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100% Clean,
Renewable Energy
and Storage for
Everything
Mark Z. Jacobson
Stanford University
Chapter 5:
Photovoltaics and
Solar Radiation
How to PV Panels Work?
Photovoltaics (PVs)
• Defined: A material or device that converts photons of light
energy to electrical voltage and current
• A photon with short enough wavelength can cause an electron
in a PV material (semiconductor, such as Si) to break free of
the atom that holds it
• If a nearby electric field is provided, electrons can be swept
toward a metallic contact, where they can become part of an
electric current
First solar cell to generate electricity –
1883 (Charles Fritts, U.S.)
Pressed a thin film of selenium against a brass metal plate, then laid an
even thinner layer of gold on top. The gold layer was so thin that sunlight
could penetrate through it. Exposing the gold to sunlight resulted in
electricity generation.
Werner Siemens, who confirmed Fritts’ experiment, commented,
“In conclusion, I would say that however great the scientific importance of
this discovery may be, its practical value will be no less obvious when we
reflect that the supply of solar energy is both without limit and without cost,
and that it will continue to pour down upon us for countless ages after all the
coal deposits of the earth have been exhausted and forgotten.”
Photovoltaics (PVs)
• PVs are semiconductor materials that convert sunlight to electricity
• Main material is silicon (Si). Other materials: Germanium (Ge),
Gallium (Ga), and Arsenic (As)
• Si has 14 electrons, including 4 in outer shell, thus a +4 nucleus
charge. Pure Si crystals have Si bonded to each other with
covalent bonds.
• Boron (B) and Phosphorus (P) are added to Silicon to create
electric field in a PV cell.
Energy Bands – Photoelectric Effect
VB = valence band;
CB = conduction band
If an electron in the valence
band acquires energy Ebg, the
electron can jump to the
conduction band.
Photovoltaics (PVs)
• Si is a semiconductor
• Metals are conductors
• Metals, semiconductors, and insulators have energy bands:
 Valence band, forbidden band, and conduction band, forbidden
band
 Electrons in conduction band contribute to current flow
• With metals, P-N junction can’t form, so free electrons move too
randomly
• Insulators require too much energy to add electrons to conduction
band
Band Gap Energy
• Forbidden band
• Gap between conduction band and valence band
• Band-gap energy (Ebg)
• Energy needed for an electron to free itself from the electrostatic force
holding it to its own nucleus and jump from the valence band to the
conduction band
• Unit of band gap energy
• Electron-volt (eV) = energy an electron acquires when its voltage is
increased by 1 V (1 eV = 1.6x10-19 J)
Band Gap Energy
• Band gap energy for Si
• 1.12 eV
• When electron jumps, it leaves +4 nucleus with only 3
electrons  net + charge or hole.
• Unless electron swept away by current, the same one will
recombine to fill hole
Photovoltaics (PVs)
• When electron freed, other electrons in lattice may fill the hole,
thus moving the location of net positive charge.
• Band-gap energy Ebg (J) = hn = hc/lbg
• h=6.626 x 10-34 J-s; c=speed of light 3x108 m/s; n=frequency, Hz;
lbg=band-gap wavelength, m
•  lbg=hc/Ebg=1.11 mm when Ebg=1.12 eV
• As such, silicon solar cells produce electricity only for solar
wavelengths less than 1.11 mm
Photovoltaics (PVs)
Only wavelengths less than 1.11 mm result in electricity production from pure Si cells
Other band gaps (eV) and band-gap wavelengths (mm):
Si 1.12 1.11
a-Si 1.7 0.73
CdTe 1.49 0.83
CuInSe2 1.04 1.19
CuGaSe2 1.67 0.74
GaAs 1.43 0.87
Shorter band-gap wavelength higher band-gap energy
Maximum PV Efficiency
Of total solar spectrum, PV converts energy below max wavelength, and
for each wavelength only up to max band-gap energy (Ebg). Thus, for Si,
• 30.2% of solar spectrum unavailable below lbg=1.11 mm because
hn>Ebg
• 20.2% unavailable above lbg= 1.11 mm
• 49.6% available
• Another 7% loss due high temperatures (Stefan Boltzmann losses
sT4)
• Another 10% loss due to recombination of electrons
 33.7% max efficiency for single-junction PV cell=Shockley-Queisser
limit
Ideal PV Efficiency
• Lower Ebghigher band-gap wavelength/fewer losses above it
but more loss below it because more hn>Ebg
• Higher Ebglower band-gap wavelength/greater losses above
it but less loss below it because less hn>Ebg
 Greatest efficiency around Ebg = 1.2-1.6 eV
Temperature Effect on Band Gap
Energy
• Band gap energy T dependent
• Higher T  less energy needed to send electron into
conduction band Ebg decreases and lbg increases
• Lower T  Ebg increases and lbg decreases
Photovoltaics (PVs)
• PV panels contain a built-in electric field to prevent electrons
from recombining with Si by carrying those in conduction band
away
• To create electric field, contaminate each respective side of
PV cell with 1 atom per 1,000 of Si of
• Element with 5 electrons in valence band (e.g., P) from
Column V
• Element with 3 electrons in valence band (e.g, B) from
Column III
N-Type Material
• P has 5 electrons in valence
band, but there are only 4
electrons from surrounding Si
atoms to form covalent bonds
with, so 5th electron breaks free
and roams while P retains an
immobile positive charge
 n-type material since P donates
negatively-charged electron
P-Type Material
• B has 3 outer shell electrons, so
forms covalent bonds form with
only 3 Si atoms. So, B borrows
electron from nearby Si to form 4th
bond,  B has net negative
immobile charge. Si now has hole
filled by another electron  hole
elsewhere.  B is p-type since
creates roaming hole
Photovoltaics (PVs)
Types of PV Cells
• Si 2nd most abundant element = 20% of Earth’s crust.
• Si from high quality Silica or quartz (SiO2) from mines or sand.
• Single crystal Si (sc-Si) – uniform structure
• Polycrystalline Si (poly-Si) rock like chunks of a multifaceted metal
– less expensive and less efficient than sc-Si
• Amorphous Si (a-Si) made by vapor deposition of silane &
hydrogen gas – used in thin-film PV cells
Types of PV Cells
• First generation: 200 mm thick
 (sc-Si or poly-Si)
• Second generation: thin film (1-10 mm thick)
 (GaAs, CdTe, CIGS, or a-Si)
• Third generation: Multijunction tandem cells
 Single thin film with multiple materials or stack of different thin films
 One film: 33.7% max efficiency; two: 47%; three: 53%
PV Modules and Arrays
• One PV cell = ~0.5 V
• Module = 72, 96, or 128 pre-wired cells in a series in a package
• Array=modules wired in series to increase v or in parallel to
increase i.
• For array, must optimize modules in series or parallel for max
p=vi
PV Modules and Arrays
• Modules first stringed in series to increase v as much as safe,
then strings put in parallel to maximize power. This minimizes
i2Rw losses too.
