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International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 144
Design and Optimization of Ball Mill for Clinker Grinding in Cement Plant
Sanjeev T. Patil
Department of Metallurgical and Materials Engineering, Visvesvaraya National Institute of Technology,
Nagpur-440010, India.
Abstract:
This study relatesbreakage rate for particle size reduction, surface area created and its specific energy
requirement. Plant data on energy consumptionfor clinker size reduction and laboratory data onsuperfine
to nanorange for likewise substances make this study more comprehensive. Proposed empirical
equations offerquick parameters estimation useful for practicing engineers. A number of relevant design
equations are used to carry out rigorous computations to quantify much sought parameters values which
are of much interest to cement plant personnel.
Introduction :
Cement is highly energy intensive,low priced commodity.Global energy costs are rising alarmingly.
Table 1 : The energy requirement for various steps in cement manufacture1
Section % Energy consumption / Ton of cement
Limestone crusher 2
Raw mix grinding 23
Coal grinding 3
Rotary kiln 28
Ball mill clinker grinding 40
Packing 2
Miscellaneous 2
Total 100
For a 1.5 million Tons/year cement plant, a very moderate saving target of just 1 kWh/Ton cement @
Rs. 6 / kWh gives annual saving of 1.5 x 106
T x Rs. 6 / kWh = Rs. 9 x 106
/year. ( 1 $ = Rs 60).
The crushers reduce mined limestone rocks from feet to inches for its easy transportation to the place of
its end use, further the raw mix milling and post clinkering ball mill grinding to ultrafine cement
production. The performance of ball mill depends on number, size and density of balls, flow rate of
material to be milled, rotation speed of the mill etc.
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 145
Grindability is relative ease with which a material can be ground, and is expressed in grams of screen
undersized product per revolution. It is the measure of specific energy consumption for size reduction
and enables choice of mill configuration. In clinker, the alite (C3S) cracks more easily than belite (C2S).
That means clinker with high lime saturation has a better grindability8
. This study considersclinker
grinding in ball mill.We proposemore precise empirical equation for modified HGI relating
withgrindability m, for broad based application for variety of minerals processing represented by
HGI = 13 + 10 m
(1)
For clinker, it is HGI = 30-50 and grindability values range 1.7-3.7. Greater is Hardgrove Grinding
Index, easier is the material grindability and requires less power for grinding2-5
.The objective of this
study was (a) to suggest model to describe comminution for wide range particles size (b) suggest
schemes to reduce power consumption in ball mill operation.
Experiment:
The laboratory ball mill has length 50 cm and diameter 30 cm. Grinding media are ceramic and steel
balls of 10 mm, 15 mm, 20 mm and 25 mm diameter and density from 4.5 to 7.8 g/cm3
. The mill rotates
at different speeds for grinding clinker, gypsum, fly ash and additives. The system parameters were
varied to study their effects on the performance of the ball mill. The amounts of undersize were found
out by sieving through # 200 mesh screen.
The first crusher product 12 mm size showed Bond work Index 13.2 kW/Ton and the second crusher
14.6 kW/Ton. The specific surface area of the powders was measured using the BET method. Particle
sizewasdetermined by means of auto-correlation spectroscopy by subjecting powder to ultrasonic
treatment in an aqueous solution of nitric acid.
Grinding kinetics and grinding energy requirement:
Following the rate of grinding is deduced by
dSw/dt = K(Sw∞.- Sw )i.e.( Sw∞.- Sw )/(Sw∞.- Sw0 ) = exp(-Kt ) i.e.ΔSw = Δ Sw∞[1–exp( - Kt ) (2)
where K is the comminution coefficient, t is the grinding time and Sw∞ is specific surface area for t = ∞
; and Sw
is specific surface area at time t. The specific surface area Sw∞ is the largest in the experimental range
achievable.
Results and Discussions:
From BET surface area measurement, the average particle size is determined. From our observation we
suggest an empirical relation to relate particle size, nm and surface area, m2
/g :dp = 2000/Sw (3)
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 146
Based on clinker grinding we put forth a simple correlation to relate grinding energy consumption in
kWh for the particle size in microns which adequately describes the data on likewise systems from ball
milling technique for ferric oxide, zinc oxide8-10
& quartz ultra fine to nano particles : E dp = 240(4)
have been pooled to cover broad range applicability.
