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Delta consulting 1
12-16 November, 2006
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Corrosion Control Techniques
5.Cathodic Protection
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Corrosion Control Techniques
5.Cathodic Protection
2- Impressed current system
DC source
Ground bed
Fe
Anode
DC
Drain Point
I
Umbrella
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Corrosion Control Techniques
5.Cathodic Protection
Basics of Impressed current system
Steel nails fixed to
dry battery terminals
The steel nails
immersed in saline
water
Results:
1- The nail at +ve
terminal Corrodes
2- The nail at –ve
terminal remains
Uncorroded
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Corrosion Control Techniques
5.Cathodic Protection
Impressed current system
Nothing happens since
the nails are in different
electrolytes
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Corrosion Control Techniques
5.Cathodic Protection
Transformer Rectifiers (T/R)
• AC input
Voltage, Single/ three phase, Frequency
• DC maximum output Amp, Volt
• Air Cooled: with sun-shade
Oil Cooled: with thermometer
• Location: according to area classification
• Explosion proof (hazardous area)
• Non-explosion proof (non-hazardous area)
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Corrosion Control Techniques
5.Cathodic Protection
Transformer Rectifiers
T/R with sun-shade
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Corrosion Control Techniques
5.Cathodic Protection
Transformer Rectifiers
Explosion-proof Wall-mounted/indoors Pole-mounted
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Corrosion Control Techniques
5.Cathodic Protection
Transformer Rectifier
Alternating Current Direct Current
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Corrosion Control Techniques
5.Cathodic Protection
Mixed Metal Oxide (MMO)
Platinized
Graphite
Common Impressed current anodes:
Si – Fe
Si – Cr – Fe
Consumable Anodes Non Consumable Anodes
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Corrosion Control Techniques
5.Cathodic Protection
Common Impressed current anodes:
Si – Fe
Si – Cr – Fe
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 Are the most common impressed current anodes
 Are used in soil, water or sea water
 Come in two grades; FeSi and FeSiCr for sea water
applications
 Cable connection to anode shall be handled with great
care.
Fe Si Anodes
Corrosion Control Techniques
5.Cathodic Protection
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Corrosion Control Techniques
5.Cathodic Protection
Common Impressed current anodes:
Mixed Metal Oxide (MMO) Anodes
Solid Titanium
Core
Titanium
Substrate
with a Copper
Core
Titanium
Tubular
Titanium
Substrate Mesh
Titanium
Substrate
Ribbon
MMO is an electrically conductive
coating that is applied onto a
Titanium substrate in order to
make it act as an Anode
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Corrosion Control Techniques
5.Cathodic Protection
Common Impressed current anodes:
Mixed Metal Oxide (MMO) Anodes
MMO Coating
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Corrosion Control Techniques
5.Cathodic Protection
Common Impressed current anodes:
Graphite Anodes
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Corrosion Control Techniques
5.Cathodic Protection
Common Impressed current anodes:
Platinized Anodes
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 Impressed current anodes are
some times packaged with the
Carbonaceous backfill.
Corrosion Control Techniques
5.Cathodic Protection
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Corrosion Control Techniques
5.Cathodic Protection
Impressed Current CP Systems
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Corrosion Control Techniques
5.Cathodic Protection
Types of ground beds:
• Deep-well GB
• Horizontal shallow GB
• Distributed Anodes
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Corrosion Control Techniques
5.Cathodic Protection
Deep well > 50m depth
Carbonaceous backfill
for anodes section
Sand topping
Non-metallic
vent tube
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Property 218-L 4518
 Resistivity,
ohm-inch
0.02 0.01
 Resistivity,
ohm-cm
0.05 0.03
 Carbon (L.O.I.
method)
99.0 99.9%
 Moisture 0.10% 0.02%
 Ash 0.35% 0.10%
 VCM 0.30% 0/22%
 Sulfur 3.75% 4.3%
 Bulk Density
(lbs/ft3)
46-50 62-66
 General Sizing
+ 4 Mesh
+ 8 Mesh
- 8 Mesh
+4M < 10%
+8M > 90%
-8M < 10%
4M 10%
+20M > 80%
-20M 10%
Corrosion Control Techniques
5.Cathodic Protection
Carbonaceous backfill
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Deep-well ground beds
Corrosion Control Techniques
5.Cathodic Protection
Non-metallic Perforated Casing
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Corrosion Control Techniques
5.Cathodic Protection
Shallow Bed
Depth 3 – 5 m
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Corrosion Control Techniques
5.Cathodic Protection
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Corrosion Control Techniques
5.Cathodic Protection
Distributed Impressed Current Anodes Arrangement
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Corrosion Control Techniques
5.Cathodic Protection
Anode Connection :
Anodes cables are connected to anode / positive junction box
Each anode can be connected via a variable resistance to
control the current output
A header cable connects the PJB to e +ve terminal of T/R
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Corrosion Control Techniques
5.Cathodic Protection
Anode Connection :
Direct connection to +ve bus bar
Anode
Cables
from
GB
Main Cable to +ve
Terminal of T/R
Positive Junction Box
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Corrosion Control Techniques
5.Cathodic Protection
Anode Connection :
Connection via
variable resistance
Anode
Cables
from
GB
Main Cable to +ve
Terminal of T/R
Positive Junction Box
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Corrosion Control Techniques
5.Cathodic Protection
Typical Impressed Current System Arrangement
Ground
Bed
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Corrosion Control Techniques
5.Cathodic Protection
Positive current flux through soil to buried
pipeline and resulting distribution of current
density on pipe wall
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Corrosion Control Techniques
5.Cathodic Protection
Pipeline attenuation and
multiple ground beds
V
vs
CSE
GB1 GB2 GB3
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Corrosion Control Techniques
5.Cathodic Protection
Typical Under-Tank Cathodic Protection
System for New Tanks
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Corrosion Control Techniques
5.Cathodic Protection
Under tank
cathodic protection
MMO anode grid
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Corrosion Control Techniques
5.Cathodic Protection
Main Problem with Under-Tank CP
Systems
The protective +ve CP current
causes decomposition of water
Since water content of the soil
underneath the tank is very limited
As a result, the GB dries up – i.e. no
electrolyte – and the CP system is
aborted
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Corrosion Control Techniques
5.Cathodic Protection
Laser Slotted PVC Tubes
Solution Installation of Under-Tank Watering System
Concrete Ring
Slotted PVC Pipes
Compacted
Soil
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Corrosion Control Techniques
5.Cathodic Protection
Installation of Under-Tank Watering System
ICCP Anode Grit
Tank
PVC
Watering
Pipe
To T/R
Compacted Soil
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Corrosion Control Techniques
5.Cathodic Protection
Peripheral Anode Cathodic Protection
System for Existing Tanks
Horizontal GB
MMO strip
anode
Existing Tank
Protecting outermost bottom
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Corrosion Control Techniques
5.Cathodic Protection
Distributed Anode
Cathodic Protection
System
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Corrosion Control Techniques
5.Cathodic Protection
Cathodic protection
installation for a well
casing
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Corrosion Control Techniques
5.Cathodic Protection
Hanging
ICCP
anode
Impressed Current Cathodic
Protection for Tank Internals
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Corrosion Control Techniques
5.Cathodic Protection
Impressed Current Cathodic
Protection for Tank Internals
ICCP anode
PVC Support
Anode Cable extended to
outside along vent tube
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Corrosion Control Techniques
5.Cathodic Protection
ICCP for jackets
1- Hanging Anodes
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Corrosion Control Techniques
5.Cathodic Protection
ICCP for jackets
2- Sub-sea Sleds
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Corrosion Control Techniques
5.Cathodic Protection
Pourbaix diagram showing the
theoretical conditions for
corrosion, passivation, and
immunity of iron in water and
dilute aqueous solutions
Cathodic Protection Criteria
7 14
Potential
2.0
1.6
0.8
1.2
-0.4
0.4
0.0
-1.6
-0.8
-1.2
0
Immunity
Fe3+
Passivity
Corrosion
pH
Fe2+
45
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Corrosion Control Techniques
5.Cathodic Protection
Fe-to-Soil Potential in
Low Resistivity Soils
showing the degree of
corrosion
The value – 850 mV is
the CP criterion for
protecting steel in
aggressive soils
Description
Potential vs Cu/CuSO4
mV
-500
Free Corrosion
-700
Zone of Cathodic Protection
-900
Intense Corrosion
-600
Sever Over-Protection
Problems
-1200
Increased Over-Protection
-1100
Some Over-Protection
-1000
Some Protection
-800
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Corrosion Control Techniques
5.Cathodic Protection
Excessive negative potentials
can cause :
Cathodic Disbonding : i.e.
loss of adhesion between
the coating and the metal
surface
Hydrogen Damage : due
hydrogen evolution at –ve
potentials
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Corrosion Control Techniques
5.Cathodic Protection
Potential criteria for cathodic protection of some metals
and alloys at 25º C (1)
(1) According to British code of practice No. CP 1021, August 1973.
(2) But not more negative than about -1.2 Volts.
