700 ,Mn ( Jam tve it and A nderson, 1992) , , ( O rto leva et al. , 1987) ( D ay et al. , 1992) Setouch i , ( K ano and Y ash i a m, 1976; , ( Y ardley et al , . K aw abata and T akafu j, 2005) i 1991; Cro e et al. , 2001; C lechenko and V alley 2003; Sm ith w , D ay et al ( 1992) . et al , 2004) . ( D zigge l et al. , 2009) ( 5) , K ano and Y ash i a ( 1976) m , K aw abata and T akafuji ( 2005) , ( Ja tv eit et al. , 1993; Cro e et al , m w . 2001; C lechenko and V alley 2003) , , , ( K a abata and T akafu j, 2005) w i , < 500~ 700M P a ( G reen and R ing ood 1968; w , G reen 1972 1992) , , 3 石榴石的微量元素环带 ( Pa ti o Douce and , Johnson, 1991; Skjerlie and Johnston, 1993; V ie lzeuf and M onte,l 1994) ( H ickm ott et al. , 1987 ; H ickmo tt and Sh i izu, m 1990; Mn ( M iller et al. , 1981 ; C lem ens and W al,l 1981, H ickm ott and Spear 1992; L anzirott, 1995; Spear and K ohn, , i 1982), S P T fH 2O 1996; Cherno ff and Ca rlson 1999) , Mn , 200~ 600 Pa ( C lemens and M , Mn W a l, 1988) l S Mn , , Strathbog ie , , ( C rd) + ( Bt) ( Phillips et al , 1981), V io let T own . , ( Crd) + ( O px ) ( C lemens and W a l, 1984) l ( H ickm ott et al. , 1987 H ickmo tt and Sh i izu, ; m G reen ( 1977) , , 1990; H ickm o tt and Spear , 1992; Spear and K ohn, 1996; Mn Cherno ff and C arlson 1999; O ta end i et al. , 2002 K on rad , m ;
  • 7. 夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因 439 5 N a ib ia m N avachab Mn Ca X ( D zigge l et al. , 2009) F ig 5 The oscillatory zoning profiles and X ray composition maps o fM n and Ca in the garnet from the N avachab go ld depo sit in . N a ibia ( m od ified afte r D z iggel et al. , 2009) m Schmo lke et al. , 2008a) H ickm ott K ohn, 1996); ( 4) , , ( H ickmo tt and Sh i izu, 1990); ( 5) m ( H ickmo tt ( H ickm ott et al. , 1987; X iao et and Spear 1992), , al , 2002); ( 6) . ( H ickm ott and Sh i izu, 1990 ), P T m ( H ickm ott et ( Schwandt et al , 1996); . al , 1987; H ickm ott and Spear 1992) , . , ( 7) ( Cherno ff ( H ickm ott et al. , 1992 H erv ig and Peacock, 1989) ; and Carlson, 1999) , , ( Jun , and H ellenbrand, 2006 K onrad Schmo lke et al. , 2008a b) ; , ( H ickm ott et al. , 1987 O B rien, 1997; K on rad Schmo lke et ; al , 2008a b) . , , Sm N d Lu H f Sm ( Y ang and R ivers 2002) , , Lu , , ( L apen et , al , 2003; K y lander C lark et al. , 2007 Cheng et al. , 2008, . ; , ! ( H ickmo tt et al , . 2009a b, 2010, 2011) , ( HREE ) 1987; Spear et al. , 1990; K ohn et al. , 1997; Py le and Spear , Y ( H ickm ott et al , 1987 Bea et al. , 1994; . ; 1999) , , H er ann, m 2002 ; O tamend i et al , . 2002; R ubatto and , H er ann 2003 2007) , m , , , , , (M REE) (HR EE) Y !( 6) ( H ickmo tt and Shi izu 1990; m , Lanziro tt, 1995; Chernoff and Car lson, 1999 O ta end iet al , i ; m . ( L anzirott,i 1995; Spea r and K ohn, 1996; 2002) , : ( 1) Py le and Spea r 1999; Chernoff and Carlson, 1999; Py le et al , , . ( L anz irott,i 1995); ( 2 ) 2001; Y ang and R ivers 2002), , ( O ta endi et al , 2002); ( 3) m . ( Chernoff and Carlson, 1999) , ( H ickmo tt et al. , 1987; Spea r and P icuris Yb Y P Ti
