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-By SURAJ P. BEGOOR
KARL FISHER REACTION
(IN SIMPLE TERMS)
Lets begin
friends!!!!!!.....
History of karl fisher reaction!!!
 S02 + I2 +2H20  2HI +H2SO
Karl
Fisher
SO2
Methanol
I2
SO
2
I2
Imidazole
Imidazol
e
Uses of each chemical in
reaction
 Karl fisher reagent contains ---- S02 + I2+ Imidazole
 [S02+I2+imidazole] + H20( i.e moisture content in our
sample of interest. )
 More the water content more the KF is taken inside
the reaction vessel.
 The resulting iodides are detected by the electrode.
 (S02+I2+imidazole) +H20 2HI+H2S04
 The resulting sulphuric acid is stabilized by imidazole
because imidazole is a weak base and acts like a
buffering agent.
Meanings of few Terms used in the
presentation.
 Buffering agents– chemicals which does
not allow a rapid change in pH to
happen.
 Precision: Fact of being exact and
accurate.
 Accuracy: State of being correct or
Degree of closeness of a measured
value.
 Drift: The amount of moisture which is
present inside the reaction vessel.
Hope that was helpful !!!
!!! Thank you and have a nice day
ahead!!!
-suraj begoor

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Karl fisher reaction.

  • 1. -By SURAJ P. BEGOOR KARL FISHER REACTION (IN SIMPLE TERMS) Lets begin friends!!!!!!.....
  • 2.
  • 3. History of karl fisher reaction!!!  S02 + I2 +2H20  2HI +H2SO
  • 6. Uses of each chemical in reaction  Karl fisher reagent contains ---- S02 + I2+ Imidazole  [S02+I2+imidazole] + H20( i.e moisture content in our sample of interest. )  More the water content more the KF is taken inside the reaction vessel.  The resulting iodides are detected by the electrode.  (S02+I2+imidazole) +H20 2HI+H2S04  The resulting sulphuric acid is stabilized by imidazole because imidazole is a weak base and acts like a buffering agent.
  • 7. Meanings of few Terms used in the presentation.  Buffering agents– chemicals which does not allow a rapid change in pH to happen.  Precision: Fact of being exact and accurate.  Accuracy: State of being correct or Degree of closeness of a measured value.  Drift: The amount of moisture which is present inside the reaction vessel.
  • 8. Hope that was helpful !!! !!! Thank you and have a nice day ahead!!! -suraj begoor