Metal/ Alloy Potential criterion (mV)
vs Cu/ Cu SO4
Iron, steel, stainless steel:
Aerobic conditions
Anaerobic conditions
-850
-950
Lead -600
Copper -500
Aluminum -950 (2)
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Corrosion Control Techniques
5.Cathodic Protection
According to ISO 15589-1 Part 1, 2003 concerning the
CP protection criteria of On-Land Pipelines :
“The CP system shall be capable of :
polarizing all parts of the buried pipeline to
potentials more negative than – 850 mV referred to
CSE,
&
to maintain such potentials throughout the design
life of the pipeline”.
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Corrosion Control Techniques
5.Cathodic Protection
“For pipelines operating in soils with very resistivity,
a protection potential more positive than – 850 mV
referred to CSE may be considered, e.g. as follows”:
- 750 mV for 10,000 < p < 100,000 ohm.cm
- 650 mV for p 100,000 ohm.cm
>
According to ISO 15589-1 Part 1, 2003 concerning the
CP protection criteria of On-Land Pipelines :
i.e., the value of – 850 mV is only for soils with p < 10,000 ohm.cm
p = Soil Resistivity
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Corrosion Control Techniques
5.Cathodic Protection
Cathodic protection monitoring
Potential Measurement
Structure/Electrolyte Potential is measure by means of a
reference electrode :
Copper / Copper Sulfate Soil
Silver / Silver Chloride Sea Water
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Corrosion Control Techniques
5.Cathodic Protection
Copper / Copper Sulfate
reference electrode
Portable Type
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Corrosion Control Techniques
5.Cathodic Protection
Copper / Copper Sulfate
reference electrode
In order to measure the structure – to – soil potential ,
the CSE must become part of the soil
This is fulfilled by inter-mixing of the CSE content with
the soil content due to diffusion down a concentration
gradient
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Corrosion Control Techniques
5.Cathodic Protection
H2O (
SO4
2-
SO4
2-
Soil)
Copper Rod
CuSO4 Saturated
Water molecules
migrate into CSE
Sulfate ions migrate
from CSE to soil
Porous Disc
AVO meter
Typical Arrangement for Pipe
– to – Soil Measurement
Solution
HIGH WATER CONTENT
HIGH SO4
2- IONS
CONTENT
Pipe
Cu
Cu2+
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Corrosion Control Techniques
5.Cathodic Protection
Typical Arrangement for Pipe – to – Soil Measurement
Icp umbrella
Icp umbrella
CSE
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Corrosion Control Techniques
5.Cathodic Protection
Voltmeter
IR error
Ep
CP current
CSE @ soil
surface
Coating
Eon Reading
Eon = Ep + IR Error
Voltmeter
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Corrosion Control Techniques
5.Cathodic Protection
Voltmeter
Ep
CSE @ soil
surface
Coating
Eoff Reading , instantaneous
Eoff = Ep
Voltmeter
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Corrosion Control Techniques
5.Cathodic Protection
Permanent Copper / Copper Sulfate
reference electrode
Prepackaged CSE
Backfill :
Gypsum +
Bentonite clay +
Sodium sulfate
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Corrosion Control Techniques
5.Cathodic Protection
Test Posts for CP Monitoring
Flush – to – ground
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Corrosion Control Techniques
4.Cathodic Protection
Electrode Placement
For pipelines : on-the-line @ every 1- 2 Km destination
For tanks : preferred under tank or closest
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Corrosion Control Techniques
5.Cathodic Protection
CP Permanent Monitoring ( Test ) Point
consists of :-
Permanent Reference Electrode ( or Portable type )
Test Post :
for pipelines : @ every 1- 2 Km intervals
for tanks : near the tank
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Corrosion Control Techniques
5.Cathodic Protection
Structure-to-Soil potential measurement using Voltmeter.
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Corrosion Control Techniques
5.Cathodic Protection
Permanently Installed Reference Electrode & Test Post
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Corrosion Control Techniques
5.Cathodic Protection
Permanent Monitoring for
Under Tank Cathodic
Protection
Tank Diameter (m) No. of Electrodes
Required
5-10 1
10-23 2
23-36 3
45 and above 4
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Corrosion Control Techniques
5.Cathodic Protection
Reference Electrodes Locations for
Under - Tank CP Systems
1/4D
1/6D
2/6D
2/8D
3/8D
1/8D
D=45m and above D=23-36m D=10.5-22.5m D=5-10m
Key : Reference Electrode
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Corrosion Control Techniques
5.Cathodic Protection
PVC pipe installed through the
concrete ring @ different locations
for CSE placement.
Concrete Ring
Under Tank Soil
PVC Pipe – See Details
Top View
PVC Pipe
Under Tank Soil
Concrete
Ring
CSE
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Corrosion Control Techniques
5.Cathodic Protection
CSE
Perforated PVC Pipe
Filled with Water
Tank
Perforated PVC Pipe Installed for Reference
Electrode Placement
AVO
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Corrosion Control Techniques
5.Cathodic Protection
Correct method for measuring structure
potentials when surface is covered with
concrete or asphalt.
AVO
CSE in Wet Soil
Buried Pipe
Concrete / Asphalt
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Corrosion Control Techniques
5.Cathodic Protection
For monitoring tank’s internal CP system use:
Hanging RE ( from roof )
Plug RE ( fixed on shell )
RE
RE
Hanging Reference Electrodes
Plug RE
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Corrosion Control Techniques
5.Cathodic Protection
Diver with portable
reference electrode
Potential Measurement of jackets / platform legs
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Corrosion Control Techniques
5.Cathodic Protection
Transponder CP
monitoring
Potential Measurement of jackets / platform legs
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Corrosion Control Techniques
5.Cathodic Protection
Potential plot after data
analysis
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Corrosion Control Techniques
5.Cathodic Protection
Potential Measurement of subsea pipelines
Trailing-wire
potential survey
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Corrosion Control Techniques
5.Cathodic Protection
TP-3
TP-1 TP-2
well
TP
TP-3 TP-4
- 850 mV Min. protection level
Un protected
area
Pipe
to
soil
potential
-
mV
What about the potential
at any point ?
Buried pipeline ( 1.2 meter deep)
Well casing
8000 feet deep
The criterion most widely used on pipelines is based on measurements
of potential differences between the pipeline and its environment
.
ie: more negative than ( - 850 mv) reference to Cu/Cu So4 cell
Potential Measurement of well casing
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Corrosion Control Techniques
5.Cathodic Protection
Potential Measurement of well casing
Up hole
Upper Centralizer
Upper Contactors
Spacer Bare
Lower Contactors
Lower Centralizer
Sinker Weight
Length
between
contactors
5
to
7
meters
V
Casing
Tool inside Casing
CASING POTENTIAL PROFILE TOOL
SPECIFICATIONS
8.5 m using 5.0 contactor spacing
10 m using 6.0 contactor spacing
length
Diameter 2.5/8 in. ( 6.5 cm) maximum
weight 440 lb.* (199.6 kg)
Max. temp. 300 deg.F (154 deg.C)
Max.
Pressure
10,000 psi (69 Mpa)
Casing
Size
4.5 in (11.4 cm) to 13.3/8 in (34 cm)
Hoisting
speed
80 ft/min (24.38 m/min
Recommended
Logging
reading
Stationary readings; average speed 25ft/
min (7.6 m/min) at 50 ft intervals
Logging
envirnment
Must be dray
Limitations
Not recommended for use in fresh
water
Typical Casing Potential Profile Tool (Courtesy of Atlas Industries, Inc.)
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Corrosion Control Techniques
5.Cathodic Protection
Potential Measurement of well casing
+ -
T R
v
OUTPUT CURRENT
= ( I )
( I )
( i1 )
( i 2 )
( i3 )
( I-i1 )
( I-i1-i2 )
( I-i1-i2 -i3)
U1
U2
U3
Casing to soil
potential= (v)
Cu/Cu So4 cell v
U1
U2
U3
-700 -850 -900 -1000
Depth
in
feet
-850mv
min.protection
level
R
R
R Ohm’s Low:
V = I x R
U = Voltage drop
= I x R pipe
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Cable – to - cable connection
Cable – to - pipe connection
Cable – to - structure connection
Corrosion Control Techniques
5.Cathodic Protection
Cable Connections
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Splice Kit : for cable-to-cable connection
Corrosion Control Techniques
5.Cathodic Protection
Cable Connections
1 2
Araldite is poured
& let to dry
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For cable-to-pipe connection :
1- Thermite ( Cad / Exothermic ) Welding
2- Pin Brazing
3- Mechanical connection ( for gas pipelines )
Corrosion Control Techniques
5.Cathodic Protection
Cable Connections
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For cable-to-pipe connection
1- Thermite Welding :
Corrosion Control Techniques
5.Cathodic Protection
Cable Connections
Crucible
Disks
Cartridge
Spark Flint
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Corrosion Control Techniques
5.Cathodic Protection
Thermite Weldment
Prior to welding :
The coating must be removed at
welding point ( 5x5 cm square )
Metal surface to be polished and
cleaned
Thermite Welding
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Corrosion Control Techniques
5.Cathodic Protection
Self-adhesive
Handy-cap
1 2 3
Protecting the Thermite Weldment
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Corrosion Control Techniques
5.Cathodic Protection
Cable Connections
For cable-to-pipe connection
2- Pin Brazing : emits less heat output
Pin Brazing Unit
Pistol / Gun
Pins & Ferrules
Lug
Grinder
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Corrosion Control Techniques
5.Cathodic Protection
Cable Connections
For cable-to-pipe connection
2- Pin Brazing
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Corrosion Control Techniques
5.Cathodic Protection
Cable Connections
For cable-to-pipe connection
2- Pin Brazing
1Clean the surface
2Load gun with pin
& ferrule
3pin braze
4Test connection
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Corrosion Control Techniques
5.Cathodic Protection
Cable Connections
For cable-to-pipe connection
3- Mechanical Connection : recommended for drain point
connection of gas pipelines
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Corrosion Control Techniques
5.Cathodic Protection
Cable Connections
Terminal Lugs :
for cable-to-structure ( tank )
connection
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Electrical isolation is made by :
Isolating flange kit ( IFK )
IFK is installed @ Aboveground / Underground Interface
Corrosion Control Techniques
4.Cathodic Protection
Electrical Isolation
Structures to be protected shall be electrically isolated
from portions which do not require protection.
