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Development of Three-Dimensional Electrode in
                  Wastewater Treatment
                                         Huang Yaokun, Wang Can*, Wang Fen*, Ji Min*
                                          School of Environmental Science and Engineering
                                                           Tianjin University
                                                         Tianjin 300072, China
Abstract—Three-dimensional electrode technology shows great
                                                                                         II.
potential in wastewater treatment. In this paper, the
developments of the technology were systematic introduced.
The optimization of feeder electrode or particle electrodes
were becoming one of the research focuses of this filed. Several
novel particle electrodes including new carbon material and
metallic oxides had been widely studied. The mechanisms to                 A.
degrade pollutants were due to the direct and indirect
oxidation, which took place near the electrode area.
Furthermore, it was pointed out that high operation cost,
feeder electrodes corrosion and particle electrodes inactivation           B.
were the main problems of three-dimensional electrode
technology. Some corresponding potential solutions for these
                                                                                H2O2   ·OH
problems had also been proposed.
Keywords: three-dimensional electrode; feeder electrode; particle

electrode; wastewater treatment

                           I.

                  three-dimensional electrode
     particle electrode                bed electrode
                                                                                       conversion                  combustion
                                                                                H2O    OH-                               ·OH
                                                                                                       ·OH
                                                                                               ·OH
                                                                                               MOx+1          ·OH
   1
                                                            2

                                                                                H2O    OH-                     ·OH              Cl-
                                                                3
                                                                                                             Cl-


                                                                                 H2O2 H2O2               Fenton                 ·OH




         978-1-4577-0290-7/11/$26.00 ©2011 IEEE
                                                                    3052
III.                                                               1




                                                     1



                                                                   ·OH

                                                                        ·OH

                                                                 ·OH
             DSA
                                                                  ·OH



                                                                   ·OH                           DSA




                                                                       A.
                                                      Yu-hong
                                                                              Guifen Lv[6]
Cui[1]             Ti/BDD Ti/Sb–SnO2 Ti/RuO2 Pt
             A                               1        Ti/BDD
                                                                                                       Xinbo Wu [7]
Ti/Sb–SnO2
                                                                                                                      X-3B
Ti/RuO2                                           Ti/BDD
                                                                                                            95%
                       Ti/Sb–SnO2                                                                                            [8]

                         DSA               Ti/SnO2 +Sb2O3[2]
Ti/Co/SnO2[3]    Ti/SnO2[4]
                                                                                                 H2O2    ·OH

                                                                       B.

                                                          [5]
                                                                                                                         Mn
                                                                       Cu Zn



                                    H2O2

                 IV.




                                                                                             2




                                                                3053
2



             Mn        Fe   Zn
                                                                                                                 [9]




                                                                            pH
                                                                                                                 [10]
             CeO2/Sb2O5
                                                                    CODCr
             Cu    Ni       Mn    Zn
                                                                                                                 [11]
                                       n                                P

             Fe    Cu Ni         Zn
                                                                                                                 [12]
             Mn                        X-3B    CODCr




2




                                                                                                      3


                                                   3



                  Sb    SnO2                                                                        E. Fockedey[2]


    -A12O3   Cu Fe
                                                                                                             [13]
                                              CuO- -A12O3>Fe2O3- -A12O3> Fe2O3-13X
                                           > -A12O3>13X                 >
                                       5                            2%CuO-9%CeO2 / -A12O3
             CuO-CeO2
                                                                                                          [14]
    -A12O3                                                   CODCr                    70%
             CuO
                                  Ce
                                                                                          Sn   Ti
                                                                                                             [15]
             Sn Ti                                     0.1            pH         3
                                       450
                                  Sn-Sb-Ag                                           Ag
                            Sn
                                                                                                             [16]
                                                        Sn-Sb
             Sb




                                                             3054
3
                                                                              V.
E. Fockedey[30]

                                                                                                                 4




                                             4




                                                          0.3L/min                   68mA/cm2
                  375mL   pH     3                Fe2+                                                  Chih-TaWang[17]


                                Fe2+      +                              20V               0.1m3/h
                  176mL                30min                CODcr                            99%         Ya Xiong[18]
                          87%