Fig. 1 describes particle size, breakage rate, specific surface area, and specific energy consumption
pattern. From micron to submicron size range particles, the breakage rate slows down drastically and
any further size reduction especially in nano range it requires considerably high power input and
extended hours grinding. It appears to take almost 60 hours ball milling to get 25 nm cement
particles.Fromclinker size 40 mm, for final size 5 micron, with corresponding breakage rate of 0.0058
min-1
, commercial cement plant employs20 minutes grinding in ball mill which seems to be much longer
period probably to be on safer side.The power input for comminution increases exponentially with
reduction in particle size,requiring~ 40 kWh/Ton clinker grinding.
In a nearbycement plant use of grinding aids tried led to some interesting results. The modified
lignoslphonatefunctions both as grinding aid and super-plasticizer imparting a high strength cement for
high end applications of bridges, dams, international highways, high rise buildings, runway strip in
airports, ready mix concrete etc.
In an integrated cement plant,in a unique situation, the carbon dioxide rich waste gas stream from soda
ash plant kilnis bubbled through calcium, magnesium- and iron-rich plant effluent slurryto precipitate
2.0E+01 2.0E+00 2.0E-01 2.0E-02 2.0E-03 2.0E-04
0.0E+00
5.0E-01
1.0E+00
1.5E+00
2.0E+00
2.5E+00
3.0E+00
3.5E+00
1.0E-04
5.1E-03
1.0E-02
1.5E-02
2.0E-02
2.5E-02
3.0E-02
3.5E-02
1.0E-08 1.0E-07 1.0E-06 1.0E-05 1.0E-04 1.0E-03 1.0E-02
Surface Area, m2/g
SpecificEnergy,kWh/kg
BreakageRate,min-1
Particle Dia, m
Figure 1 : Relation between particle size , surface area , breakage
rate , and specific energy consumption
Specific Energy
Breakage rate
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 147
their carbonates and filtered to get wetcake almost reduced its dependence on mining
limestone.Blending fly ash from captive power plant up to 20% replaced clinker in masonry cement.
Suggested cement production plantpersonnel for using topside ball size130 mm (at present top side ball
size 90 mm is used)and smaller size 5 mm and 10 mm as wellfor implementation shortly. In our next
work,laboratory ball mill uses 3 mm, 5 mm and 9 mm balls in which case we are optimistic to reduce
grinding time and power input further to produce ultrafine particles, along side achieve cement with
higher strength in relatively short grinding time, in presence of grinding aids etc. Empirical equations
(1), (3) and (4) proposed by this study are consistent with our data and those from likewise systems by
other researches.
Visited cement machinery fabricators and suppliers ( courtesy PATFAB Engineers Pvt. Ltd.,
Ahmedabad, India ), to share experienceon mechanically activating fly ash as partial replacement for
clinker. With increasing energy cost, in future vertical or horizontal roller mill ( ~25 kWh/Ton ) are
likely to replace ball mills, to save almost 40-45% grinding energy cost.
In our limited study on grinding aid use, DEG and modified ligno-sulphonates showed expected trend,
an increase in throughput by 15-20% and reduction in specific energy. Further, the modified ligno-
sulphonate functioned as super plasticizer for enhanced cement strength significantly.
Table 2 : Plant trial results for grinding aids use
Additive % Dosage
level
Increase in
productivity
Savings in grinding time Savings in energy
Di ethylene
glycol
0.1-0.2 20% - ~ 20%
Lignin
compound
0.1-0.2 15% 12% ~ 12-15%
Urea 0.1-0.2 30%- - ~ 15%
For commercial cement plant ball mill 12 m long, 3.8 m diameter, calculations performed using design
equations showed top side steel ball size M = 127 mm; mill speed actual n = 16.6 rpm; grindability G =
1.69 g/rev, for throughput 80 T/hr clinker grinding from ~ 40 mm size down to average 5–6 microns,
employing retention time in the ball mill 20 minutes, feed linear velocity 36 m/hr; hold up 70 Tons,
specific energy requirement for clinker grinding ~ 40 kWh / Ton in ball mill before this study and 30
kWh/T now.Therefore there is merit in using appropriate size and number of balls, fly ash, grinding aid
and mill configuration to reduce power requirement for clinkergrinding in ball mill..