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Isolating flange kit ( IFK )
Corrosion Control Techniques
4.Cathodic Protection
Electrical Isolation
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Corrosion Control Techniques
4.Cathodic Protection
Isolating flange kits
In hazardous areas , IFK’s are
protected by means of Spark Gaps
Spark Gap Fitted
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Monolithic Blocks
Corrosion Control Techniques
4.Cathodic Protection
Electrical Isolation
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Monolithic Blocks
+ Polarization Cell
Corrosion Control Techniques
4.Cathodic Protection
The monolithic blocks are
protected against electrostatic
charges and lightening by
polarization cell
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Casings for Road Crossings
Corrosion Control Techniques
4.Cathodic Protection
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Casings for Road Crossings
There should NOT be any contact
between the pipe & casing
Test posts usually installed @
crossings to monitor the potential
of pipe and casing separately
Corrosion Control Techniques
5.Cathodic Protection
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Corrosion Control Techniques
4.Cathodic Protection
Clamp Meter
Clamp Meters are used to
check:
electric cables integrity
current output of each anode
Clamp Meter
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Corrosion Control Techniques
5.Cathodic Protection
Pipeline & Cable Warning Markers
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Corrosion Control Techniques
5.Cathodic Protection
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Corrosion Control Techniques
5.Cathodic Protection
There are numerous codes and references that shall be
referred to when dealing with cathodic protection among
these are:
NACE RP 0169
NACE RP 0176
NACE RP 177
NACE RP 575
ISO 15589-1, PART I – 2003, “On-land Pipelines”
ISO 15589-2, PART II – 2004, “Offshore Pipelines”
DnV RP B 401
API 651
J. Morgan, “Cathodic Protection”
A.W. Peabody, “Control of Pipeline Corrosion”
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Terms & Definitions
Natural Potential:
Is potential of structure to be protected whenever no cathodic protection
system is applied.
Protection Potential:
Is the potential of structure to be protected whenever corrosion rate is
insignificant.
Anode Backfill:
Materials with low resistivity surrounding buried anode, may be moisture
retaining materials, used for decrease anode to electrolyte resistance and
prevent anode polarization.
Corrosion Control Techniques
5.Cathodic Protection Design
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Terms & Definitions
Drain Point:
Location of negative cable connection to the structure to be protected through
which the cathodic protection current returns to its source.
Coating Break-down Factor:
Is the ration between the current density required to polarize coated surface
and density required to polarize bare surface.
Initial Current Density
Estimated current density required for polarization of structure to be protected
at the start of the lifetime.
Final Current Density:
Estimated current density required to maintain polarization at the end of the
lifetime.
Corrosion Control Techniques
5.Cathodic Protection Design
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Terms & Definitions
Mean Current Density:
Estimated current density for the entire of the lifetime
Anode Electro-chemical Capacity:
The amount of electricity expressed by (Amper.Hour/kg) that is produced due
to anode consumption.
Cathodic Protection Criteria:
Limits of protection potentials.
Corrosion Control Techniques
5.Cathodic Protection Design
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Corrosion Control Techniques
5.Cathodic Protection
CP System Design :
Basic information for design considerations
1. Type of electrolyte (environment)
• Soil
• Fresh/ saline water.
2. Availability of power supply
3. Temperature
4. Type of coating
5. For pipelines:
• Pipeline route
• Crossings (foreign pipeline, roads, rivers, etc.)
• Presence of high transmission power lines
• Presence of foreign metallic structures.
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Corrosion Control Techniques
5.Cathodic Protection
Soil resistivity
Soil represents the electrolyte
Soils with low resistivity have high conductivity; i.e.
corrosive
NACE ranking :
Soil resistivity (ohm.cm) Corrosivity
up to 1,000 Severely corrosive
1,000-5,000 Corrosive
5,000-10,000 Moderately corrosive
10,000-20,000 Slightly corrosive
20,000 and above Non-corrosive
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Corrosion Control Techniques
5.Cathodic Protection
Four-Terminals (Wenner) Method :
For Measurement of Soil Resistivity.
Kit
Power Unit
Stainless Steel Pins
Cables
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Corrosion Control Techniques
5.Cathodic Protection
4-Terminals Arrangement
Ohm’s Low : R = V/I
R : Resistance (ohm)
V : Applied Voltage
I : Recorded Amperage
a a a
Depth = a
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Current demand for CP:
Current density : it is the current required to polarize
(1 meter)2 of bare steel in a given electrolyte.
Corrosion Control Techniques
5.Cathodic Protection Design
Current density increases with increasing temperature
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Corrosion Control Techniques
5.Cathodic Protection Design
Temperature : current demand shall be increased by 25% per
every 10º C incremental rise above 30º C. This requirement is
described by the following equation:
i = i0 + [i0 x 0.25 (t - t0)] / 10
Where,
i = current density at operating temperature, Amp/m2
i0 = base current density at standard temperature
t = operating temperature ºC
t0 = standard temperature (30ºC)
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Corrosion Control Techniques
5.Cathodic Protection
Current density determined in mA/m2 is dependant on the
media aggressivity.
Therefore if soil resistivity is low then current density shall be
high
Media Current Density
mA/m2
Aggressive Soil 10
Normal soil 5
Sea water 90
Fresh water 30
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Corrosion Control Techniques
5.Cathodic Protection
Power Supply :
The T/R is fed with AC current from the nearest power
supply.
If there is no power supply available, Solar Units to be
used instead of T/R.
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Corrosion Control Techniques
5.Cathodic Protection
240 Watt Solar Array
0-24 Volt
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Corrosion Control Techniques
5.Cathodic Protection
GB Pipe to be protected
Converter
Regulator
Batteries
Junction Box
Solar Modules
Structure
(-)
(+)
Typical Arrangement for ICCP Using Solar Energy
Sun
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Corrosion Control Techniques
5.Cathodic Protection
Typical Coating Resistances for various coating
qualities
Coating quality Range of specific
leakage resistance
(RC), ohm.m2
Poor 1,000-2,500
Fair 5,000-10,000
good 25,000-50,000
Excellent 100,000-500,000
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Corrosion Control Techniques
5.Cathodic Protection
Typical Coating Breakdown Values
Coating type % breakdown
Initial Mean Final
Thick coating ≤ 1 5 10
Epoxy coal tar ≤ 2 5-10 10-20
Fusion bonded
epoxy
1-2 5-10 5-20
Polypropylene (25
yrs)
0.5 2 5
Polyethylene (25 yrs) 0.5 1 3
CP
current
Delta consulting 115
Corrosion Control Techniques
5.Cathodic Protection
Recommended potential limits for different coatings
to avoid coating disbondment
Coating type Volt (vs Cu/ CuSO4)
Asphalt Enamel -2
Epoxy coal tar -1.5
Fusion bonded epoxy -1.5
Tape wrap -1.5
Polyethylene -1.0
Delta consulting 116
Corrosion Control Techniques
5.Cathodic Protection
Pipeline Route
Cross-country P/L’s pass through different types of soils,
i.e. different electrolytes
Presence of high voltage power transmission lines
Delta consulting 117
Corrosion Control Techniques
5.Cathodic Protection
Pipeline Route
Delta consulting 118
Corrosion Control Techniques
5.Cathodic Protection
Pipeline AC interference from
electromagnetic field
Delta consulting 119
For protection against stray current
from high tension lines, zinc ribbon
and polarization cells are used
Corrosion Control Techniques
5.Cathodic Protection
Delta consulting 120
In case of pipe-crossing of cathodically
protected pipelines BONDING is
required by means of :
Solid boning, or
Resistance bonding
Corrosion Control Techniques
5.Cathodic Protection
Stray current interference
Delta consulting 121
Stray-current corrosion
