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Dishwashing Chemistry 101

       Diane Hoffmann
What things impact the performance of the Dishwasher?




                                                        Confidential – Property of RB
How to get the Most out of your Dishwasher

•  Loading the dishwasher
   – Soil towards bottom / Sprayer Arm
   – Avoid nesting
   – Dishwasher Safe Items
• Make sure Dishwasher is filling with Hot Water
• Make sure you are using the Right Detergent
   – Freshness
   – Types of Cleaning agents and stains
• Make sure you purchase any Additives that will enhance
  your performance

                                              Confidential – Property of RB
Dishwashing Detergents are Changing
The European Market Provides a Clear Road Map to the Future of ADWD in Canada!
                                                        Europe                                                                                                                           USA

            100%   3.2   5.5 6.9 10.0                                                                                                         100%
            90%                          15.7                                                                                                            14.5   16.1
                   20.8 19.9 18.1               23.1                                                                                                                   19.8
                                                       31.7                                                                                                                    25.3    25.3   29.6     30.4
            80%                   16.6                        39.0                                                                                                                                            36.3   37.2
                                         13.7                        47.3                                                                        80%                                                                        43.1
                                                11.6                        54.5                                                                                                                                                   52.1   53.5
            70%                                                                    63.1
                                                       10.2                               70.6                                                           39.0
                                                                                                 77.6 83.1                                                      40.2
% $ Sales




            60%                                                                                                                                  60%                   39.9
                                                              8.8




                                                                                                                                  % $ Sales
                                                                                                           88.1 92.6
            50%                                                       4.5                                                                                                      38.1    39.0
                                                                                                                                                                                              38.2     36.9
                                                                            6.4                                                                                                                               33.2   35.5
            40%    76.0 74.6 75.0 73.4 70.6                                                                                                      40%                                                                        31.4
                                            65.3                                   5.9
            30%                                        58.1                                                                                                                                                                        26.8
                                                              52.2 48.2                   5.0                                                                                                                                             28.5
            20%                                                             39.1                 3.0
                                                                                   31.0                   1.5                                            46.5   43.7
                                                                                          24.4 19.4                                              20%                   40.3    36.6    35.7
            10%                                                                                          1.0                                                                                  32.2     32.7   30.5
                                                                                                    15.4 10.9 0.5                                                                                                    27.3   25.5
                                                                                                              6.9                                                                                                                  21.1   18.0
             0%
                                                                                                                                                   0%
                 92



                 94

                 95



                 97

                 98



                 00

                 01



                 03

                 04
                 90

                 91



                 93




                 96




                 99




                 02




                 05
                                                                                                                                                        2000    2001   2002    2003    2004   2005     2006   2007   2008   2009   2010   2011
              19




              19




              19




              20




              20
              19

              19



              19

              19



              19

              19



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              20

              20



              20
                                                                Year                                                                                                                             Year

                                                   Powder       Gel     Monodose                                                                                                       Powder    Gel     Monodose


                                                                                                                        Canada
                                                                            100%
                                                                                          16.7     18.8
                                                                                                                24.9
                                                                                                                       30.3
                                                                                                                              36.0
                                                                            80%                                                                  41.2
                                                                                                                                                        48.4
                                                                                          21.9                                                                  55.4
                                                                                                   24.8                                                                 60.9
                                                                                                                                                                                67.4
                                                                                                                25.0
                                                                            60%                                        25.2
                                                                                                                              25.2
                                                                                                                                                 25.3
                                                                            40%                                                                         24.7
                                                                                                                                                                22.7
                                                                                          61.5
                                                                                                   56.4                                                                 20.7
                                                                                                                50.1                                                            18.0
                                                                                                                       44.4
                                                                            20%                                               38.8
                                                                                                                                                 33.5
                                                                                                                                                        26.9
                                                                                                                                                                22.0    18.4
                                                                                                                                                                                14.6

                                                                              0%
                                                                                                                                                                        2010

                                                                                                                                                                                2011
                                                                                          2002

                                                                                                   2003

                                                                                                                2004

                                                                                                                       2005

                                                                                                                              2006

                                                                                                                                                 2007

                                                                                                                                                        2008

                                                                                                                                                                2009




ACNielsen Homescan Panel: ending Q4 2009, 2006, Europe Yr. 1 = 1990, USA Yr. 1 = 1999                                   Powders           Gels            CONFIDENTIAL – Property of Reckitt Benckiser
                                                                                                                                                    Monodose
Enzymes are used in today’s automatic dishwashing cleaners to break down the
                   below stains.