                                                 167mA/cm2 pH             11 NaCl
                                                                                                          Bo Wang[19]
                  150mL   11g/L                     60min        CODCr
                            86.3% 75%                    40min     BOD/CODCr
                                                          20 V           pH        2.5
                                                                                                                [20]
                  1.2L               1000 mg/L                   0.3 mg/L
                            90 min       CODcr                 70.1%

                                                                                            4:1
                                       57.1,mA/cm2                  0.2,m3/h        Fe2+
                                                                                                                [21]
                  3.7L    1.0,mmol/       pH        4.0                                  180,min
                          CODCr        TOC                                                 80.8%
                          73.3% 55.2% 98.6%


                                                          15V                      60min           pH
                                                                                                                 [22]
                  3.5L          8                  8mm                                     75%
                          500g
                          60%
                                                         12V              30min pH                8.5
                                                                                                                 [23]
                  25mL




                                                            3055
4
                                              ·OH
                                            Fenton                     ·OH
                                                                       [26]
                       1L




          VI.

1




                                                         /
2


                            DSA
                                                     2
                                                                    DSA
                                                                                                  DSA
3
                                                         BDD
                                                                                                  DSA

        [24]
                                                                              Ya-qiong Wang[27]

                              [25]
                                                Ti/ SnO2 +Sb2O3/PbO2                   SnO2 +Sb2O3
                                                         Ti//PbO2
                                                     3



                [13]




                                              NO.2008ZX07314-001-02
         VII.

1                                                                   References




                                     3056
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       Materials, Vol 165, pp. 961-966, June 2009.                                         treatment of paper mill wastewater using three-dimensional
[7]    Xinbo Wu, Xiaoqing Yang, and Dingcai Wu, Feasibility study of                       electrodes with Ti/Co/SnO2-Sb2O5 anode. Journal of Hazardous
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                                                                               3057

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Development of electrodes (1)