Corrosion Control Techniques
5.Cathodic Protection
Pipeline potential shifts in anodic
direction ( more positive values )
Possibility of high anodic current
densities , i.e. high corrosion rates
Pipeline potential shifts in cathodic
direction ( more negative values )
Possibility of coating disbondment
and hydrogen damage
Delta consulting 122
Corrosion Control Techniques
5.Cathodic Protection
Stray-current corrosion
Delta consulting 123
Corrosion Control Techniques
5.Cathodic Protection
Delta consulting 124
CP Current Requirement
CD= S x a x CBDC
Corrosion Control Techniques
5.Cathodic Protection
CD : Current Demand (A)
S : Design Current Density (A/m2)
a : Surface Area (m2)
CBDF : Coating Break-down Factor %
Current Rating : (1.5 times final CD)
Temperature (°C) 50 Initial Average Final
Current Density (mA/m2
) 5 CBDF (%) 0.01 2 3
Design Density (mA/m2
) 7.5 Current Demad (A) 0.0 5.7 8.6
Pipeline Length (km) 30
Pipeline Diameter (inch) 16 Current Rating (A) 13
Delta consulting 125
Anodes Weight & Quantity Requirement
Corrosion Control Techniques
5.Cathodic Protection
# of Anodes Required
Wt = Weight per anode (kg) Wt = 27.2 kg
CR = Consumption rate (kg/amp-year) CR = 0.34 kg/A-yr
DL = Desired life (years) DL = 20 yrs
Current = Current required (amps) Current = 5.70 A
UF = Utilization factor UF = 0.60
# anodes = 3.00
# of Anodes Required Based on Current Discharge
* from anode manufacturer data
MD = Maximum discharge per anode (amps) MD = 1.50 A
Current = Current required (amps) Current = 5.70 A
# anodes = 4.00
Impressed Current (On-land) Systems
Delta consulting 126
CP Circuit Resistance : (ICCP systems)
Corrosion Control Techniques
5.Cathodic Protection
R Gbed =Ground-bed resistance (ohms)
R C =Cable resistance (ohms)
R S =Pipeline/structure to earth resistance (ohms) 0.00 ohms
R T =Total circuit resistance (ohms) 0.00 ohms
Delta consulting 127
CP Ground-Bed Resistance :
Corrosion Control Techniques
5.Cathodic Protection
1) Dwight's Equation for Single Vertical Anode
ρ = Resistivity of backfill material (or earth) in ohm-cm 1,000 ohm-cm
L = Length of backfill (or anode) in meters 2.00 m
d = Diameter of backfill (or anode) in meters 0.30 m
R v = Resistance of one vertical anode to earth in ohms 2.366 ohms
Delta consulting 128
Corrosion Control Techniques
5.Cathodic Protection
2) Dwight's Equation for Multiple Vertical Anodes in Parallel
ρ = Soil (or Backfill) resistivity in ohm-cm 1,000 ohm-cm
N = Number of anodes in parallel 4 each
L = Length of backfill (or anode) in meters 2.0 m
d = Diameter of backfill (or anode) in meters 0.3 m
S = Anode spacing in meters 3.0 m
R = Resistance of vertical anodes in parallel to earth in ohms 0.8 ohms
CP Ground-Bed Resistance (cont’) :
Delta consulting 129
Corrosion Control Techniques
5.Cathodic Protection
3) Modified Dwight's Equation for Single (or Multiple) Anodes Installed Horizontally
ρ = Resistivity of Soil or (backfill) material 1,000 ohm-cm
L = Length of backfill (or anode) in meters 8.00 m
S = Twice depth of anode in meters 3.0 m
d = Diameter of backfill (or anode) in meters 0.3 m
RH = Resistance of horizontal anode (or multiple) to earth 0.9 ohms
CP Ground-Bed Resistance (cont’) :
Delta consulting 130
CP Ground-Bed Resistance :
Corrosion Control Techniques
5.Cathodic Protection
4) Dwight's Equation for Deep-Well Anodes
ρ = Effective Resistivity of earth in ohm-cm 1,000 ohm-cm
L = Length of backfill (or anode) in meters 8.00 m
d = Diameter of backfill (or anode) in meters 0.30 m
R v = Resistance of deep-well anode to earth in ohms 0.867 ohms
Delta consulting 131
Corrosion Control Techniques
5.Cathodic Protection
Cable Resistance
R CABLE = Resistance per km 0.833 ohms/km
L CABLE = Length in meters (sum of positive and negative cables) 150 m
R C = Cable resistance 0.125 ohms
CP Cables Resistance :
Delta consulting 132
CP Circuit Resistance & Driving Voltage : (ICCP systems)
Corrosion Control Techniques
5.Cathodic Protection
Driving Voltage = Max. Current x RT
R Gbed =Ground-bed resistance (ohms) 0.90 ohms
R C =Cable resistance (ohms) 0.125 ohms
R S =Pipeline/structure to earth resistance (ohms) 0.00 ohms
R T =Total circuit resistance (ohms) 1.03 ohms
Max. current (A) 13
Driving Voltage (v) 13.3
Delta consulting 133
Transformer/Rectifier (T/R) Rating:
Corrosion Control Techniques
5.Cathodic Protection
Max. current (A) 13.0
Driving Voltage (v) 13.3
T/R Output Rating:
Select near standard T/R rating:
(e.g. 12V, 24V, 36V, 48V, 5A, 10A, 15A, 20A…etc)
T/R output: 15A/24V DC
T/R Input Characteristics:
Check available electrical power characteristics:
Either 3PH, 400V AC, 50Hz Or 1PH, 230V AC, 50Hz
T/R Input: 3PH, 400V AC, 50Hz
Delta consulting 134
CP Current Attenuation (Spread) Check
(for Pipelines)
Corrosion Control Techniques
5.Cathodic Protection
En (v) Pipeline Natural Potential -0.55
∆Ea/∆Em = Cosh(αL) Ea (v) Pipeline Protective Potential at Drain Point -1.3
∆Ea (v) Pipeline Potential Shift at Drain Point -0.75
∆Ea = Ea - En Em (v) Pipeline Protective Potential at Distance (L) -0.95
∆Em = Em - En ∆Em (v) Pipeline Potential Shift at Distance (L) -0.4
α (m-1) Attenuation Constant 3.1623E-05
α = √ (Rs/Rlf) Rlf (ohm.m) Linear Coating Insulation Resistivity (final) 15664.8566
Rf (ohm.m2) Coating Insualtion Resistivity (final) 20000
Rlf = Rf/(π * D) Rs (ohm/m) Linear Pipeline Steel Conductivity 1.5665E-05
Rs = ρs/ (π * D * t) ρs (ohm.m) Pipeline Steel Specific Resistivity 0.00000019
D (m) Pipeline Diameter 0.4064
t (m) Pipeline Wall Thickness 0.0095
L (Km) Attenuation Distance 39.26
Delta consulting 135
Corrosion Control Techniques
5.Cathodic Protection
Typical Coating Resistance (for various coating qualities)
Coating quality Range of specific
leakage resistance
(Rl), ohm.m2
Poor 1,000-2,500
Fair 5,000-10,000
good 25,000-50,000
Excellent 100,000-500,000
Delta consulting 136
CP Current Requirement
CD= S x a x CBDC
Corrosion Control Techniques
5.Cathodic Protection
S : Design Current Density (A/m2)
a : Surface Area (m2)
CBDF : Coating Break-down Factor %
Temperature (°C) 50 Initial Mean Final
Current Density (mA/m2
) 90 CBDF (%) 0.01 2 3
Design Density (mA/m2
) 135 Current Demad (A) 0.5 103.4 155.1
Pipeline Length (km) 30
Pipeline Diameter (inch) 16
Coating 3PP
Sacrificial Anode Systems
Delta consulting 137
Anode Material & Dimensions Selection
Anode Material Selection
Corrosion Control Techniques
5.Cathodic Protection
Delta consulting 138
Anodes Weight & Quantity Requirement
Corrosion Control Techniques
5.Cathodic Protection
Total Mass Required
Icm = Mean Current Demand (A) 103.40 A
tdl = Design Lifetime (Year) 20 yrs
u = Utilization factor 0.80
ε = Design Electrochemical Capacity (A.hr/kg) 2500 A-hr/kg
m = Total Mass of Anodes (kg) 9057.8 kg
# of Anodes Required Based on Total Required Mass
ma = Standard Net Anode Mass (kg) 100.0 kg
n = Anodes Qty # anodes = 91
Delta consulting 139
Sacrificial VS Impressed Current CP
Sacrificial Impressed current
No need for external power source Requires an external power source
Easy to design and install Requires skillful design and
installation
uncontrollable Can be controlled
Used only for limited surface areas
and well coated structures
Can be used for uncoated surfaces
and used for any surfaces
Has no detrimental effects Can cause serious problems if not
handled carefully
Is limited to low resistivity can be used at any resistivity
Low maintenance High maintenance
Corrosion Control Techniques
4.Cathodic Protection
Delta consulting 140
Corrosion Control Techniques
5.Cathodic Protection
Sacrificial VS Impressed Current CP
141
142
143
Delta consulting 144
Thank You and Good Luck

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protection protection presentation plus image 5.ppt

  • 1. Delta consulting 1 12-16 November, 2006
  • 2. Delta consulting 2 Corrosion Control Techniques 5.Cathodic Protection
  • 3. Delta consulting 3 Corrosion Control Techniques 5.Cathodic Protection 2- Impressed current system DC source Ground bed Fe Anode DC Drain Point I Umbrella
  • 4. Delta consulting 4 Corrosion Control Techniques 5.Cathodic Protection Basics of Impressed current system Steel nails fixed to dry battery terminals The steel nails immersed in saline water Results: 1- The nail at +ve terminal Corrodes 2- The nail at –ve terminal remains Uncorroded
  • 5. Delta consulting 5 Corrosion Control Techniques 5.Cathodic Protection Impressed current system Nothing happens since the nails are in different electrolytes
  • 6. Delta consulting 6 Corrosion Control Techniques 5.Cathodic Protection Transformer Rectifiers (T/R) • AC input Voltage, Single/ three phase, Frequency • DC maximum output Amp, Volt • Air Cooled: with sun-shade Oil Cooled: with thermometer • Location: according to area classification • Explosion proof (hazardous area) • Non-explosion proof (non-hazardous area)