  • 8. 440 A cta P etro log ica Sinica 岩石学报 2011, 27( 2) 6 ( Y ang and R ivers 2002) , F ig 6 A schem atic diag ra show ing the va riation o f ga rnet . m com patible and inco pa tible e le en ts formed by ga rnet m m resorp tion and subsequent reg row th ( m od ified a fter Y ang and R ivers 2002) , Sc , Ca , , ; 7 V erpenesse t 714 3 , 4 ( a), ( Chernoff and Carlson, 1999) 4 ( b) ( K onrad , Schm olke et al , 2008a) . ( Chernoff and C arlson 1997, 1999) , F ig 7 . R EE zon ing profiles o f g arnet fo r sa ple 714 3 fro m m , , V erpenesset ( a) and four d ifferen tR EE pa tterns co rrespond to four stag es o f garnet grow th ( b ) ( mod ified afte r K onrad , ( P Ca Schm olke et al , 2008a) . REE ) , , , LREE HREE , , ; M REE ! REE ( Zone , ; HREE , 2), HREE M REE , ( Y ang and R ivers 2002) , HREE M REE , , , Ep , , K onrad Schm o lke et al. ( 2008a) ( ) Amp+ Ep∃ G rt( 2) ( G rs ) + Cpx ( 1) + K y+ Q tz , + H 2O REE M REE , HREE , LREE ( Z one 3), , , , , ( 7) ( ) Amp + Cpx ( 1) ∃ G rt( 3) + Cpx ( 2 ) + Q tz+ REE ( Zone 1), HREE H 2O REE M REE , HREE M REE , HREE , MR EE ( Zone 4), , , , Ky, Cpx( 2) + Chl+ Ep+ Q tz∃ ( A l ) G rt( 1) + ( m ) K y∃ G rt( 4) + Cpx ( 3) + Q tz Amp+ H 2 O, HREE ( SI S) M
  • 9. 夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因 441 ( LA ICP M S) , , ( ), M REE HREE TTG ( B ea et al , 1996; G r iffin et al. , 1996, 1999; Egg in, 2003; Rusk et . ( Z hang et al , 2009, 2010) . al , 2004; Luguet et al. , 2005 R ighter et al. , 2005; . ; , 2005 2006) , Sass i et al. ( 2000) SI S M 4 石榴石的氧同位素环带 , HREE , 20 90 Jahn et al. ( 2003 2005) , ( Chamber la in and Conrad 1991, 1993; Y oung and , LA I M S CP , R um ble 1993; Ja tve it and H erv ig 1994), , m , K ohn et al. , ( 1993) X iao et T ie rra de l F uego al ( 2001 2002) . , , 18 O 5∋ , LA ICPM S , 75 ( 2004) ( K ohn et al. , 1993) LA I M S CP , , Ce , ( 2006) ( CCSD ) ( Chamber la in and Conrad, 1991, 1993; Y oung and Rum ble, , M REE 1993; Ja tve it and H erv ig 1994; K ohn and V a lley 1994; V an m , , M REE HREE H aren et al. , 1996 Crowe et al. , 2001; Ske lton et al. , 2002; ; , Sm Lu ( H aur i et al , . M a rtin et al , 2006) . K ohn et al. ( 1997) 1994), , , , HREE MR EE , , ( H ickm ott et al. , 1987 ; H ickm o tt and Sh i izu, m 1990; X iao et al. ( 2002) Schwandt et al. , 1996) CCSD / M REE , ( 2006) , 5 8 ( 5 2mm 18 O HREE ( 8 9∋ ~ 9 3∋ ), ( ) 18 , HREE ( K le in et al , 2000), . O ( 6 8∋ ~ 7 4∋ ) , ( K osler 2001 ), , , 18 HREE O , , , 18 HREE , / , O 18 , , O, 18 HREE , O , X iao et al. ( 2002 ) 18 !: ( 1) O M REE HREE , ( Rubatto 2002; W h itehouse and P latt 2003); ( 2) , , Lu H f 176 L u /177 H f 176 H f/ 177 Hf ( Zheng et al. , 2005 W u et al. , 2006) ; 5 石榴石中的矿物包裹体研究 , ( X ia et al , 2009, 2010; Zheng 2009a Chen et al , . , ; . ( 2010), ( ) , ) ( ) , ( , 2004) HREE , 900 , DZr/ Grt % 1, 850 DZ r/G rt # 5( R ubatto and H er ann, 2007) m & 850 , /