• For series, total v is sum of individual module v’s and total i is
just the i in any one module.
PV Modules and Arrays
For strings in parallel, total current is sum of currents of each
string and total v is just the v of individual string.
Output of PV Panels
Solar PV Panel I-V and P-V Curves
Fill Factor and Panel Efficiency
Fill Factor
FF= pMPP / (iSCvOC)
Panel Efficiency
Epanel = pMPP,STC / (F1000 Apanel)
.
I-V Curves For Series or Parallel
Panels
PV Losses
PAC=PDC,STC x Derate Factor x Ctemp
Derate factor (range)
PV module nameplate DC rating 0.98 (0.9-1.05)
Inverter DC to AC efficiency 0.98 (0.97-0.99)
Diodes and connections 0.995 (0.99-0.997)
DC wiring 0.98 (0.97-0.99)
AC wiring 0.99 (0.98-0.993)
Soiling 0.98 (0.7-0.995)
System availability 0.99 (0.7-1)
Age 0.98 (0.7-1) (0.5% per year)
Shading 0.97 (0.7-1)
Total derate factor 0.864 (0.2-1)
PV Output Correction for Cell
Temperature
Ctemp = 1 – brefmax(min(Tc-Tref,55),0)
bref = Temperature coefficient (0.0011-0.0063 K-1) (e.g., 0.0025
K-1)
Tc = Ta+0.32Ftot/(8.91+2w) = PV cell temperature (K)
Tref = reference temperature (298.15 K)
w = ambient wind speed (m/s)
Ftot = solar flux (W/m2) normal to a panel
Shading Derate Factor
• Ground Cover Ratio (GCR)=Collector Area (AC)/Total Ground Area (AG)
• AC= panel height x width
• AG= (panel height x cos(tilt angle)+distance between panels) x width
• For tilt angle=30o, panel width=1.2 m, panel height=0.6 m, d= 0.76 m,
• GCR = 0.6 x 1.2 / [(0.6 cos(30o) + 0.76) x 1.2] = 0.47.
• This gives a derate factor for 30o fixed tilt of 0.975 (next slide)
Shading Derate Factor
Solar Output With Tilted and Tracked
PV Panels
Geometry For Calculating Solar Zenith
Angle on a Sphere
Solar Zenith Angle
• Cosine of solar zenith angle
• Solar declination angle (d)
 Angle between the equator and the north or south latitude of the point
the point at which the sun is directly overhead
• Local hour angle (Ha)
 Angle, measured westward, between longitude of the point at which
which the sun is directly overhead and longitude of location of
interest.
cos qs = sinjsind + cos jcos dcos Ha
Solar Declination Angle
• Solar declination angle (angle between equator and point at which sun is
overhead)
• Obliquity of the ecliptic [Angle between the plane of the Earth's equator and the
plane of the Earth's orbit around the Sun (ecliptic)].
• Number of days since 12 PM GMT, January 1, 2000
NJD = 364.5 + 365 (Y – 2001) + DL + DJ
eob = 23
o
.439 - 0
o
.0000004NJD
d = sin-1
sineob sinlec
( )
Solar Declination Angle Terms
• Ecliptic longitude of the sun
Angular distance along the plane of Earth’s orbit around the sun (ecliptic) between a
line from the sun to the current position of the Earth and a reference line found when
the sun passes closest to the Earth (perihelion) during the NH spring equinox on a
specific date
• Mean longitude of the sun. Same as ecliptic longitude, but assuming a circular orbit.
• Mean anomaly of the sun. Angular distance of Earth at its perihelion with elliptical
versus circular orbit
LM = 280
o
.460 +0
o
.9856474NJD
gM = 357
o
.528 + 0
o
.9856003NJD
lec = LM +1
o
.915singM +0
o
.020sin2gM
Solar Zenith Angle
• Local hour angle (longitude angle between point of interest and overhead
sun; ts=# seconds past local noon)
• Example:
 At noon, when sun is directly overhead, Ha = 0 --->
 When the sun is over the equator, d = 0 --->
Ha =
2pts
86,400
cos qs = sinjsind + cos jcos d
cos qs = cosjcos Ha
cos qs = sinjsind + cos jcos dcos Ha
Solar Zenith Angle
Example:
1:00 p.m., PST, Feb. 27, 2018,  = 35 oN
---> NJD = 6,631.4
---> gM = 6893.4o (mean anomaly of sun)
---> Lm = 6816.7o (mean longitude of sun)
---> lec = 6818.2o (ecliptic longitude of sun)
---> ob = 23.436o (obliquity of ecliptic)
---> d = -8.489o (solar declination)
---> Ha = 15.0o (hour angle)
---> s = arccos[sin(35o)sin(-8.489o)+cos(35o)cos(-
8.489o)cos(15o)]=45.7o
Optimal Tilt Angles by
Country/Latitude
Jacobson and Jadhav (2018)
Northern Hemisphere Southern
Hemisphere
0
10
20
30
40
50
60
70
0
10
20
30
40
50
60
70
0 8 16 24 32 40 48 56 64
C09: 2.14+ j0.764
T11: 7.203+ j0.6804
This study: 1.3793+ j(1.2011+ j(-0.014404
+j0.000080509)) (R=0.96)
Optimal
Tilt
Angle
(degrees)
Latitude (degrees)
Northern Hemisphere
-50
-40
-30
-20
-10
0
10
-50
-40
-30
-20
-10
0
10
-50 -40 -30 -20 -10 0
C09: -2.14+ j0.764
T11: -7.203+ j0.6804
This study:-0.41657+ j(1.4216+ j(0.024051
+j0.00021828)) (R=0.97)
Optimal
Tilt
Angle
(degrees)
Latitude (degrees)
Southern Hemisphere
Solar Zenith Angles in a Vacuum For
Tilting/Tracking
Horizontal cosz=sin sin(d) + cos cos(d) cosH
Optimal tilt cosz=sin sin(d + b) + coscos(d + b)cosH
1-Axis vertical tracking cosz=sin2 + cos2 cosH
1-Axis horizontal tracking cosz=sin sin(d + b) + cos cos(d + b)
2-Axis tracking cosz=sin2 + cos2 z=1