  • 7. Delta consulting 7 Corrosion Control Techniques 5.Cathodic Protection Transformer Rectifiers T/R with sun-shade
  • 8. Delta consulting 8 Corrosion Control Techniques 5.Cathodic Protection Transformer Rectifiers Explosion-proof Wall-mounted/indoors Pole-mounted
  • 9. Delta consulting 9 Corrosion Control Techniques 5.Cathodic Protection Transformer Rectifier Alternating Current Direct Current
  • 10. Delta consulting 10 Corrosion Control Techniques 5.Cathodic Protection Mixed Metal Oxide (MMO) Platinized Graphite Common Impressed current anodes: Si – Fe Si – Cr – Fe Consumable Anodes Non Consumable Anodes
  • 11. Delta consulting 11 Corrosion Control Techniques 5.Cathodic Protection Common Impressed current anodes: Si – Fe Si – Cr – Fe
  • 12. Delta consulting 12  Are the most common impressed current anodes  Are used in soil, water or sea water  Come in two grades; FeSi and FeSiCr for sea water applications  Cable connection to anode shall be handled with great care. Fe Si Anodes Corrosion Control Techniques 5.Cathodic Protection
  • 13. Delta consulting 13 Corrosion Control Techniques 5.Cathodic Protection Common Impressed current anodes: Mixed Metal Oxide (MMO) Anodes Solid Titanium Core Titanium Substrate with a Copper Core Titanium Tubular Titanium Substrate Mesh Titanium Substrate Ribbon MMO is an electrically conductive coating that is applied onto a Titanium substrate in order to make it act as an Anode
  • 14. Delta consulting 14 Corrosion Control Techniques 5.Cathodic Protection Common Impressed current anodes: Mixed Metal Oxide (MMO) Anodes MMO Coating
  • 15. Delta consulting 15 Corrosion Control Techniques 5.Cathodic Protection Common Impressed current anodes: Graphite Anodes
  • 16. Delta consulting 16 Corrosion Control Techniques 5.Cathodic Protection Common Impressed current anodes: Platinized Anodes
  • 17. Delta consulting 17  Impressed current anodes are some times packaged with the Carbonaceous backfill. Corrosion Control Techniques 5.Cathodic Protection
  • 18. Delta consulting 18 Corrosion Control Techniques 5.Cathodic Protection Impressed Current CP Systems
  • 19. Delta consulting 19 Corrosion Control Techniques 5.Cathodic Protection Types of ground beds: • Deep-well GB • Horizontal shallow GB • Distributed Anodes
  • 20. Delta consulting 20 Corrosion Control Techniques 5.Cathodic Protection Deep well > 50m depth Carbonaceous backfill for anodes section Sand topping Non-metallic vent tube
  • 21. Delta consulting 21 Property 218-L 4518  Resistivity, ohm-inch 0.02 0.01  Resistivity, ohm-cm 0.05 0.03  Carbon (L.O.I. method) 99.0 99.9%  Moisture 0.10% 0.02%  Ash 0.35% 0.10%  VCM 0.30% 0/22%  Sulfur 3.75% 4.3%  Bulk Density (lbs/ft3) 46-50 62-66  General Sizing + 4 Mesh + 8 Mesh - 8 Mesh +4M < 10% +8M > 90% -8M < 10% 4M 10% +20M > 80% -20M 10% Corrosion Control Techniques 5.Cathodic Protection Carbonaceous backfill
  • 22. Delta consulting 22 Deep-well ground beds Corrosion Control Techniques 5.Cathodic Protection Non-metallic Perforated Casing
  • 23. Delta consulting 23 Corrosion Control Techniques 5.Cathodic Protection Shallow Bed Depth 3 – 5 m
  • 24. Delta consulting 24 Corrosion Control Techniques 5.Cathodic Protection
  • 25. Delta consulting 25 Corrosion Control Techniques 5.Cathodic Protection Distributed Impressed Current Anodes Arrangement
  • 26. Delta consulting 26 Corrosion Control Techniques 5.Cathodic Protection Anode Connection : Anodes cables are connected to anode / positive junction box Each anode can be connected via a variable resistance to control the current output A header cable connects the PJB to e +ve terminal of T/R
  • 27. Delta consulting 27 Corrosion Control Techniques 5.Cathodic Protection Anode Connection : Direct connection to +ve bus bar Anode Cables from GB Main Cable to +ve Terminal of T/R Positive Junction Box
  • 28. Delta consulting 28 Corrosion Control Techniques 5.Cathodic Protection Anode Connection : Connection via variable resistance Anode Cables from GB Main Cable to +ve Terminal of T/R Positive Junction Box
  • 29. Delta consulting 29 Corrosion Control Techniques 5.Cathodic Protection Typical Impressed Current System Arrangement Ground Bed
  • 30. Delta consulting 30 Corrosion Control Techniques 5.Cathodic Protection Positive current flux through soil to buried pipeline and resulting distribution of current density on pipe wall
  • 31. Delta consulting 31 Corrosion Control Techniques 5.Cathodic Protection Pipeline attenuation and multiple ground beds V vs CSE GB1 GB2 GB3
  • 32. Delta consulting 32 Corrosion Control Techniques 5.Cathodic Protection Typical Under-Tank Cathodic Protection System for New Tanks
  • 33. Delta consulting 33 Corrosion Control Techniques 5.Cathodic Protection Under tank cathodic protection MMO anode grid
  • 34. Delta consulting 34 Corrosion Control Techniques 5.Cathodic Protection Main Problem with Under-Tank CP Systems The protective +ve CP current causes decomposition of water Since water content of the soil underneath the tank is very limited As a result, the GB dries up – i.e. no electrolyte – and the CP system is aborted
  • 35. Delta consulting 35 Corrosion Control Techniques 5.Cathodic Protection Laser Slotted PVC Tubes Solution Installation of Under-Tank Watering System Concrete Ring Slotted PVC Pipes Compacted Soil
  • 36. Delta consulting 36 Corrosion Control Techniques 5.Cathodic Protection Installation of Under-Tank Watering System ICCP Anode Grit Tank PVC Watering Pipe To T/R Compacted Soil
  • 37. Delta consulting 37 Corrosion Control Techniques 5.Cathodic Protection Peripheral Anode Cathodic Protection System for Existing Tanks Horizontal GB MMO strip anode Existing Tank Protecting outermost bottom
  • 38. Delta consulting 38 Corrosion Control Techniques 5.Cathodic Protection Distributed Anode Cathodic Protection System
  • 39. Delta consulting 39 Corrosion Control Techniques 5.Cathodic Protection Cathodic protection installation for a well casing
  • 40. Delta consulting 40 Corrosion Control Techniques 5.Cathodic Protection Hanging ICCP anode Impressed Current Cathodic Protection for Tank Internals
  • 41. Delta consulting 41 Corrosion Control Techniques 5.Cathodic Protection Impressed Current Cathodic Protection for Tank Internals ICCP anode PVC Support Anode Cable extended to outside along vent tube
  • 42. Delta consulting 42 Corrosion Control Techniques 5.Cathodic Protection ICCP for jackets 1- Hanging Anodes
  • 43. Delta consulting 43 Corrosion Control Techniques 5.Cathodic Protection ICCP for jackets 2- Sub-sea Sleds
  • 44. Delta consulting 44 Corrosion Control Techniques 5.Cathodic Protection Pourbaix diagram showing the theoretical conditions for corrosion, passivation, and immunity of iron in water and dilute aqueous solutions Cathodic Protection Criteria 7 14 Potential 2.0 1.6 0.8 1.2 -0.4 0.4 0.0 -1.6 -0.8 -1.2 0 Immunity Fe3+ Passivity Corrosion pH Fe2+
  • 45. 45
  • 46. Delta consulting 46 Corrosion Control Techniques 5.Cathodic Protection Fe-to-Soil Potential in Low Resistivity Soils showing the degree of corrosion The value – 850 mV is the CP criterion for protecting steel in aggressive soils Description Potential vs Cu/CuSO4 mV -500 Free Corrosion -700 Zone of Cathodic Protection -900 Intense Corrosion -600 Sever Over-Protection Problems -1200 Increased Over-Protection -1100 Some Over-Protection -1000 Some Protection -800
  • 47. Delta consulting 47 Corrosion Control Techniques 5.Cathodic Protection Excessive negative potentials can cause : Cathodic Disbonding : i.e. loss of adhesion between the coating and the metal surface Hydrogen Damage : due hydrogen evolution at –ve potentials
  • 48. Delta consulting 48 Corrosion Control Techniques 5.Cathodic Protection Potential criteria for cathodic protection of some metals and alloys at 25º C (1) (1) According to British code of practice No. CP 1021, August 1973. (2) But not more negative than about -1.2 Volts. Metal/ Alloy Potential criterion (mV) vs Cu/ Cu SO4 Iron, steel, stainless steel: Aerobic conditions Anaerobic conditions -850 -950 Lead -600 Copper -500 Aluminum -950 (2)
  • 49. Delta consulting 49 Corrosion Control Techniques 5.Cathodic Protection According to ISO 15589-1 Part 1, 2003 concerning the CP protection criteria of On-Land Pipelines : “The CP system shall be capable of : polarizing all parts of the buried pipeline to potentials more negative than – 850 mV referred to CSE, & to maintain such potentials throughout the design life of the pipeline”.