Conclusions:
This study proposes correlationsfor quick calculations, relating submicron/ultrafine particle size
expressed in nm;specific surface area, m2
/g; simply denoted by dp = 2000/Sw .
The power consumption kWh, and particle size, mm relation is given by Edp = 240.
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 148
Putforth a better and improved equation relating Hardgrove’s grinding index and grindability of several
such mineral materials is represented by HGI = 13 + 10 m .
The suggested model describes breaking rate-grinding energy-over wide range particle size excellently.
Proposed to local cement plant use of topside ball size 130 mm ( topside 90 mm balls used presently );
and other end 5 mm, 10 mm as well to improve grinding efficiency ( 15 mm balls are used so far ).
The fly ash blendingupto18% as clinker replacement has been achieved for masonry cement, use of
chemical plant solid effluent; grinding aidssuperplasticizerligno-sulphonates; these strategies resulted in
high strength,energy saving ultra-fine cement.
The use of bifunctional additive lignosulphonate; up to 20% flyash replacement for clinker,
rationalization of number and size of balls (adding 190 mm, 15 mm, 10 mm balls) would offer near
optimal ball mill performance.
In the passing, laboratory- and plant data have been incorporated to carry out set of calculations to
quantify ball mill design parametersto reduce energy requirement for clinker grinding significantly as
evidenced in Annexure I. These design equations and calculations are of immense help for cement plant
personnel.
References:
1. S. Peddanna, Energy Audit to Evolve Energy Conservation Measures by ERCOM Consulting
Engineers Pvt. Ltd. India.
2. John W. Schlanz “Grinding : ( http://mrl.ncsu.edu/reports/87-31-
P_Grinding_Operations_Design.pdf )
3. (http://www.thecementgrindingoffice.com/calculators/grindability/grindability.htm):Grindability
estimation.
4. B4 Milling ( Ball Mills ) Cement Plant Operations Handbook ICR 4th
Edn. ( 2005 ).
5. A. Sahoo and G K Roy : “Correlation for the grindability of the ball mill as a measure of its
performance” Asia Pacific Journal of Chemical Engineering 3(2) p. 230-235 ( 2008 ).
6. Balaz, P. “Mechanochemistry in Nanoscience and Minerals Engineering” P. 103-128 (2008).
7. Ernst Worrell & Christina Galitsky,: (http://www.energystar.gov/ia/business/industry/LBNL-
54036.pdf 1, March 2008 ).
8. Consistent Milling on a Nano Scale in Ceramic Industry : Ceramic Integration and Joining
Technologies
( http : www.retsch-us.com ).
9. http://en.wikipedia.org/wiki/Cementmill.
10. High energy ball milling technique for ZnO nanoparticles: Intl. Jl. of Nano-medicine 6, 863-869
( 2011 ) ( http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3124392/).
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 149
Annexure - I
Applicability of Design Equations
Top side ball size ( grinding media charge ) : ( M )
M = ( F Wi / K Cs )0.5
{ ρ / ( D0.5
) }0.5
(5)
M = Topside media diameter, in inches
F = size in microns of the screen opening which 80% of the feed will pass
ρ = specific gravity of feed
Wi = work index
Cs = percent critical speed
D = diameter of mill inside liners, in ft.
K = Constant, = 200 for ball mills and = 300 for rod mills .
M = [ 40000 x 13.7 / ( 200 x 75 )]0.5
{1.2 / (3.8)0.5
}0.5
= [ 40000 x 13.7 /(200 x 75 )]0.5
{ 1.2 /
(3.8)0.5
}0.5
= 6.044 x 0.7846 = 4.742 inches = 12.05 cm = 120.5 mm
Ball Size ( M ) :
Ball size charge is computation [ Trans. Am. Inst. Min. Met. Pet. Eng. 153, 373 (1943 ) ] and the
recommended optimum size make up rod and balls is given by [ Min. Eng. 10, 592-595 ( 1958) ]
Db= [XpEi / Knr ]0.5
[ρ f / D0.5
] 0.5
(6)
Db = [ 0.05 x 13.7 / (35 x 75 ) ]0.5
[ 1.2 / ( 3.8 )0.5
]0.5
= 12.67 cm = 127 mm
D = ball mill diameter, m ( ft ) = 3.8 m
Db = ball or rod diameter, cm or in
Ei = Bond work index of the feed = 13.7
K = grindabilityconstant =35 for dolomite 55 forcherk
K = constant 214 for rods when D and Db expressed in cm and 143 for balls when
expressed in m
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 150
300 for rods when D and Db expressed in inch and 200 for balls when expressed
in ft. respectively.
nr = percent of critical speed = 75 %
Xp = coarser feed ( to ball mill ) particle size, cm. 5 cm = 0.05 m
ρ f = feed density = 1200kg/m3
.