 = latitude
d = solar declination
H = hour angle
b = optimal tilt angle
Solar Zenith in Air for Tilting/Tracking
z,air = arcsin(sinz/rair) for z ≤ p /2
z,air = z + z,crit - p/2 for z > p/2
Critical zenith angle
z,crit = arcsin(1/rair) = 88.649o
Refractive index of air at 550 nm
rair = 1.000278
Solar Flux Normal to a Panel
Solar flux (W/m2/mm) normal to a panel at wavelength l
Ftot,l = Fdiffuse,l + cosz,airFdirect,l
Fdiffuse,l = diffuse irradiance normal to a panel at wavelength l
Fdirect,l = direct irradiance parallel to solar beam at
wavelength l
z,air = solar zenith angle in air
0
1
2
3
4
5
6
7
0
1
2
3
4
5
6
7
-80 -40 0 40 80
Latitude (degrees)
Annual average
0
1
2
3
4
5
6
7
0
1
2
3
4
5
6
7
-80 -40 0 40 80
GATOR-GCMOM 2050 2o
x2.5o
(global: 4.48)
ESS data 1983-2005 1
o
x1
o
(global: 4.53)
Global
horizontal
radiation
(kWh/m
2
/day)
1
1.2
1.4
1.6
1.8
2
2.2
2.4
2.6
1
1.2
1.4
1.6
1.8
2
2.2
2.4
2.6
-80 -40 0 40 80
Optimal tilt
1-Axis vertical tracking
1-Axis horizontal tracking
2-Axis tracking
Ratio
diffuse+direct
radiation
Latitude (degrees)
Annual average
normal
to
tilted
or
tracked
panel
versus
horizontal
panel
0
2
4
6
8
0
2
4
6
8
-80 -40 0 40 80
Horizontal
Optimal tilt
1-Axis vertical tracking
1-Axis horizontal tracking
2-axis tracking
(d) Latitude (degrees)
Annual average
Direct+diffuse
radiation
(kWh/m
2
/day)
Ann. Avg. Model v. SSE Data
Direct + Diffuse Solar Radiation
to Horizontal PV panel
Modeled Ratio of Radiation to
Tilted or Tracked PV Panel to
Horizontal PV Panel
Modeled Direct + Diffuse Solar
Radiation Reaching Tilted or
Tracked PV Panel
JacobsonandJadhav(2018)
Annual Average Incident Direct+Diffuse
Solar Radiation to Horizontal PV Panel
Incident solar, horizontal panel (kWh/m2/day) (g:4.57; l:4.48; o:4.60)
2
3
4
5
6
-180 -90 0 90 180
-90
0
90
JacobsonandJadhav(2018)
Incident solar, horizontal panel (kWh/m2/day) (g:4.57; l:4.48; o:4.60)
2
3
4
5
6
-180 -90 0 90 180
-90
0
90
Incident solar ratio, 2-axis track:flat panel (gl:1.39; l:1.50; o:1.34
1
1.5
2
2.5
-180 -90 0 90 180
-90
0
90
Annual Avg Direct+Diffuse Solar Radiation
Reaching Horizontal PV Panel
Ratio of Solar Radiation
Reaching 2-Axis Tracked v.
Horizontal PV Panel
JacobsonandJadhav(2018)
Calculation Solar Radiation Reaching
the Surface of the Earth
Solar Radiation at Surface Depends on
Cloudiness
MODIS Cloud Fraction 2001-5 average (0.693)
0
0.5
1
-180 -90 0 90 180
-90
0
Incident solar, horizontal panel (kWh/m2/day) (g:4.57; l:4.48; o:4.60)
2
3
4
5
6
-180 -90 0 90 180
-90
0
90
kWh/m2/day)
World Solar Resource
(TW, Annually Averaged)
Land Ocean Global
Solar hitting ground 27,800 69,200 97,000
Max electricity 5,600 13,800 19,400
Practical electricity 1,300 50 1,350
Radiation Spectrum
10
-28
10
-20
10
-12
10
-4
104
10
12
1020
10
28
1036
10-6
10-4
10-2
100
102
104
106
108
1010
1012
10
-6
10
-4
10
-2
10
0
10
2
10
4
10
6
10
8
10
10
10
12
Radiation
intensity
(W
m
-2
mm
-1
)
Wavelength (mm)
6000
K
15
million
K
Gamma
X
UV
Visible
Infrared
Short
radio
AM
radio
Long
radio
Television
&
FM
radio
300
K
1
K
Radiation Spectra of Earth and Sun
10
-4
10
-2
10
0
10
2
10
4
0.01 0.1 1 10 100
Radiation
intensity
(W
m
-2
mm
-1
)
Wavelength (mm)
Sun
Earth
Ultraviolet
Visible
Infrared
Stefan-Boltzmann Law
Integrate spectral irradiance over all wavelengths
Stefan-Boltzmann law (W m-2)
Fb = sBT4
Stefan-Boltzmann constant
sB = 5.67 x 10-8 W/m2-K4
Example
T = 5800 K ---> Fb = 64 million W/m2
T = 288 K ---> Fb = 390 W/m2
Wien’s Law
100
102
104
106
108
0.01 0.1 1 10 100
Spectral
irradiance
(W
m
-2
mm
-1
)
Wavelength (mm)
6000 K
4000 K
2000 K
1000 K
300 K
0.5 mm
10 mm
Radiation
Intensity
(W/m
2
/mm)
Wien’s Displacement Law
Differentiate Planck's law with respect to wavelength at constant
temperature and set result to zero
Peak wavelength of emissions from blackbody
Sun’s photosphere lp = 2897/5800 K = 0.5 mm
Earth’s surface lp = 2897/288 K = 10.1 mm
lp mm
( ) »
2897
T K
( )
Earth-Sun Distance Varies Over Year
Solar Flux to Earth
Solar flux at top of Earth’s atmosphere (W/m2)
Averages 1,365 W/m2 over a year but varies daily
Res = Earth-sun distance (Astronomical Units, AU)×149,598,000 km/AU
Rp = radius of sun’s photosphere = 693,600 km
Fp = solar flux at photosphere = 63.5 million W/m2
Fe = Fp
Rp
Res
æ
è
ç
ç
ö
ø
÷
÷
2
Earth-Sun Distance
Earth-sun dist. (Astronomical Units, AU) Varies
0.984 to 1.018 (3.4%)
Res,AUs = 1.0014-0.01671cos(gM)-
0.00014cos(2gM)
Radiation intensity proportional to 1/Res
2 – varies
0.97 to 1.04 (by 7%)
Mean anomaly of the sun gM=357o.528 +
0o.9856003NJD
NJD=Number days (including leap days) from 12
PM GMT Jan 1, 2000. NJD=1 at 12 PM January
2, 2000;
NJD=366 at 12 PM January 1, 2001
Solid Angle
Radiance emitted from point (O) passes through
incremental area dAs at distance rs from the point.