  • 50. Delta consulting 50 Corrosion Control Techniques 5.Cathodic Protection “For pipelines operating in soils with very resistivity, a protection potential more positive than – 850 mV referred to CSE may be considered, e.g. as follows”: - 750 mV for 10,000 < p < 100,000 ohm.cm - 650 mV for p 100,000 ohm.cm > According to ISO 15589-1 Part 1, 2003 concerning the CP protection criteria of On-Land Pipelines : i.e., the value of – 850 mV is only for soils with p < 10,000 ohm.cm p = Soil Resistivity
  • 51. Delta consulting 51 Corrosion Control Techniques 5.Cathodic Protection Cathodic protection monitoring Potential Measurement Structure/Electrolyte Potential is measure by means of a reference electrode : Copper / Copper Sulfate Soil Silver / Silver Chloride Sea Water
  • 52. 52
  • 53. Delta consulting 53 Corrosion Control Techniques 5.Cathodic Protection Copper / Copper Sulfate reference electrode Portable Type
  • 54. Delta consulting 54 Corrosion Control Techniques 5.Cathodic Protection Copper / Copper Sulfate reference electrode In order to measure the structure – to – soil potential , the CSE must become part of the soil This is fulfilled by inter-mixing of the CSE content with the soil content due to diffusion down a concentration gradient
  • 55. Delta consulting 55 Corrosion Control Techniques 5.Cathodic Protection H2O ( SO4 2- SO4 2- Soil) Copper Rod CuSO4 Saturated Water molecules migrate into CSE Sulfate ions migrate from CSE to soil Porous Disc AVO meter Typical Arrangement for Pipe – to – Soil Measurement Solution HIGH WATER CONTENT HIGH SO4 2- IONS CONTENT Pipe Cu Cu2+
  • 56. Delta consulting 56 Corrosion Control Techniques 5.Cathodic Protection Typical Arrangement for Pipe – to – Soil Measurement Icp umbrella Icp umbrella CSE
  • 57. Delta consulting 57 Corrosion Control Techniques 5.Cathodic Protection Voltmeter IR error Ep CP current CSE @ soil surface Coating Eon Reading Eon = Ep + IR Error Voltmeter
  • 58. Delta consulting 58 Corrosion Control Techniques 5.Cathodic Protection Voltmeter Ep CSE @ soil surface Coating Eoff Reading , instantaneous Eoff = Ep Voltmeter
  • 59. Delta consulting 59 Corrosion Control Techniques 5.Cathodic Protection Permanent Copper / Copper Sulfate reference electrode Prepackaged CSE Backfill : Gypsum + Bentonite clay + Sodium sulfate
  • 60. Delta consulting 60 Corrosion Control Techniques 5.Cathodic Protection Test Posts for CP Monitoring Flush – to – ground
  • 61. Delta consulting 61 Corrosion Control Techniques 4.Cathodic Protection Electrode Placement For pipelines : on-the-line @ every 1- 2 Km destination For tanks : preferred under tank or closest
  • 62. Delta consulting 62 Corrosion Control Techniques 5.Cathodic Protection CP Permanent Monitoring ( Test ) Point consists of :- Permanent Reference Electrode ( or Portable type ) Test Post : for pipelines : @ every 1- 2 Km intervals for tanks : near the tank
  • 63. Delta consulting 63 Corrosion Control Techniques 5.Cathodic Protection Structure-to-Soil potential measurement using Voltmeter.
  • 64. Delta consulting 64 Corrosion Control Techniques 5.Cathodic Protection Permanently Installed Reference Electrode & Test Post
  • 65. Delta consulting 65 Corrosion Control Techniques 5.Cathodic Protection Permanent Monitoring for Under Tank Cathodic Protection Tank Diameter (m) No. of Electrodes Required 5-10 1 10-23 2 23-36 3 45 and above 4
  • 66. Delta consulting 66 Corrosion Control Techniques 5.Cathodic Protection Reference Electrodes Locations for Under - Tank CP Systems 1/4D 1/6D 2/6D 2/8D 3/8D 1/8D D=45m and above D=23-36m D=10.5-22.5m D=5-10m Key : Reference Electrode
  • 67. Delta consulting 67 Corrosion Control Techniques 5.Cathodic Protection PVC pipe installed through the concrete ring @ different locations for CSE placement. Concrete Ring Under Tank Soil PVC Pipe – See Details Top View PVC Pipe Under Tank Soil Concrete Ring CSE
  • 68. Delta consulting 68 Corrosion Control Techniques 5.Cathodic Protection CSE Perforated PVC Pipe Filled with Water Tank Perforated PVC Pipe Installed for Reference Electrode Placement AVO
  • 69. Delta consulting 69 Corrosion Control Techniques 5.Cathodic Protection Correct method for measuring structure potentials when surface is covered with concrete or asphalt. AVO CSE in Wet Soil Buried Pipe Concrete / Asphalt
  • 70. Delta consulting 70 Corrosion Control Techniques 5.Cathodic Protection For monitoring tank’s internal CP system use: Hanging RE ( from roof ) Plug RE ( fixed on shell ) RE RE Hanging Reference Electrodes Plug RE
  • 71. Delta consulting 71 Corrosion Control Techniques 5.Cathodic Protection Diver with portable reference electrode Potential Measurement of jackets / platform legs
  • 72. Delta consulting 72 Corrosion Control Techniques 5.Cathodic Protection Transponder CP monitoring Potential Measurement of jackets / platform legs
  • 73. Delta consulting 73 Corrosion Control Techniques 5.Cathodic Protection Potential plot after data analysis
  • 74. Delta consulting 74 Corrosion Control Techniques 5.Cathodic Protection Potential Measurement of subsea pipelines Trailing-wire potential survey
  • 75. Delta consulting 75 Corrosion Control Techniques 5.Cathodic Protection TP-3 TP-1 TP-2 well TP TP-3 TP-4 - 850 mV Min. protection level Un protected area Pipe to soil potential - mV What about the potential at any point ? Buried pipeline ( 1.2 meter deep) Well casing 8000 feet deep The criterion most widely used on pipelines is based on measurements of potential differences between the pipeline and its environment . ie: more negative than ( - 850 mv) reference to Cu/Cu So4 cell Potential Measurement of well casing
  • 76. Delta consulting 76 Corrosion Control Techniques 5.Cathodic Protection Potential Measurement of well casing Up hole Upper Centralizer Upper Contactors Spacer Bare Lower Contactors Lower Centralizer Sinker Weight Length between contactors 5 to 7 meters V Casing Tool inside Casing CASING POTENTIAL PROFILE TOOL SPECIFICATIONS 8.5 m using 5.0 contactor spacing 10 m using 6.0 contactor spacing length Diameter 2.5/8 in. ( 6.5 cm) maximum weight 440 lb.* (199.6 kg) Max. temp. 300 deg.F (154 deg.C) Max. Pressure 10,000 psi (69 Mpa) Casing Size 4.5 in (11.4 cm) to 13.3/8 in (34 cm) Hoisting speed 80 ft/min (24.38 m/min Recommended Logging reading Stationary readings; average speed 25ft/ min (7.6 m/min) at 50 ft intervals Logging envirnment Must be dray Limitations Not recommended for use in fresh water Typical Casing Potential Profile Tool (Courtesy of Atlas Industries, Inc.)
  • 77. Delta consulting 77 Corrosion Control Techniques 5.Cathodic Protection Potential Measurement of well casing + - T R v OUTPUT CURRENT = ( I ) ( I ) ( i1 ) ( i 2 ) ( i3 ) ( I-i1 ) ( I-i1-i2 ) ( I-i1-i2 -i3) U1 U2 U3 Casing to soil potential= (v) Cu/Cu So4 cell v U1 U2 U3 -700 -850 -900 -1000 Depth in feet -850mv min.protection level R R R Ohm’s Low: V = I x R U = Voltage drop = I x R pipe
  • 78. Delta consulting 78 Cable – to - cable connection Cable – to - pipe connection Cable – to - structure connection Corrosion Control Techniques 5.Cathodic Protection Cable Connections
  • 79. Delta consulting 79 Splice Kit : for cable-to-cable connection Corrosion Control Techniques 5.Cathodic Protection Cable Connections 1 2 Araldite is poured & let to dry
  • 80. Delta consulting 80 For cable-to-pipe connection : 1- Thermite ( Cad / Exothermic ) Welding 2- Pin Brazing 3- Mechanical connection ( for gas pipelines ) Corrosion Control Techniques 5.Cathodic Protection Cable Connections
  • 81. Delta consulting 81 For cable-to-pipe connection 1- Thermite Welding : Corrosion Control Techniques 5.Cathodic Protection Cable Connections Crucible Disks Cartridge Spark Flint
  • 82. Delta consulting 82 Corrosion Control Techniques 5.Cathodic Protection Thermite Weldment Prior to welding : The coating must be removed at welding point ( 5x5 cm square ) Metal surface to be polished and cleaned Thermite Welding
  • 83. Delta consulting 83 Corrosion Control Techniques 5.Cathodic Protection Self-adhesive Handy-cap 1 2 3 Protecting the Thermite Weldment
  • 84. Delta consulting 84 Corrosion Control Techniques 5.Cathodic Protection Cable Connections For cable-to-pipe connection 2- Pin Brazing : emits less heat output Pin Brazing Unit Pistol / Gun Pins & Ferrules Lug Grinder
  • 85. Delta consulting 85 Corrosion Control Techniques 5.Cathodic Protection Cable Connections For cable-to-pipe connection 2- Pin Brazing
  • 86. Delta consulting 86 Corrosion Control Techniques 5.Cathodic Protection Cable Connections For cable-to-pipe connection 2- Pin Brazing 1Clean the surface 2Load gun with pin & ferrule 3pin braze 4Test connection
  • 87. Delta consulting 87 Corrosion Control Techniques 5.Cathodic Protection Cable Connections For cable-to-pipe connection 3- Mechanical Connection : recommended for drain point connection of gas pipelines
  • 88. Delta consulting 88 Corrosion Control Techniques 5.Cathodic Protection Cable Connections Terminal Lugs : for cable-to-structure ( tank ) connection
  • 89. Delta consulting 89 Electrical isolation is made by : Isolating flange kit ( IFK ) IFK is installed @ Aboveground / Underground Interface Corrosion Control Techniques 4.Cathodic Protection Electrical Isolation Structures to be protected shall be electrically isolated from portions which do not require protection.