  • 1. Development of Three-Dimensional Electrode in Wastewater Treatment Huang Yaokun, Wang Can*, Wang Fen*, Ji Min* School of Environmental Science and Engineering Tianjin University Tianjin 300072, China Abstract—Three-dimensional electrode technology shows great II. potential in wastewater treatment. In this paper, the developments of the technology were systematic introduced. The optimization of feeder electrode or particle electrodes were becoming one of the research focuses of this filed. Several novel particle electrodes including new carbon material and metallic oxides had been widely studied. The mechanisms to A. degrade pollutants were due to the direct and indirect oxidation, which took place near the electrode area. Furthermore, it was pointed out that high operation cost, feeder electrodes corrosion and particle electrodes inactivation B. were the main problems of three-dimensional electrode technology. Some corresponding potential solutions for these H2O2 ·OH problems had also been proposed. Keywords: three-dimensional electrode; feeder electrode; particle electrode; wastewater treatment I. three-dimensional electrode particle electrode bed electrode conversion combustion H2O OH- ·OH ·OH ·OH MOx+1 ·OH 1 2 H2O OH- ·OH Cl- 3 Cl- H2O2 H2O2 Fenton ·OH 978-1-4577-0290-7/11/$26.00 ©2011 IEEE 3052
  • 2. III. 1 1 ·OH ·OH ·OH DSA ·OH ·OH DSA A. Yu-hong Guifen Lv[6] Cui[1] Ti/BDD Ti/Sb–SnO2 Ti/RuO2 Pt A 1 Ti/BDD Xinbo Wu [7] Ti/Sb–SnO2 X-3B Ti/RuO2 Ti/BDD 95% Ti/Sb–SnO2 [8] DSA Ti/SnO2 +Sb2O3[2] Ti/Co/SnO2[3] Ti/SnO2[4] H2O2 ·OH B. [5] Mn Cu Zn H2O2 IV. 2 3053
  • 3. 2 Mn Fe Zn [9] pH [10] CeO2/Sb2O5 CODCr Cu Ni Mn Zn [11] n P Fe Cu Ni Zn [12] Mn X-3B CODCr 2 3 3 Sb SnO2 E. Fockedey[2] -A12O3 Cu Fe [13] CuO- -A12O3>Fe2O3- -A12O3> Fe2O3-13X > -A12O3>13X > 5 2%CuO-9%CeO2 / -A12O3 CuO-CeO2 [14] -A12O3 CODCr 70% CuO Ce Sn Ti [15] Sn Ti 0.1 pH 3 450 Sn-Sb-Ag Ag Sn [16] Sn-Sb Sb 3054
  • 4. 3 V. E. Fockedey[30] 4 4 0.3L/min 68mA/cm2 375mL pH 3 Fe2+ Chih-TaWang[17] Fe2+ + 20V 0.1m3/h 176mL 30min CODcr 99% Ya Xiong[18] 87% 167mA/cm2 pH 11 NaCl Bo Wang[19] 150mL 11g/L 60min CODCr 86.3% 75% 40min BOD/CODCr 20 V pH 2.5 [20] 1.2L 1000 mg/L 0.3 mg/L 90 min CODcr 70.1% 4:1 57.1,mA/cm2 0.2,m3/h Fe2+ [21] 3.7L 1.0,mmol/ pH 4.0 180,min CODCr TOC 80.8% 73.3% 55.2% 98.6% 15V 60min pH [22] 3.5L 8 8mm 75% 500g 60% 12V 30min pH 8.5 [23] 25mL 3055
  • 5. 4 ·OH Fenton ·OH [26] 1L VI. 1 / 2 DSA 2 DSA DSA 3 BDD DSA [24] Ya-qiong Wang[27] [25] Ti/ SnO2 +Sb2O3/PbO2 SnO2 +Sb2O3 Ti//PbO2 3 [13] NO.2008ZX07314-001-02 VII. 1 References 3056
  • 6. [1] Yu-hong Cui, Xiao-yan Li, and Guohua Chen, Electrochemical [14] Yue Lin, Wang Qi-shan, and Shi Ya, Degradation of landfill leachate degradation of bisphenol A on different Anodes. Water Research, by electro-heterogeneous catalysis. China Environmental Science, Vol 43, pp. 1968-1976, April 2009. Vol 28, pp. 131-135, February 2008.(In Chinese). [2] E. Fockedey, A. Van Lierde, Coupling of anodic and cathodic [15] Xin YueHong, Wei Gang, and Wei YunPeng, Preparation of reactions for phenol electro-oxidation using three-dimensional particle-electrodes of zeolites loaded with composite oxides and a electrodes. Water Research, Vol 36, pp. 4169-4175, September 2002. study of their electrocatalytic activity. Journal of Beijing University [3] Wuping Kong, Bo Wang, and Hongzhu Ma, Electrochemical of Chemical Technology, Vol 37, pp. 58-54, February 2010.(In treatment of anionic surfactants in synthetic wastewater with Chinese). three-dimensional electrodes. Journal of Hazardous Materials, Vol [16] Xue hong-min, The Study on the Pretreatment of Nitrobenzene (TNT, B137, pp. 1532-1537, October 2006. DNT) Wastewater by three-dimensional electrode reactor. Master [4] Lizhang Wang , Jianfeng Fu, and Qicheng Qiao, Kinetic modeling of Thesis, Nanjing: Nanjing University of Science and Technology, electrochemical degradation of phenol in a three-dimension electrode 2006, pp. 37-74 (In Chinese). process. Journal of Hazardous Materials, Vol 144, pp. 118-125, June [17] Chih-Ta