Critical Speed:
Critical speed of the mill is rotational speed relative to speed at which centrifugal force just counters
gravitation and holds the charge against the shell during rotation. Cement mills usually operate at 74-
76% of critical speed.
nc = 42.3 / D0.5
( 7 )
Where D = effective mill diameter, m.
% critical speed = ns = 100 n / Cs and/ ornc = ( 1 / 2π ) { g /( R-r ) }0.5
(8 )
Where n = actual mill speed, rpm .
Grinding Laws :
These laws are all empirical derived from laboratory results based on number of assumptions and do not
consider mechanical concepts such as recycle ratio, mill power lifter design, optimum media charge,
changes in mill feed etc.
Rittinger’sLaw : It states that the energy required to fracture particle is proportional to the new surface
produced.
Here, grinding rate proportional to particle size is valid for hard materials over limited size ranges ( d<
50 µ ).
ER = CR ( 1/d2 – 1/d1 ) (9a)
Where ER = specific energy, kWh/kg; CR = constant; d1= feed size; d2 = productsize.
Kirk’s Law : Energy required for fracture is proportional to volume, implying that grinding rate is
independent of particle size, as it is based on a constant and a reduction ratio. More energy is required
for fine grinding. This is valid for very short grinding times with particles confined in coarse size ranges
( validity d > 5 cm ).
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 151
EK = CK log ( d2/d1 ) (9b)
Here, EK = specific energy, kWh/kg; CK = constant ; d1 = feed size ; d2 = product size .
Bond’s Law :
Most accepted. Work input is proportional to the new crack tip length produced in particle breakage.
Applicable reasonably in conventional ball mill and rod mill grinding ( holds good for 5 cm – 50 µ ).
The power input is computed from Bond work index, feed and product particle sizes by
W = ( 10 Wi /P0.5
- 10 Wi /F0.5
) (9c)
W = power input ; Wi = work index ; F = 80% passing size of feed ; P = 80% passing size
of product .
The Bond work index ( Wi) is related to Hardgrove Index ( HGI ) :
Wi= 435 / HGI0.91
(10)
Grindability G( in g / rev ) :
G = 1.0402 x [ { (n/nc)1.897
( t/tc)0.073
( N ) 0.059
} / { ( dF/db)0.054
(ρF / ρb )0.04
} ] (11)
= 1.0402 x [{ (0.75)1.897
( 1)0.073
( 8334117) 0.059
} / { ( 4cm/5.5cm)0.054
(1.2 / 7.66 )0.04
}]
= 1.691 g / rev .
where
G = Grindability , ( g/ rev )
n = mill speed actual, rpm
nc = mill speed critical, rpm
t = grinding time actual, min
tc = grinding time standard, min
N = number of balls in both chambers of the mill together .
dF = feed clinker size, cm
db = average size, cm
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 152
ρF = specific gravity of feed charge
ρb = specific gravity of media charge
Grinding time is related to media diameter and mill speed. ( 3.35 MJ = 0.93 kWh/1 kg cement )
Grinding time t = KD2
/N0.5
(12 )
t = 1.43 x 3.82
/ 16.30.5
= 20.65 /4.03 = 5.1 min.
The nearby cement plant operates with 20 mins retention time for clinker grinding in the ball mill & 70
Ton hold up.
Power consumption = kW = 7.5 x Gw x D0.5
= 7.5 x 163 x 3.80.5
= 2383 kW. (Check its correctness) (13)
Grinding energy = 30-35 kWh / Ton cement .
Here, Gw = ball charge, ( Ton ); and D = Effective mill diameter, ( m ).
G = ( HGI – 13 ) / 6.93 (14)
where, G = grindability of the mill, g/rev.
Mill Power:
Bond’s theory enables estimation of specific power consumption ( kwh / Ton ) from the work index, Wi
of the material being ground which conforms to mill motor output power of an 8 ft diameter wet
grinding overflow ball mill in closed circuit.