                            -        protein-based stains

                            -        starch-based stains

                                                                                                 Egg

                                                                                               Oatmeal

                                                                                          Macaroni & Cheese



                                                                                  In general, enzymes used in ADW
Relative total activity %




                                                                                  cleaners work best at temperatures
                                                                                  around 122°F – Temperature at the
                                                                                  beginning of the main wash cycle


                                86         104      122     140       158   176

                            Temperature, °F      Protease   Amylase
                                                                                                       Confidential – Property of RB
The bleach and activator eliminates certain soils (e.g. tea and coffee stains) by oxidizing them
                  and make them water removable




                  Oxygen Bleach + Activator

                        30         Percarbonate /TAED

                        25

                        20
Remission increase, %




                                                                                In general, bleach used in ADW
                        15
                                                                                cleaners work best at temperatures
                        10
                                                   Percarbonate                 around 140°F – High Temperature
                        5                                                       reached during the main wash cycle

                             34      68        104        140        176
                             Temperature, °F
                             (Max. activity between 122 - 158°F (= 50 - 70°C)

                                                                                                     Confidential – Property of RB
What makes Quantum work so well?


                     White Powder
                     •   Enzymes
                     •   Bleach activator
1. Detergent
                     Red PowerBall Shine Gel
   (Bleach and       •   Surface active ingredients
   Enzyme)               (rinse function)

                     Light Blue Powder
2. Rinse function    •   Bleach
                     •   Builders

3. Etch Protection   PVOH Shell
                     •  3 separate compartments
                     •  Separation of ingredients
                     •  Dissolves completely
                     •  Lowers the surface
                        tension of water


                                         Confidential – Property of RB
Technician Survey - July 2011
                     (212 Responses – Top reasons for repair calls)




•    Residue left on glasses and cutlery – 172 techs
•    Leftover food particles on items – 157 techs
•    Items come out wet from DW – 141 techs
•    Hard Water/ Limescale issues – 131 techs
•    Odor coming from DW – 104 techs




                                                                      Confidential – Property of RB

    212 Technicians were interviewed via Survey Monkey in July 2011
Finish® Jet-Dry® Rinse
Agent

                              The main tasks of the rinse agent are …
                                -       To ensure shiny dishes
                                -       To assist the drying function


                              Lowers the surface tension of water and turn a
                              droplet into a thin layer which …

                                    -   Will “sheet” off vertical surfaces (plates,
                                        glasses, etc)
                                    -   Can more easily evaporate
                                    -   Polymer helps with the shine
high surface   Residue
tension        is visible

   + Rinse Agent



low surface    Residue
tension        is invisible                                               Confidential – Property of RB
Finish® Dishwasher Cleaner




                  Home Use Test - 7 months of
                  use in extremely hard water


   Before           After

                                     Before            After




                                                Confidential – Property of RB
Types of Glass Corrosion (Etching) – Caused by Soft Water




Vinegar Test


      Full corrosion   Partial corrosion   Line corrosion   Iridescent corrosion




                                                            Confidential – Property of RB
Questions??

