Refrigeration is the process of cooling substances and is achieved through devices like refrigerators and heat pumps. Refrigerating effect quantifies the heat removed from a cold space in given time, while cooling capacity is measured in tons of refrigeration, where one ton is the heat needed to freeze one ton of water in 24 hours at 0°C. Refrigerants, such as ammonia, carbon dioxide, and freon, are substances that absorb heat through vaporization and release it during condensation.