Incremental surface area
Incremental solid angle (sr)
Steradians analogous to radians
Solid angle around a sphere
dAs = rsdq
( ) rs sinqdf
( )= rs
2
sinqdqdf
dWa =
dAs
rs
2
= sinqdqdf
Wa = dWa
Wa
ò = sinqdqdf
0
p
ò
0
2p
ò = 4p
Spectral Irradiance
Flux of radiant energy propagating across a flat surface
Incremental spectral irradiance
Integral of dFl over the hemisphere above the x-y plane
Isotropic spectral irradiance
dFl = Il cosqdWa
Fl = dFl
Wa
ò = Il cosqdWa
Wa
ò = Il cosqsinqdqdf
0
p 2
ò
0
2p
ò
F
l = Il cosq sinqdqdf
0
p 2
ò
0
2p
ò = pIl
Extinction Coefficient
Loss of radiation through the atmosphere per unit distance
Total extinction coefficient (km-1)
ss,g = due to scattering by gases
sag = due to absorption by gases
ssp = due to scattering by aerosol and cloud particles
sap = due to absorption by aerosol and cloud particles
l = wavelength
sl = ss,g,l +sa,g,l +ss,p,l +sa,p,l
Particle Scattering
Combination of reflection, refraction, and diffraction
Optical Depth
Dimensionless = extinction coefficient
multiplied by distance thru air
dSb = incremental distance along solar
beam
dt = -sld = zincremental optical depth
dz = incremental altitude distance
m = cosine of solar zenith angle
tl = sl dz
¥
z
ò = slms dSb
¥
Sb
ò
dz = cosqsdSb =msdSb
Radiative Transfer Equation
Change in radiance / irradiance along a beam of interest
Change in radiance along incremental path length
Scattering of radiation out of the beam
Absorption of radiation along the beam
dIl = -dIso,l -dIao,l +dIsi,l +dISi,l
dIso,l = Ilss,ldSb
dIao,l = Ilsa,ldSb
Scattering Angles
Single scattering of direct solar
radiation and multiple
scattering of diffuse radiation.
Radiative Transfer Equation
Multiple scattering of diffuse radiation into the beam
Single scattering of direct solar radiation into beam
dIsi,l =
ss,k,l
4p
Il, ¢
m , ¢
f Ps,k,l,m, ¢
m ,f, ¢
f d ¢
m
-1
1
ò d ¢
f
0
2p
ò
æ
è
ç
ç
ö
ø
÷
÷
k
å
é
ë
ê
ê
ù
û
ú
ú
dSb
dISi,l =
ss,k,l
4p
Ps,k,lm,-ms ,f,fs
æ
è
ç
ç
ö
ø
÷
÷
k
å
é
ë
ê
ê
ù
û
ú
ú
Fs,le
-tl ms
dSb
Extinction Coefficients
Extinction due to total scattering
Extinction due to total absorption
Extinction due to total scattering plus absorption
ss,l = ssg,l +ssp,l
sa,l = sag,l +sap,l
sl = ss,l + sa,l
Scattering Phase Function
Gives angular distribution of scattered energy vs. direction
Scattering phase function for diffuse radiation
redirects diffuse radiation from m’, ’ to m, 
Scattering phase function for direct radiation
redirects direct solar radiation from -ms,
s to m, 
P
s,k,l,m, ¢
m ,f, ¢
f
P
s,k,l,m,-ms,f,fs
Scattering Phase Function
Scattering phase function defined such that
 = angle between directions m’, ’ and m, 
Substitute -->
1
4p
P
s,k,l Q
( )
4p
ò dWa =1
dWa =sin QdQdf
1
4p
P
s,k,l Q
( )sinQdQdf
0
p
ò
0
2p
ò = 1
Scattering Phase Function
Phase function for isotropic scattering
Phase function for Rayleigh scattering
Ps,k,l Q
( )=1
Ps,k,l Q
( )=
3
4
1+cos2
Q
( )
Scattering Phase Function
Scattering phase functions for (a) isotropic and (b) Rayleigh
scattering
-1.5
-1
-0.5
0
0.5
1
1.5
-2
-1.5
-1
-0.5
0
0.5
1
1.5
2
Q
(Q)
Ps
Asymmetry Factor
First moment of phase function -- relative direction of scattering
ga,k,l
> 0 forward (Mie) scattering
= 0 isotropic or Rayleigh scattering
< 0 backward scattering
ì
í
ï
î
ï
ga,k,l =
1
4p
Ps,k,l Q
( )cosQsinQdQdf
0
p
ò
0
2p
ò
Radiative Transfer Equation
Single scattering albedo
dIl,m,f
dSb
= -Il,m,f ss,l +sa,l
( )+
ss,k,l
4p
Il, ¢
m , ¢
f Ps,k,l,m, ¢
m ,f, ¢
f d ¢
m
-1
1
ò d ¢
f
0
2p
ò
æ
è
ç
ç
ö
ø
÷
÷
k
å
+Fs,le
-tl ms
ss,k,l
4p
Ps,k,l,m,-ms ,f,fs
æ
è
ç
ç
ö
ø
÷
÷
k
å
ss,l
sl
=
ss,g,l +ss,p,l
ss,g,l +sa,g,l +ss,p,l +sa,p,l
= ws,l
Rewrite Radiative Transfer Equation
where
m
dIl,m,f
dtl
= Il,m,f - Jl,m,f
diffuse
- Jl,m,f
direct
Jl,m,f
diffuse
=
1
4p
ss,k,l
sl
Il, ¢
m , ¢
f Ps,k,l,m, ¢
m ,f, ¢
f d ¢
m
-1
1
ò d ¢
f
0
2p
ò
æ
è
ç
ç
ö
ø
÷
÷
k
å
Jl,m,f
direct
=
1
4p
Fs,le
-tl ms
ss,k,l
sl
Ps,k,l,m,-ms ,f,fs
æ
è
ç
ç
ö
ø
÷
÷
k
å
Two-Stream Method
Divide phase function into upward (+) and downward
component
1
4p
Il, ¢
m , ¢
f Ps,k,l,m, ¢
m ,f, ¢
f d ¢
m
-1
1
ò d ¢
f
0
2p
ò »
1+ ga,k,l
( )
2
I ­+
1- ga,k,l
( )
2
I ¯ upward
1+ ga,k,l
( )
2
I ¯+
1- ga,k,l
( )
2
I ­ downward
ì
í
ï
ï
î
ï
ï
Substitute this equation into Jdiffuse
1
4p
ss,k,l
sl
Il, ¢
m , ¢
f Ps,k,l,m, ¢
m ,f, ¢
f d ¢
m
-1
1
ò d ¢
f
0
2p
ò
æ
è
ç
ç
ö
ø
÷
÷
k
å »
ws,l 1- bl
( )I ­+ws,lblI ¯
ws,l 1- bl
( )I ¯+ws,lblI ­
ì
í
ï
î
ï
Two-Stream Method
Integrated fraction of forward scattered energy
Integrated fraction of backscattered energy
1 - bl =
1+ ga,l
2
Effective asymmetry parameter
bl =
1- ga,l
2
ga,l =
ss,a,lga,p,l
ss,g,l +ss,p,l
Two-Stream Approximation
Upward radiance equation
Downward radiance equation
Irradiances in terms of radiance for two-stream approximation
m1
dI -
dt
= I --ws 1- b
( )I --wsbI ¯-
ws
4p
1-3gam1ms
( )Fse
-t ms
-m1
dI ¯
dt
= I ¯-ws 1- b
( )I ¯-wsbI --
ws
4p
1+3gam1ms
( )Fse
-t ms
F ¯= 2pm1I ¯
F -= 2pm1I -
Two-Stream Approximation
Substitute irradiances and generalize for different phase function
approximations
Surface boundary condition
dF -
dt
= g1F --g2F ¯-g3wsFse
-t ms
dF ¯
dt
= -g1F ¯+g2F -+ 1- g3
( )wsFse
-t ms
F -B= AeF ¯B +AemsFse
-tNL+1 2
ms
Two-Stream Approximation
Coefficients for two stream approximations using two
techniques
g1 =
1-ws 1+ ga
( ) 2
m1
g2 =
ws 1- ga
( )
2m1
g3 =
1-3gam1ms
2

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SolarPV&SolarResources.pptx

  • 1. 100% Clean, Renewable Energy and Storage for Everything Mark Z. Jacobson Stanford University
  • 3. How to PV Panels Work?