  • 10. 442 A cta P etro log ica Sinica 岩石学报 2011, 27( 2) , ( Na K A l S i ), ( X iao et al. , 2000, , , 2001, 2002 Franz et al , 2001; ; . Scambe llur i and Philippo t , ( Scambellur i and Philippo t 2001; , , 2009) 2001; T ouret 2001; Fu et al , 2001, 2002 2003a b; Fan et , . , , al , . 2002, 2003, 2005; Shen et al. , 2003 ; T ou ret and , Co pagnon,i 2003; m , 2005 2006; , , 2005 ; , 2005, 2006; Zhang et al. , 2005b, 2006 2007, 2008) , ( Parkinson, 2000; K a abata and T akafuj,i 2005 Cutts et w ; ( Zheng, al , 2010) . K awabata and T akafuji ( 2005) 2008; Zheng et al. , 2009a ), Setouch i , ( Zheng, , 2009a b; Zheng et a l , 2009b, 2011) , . ; , , P ark inson ( O kay et al. , 1989; W ang et al , 1989 1992 ) . , ( 2000) K okche tav , ( Xu et al. , 1992) , ( > 100km ), , , ( 8): ( T ype 1 ); , ( + + ) , , ( Okay et al. , 1989) , , , ( T ype 2) ; + , , ( Type 3); , W ang and , , ( T ype L iou ( 1991) 4); , T ype 1 , (T = 380~ 580 , P < 1 0G Pa); 3 ( Ferrando et al , 2005; M a lasp ina et al , . . , 2006; , 2009) Ferrando et al. ( 2005) ( P ~ 2 6G Pa T ~ 600 , ) , K okche tav W ang , + + ∀ et al ( 1992) . ∀ Zn ∀ ∀ ∀ ∀ ∀ , , ∀ M a laspina et al. ( 2006) , ( ), , 10% ~ 20% 80% ~ 90% 400 1 2~ 1 5GP a ( + ∀ ∀ ∀ ) , , , , 600 , / 2 0~ 2 2GP a Saxon ian E rzg eb irge , (Hw ang et al , 2001 Stockhert et al. , 2001) . ; Cutts et al. ( 2010) M oine Superg roup K okchetav , LA I CP (Hw ang et al. , 2003) MS U Pb , , U Pb 825 ~ 780M a, / ( Ph ilippot ; U Pb 724 and Se lverstone, 1991; Ph ilippot , 1993; Ph ilippot et al , . ∀ 6M a, SI S M U Pb 725 ∀ 4M a , 1995; Zhang et al. , 2008 M posko s et al. , 2009 ), ; ; (H ura i et al. , 2010) U Pb 464 ∀ 3 a M , 462 ∀ , 2M a SI S M 463 ∀ 4M a , , , ,
  • 11. 夏琼霞等: 高压 超高压变质岩石中石榴石的环带和成因 443 8 K ulet , ( Park inson, 2000 ) F ig 8 . Sketch of garnet po rphyrob last in K ulet wh itesch ist ( N 307 ), show ing co rre lation betw een inc lusion asse lages and mb prograde co pos itiona l zona tion m N ote rad ial fractu ring around sil ica inclusions in them an tle reg ion U pp er right in set show s com pos itional l ine p rofile of th eG rt and low er right in set , , system atic d istribu tion of s ilica inclus ion types Q tz and / or C oe in the G rt ( after Park inson, 2000 ) U Pb , , , 6 结语 : ( 1) , ( K awabata and T akafuj,i 2005); ( 2) , , , , ( O kay et al. , 1989 W ang et al. , 1989, ; 1992; Parkinson, 2000); ( 3) , , + , ( van R oer und and D rury 1998 Y e et al. , 2000; m , ; , 2002; Song et a l , 2004) , . , , , , , , ,