Wang , Jen-Lu Hua, and Wei-Lung Chou, Removal of color 2007. from real dyeing wastewater by Electro-Fenton technology using a [5] Ban F C, Liu J T, and Cheng L, The effect of electrode material on three-dimensional graphite cathode. Journal of Hazardous Materials, treatment of simulated phenol wastewater with a three-dimensional Vol 152, pp. 601-606, April 2008. electrode reactor. Acta Scientiae Circumstantiae, Vol 29, pp. [18] Ya Xiong, Peter J.Strunk, and Hongyun Xia, Treatment of dye 2076-2089, October 2009(In Chinese). wastewater containing acid orange II using a cell with three-phase [6] Guifen Lv, DingcaiWu, and Ruowen Fu, Performance of carbon three-dimensional Electrode. Water Research, Vol 35, pp. 4226-4230, aerogels particle electrodes for the aqueous phase electro-catalytic December 2001. oxidation of simulated phenol wastewaters. Journal of Hazardous [19] Bo Wang, Wuping Kong, and Hongzhu Ma, Electrochemical Materials, Vol 165, pp. 961-966, June 2009. treatment of paper mill wastewater using three-dimensional [7] Xinbo Wu, Xiaoqing Yang, and Dingcai Wu, Feasibility study of electrodes with Ti/Co/SnO2-Sb2O5 anode. Journal of Hazardous using carbon aerogel as particle electrodes for decoloration of RBRX Materials, Vol 146, pp. 295-301, July 2007. dye solution in a three-dimensional electrode reactor. Chemical [20] Wu Dan, Shi Qi-cai, and Zhou Ji-ti, Deep Treatment of Pulping Engineering Journal, Vol 138, pp. 47-54, May 2008. Wastewater Using Three Phase Fluidized Bed Electrode Reactor. [8] Linna Wang, Research on preparation and application of new EG Electrochemistry, Vol 12, pp. 412-415, November 2006.(In Chinese). particle electrode. Master Thesis, Guangzhou: Sun Yat-sen [21] Shi Yan, Wang Qi-shan, and Yue Lin, Treatment of Landfill University, 2009, pp. 64-91 (In Chinese). Leachate by Three-Dimensional-Electrode electro-Fenton Process. [9] Kong Ling-guo, Wang Ling, and Xue Jian-ju, Process of methyl Journal of Tianjin University, Vol 42, pp. 248-252, March 2009.(In orange simulated wastewater degraded by supported bipolar Chinese). three-dimension particle electrodes. China Environmental Science, [22] Anhua Xiong, Study on Advanced Treatment Techniques of Vol 30, pp. 517-521, April 2010.(In Chinese). Antibiotics Wastewater. Master Thesis, Beijing: Beijing University [10] Chen Kai-han, Wu W ei-bin, and Li Guo-qing, of Chemical Technology, 2006, pp. 30-44 (In Chinese). Electrocatalysis-oxidative degradation of azo-dye in water by three [23] Chen Jianpeng, Applied Research of Three-dimensional Electrode dimention electrode with activated carbon carried with CeO2/Sb2O5. System in Treating Pharmaceutical Wastewater of Cephalosporin. Technology of Water Treatment, Vol 31, pp. 11-14, May 2005.(In Master Thesis, Guangzhou: Sun Yat-sen University, 2009, pp. 41-69 Chinese). (In Chinese). [11] Guifen Lv, Research on electrochemical performances and [24] Ya Xiong, Hans T. Karlsson, An experimental investigation of application of metal oxides doped carbon aerogel. PhD Treatise, chemical oxygen demand removal from the wastewater containing Guangzhou: Sun Yat-sen University, 2008, pp. 97-124 (In Chinese). oxalic acid using three-phase three-dimensional electrode reactor. [12] Xinbo Wu, Adsorption of carbon aerogels and their electrochemical Advances in Environmental Research, Vol 7, pp. 139-145, November property as particle electrodes for dyes. PhD Treatise, Guangzhou: 2002. Sun Yat-sen University, 2007, pp. 114-136 (In Chinese). [25] Anhua Xiong, Study on Electrochemical Regeneration of Activeed [13] Weili Liu, Study on the Treatment of Aniline Wastewater by Carbon. Master Thesis, Beijing: Beijing University of Chemical Electro-Heterogeneous Catalysis Coupling Reactor. Master Thesis, Technology, 2006, pp. 30-41 (In Chinese). Dalian: Dalian University of Technology, 2006, pp. 37-74 (In [26] Ya-qiongWang, Bin Gu, and Wen-lin Xu, Electro-catalytic Chinese). degradation of phenol on several metal-oxide anodes. Journal of Hazardous Materials, Vol 162, pp. 1159-1164, March 2009. 3057