  • 4. Photovoltaics (PVs) • Defined: A material or device that converts photons of light energy to electrical voltage and current • A photon with short enough wavelength can cause an electron in a PV material (semiconductor, such as Si) to break free of the atom that holds it • If a nearby electric field is provided, electrons can be swept toward a metallic contact, where they can become part of an electric current
  • 5. First solar cell to generate electricity – 1883 (Charles Fritts, U.S.) Pressed a thin film of selenium against a brass metal plate, then laid an even thinner layer of gold on top. The gold layer was so thin that sunlight could penetrate through it. Exposing the gold to sunlight resulted in electricity generation. Werner Siemens, who confirmed Fritts’ experiment, commented, “In conclusion, I would say that however great the scientific importance of this discovery may be, its practical value will be no less obvious when we reflect that the supply of solar energy is both without limit and without cost, and that it will continue to pour down upon us for countless ages after all the coal deposits of the earth have been exhausted and forgotten.”
  • 6. Photovoltaics (PVs) • PVs are semiconductor materials that convert sunlight to electricity • Main material is silicon (Si). Other materials: Germanium (Ge), Gallium (Ga), and Arsenic (As) • Si has 14 electrons, including 4 in outer shell, thus a +4 nucleus charge. Pure Si crystals have Si bonded to each other with covalent bonds. • Boron (B) and Phosphorus (P) are added to Silicon to create electric field in a PV cell.
  • 7. Energy Bands – Photoelectric Effect VB = valence band; CB = conduction band If an electron in the valence band acquires energy Ebg, the electron can jump to the conduction band.
  • 8. Photovoltaics (PVs) • Si is a semiconductor • Metals are conductors • Metals, semiconductors, and insulators have energy bands:  Valence band, forbidden band, and conduction band, forbidden band  Electrons in conduction band contribute to current flow • With metals, P-N junction can’t form, so free electrons move too randomly • Insulators require too much energy to add electrons to conduction band
  • 9. Band Gap Energy • Forbidden band • Gap between conduction band and valence band • Band-gap energy (Ebg) • Energy needed for an electron to free itself from the electrostatic force holding it to its own nucleus and jump from the valence band to the conduction band • Unit of band gap energy • Electron-volt (eV) = energy an electron acquires when its voltage is increased by 1 V (1 eV = 1.6x10-19 J)
  • 10. Band Gap Energy • Band gap energy for Si • 1.12 eV • When electron jumps, it leaves +4 nucleus with only 3 electrons  net + charge or hole. • Unless electron swept away by current, the same one will recombine to fill hole
  • 11. Photovoltaics (PVs) • When electron freed, other electrons in lattice may fill the hole, thus moving the location of net positive charge. • Band-gap energy Ebg (J) = hn = hc/lbg • h=6.626 x 10-34 J-s; c=speed of light 3x108 m/s; n=frequency, Hz; lbg=band-gap wavelength, m •  lbg=hc/Ebg=1.11 mm when Ebg=1.12 eV • As such, silicon solar cells produce electricity only for solar wavelengths less than 1.11 mm
  • 12. Photovoltaics (PVs) Only wavelengths less than 1.11 mm result in electricity production from pure Si cells Other band gaps (eV) and band-gap wavelengths (mm): Si 1.12 1.11 a-Si 1.7 0.73 CdTe 1.49 0.83 CuInSe2 1.04 1.19 CuGaSe2 1.67 0.74 GaAs 1.43 0.87 Shorter band-gap wavelength higher band-gap energy
  • 13. Maximum PV Efficiency Of total solar spectrum, PV converts energy below max wavelength, and for each wavelength only up to max band-gap energy (Ebg). Thus, for Si, • 30.2% of solar spectrum unavailable below lbg=1.11 mm because hn>Ebg • 20.2% unavailable above lbg= 1.11 mm • 49.6% available • Another 7% loss due high temperatures (Stefan Boltzmann losses sT4) • Another 10% loss due to recombination of electrons  33.7% max efficiency for single-junction PV cell=Shockley-Queisser limit
  • 14. Ideal PV Efficiency • Lower Ebghigher band-gap wavelength/fewer losses above it but more loss below it because more hn>Ebg • Higher Ebglower band-gap wavelength/greater losses above it but less loss below it because less hn>Ebg  Greatest efficiency around Ebg = 1.2-1.6 eV
  • 15. Temperature Effect on Band Gap Energy • Band gap energy T dependent • Higher T  less energy needed to send electron into conduction band Ebg decreases and lbg increases • Lower T  Ebg increases and lbg decreases
  • 16. Photovoltaics (PVs) • PV panels contain a built-in electric field to prevent electrons from recombining with Si by carrying those in conduction band away • To create electric field, contaminate each respective side of PV cell with 1 atom per 1,000 of Si of • Element with 5 electrons in valence band (e.g., P) from Column V • Element with 3 electrons in valence band (e.g, B) from Column III
  • 17. N-Type Material • P has 5 electrons in valence band, but there are only 4 electrons from surrounding Si atoms to form covalent bonds with, so 5th electron breaks free and roams while P retains an immobile positive charge  n-type material since P donates negatively-charged electron
  • 18. P-Type Material • B has 3 outer shell electrons, so forms covalent bonds form with only 3 Si atoms. So, B borrows electron from nearby Si to form 4th bond,  B has net negative immobile charge. Si now has hole filled by another electron  hole elsewhere.  B is p-type since creates roaming hole
  • 20. Types of PV Cells • Si 2nd most abundant element = 20% of Earth’s crust. • Si from high quality Silica or quartz (SiO2) from mines or sand. • Single crystal Si (sc-Si) – uniform structure • Polycrystalline Si (poly-Si) rock like chunks of a multifaceted metal – less expensive and less efficient than sc-Si • Amorphous Si (a-Si) made by vapor deposition of silane & hydrogen gas – used in thin-film PV cells
  • 21. Types of PV Cells • First generation: 200 mm thick  (sc-Si or poly-Si) • Second generation: thin film (1-10 mm thick)  (GaAs, CdTe, CIGS, or a-Si) • Third generation: Multijunction tandem cells  Single thin film with multiple materials or stack of different thin films  One film: 33.7% max efficiency; two: 47%; three: 53%
  • 22. PV Modules and Arrays • One PV cell = ~0.5 V • Module = 72, 96, or 128 pre-wired cells in a series in a package • Array=modules wired in series to increase v or in parallel to increase i. • For array, must optimize modules in series or parallel for max p=vi
  • 23. PV Modules and Arrays • Modules first stringed in series to increase v as much as safe, then strings put in parallel to maximize power. This minimizes i2Rw losses too. • For series, total v is sum of individual module v’s and total i is just the i in any one module.
