Green HRM is the use of HRM policies to promote the sustainable use of resources within organizational businesses and more generally promotes the cause of environmental sustainability. The range of these activities is perceived highly relevant and the range of possible green human resource interventions is much wider. There is an increasing growing need of integrating environment management system into Human Resource Management (HRM) i.e., Green HRM practices of how corporations can develop human resource policies for promoting environment management initiatives on the impacts of mining and industrialization. This paper examines the nature and implications of Green HRM initiatives and its practices towards environmental sustainability which could in turn benefit the livelihood of tribal people. An attempt is made to promote the importance of Green HRM and tries to link its implications on preserving the habitations of the tribal populated areas.