Windows Workflow Foundation (WF) is a programming model and runtime for building workflows in .NET applications. Microsoft BizTalk Server is a product for integrating disparate systems and automating business processes across applications. BizTalk Services provides a cloud-based integration service for building B2B and EAI solutions.
WF and BizTalk are complementary but serve different purposes. WF is for implementing workflows within an application while BizTalk is for orchestrating workflows across applications. BizTalk provides capabilities for integration, scalability, transactions, and administration that developers would have to build with WF. The document compares the features of WF, BizTalk Server, and BizTalk Services to determine when each technology should be used