  • 24. PV Modules and Arrays For strings in parallel, total current is sum of currents of each string and total v is just the v of individual string.
  • 25. Output of PV Panels
  • 26. Solar PV Panel I-V and P-V Curves
  • 27. Fill Factor and Panel Efficiency Fill Factor FF= pMPP / (iSCvOC) Panel Efficiency Epanel = pMPP,STC / (F1000 Apanel) .
  • 28. I-V Curves For Series or Parallel Panels
  • 29. PV Losses PAC=PDC,STC x Derate Factor x Ctemp Derate factor (range) PV module nameplate DC rating 0.98 (0.9-1.05) Inverter DC to AC efficiency 0.98 (0.97-0.99) Diodes and connections 0.995 (0.99-0.997) DC wiring 0.98 (0.97-0.99) AC wiring 0.99 (0.98-0.993) Soiling 0.98 (0.7-0.995) System availability 0.99 (0.7-1) Age 0.98 (0.7-1) (0.5% per year) Shading 0.97 (0.7-1) Total derate factor 0.864 (0.2-1)
  • 30. PV Output Correction for Cell Temperature Ctemp = 1 – brefmax(min(Tc-Tref,55),0) bref = Temperature coefficient (0.0011-0.0063 K-1) (e.g., 0.0025 K-1) Tc = Ta+0.32Ftot/(8.91+2w) = PV cell temperature (K) Tref = reference temperature (298.15 K) w = ambient wind speed (m/s) Ftot = solar flux (W/m2) normal to a panel
  • 31. Shading Derate Factor • Ground Cover Ratio (GCR)=Collector Area (AC)/Total Ground Area (AG) • AC= panel height x width • AG= (panel height x cos(tilt angle)+distance between panels) x width • For tilt angle=30o, panel width=1.2 m, panel height=0.6 m, d= 0.76 m, • GCR = 0.6 x 1.2 / [(0.6 cos(30o) + 0.76) x 1.2] = 0.47. • This gives a derate factor for 30o fixed tilt of 0.975 (next slide)
  • 33. Solar Output With Tilted and Tracked PV Panels
  • 34. Geometry For Calculating Solar Zenith Angle on a Sphere
  • 35. Solar Zenith Angle • Cosine of solar zenith angle • Solar declination angle (d)  Angle between the equator and the north or south latitude of the point the point at which the sun is directly overhead • Local hour angle (Ha)  Angle, measured westward, between longitude of the point at which which the sun is directly overhead and longitude of location of interest. cos qs = sinjsind + cos jcos dcos Ha
  • 36. Solar Declination Angle • Solar declination angle (angle between equator and point at which sun is overhead) • Obliquity of the ecliptic [Angle between the plane of the Earth's equator and the plane of the Earth's orbit around the Sun (ecliptic)]. • Number of days since 12 PM GMT, January 1, 2000 NJD = 364.5 + 365 (Y – 2001) + DL + DJ eob = 23 o .439 - 0 o .0000004NJD d = sin-1 sineob sinlec ( )
  • 37. Solar Declination Angle Terms • Ecliptic longitude of the sun Angular distance along the plane of Earth’s orbit around the sun (ecliptic) between a line from the sun to the current position of the Earth and a reference line found when the sun passes closest to the Earth (perihelion) during the NH spring equinox on a specific date • Mean longitude of the sun. Same as ecliptic longitude, but assuming a circular orbit. • Mean anomaly of the sun. Angular distance of Earth at its perihelion with elliptical versus circular orbit LM = 280 o .460 +0 o .9856474NJD gM = 357 o .528 + 0 o .9856003NJD lec = LM +1 o .915singM +0 o .020sin2gM
  • 38. Solar Zenith Angle • Local hour angle (longitude angle between point of interest and overhead sun; ts=# seconds past local noon) • Example:  At noon, when sun is directly overhead, Ha = 0 --->  When the sun is over the equator, d = 0 ---> Ha = 2pts 86,400 cos qs = sinjsind + cos jcos d cos qs = cosjcos Ha cos qs = sinjsind + cos jcos dcos Ha
  • 39. Solar Zenith Angle Example: 1:00 p.m., PST, Feb. 27, 2018,  = 35 oN ---> NJD = 6,631.4 ---> gM = 6893.4o (mean anomaly of sun) ---> Lm = 6816.7o (mean longitude of sun) ---> lec = 6818.2o (ecliptic longitude of sun) ---> ob = 23.436o (obliquity of ecliptic) ---> d = -8.489o (solar declination) ---> Ha = 15.0o (hour angle) ---> s = arccos[sin(35o)sin(-8.489o)+cos(35o)cos(- 8.489o)cos(15o)]=45.7o
  • 40. Optimal Tilt Angles by Country/Latitude Jacobson and Jadhav (2018) Northern Hemisphere Southern Hemisphere 0 10 20 30 40 50 60 70 0 10 20 30 40 50 60 70 0 8 16 24 32 40 48 56 64 C09: 2.14+ j0.764 T11: 7.203+ j0.6804 This study: 1.3793+ j(1.2011+ j(-0.014404 +j0.000080509)) (R=0.96) Optimal Tilt Angle (degrees) Latitude (degrees) Northern Hemisphere -50 -40 -30 -20 -10 0 10 -50 -40 -30 -20 -10 0 10 -50 -40 -30 -20 -10 0 C09: -2.14+ j0.764 T11: -7.203+ j0.6804 This study:-0.41657+ j(1.4216+ j(0.024051 +j0.00021828)) (R=0.97) Optimal Tilt Angle (degrees) Latitude (degrees) Southern Hemisphere
  • 41. Solar Zenith Angles in a Vacuum For Tilting/Tracking Horizontal cosz=sin sin(d) + cos cos(d) cosH Optimal tilt cosz=sin sin(d + b) + coscos(d + b)cosH 1-Axis vertical tracking cosz=sin2 + cos2 cosH 1-Axis horizontal tracking cosz=sin sin(d + b) + cos cos(d + b) 2-Axis tracking cosz=sin2 + cos2 z=1  = latitude d = solar declination H = hour angle b = optimal tilt angle
  • 42. Solar Zenith in Air for Tilting/Tracking z,air = arcsin(sinz/rair) for z ≤ p /2 z,air = z + z,crit - p/2 for z > p/2 Critical zenith angle z,crit = arcsin(1/rair) = 88.649o Refractive index of air at 550 nm rair = 1.000278
  • 43. Solar Flux Normal to a Panel Solar flux (W/m2/mm) normal to a panel at wavelength l Ftot,l = Fdiffuse,l + cosz,airFdirect,l Fdiffuse,l = diffuse irradiance normal to a panel at wavelength l Fdirect,l = direct irradiance parallel to solar beam at wavelength l z,air = solar zenith angle in air