E = ( Wi/ f1
0.5
– Wi/f2
0.5
) C1C2 (15)
E = 13.7 [ 1 / (15) 0.5
– 1 / (40000) 0.5
] x 1.3 x 0.915 = 13.7 x 0.2534 x 1.1895 = 41.3 kWh/Ton
f1 = the micron size which 80% of feed passes
f2 = the micron size which 80% of product passes
C1 = 1.3 for dry grinding
C2 = ( 2.438 / D)0.2
= ( 2.438/3.8 )0.2
= ( 0.6416 )0.2
= 0.915
D = effective mill inside diameter, m .
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 153
Wi = Work Index according to Bond test mill is given by
Wiin kWh / Ton = 88 / ( HGI )0.95
= It is in the range of
88/ ( 30 )0.95 to 88 /
( 50 )0.95
= 12.5 – 16.0 kWh/Ton
Further, the Bond work index ( Wi) is related to HardgroveGrindability Index ( HGI ) :
Wiin kWh / Ton = 435 / HGI0.91
(16)
Power input to ball mill :
W or E = ( 10Wi/ f1
0.5
– 10Wi/f2
0.5
) (17)
= 10Wi[1 / (15)0.5
– 1 / (40000)0.5
]
= 10 Wi [ ( 1 / 3.86 ) - ( 1 / 200 ) ]
= 10 x 13.7 [0.2584 – 0.005] =34.67 kWh/Ton
And for grinding to 5 microns it is E= 10 x 13.7 [0.4472 – 0.005] =60.6 kWh/Ton.
Energy Conservation technique in cement production process :
It is important to enhance operation efficiency of mill. Mill performance depends on various factors:
critical mill speed, hardness and quantity of material to be crushed, ball charge, mill drive power etc .
Mill drive power:
N = Power consumption
= C.G.Di.n = 0.255 x 80 x 3.8 x 16.6 = 1287 kWh (18)
Considering ball load, = 0.255 x 136 x 3.8 x 16.6 =2188 kWh
Where,
N = Power consumption (kW) = 2161 kWh or 1245 kWh
G = Weight of mill charge (Ton) = 136 Ton or 80 T/hr.?Which is correct ?
Di = Internal diameter of the mill (m) = 3.8 m
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 154
n = Actual speed of the mill (rpm) = 16.6 rpm
C = power factor = 0.255
Power consumption of a mill can also be determined from: kW = 7.5Gw (d)0.5
(19)
Where Gw= ball charge , Ton
D = effective mill internal diameter, m
Retention time, τ = Hold up in the ball mill, m3
/(Feed rate m3
/hr) = 22 m3
/66.67 m3
/hr = 20 mins.
( Plant ) (20)
= mill length / linear velocity of feed material = 12 m/ 30 m/hr = 24 min. for cement
plant mill.
The Work Index is calculated as Wi = 1622 / ( HGI )1.08
Wi = 88 / HGI0.5
= 13.8 kWh/ Ton ( proposed by Bond in 1951 )
Wi = 1622 / HGI1.08
( byMcintyre and Plitt in 1980 for Wi> 8.5 )
Mill Power Draw Determination( N ) :
Using desired product rate and expected specific power consumption figure from the grindability testing,
the net power requirement delivered by the ball mill is determined. Net power draw for an industrial mill
is calculated by one of the methods as :
N = k x F x n x µ x D x a (21)
Where,
N = Net power (kW)
k = Constant for unit conversion
F = Quantity ball charge, (Ton) and mill filling about 28 – 35% of available
millvolume
n = Mill rotation, ( rpm )
International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014
Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954
R S. Publication, rspublicationhouse@gmail.com Page 155
µ = Torque factor 0.7 – 0.73
D = Effective mill compartment inside diameter, ( m )
a = Distance between mill centre of gravity for the charge.
Comes out to be 0.4 m .