  • 90. Delta consulting 90 Isolating flange kit ( IFK ) Corrosion Control Techniques 4.Cathodic Protection Electrical Isolation
  • 91. Delta consulting 91 Corrosion Control Techniques 4.Cathodic Protection Isolating flange kits In hazardous areas , IFK’s are protected by means of Spark Gaps Spark Gap Fitted
  • 92. Delta consulting 92 Monolithic Blocks Corrosion Control Techniques 4.Cathodic Protection Electrical Isolation
  • 93. Delta consulting 93 Monolithic Blocks + Polarization Cell Corrosion Control Techniques 4.Cathodic Protection The monolithic blocks are protected against electrostatic charges and lightening by polarization cell
  • 94. Delta consulting 94 Casings for Road Crossings Corrosion Control Techniques 4.Cathodic Protection
  • 95. Delta consulting 95 Casings for Road Crossings There should NOT be any contact between the pipe & casing Test posts usually installed @ crossings to monitor the potential of pipe and casing separately Corrosion Control Techniques 5.Cathodic Protection
  • 96. Delta consulting 96 Corrosion Control Techniques 4.Cathodic Protection Clamp Meter Clamp Meters are used to check: electric cables integrity current output of each anode Clamp Meter
  • 97. Delta consulting 97 Corrosion Control Techniques 5.Cathodic Protection Pipeline & Cable Warning Markers
  • 98. Delta consulting 98 Corrosion Control Techniques 5.Cathodic Protection
  • 99. Delta consulting 99 Corrosion Control Techniques 5.Cathodic Protection There are numerous codes and references that shall be referred to when dealing with cathodic protection among these are: NACE RP 0169 NACE RP 0176 NACE RP 177 NACE RP 575 ISO 15589-1, PART I – 2003, “On-land Pipelines” ISO 15589-2, PART II – 2004, “Offshore Pipelines” DnV RP B 401 API 651 J. Morgan, “Cathodic Protection” A.W. Peabody, “Control of Pipeline Corrosion”
  • 100. Delta consulting 100 Terms & Definitions Natural Potential: Is potential of structure to be protected whenever no cathodic protection system is applied. Protection Potential: Is the potential of structure to be protected whenever corrosion rate is insignificant. Anode Backfill: Materials with low resistivity surrounding buried anode, may be moisture retaining materials, used for decrease anode to electrolyte resistance and prevent anode polarization. Corrosion Control Techniques 5.Cathodic Protection Design
  • 101. Delta consulting 101 Terms & Definitions Drain Point: Location of negative cable connection to the structure to be protected through which the cathodic protection current returns to its source. Coating Break-down Factor: Is the ration between the current density required to polarize coated surface and density required to polarize bare surface. Initial Current Density Estimated current density required for polarization of structure to be protected at the start of the lifetime. Final Current Density: Estimated current density required to maintain polarization at the end of the lifetime. Corrosion Control Techniques 5.Cathodic Protection Design
  • 102. Delta consulting 102 Terms & Definitions Mean Current Density: Estimated current density for the entire of the lifetime Anode Electro-chemical Capacity: The amount of electricity expressed by (Amper.Hour/kg) that is produced due to anode consumption. Cathodic Protection Criteria: Limits of protection potentials. Corrosion Control Techniques 5.Cathodic Protection Design
  • 103. Delta consulting 103 Corrosion Control Techniques 5.Cathodic Protection CP System Design : Basic information for design considerations 1. Type of electrolyte (environment) • Soil • Fresh/ saline water. 2. Availability of power supply 3. Temperature 4. Type of coating 5. For pipelines: • Pipeline route • Crossings (foreign pipeline, roads, rivers, etc.) • Presence of high transmission power lines • Presence of foreign metallic structures.
  • 104. Delta consulting 104 Corrosion Control Techniques 5.Cathodic Protection Soil resistivity Soil represents the electrolyte Soils with low resistivity have high conductivity; i.e. corrosive NACE ranking : Soil resistivity (ohm.cm) Corrosivity up to 1,000 Severely corrosive 1,000-5,000 Corrosive 5,000-10,000 Moderately corrosive 10,000-20,000 Slightly corrosive 20,000 and above Non-corrosive
  • 105. Delta consulting 105 Corrosion Control Techniques 5.Cathodic Protection Four-Terminals (Wenner) Method : For Measurement of Soil Resistivity. Kit Power Unit Stainless Steel Pins Cables
  • 106. Delta consulting 106 Corrosion Control Techniques 5.Cathodic Protection 4-Terminals Arrangement Ohm’s Low : R = V/I R : Resistance (ohm) V : Applied Voltage I : Recorded Amperage a a a Depth = a
  • 107. Delta consulting 107 Current demand for CP: Current density : it is the current required to polarize (1 meter)2 of bare steel in a given electrolyte. Corrosion Control Techniques 5.Cathodic Protection Design Current density increases with increasing temperature
  • 108. Delta consulting 108 Corrosion Control Techniques 5.Cathodic Protection Design Temperature : current demand shall be increased by 25% per every 10º C incremental rise above 30º C. This requirement is described by the following equation: i = i0 + [i0 x 0.25 (t - t0)] / 10 Where, i = current density at operating temperature, Amp/m2 i0 = base current density at standard temperature t = operating temperature ºC t0 = standard temperature (30ºC)
  • 109. Delta consulting 109 Corrosion Control Techniques 5.Cathodic Protection Current density determined in mA/m2 is dependant on the media aggressivity. Therefore if soil resistivity is low then current density shall be high Media Current Density mA/m2 Aggressive Soil 10 Normal soil 5 Sea water 90 Fresh water 30
  • 110. Delta consulting 110 Corrosion Control Techniques 5.Cathodic Protection Power Supply : The T/R is fed with AC current from the nearest power supply. If there is no power supply available, Solar Units to be used instead of T/R.