  • 44. 0 1 2 3 4 5 6 7 0 1 2 3 4 5 6 7 -80 -40 0 40 80 Latitude (degrees) Annual average 0 1 2 3 4 5 6 7 0 1 2 3 4 5 6 7 -80 -40 0 40 80 GATOR-GCMOM 2050 2o x2.5o (global: 4.48) ESS data 1983-2005 1 o x1 o (global: 4.53) Global horizontal radiation (kWh/m 2 /day) 1 1.2 1.4 1.6 1.8 2 2.2 2.4 2.6 1 1.2 1.4 1.6 1.8 2 2.2 2.4 2.6 -80 -40 0 40 80 Optimal tilt 1-Axis vertical tracking 1-Axis horizontal tracking 2-Axis tracking Ratio diffuse+direct radiation Latitude (degrees) Annual average normal to tilted or tracked panel versus horizontal panel 0 2 4 6 8 0 2 4 6 8 -80 -40 0 40 80 Horizontal Optimal tilt 1-Axis vertical tracking 1-Axis horizontal tracking 2-axis tracking (d) Latitude (degrees) Annual average Direct+diffuse radiation (kWh/m 2 /day) Ann. Avg. Model v. SSE Data Direct + Diffuse Solar Radiation to Horizontal PV panel Modeled Ratio of Radiation to Tilted or Tracked PV Panel to Horizontal PV Panel Modeled Direct + Diffuse Solar Radiation Reaching Tilted or Tracked PV Panel JacobsonandJadhav(2018)
  • 45. Annual Average Incident Direct+Diffuse Solar Radiation to Horizontal PV Panel Incident solar, horizontal panel (kWh/m2/day) (g:4.57; l:4.48; o:4.60) 2 3 4 5 6 -180 -90 0 90 180 -90 0 90 JacobsonandJadhav(2018)
  • 46. Incident solar, horizontal panel (kWh/m2/day) (g:4.57; l:4.48; o:4.60) 2 3 4 5 6 -180 -90 0 90 180 -90 0 90 Incident solar ratio, 2-axis track:flat panel (gl:1.39; l:1.50; o:1.34 1 1.5 2 2.5 -180 -90 0 90 180 -90 0 90 Annual Avg Direct+Diffuse Solar Radiation Reaching Horizontal PV Panel Ratio of Solar Radiation Reaching 2-Axis Tracked v. Horizontal PV Panel JacobsonandJadhav(2018)
  • 47. Calculation Solar Radiation Reaching the Surface of the Earth
  • 48. Solar Radiation at Surface Depends on Cloudiness MODIS Cloud Fraction 2001-5 average (0.693) 0 0.5 1 -180 -90 0 90 180 -90 0 Incident solar, horizontal panel (kWh/m2/day) (g:4.57; l:4.48; o:4.60) 2 3 4 5 6 -180 -90 0 90 180 -90 0 90
  • 50. World Solar Resource (TW, Annually Averaged) Land Ocean Global Solar hitting ground 27,800 69,200 97,000 Max electricity 5,600 13,800 19,400 Practical electricity 1,300 50 1,350
  • 52. Radiation Spectra of Earth and Sun 10 -4 10 -2 10 0 10 2 10 4 0.01 0.1 1 10 100 Radiation intensity (W m -2 mm -1 ) Wavelength (mm) Sun Earth Ultraviolet Visible Infrared
  • 53. Stefan-Boltzmann Law Integrate spectral irradiance over all wavelengths Stefan-Boltzmann law (W m-2) Fb = sBT4 Stefan-Boltzmann constant sB = 5.67 x 10-8 W/m2-K4 Example T = 5800 K ---> Fb = 64 million W/m2 T = 288 K ---> Fb = 390 W/m2
  • 54. Wien’s Law 100 102 104 106 108 0.01 0.1 1 10 100 Spectral irradiance (W m -2 mm -1 ) Wavelength (mm) 6000 K 4000 K 2000 K 1000 K 300 K 0.5 mm 10 mm Radiation Intensity (W/m 2 /mm)
  • 55. Wien’s Displacement Law Differentiate Planck's law with respect to wavelength at constant temperature and set result to zero Peak wavelength of emissions from blackbody Sun’s photosphere lp = 2897/5800 K = 0.5 mm Earth’s surface lp = 2897/288 K = 10.1 mm lp mm ( ) » 2897 T K ( )
  • 57. Solar Flux to Earth Solar flux at top of Earth’s atmosphere (W/m2) Averages 1,365 W/m2 over a year but varies daily Res = Earth-sun distance (Astronomical Units, AU)×149,598,000 km/AU Rp = radius of sun’s photosphere = 693,600 km Fp = solar flux at photosphere = 63.5 million W/m2 Fe = Fp Rp Res æ è ç ç ö ø ÷ ÷ 2
  • 58. Earth-Sun Distance Earth-sun dist. (Astronomical Units, AU) Varies 0.984 to 1.018 (3.4%) Res,AUs = 1.0014-0.01671cos(gM)- 0.00014cos(2gM) Radiation intensity proportional to 1/Res 2 – varies 0.97 to 1.04 (by 7%) Mean anomaly of the sun gM=357o.528 + 0o.9856003NJD NJD=Number days (including leap days) from 12 PM GMT Jan 1, 2000. NJD=1 at 12 PM January 2, 2000; NJD=366 at 12 PM January 1, 2001
  • 59. Solid Angle Radiance emitted from point (O) passes through incremental area dAs at distance rs from the point. Incremental surface area Incremental solid angle (sr) Steradians analogous to radians Solid angle around a sphere dAs = rsdq ( ) rs sinqdf ( )= rs 2 sinqdqdf dWa = dAs rs 2 = sinqdqdf Wa = dWa Wa ò = sinqdqdf 0 p ò 0 2p ò = 4p
  • 60. Spectral Irradiance Flux of radiant energy propagating across a flat surface Incremental spectral irradiance Integral of dFl over the hemisphere above the x-y plane Isotropic spectral irradiance dFl = Il cosqdWa Fl = dFl Wa ò = Il cosqdWa Wa ò = Il cosqsinqdqdf 0 p 2 ò 0 2p ò F l = Il cosq sinqdqdf 0 p 2 ò 0 2p ò = pIl
  • 61. Extinction Coefficient Loss of radiation through the atmosphere per unit distance Total extinction coefficient (km-1) ss,g = due to scattering by gases sag = due to absorption by gases ssp = due to scattering by aerosol and cloud particles sap = due to absorption by aerosol and cloud particles l = wavelength sl = ss,g,l +sa,g,l +ss,p,l +sa,p,l
  • 62. Particle Scattering Combination of reflection, refraction, and diffraction
  • 63. Optical Depth Dimensionless = extinction coefficient multiplied by distance thru air dSb = incremental distance along solar beam dt = -sld = zincremental optical depth dz = incremental altitude distance m = cosine of solar zenith angle tl = sl dz ¥ z ò = slms dSb ¥ Sb ò dz = cosqsdSb =msdSb
  • 64. Radiative Transfer Equation Change in radiance / irradiance along a beam of interest Change in radiance along incremental path length Scattering of radiation out of the beam Absorption of radiation along the beam dIl = -dIso,l -dIao,l +dIsi,l +dISi,l dIso,l = Ilss,ldSb dIao,l = Ilsa,ldSb
  • 65. Scattering Angles Single scattering of direct solar radiation and multiple scattering of diffuse radiation.