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Finish Dishwasher Webinar

  • 1. Dishwashing Chemistry 101 Diane Hoffmann
  • 2. What things impact the performance of the Dishwasher? Confidential – Property of RB
  • 3. How to get the Most out of your Dishwasher • Loading the dishwasher – Soil towards bottom / Sprayer Arm – Avoid nesting – Dishwasher Safe Items • Make sure Dishwasher is filling with Hot Water • Make sure you are using the Right Detergent – Freshness – Types of Cleaning agents and stains • Make sure you purchase any Additives that will enhance your performance Confidential – Property of RB
  • 4. Dishwashing Detergents are Changing The European Market Provides a Clear Road Map to the Future of ADWD in Canada! Europe USA 100% 3.2 5.5 6.9 10.0 100% 90% 15.7 14.5 16.1 20.8 19.9 18.1 23.1 19.8 31.7 25.3 25.3 29.6 30.4 80% 16.6 39.0 36.3 37.2 13.7 47.3 80% 43.1 11.6 54.5 52.1 53.5 70% 63.1 10.2 70.6 39.0 77.6 83.1 40.2 % $ Sales 60% 60% 39.9 8.8 % $ Sales 88.1 92.6 50% 4.5 38.1 39.0 38.2 36.9 6.4 33.2 35.5 40% 76.0 74.6 75.0 73.4 70.6 40% 31.4 65.3 5.9 30% 58.1 26.8 52.2 48.2 5.0 28.5 20% 39.1 3.0 31.0 1.5 46.5 43.7 24.4 19.4 20% 40.3 36.6 35.7 10% 1.0 32.2 32.7 30.5 15.4 10.9 0.5 27.3 25.5 6.9 21.1 18.0 0% 0% 92 94 95 97 98 00 01 03 04 90 91 93 96 99 02 05 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 19 19 19 20 20 19 19 19 19 19 19 19 20 20 20 20 Year Year Powder Gel Monodose Powder Gel Monodose Canada 100% 16.7 18.8 24.9 30.3 36.0 80% 41.2 48.4 21.9 55.4 24.8 60.9 67.4 25.0 60% 25.2 25.2 25.3 40% 24.7 22.7 61.5 56.4 20.7 50.1 18.0 44.4 20% 38.8 33.5 26.9 22.0 18.4 14.6 0% 2010 2011 2002 2003 2004 2005 2006 2007 2008 2009 ACNielsen Homescan Panel: ending Q4 2009, 2006, Europe Yr. 1 = 1990, USA Yr. 1 = 1999 Powders Gels CONFIDENTIAL – Property of Reckitt Benckiser Monodose
  • 5. Enzymes are used in today’s automatic dishwashing cleaners to break down the below stains. - protein-based stains - starch-based stains Egg Oatmeal Macaroni & Cheese In general, enzymes used in ADW Relative total activity % cleaners work best at temperatures around 122°F – Temperature at the beginning of the main wash cycle 86 104 122 140 158 176 Temperature, °F Protease Amylase Confidential – Property of RB
  • 6. The bleach and activator eliminates certain soils (e.g. tea and coffee stains) by oxidizing them and make them water removable Oxygen Bleach + Activator 30 Percarbonate /TAED 25 20 Remission increase, % In general, bleach used in ADW 15 cleaners work best at temperatures 10 Percarbonate around 140°F – High Temperature 5 reached during the main wash cycle 34 68 104 140 176 Temperature, °F (Max. activity between 122 - 158°F (= 50 - 70°C) Confidential – Property of RB
  • 7. What makes Quantum work so well? White Powder • Enzymes • Bleach activator 1. Detergent Red PowerBall Shine Gel (Bleach and • Surface active ingredients Enzyme) (rinse function) Light Blue Powder 2. Rinse function • Bleach • Builders 3. Etch Protection PVOH Shell • 3 separate compartments • Separation of ingredients • Dissolves completely • Lowers the surface tension of water Confidential – Property of RB
  • 8. Technician Survey - July 2011 (212 Responses – Top reasons for repair calls) • Residue left on glasses and cutlery – 172 techs • Leftover food particles on items – 157 techs • Items come out wet from DW – 141 techs • Hard Water/ Limescale issues – 131 techs • Odor coming from DW – 104 techs Confidential – Property of RB 212 Technicians were interviewed via Survey Monkey in July 2011
  • 9. Finish® Jet-Dry® Rinse Agent The main tasks of the rinse agent are … - To ensure shiny dishes - To assist the drying function Lowers the surface tension of water and turn a droplet into a thin layer which … - Will “sheet” off vertical surfaces (plates, glasses, etc) - Can more easily evaporate - Polymer helps with the shine high surface Residue tension is visible + Rinse Agent low surface Residue tension is invisible Confidential – Property of RB
  • 10. Finish® Dishwasher Cleaner Home Use Test - 7 months of use in extremely hard water Before After Before After Confidential – Property of RB
  • 11. Types of Glass Corrosion (Etching) – Caused by Soft Water Vinegar Test Full corrosion Partial corrosion Line corrosion Iridescent corrosion Confidential – Property of RB