  • 111. Delta consulting 111 Corrosion Control Techniques 5.Cathodic Protection 240 Watt Solar Array 0-24 Volt
  • 112. Delta consulting 112 Corrosion Control Techniques 5.Cathodic Protection GB Pipe to be protected Converter Regulator Batteries Junction Box Solar Modules Structure (-) (+) Typical Arrangement for ICCP Using Solar Energy Sun
  • 113. Delta consulting 113 Corrosion Control Techniques 5.Cathodic Protection Typical Coating Resistances for various coating qualities Coating quality Range of specific leakage resistance (RC), ohm.m2 Poor 1,000-2,500 Fair 5,000-10,000 good 25,000-50,000 Excellent 100,000-500,000
  • 114. Delta consulting 114 Corrosion Control Techniques 5.Cathodic Protection Typical Coating Breakdown Values Coating type % breakdown Initial Mean Final Thick coating ≤ 1 5 10 Epoxy coal tar ≤ 2 5-10 10-20 Fusion bonded epoxy 1-2 5-10 5-20 Polypropylene (25 yrs) 0.5 2 5 Polyethylene (25 yrs) 0.5 1 3 CP current
  • 115. Delta consulting 115 Corrosion Control Techniques 5.Cathodic Protection Recommended potential limits for different coatings to avoid coating disbondment Coating type Volt (vs Cu/ CuSO4) Asphalt Enamel -2 Epoxy coal tar -1.5 Fusion bonded epoxy -1.5 Tape wrap -1.5 Polyethylene -1.0
  • 116. Delta consulting 116 Corrosion Control Techniques 5.Cathodic Protection Pipeline Route Cross-country P/L’s pass through different types of soils, i.e. different electrolytes Presence of high voltage power transmission lines
  • 117. Delta consulting 117 Corrosion Control Techniques 5.Cathodic Protection Pipeline Route
  • 118. Delta consulting 118 Corrosion Control Techniques 5.Cathodic Protection Pipeline AC interference from electromagnetic field
  • 119. Delta consulting 119 For protection against stray current from high tension lines, zinc ribbon and polarization cells are used Corrosion Control Techniques 5.Cathodic Protection
  • 120. Delta consulting 120 In case of pipe-crossing of cathodically protected pipelines BONDING is required by means of : Solid boning, or Resistance bonding Corrosion Control Techniques 5.Cathodic Protection Stray current interference
  • 121. Delta consulting 121 Stray-current corrosion Corrosion Control Techniques 5.Cathodic Protection Pipeline potential shifts in anodic direction ( more positive values ) Possibility of high anodic current densities , i.e. high corrosion rates Pipeline potential shifts in cathodic direction ( more negative values ) Possibility of coating disbondment and hydrogen damage
  • 122. Delta consulting 122 Corrosion Control Techniques 5.Cathodic Protection Stray-current corrosion
  • 123. Delta consulting 123 Corrosion Control Techniques 5.Cathodic Protection
  • 124. Delta consulting 124 CP Current Requirement CD= S x a x CBDC Corrosion Control Techniques 5.Cathodic Protection CD : Current Demand (A) S : Design Current Density (A/m2) a : Surface Area (m2) CBDF : Coating Break-down Factor % Current Rating : (1.5 times final CD) Temperature (°C) 50 Initial Average Final Current Density (mA/m2 ) 5 CBDF (%) 0.01 2 3 Design Density (mA/m2 ) 7.5 Current Demad (A) 0.0 5.7 8.6 Pipeline Length (km) 30 Pipeline Diameter (inch) 16 Current Rating (A) 13
  • 125. Delta consulting 125 Anodes Weight & Quantity Requirement Corrosion Control Techniques 5.Cathodic Protection # of Anodes Required Wt = Weight per anode (kg) Wt = 27.2 kg CR = Consumption rate (kg/amp-year) CR = 0.34 kg/A-yr DL = Desired life (years) DL = 20 yrs Current = Current required (amps) Current = 5.70 A UF = Utilization factor UF = 0.60 # anodes = 3.00 # of Anodes Required Based on Current Discharge * from anode manufacturer data MD = Maximum discharge per anode (amps) MD = 1.50 A Current = Current required (amps) Current = 5.70 A # anodes = 4.00 Impressed Current (On-land) Systems
  • 126. Delta consulting 126 CP Circuit Resistance : (ICCP systems) Corrosion Control Techniques 5.Cathodic Protection R Gbed =Ground-bed resistance (ohms) R C =Cable resistance (ohms) R S =Pipeline/structure to earth resistance (ohms) 0.00 ohms R T =Total circuit resistance (ohms) 0.00 ohms
  • 127. Delta consulting 127 CP Ground-Bed Resistance : Corrosion Control Techniques 5.Cathodic Protection 1) Dwight's Equation for Single Vertical Anode ρ = Resistivity of backfill material (or earth) in ohm-cm 1,000 ohm-cm L = Length of backfill (or anode) in meters 2.00 m d = Diameter of backfill (or anode) in meters 0.30 m R v = Resistance of one vertical anode to earth in ohms 2.366 ohms
  • 128. Delta consulting 128 Corrosion Control Techniques 5.Cathodic Protection 2) Dwight's Equation for Multiple Vertical Anodes in Parallel ρ = Soil (or Backfill) resistivity in ohm-cm 1,000 ohm-cm N = Number of anodes in parallel 4 each L = Length of backfill (or anode) in meters 2.0 m d = Diameter of backfill (or anode) in meters 0.3 m S = Anode spacing in meters 3.0 m R = Resistance of vertical anodes in parallel to earth in ohms 0.8 ohms CP Ground-Bed Resistance (cont’) :
  • 129. Delta consulting 129 Corrosion Control Techniques 5.Cathodic Protection 3) Modified Dwight's Equation for Single (or Multiple) Anodes Installed Horizontally ρ = Resistivity of Soil or (backfill) material 1,000 ohm-cm L = Length of backfill (or anode) in meters 8.00 m S = Twice depth of anode in meters 3.0 m d = Diameter of backfill (or anode) in meters 0.3 m RH = Resistance of horizontal anode (or multiple) to earth 0.9 ohms CP Ground-Bed Resistance (cont’) :
  • 130. Delta consulting 130 CP Ground-Bed Resistance : Corrosion Control Techniques 5.Cathodic Protection 4) Dwight's Equation for Deep-Well Anodes ρ = Effective Resistivity of earth in ohm-cm 1,000 ohm-cm L = Length of backfill (or anode) in meters 8.00 m d = Diameter of backfill (or anode) in meters 0.30 m R v = Resistance of deep-well anode to earth in ohms 0.867 ohms
  • 131. Delta consulting 131 Corrosion Control Techniques 5.Cathodic Protection Cable Resistance R CABLE = Resistance per km 0.833 ohms/km L CABLE = Length in meters (sum of positive and negative cables) 150 m R C = Cable resistance 0.125 ohms CP Cables Resistance :
  • 132. Delta consulting 132 CP Circuit Resistance & Driving Voltage : (ICCP systems) Corrosion Control Techniques 5.Cathodic Protection Driving Voltage = Max. Current x RT R Gbed =Ground-bed resistance (ohms) 0.90 ohms R C =Cable resistance (ohms) 0.125 ohms R S =Pipeline/structure to earth resistance (ohms) 0.00 ohms R T =Total circuit resistance (ohms) 1.03 ohms Max. current (A) 13 Driving Voltage (v) 13.3
  • 133. Delta consulting 133 Transformer/Rectifier (T/R) Rating: Corrosion Control Techniques 5.Cathodic Protection Max. current (A) 13.0 Driving Voltage (v) 13.3 T/R Output Rating: Select near standard T/R rating: (e.g. 12V, 24V, 36V, 48V, 5A, 10A, 15A, 20A…etc) T/R output: 15A/24V DC T/R Input Characteristics: Check available electrical power characteristics: Either 3PH, 400V AC, 50Hz Or 1PH, 230V AC, 50Hz T/R Input: 3PH, 400V AC, 50Hz
  • 134. Delta consulting 134 CP Current Attenuation (Spread) Check (for Pipelines) Corrosion Control Techniques 5.Cathodic Protection En (v) Pipeline Natural Potential -0.55 ∆Ea/∆Em = Cosh(αL) Ea (v) Pipeline Protective Potential at Drain Point -1.3 ∆Ea (v) Pipeline Potential Shift at Drain Point -0.75 ∆Ea = Ea - En Em (v) Pipeline Protective Potential at Distance (L) -0.95 ∆Em = Em - En ∆Em (v) Pipeline Potential Shift at Distance (L) -0.4 α (m-1) Attenuation Constant 3.1623E-05 α = √ (Rs/Rlf) Rlf (ohm.m) Linear Coating Insulation Resistivity (final) 15664.8566 Rf (ohm.m2) Coating Insualtion Resistivity (final) 20000 Rlf = Rf/(π * D) Rs (ohm/m) Linear Pipeline Steel Conductivity 1.5665E-05 Rs = ρs/ (π * D * t) ρs (ohm.m) Pipeline Steel Specific Resistivity 0.00000019 D (m) Pipeline Diameter 0.4064 t (m) Pipeline Wall Thickness 0.0095 L (Km) Attenuation Distance 39.26
  • 135. Delta consulting 135 Corrosion Control Techniques 5.Cathodic Protection Typical Coating Resistance (for various coating qualities) Coating quality Range of specific leakage resistance (Rl), ohm.m2 Poor 1,000-2,500 Fair 5,000-10,000 good 25,000-50,000 Excellent 100,000-500,000
  • 136. Delta consulting 136 CP Current Requirement CD= S x a x CBDC Corrosion Control Techniques 5.Cathodic Protection S : Design Current Density (A/m2) a : Surface Area (m2) CBDF : Coating Break-down Factor % Temperature (°C) 50 Initial Mean Final Current Density (mA/m2 ) 90 CBDF (%) 0.01 2 3 Design Density (mA/m2 ) 135 Current Demad (A) 0.5 103.4 155.1 Pipeline Length (km) 30 Pipeline Diameter (inch) 16 Coating 3PP Sacrificial Anode Systems
  • 137. Delta consulting 137 Anode Material & Dimensions Selection Anode Material Selection Corrosion Control Techniques 5.Cathodic Protection
  • 138. Delta consulting 138 Anodes Weight & Quantity Requirement Corrosion Control Techniques 5.Cathodic Protection Total Mass Required Icm = Mean Current Demand (A) 103.40 A tdl = Design Lifetime (Year) 20 yrs u = Utilization factor 0.80 ε = Design Electrochemical Capacity (A.hr/kg) 2500 A-hr/kg m = Total Mass of Anodes (kg) 9057.8 kg # of Anodes Required Based on Total Required Mass ma = Standard Net Anode Mass (kg) 100.0 kg n = Anodes Qty # anodes = 91
  • 139. Delta consulting 139 Sacrificial VS Impressed Current CP Sacrificial Impressed current No need for external power source Requires an external power source Easy to design and install Requires skillful design and installation uncontrollable Can be controlled Used only for limited surface areas and well coated structures Can be used for uncoated surfaces and used for any surfaces Has no detrimental effects Can cause serious problems if not handled carefully Is limited to low resistivity can be used at any resistivity Low maintenance High maintenance Corrosion Control Techniques 4.Cathodic Protection
  • 140. Delta consulting 140 Corrosion Control Techniques 5.Cathodic Protection Sacrificial VS Impressed Current CP
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  • 144. Delta consulting 144 Thank You and Good Luck