  • 66. Radiative Transfer Equation Multiple scattering of diffuse radiation into the beam Single scattering of direct solar radiation into beam dIsi,l = ss,k,l 4p Il, ¢ m , ¢ f Ps,k,l,m, ¢ m ,f, ¢ f d ¢ m -1 1 ò d ¢ f 0 2p ò æ è ç ç ö ø ÷ ÷ k å é ë ê ê ù û ú ú dSb dISi,l = ss,k,l 4p Ps,k,lm,-ms ,f,fs æ è ç ç ö ø ÷ ÷ k å é ë ê ê ù û ú ú Fs,le -tl ms dSb
  • 67. Extinction Coefficients Extinction due to total scattering Extinction due to total absorption Extinction due to total scattering plus absorption ss,l = ssg,l +ssp,l sa,l = sag,l +sap,l sl = ss,l + sa,l
  • 68. Scattering Phase Function Gives angular distribution of scattered energy vs. direction Scattering phase function for diffuse radiation redirects diffuse radiation from m’, ’ to m,  Scattering phase function for direct radiation redirects direct solar radiation from -ms, s to m,  P s,k,l,m, ¢ m ,f, ¢ f P s,k,l,m,-ms,f,fs
  • 69. Scattering Phase Function Scattering phase function defined such that  = angle between directions m’, ’ and m,  Substitute --> 1 4p P s,k,l Q ( ) 4p ò dWa =1 dWa =sin QdQdf 1 4p P s,k,l Q ( )sinQdQdf 0 p ò 0 2p ò = 1
  • 70. Scattering Phase Function Phase function for isotropic scattering Phase function for Rayleigh scattering Ps,k,l Q ( )=1 Ps,k,l Q ( )= 3 4 1+cos2 Q ( )
  • 71. Scattering Phase Function Scattering phase functions for (a) isotropic and (b) Rayleigh scattering -1.5 -1 -0.5 0 0.5 1 1.5 -2 -1.5 -1 -0.5 0 0.5 1 1.5 2 Q (Q) Ps
  • 72. Asymmetry Factor First moment of phase function -- relative direction of scattering ga,k,l > 0 forward (Mie) scattering = 0 isotropic or Rayleigh scattering < 0 backward scattering ì í ï î ï ga,k,l = 1 4p Ps,k,l Q ( )cosQsinQdQdf 0 p ò 0 2p ò
  • 73. Radiative Transfer Equation Single scattering albedo dIl,m,f dSb = -Il,m,f ss,l +sa,l ( )+ ss,k,l 4p Il, ¢ m , ¢ f Ps,k,l,m, ¢ m ,f, ¢ f d ¢ m -1 1 ò d ¢ f 0 2p ò æ è ç ç ö ø ÷ ÷ k å +Fs,le -tl ms ss,k,l 4p Ps,k,l,m,-ms ,f,fs æ è ç ç ö ø ÷ ÷ k å ss,l sl = ss,g,l +ss,p,l ss,g,l +sa,g,l +ss,p,l +sa,p,l = ws,l
  • 74. Rewrite Radiative Transfer Equation where m dIl,m,f dtl = Il,m,f - Jl,m,f diffuse - Jl,m,f direct Jl,m,f diffuse = 1 4p ss,k,l sl Il, ¢ m , ¢ f Ps,k,l,m, ¢ m ,f, ¢ f d ¢ m -1 1 ò d ¢ f 0 2p ò æ è ç ç ö ø ÷ ÷ k å Jl,m,f direct = 1 4p Fs,le -tl ms ss,k,l sl Ps,k,l,m,-ms ,f,fs æ è ç ç ö ø ÷ ÷ k å
  • 75. Two-Stream Method Divide phase function into upward (+) and downward component 1 4p Il, ¢ m , ¢ f Ps,k,l,m, ¢ m ,f, ¢ f d ¢ m -1 1 ò d ¢ f 0 2p ò » 1+ ga,k,l ( ) 2 I ­+ 1- ga,k,l ( ) 2 I ¯ upward 1+ ga,k,l ( ) 2 I ¯+ 1- ga,k,l ( ) 2 I ­ downward ì í ï ï î ï ï Substitute this equation into Jdiffuse 1 4p ss,k,l sl Il, ¢ m , ¢ f Ps,k,l,m, ¢ m ,f, ¢ f d ¢ m -1 1 ò d ¢ f 0 2p ò æ è ç ç ö ø ÷ ÷ k å » ws,l 1- bl ( )I ­+ws,lblI ¯ ws,l 1- bl ( )I ¯+ws,lblI ­ ì í ï î ï
  • 76. Two-Stream Method Integrated fraction of forward scattered energy Integrated fraction of backscattered energy 1 - bl = 1+ ga,l 2 Effective asymmetry parameter bl = 1- ga,l 2 ga,l = ss,a,lga,p,l ss,g,l +ss,p,l
  • 77. Two-Stream Approximation Upward radiance equation Downward radiance equation Irradiances in terms of radiance for two-stream approximation m1 dI - dt = I --ws 1- b ( )I --wsbI ¯- ws 4p 1-3gam1ms ( )Fse -t ms -m1 dI ¯ dt = I ¯-ws 1- b ( )I ¯-wsbI -- ws 4p 1+3gam1ms ( )Fse -t ms F ¯= 2pm1I ¯ F -= 2pm1I -
  • 78. Two-Stream Approximation Substitute irradiances and generalize for different phase function approximations Surface boundary condition dF - dt = g1F --g2F ¯-g3wsFse -t ms dF ¯ dt = -g1F ¯+g2F -+ 1- g3 ( )wsFse -t ms F -B= AeF ¯B +AemsFse -tNL+1 2 ms
  • 79. Two-Stream Approximation Coefficients for two stream approximations using two techniques g1 = 1-ws 1+ ga ( ) 2 m1 g2 = ws 1- ga ( ) 2m1 g3 = 1-3gam1ms 2