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Ball Mill Optimization

  • 1. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 144 Design and Optimization of Ball Mill for Clinker Grinding in Cement Plant Sanjeev T. Patil Department of Metallurgical and Materials Engineering, Visvesvaraya National Institute of Technology, Nagpur-440010, India. Abstract: This study relatesbreakage rate for particle size reduction, surface area created and its specific energy requirement. Plant data on energy consumptionfor clinker size reduction and laboratory data onsuperfine to nanorange for likewise substances make this study more comprehensive. Proposed empirical equations offerquick parameters estimation useful for practicing engineers. A number of relevant design equations are used to carry out rigorous computations to quantify much sought parameters values which are of much interest to cement plant personnel. Introduction : Cement is highly energy intensive,low priced commodity.Global energy costs are rising alarmingly. Table 1 : The energy requirement for various steps in cement manufacture1 Section % Energy consumption / Ton of cement Limestone crusher 2 Raw mix grinding 23 Coal grinding 3 Rotary kiln 28 Ball mill clinker grinding 40 Packing 2 Miscellaneous 2 Total 100 For a 1.5 million Tons/year cement plant, a very moderate saving target of just 1 kWh/Ton cement @ Rs. 6 / kWh gives annual saving of 1.5 x 106 T x Rs. 6 / kWh = Rs. 9 x 106 /year. ( 1 $ = Rs 60). The crushers reduce mined limestone rocks from feet to inches for its easy transportation to the place of its end use, further the raw mix milling and post clinkering ball mill grinding to ultrafine cement production. The performance of ball mill depends on number, size and density of balls, flow rate of material to be milled, rotation speed of the mill etc.
  • 2. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 145 Grindability is relative ease with which a material can be ground, and is expressed in grams of screen undersized product per revolution. It is the measure of specific energy consumption for size reduction and enables choice of mill configuration. In clinker, the alite (C3S) cracks more easily than belite (C2S). That means clinker with high lime saturation has a better grindability8 . This study considersclinker grinding in ball mill.We proposemore precise empirical equation for modified HGI relating withgrindability m, for broad based application for variety of minerals processing represented by HGI = 13 + 10 m (1) For clinker, it is HGI = 30-50 and grindability values range 1.7-3.7. Greater is Hardgrove Grinding Index, easier is the material grindability and requires less power for grinding2-5 .The objective of this study was (a) to suggest model to describe comminution for wide range particles size (b) suggest schemes to reduce power consumption in ball mill operation. Experiment: The laboratory ball mill has length 50 cm and diameter 30 cm. Grinding media are ceramic and steel balls of 10 mm, 15 mm, 20 mm and 25 mm diameter and density from 4.5 to 7.8 g/cm3 . The mill rotates at different speeds for grinding clinker, gypsum, fly ash and additives. The system parameters were varied to study their effects on the performance of the ball mill. The amounts of undersize were found out by sieving through # 200 mesh screen. The first crusher product 12 mm size showed Bond work Index 13.2 kW/Ton and the second crusher 14.6 kW/Ton. The specific surface area of the powders was measured using the BET method. Particle sizewasdetermined by means of auto-correlation spectroscopy by subjecting powder to ultrasonic treatment in an aqueous solution of nitric acid. Grinding kinetics and grinding energy requirement: Following the rate of grinding is deduced by dSw/dt = K(Sw∞.- Sw )i.e.( Sw∞.- Sw )/(Sw∞.- Sw0 ) = exp(-Kt ) i.e.ΔSw = Δ Sw∞[1–exp( - Kt ) (2) where K is the comminution coefficient, t is the grinding time and Sw∞ is specific surface area for t = ∞ ; and Sw is specific surface area at time t. The specific surface area Sw∞ is the largest in the experimental range achievable. Results and Discussions: From BET surface area measurement, the average particle size is determined. From our observation we suggest an empirical relation to relate particle size, nm and surface area, m2 /g :dp = 2000/Sw (3)
  • 3. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 146 Based on clinker grinding we put forth a simple correlation to relate grinding energy consumption in kWh for the particle size in microns which adequately describes the data on likewise systems from ball milling technique for ferric oxide, zinc oxide8-10 & quartz ultra fine to nano particles : E dp = 240(4) have been pooled to cover broad range applicability. Fig. 1 describes particle size, breakage rate, specific surface area, and specific energy consumption pattern. From micron to submicron size range particles, the breakage rate slows down drastically and any further size reduction especially in nano range it requires considerably high power input and extended hours grinding. It appears to take almost 60 hours ball milling to get 25 nm cement particles.Fromclinker size 40 mm, for final size 5 micron, with corresponding breakage rate of 0.0058 min-1 , commercial cement plant employs20 minutes grinding in ball mill which seems to be much longer period probably to be on safer side.The power input for comminution increases exponentially with reduction in particle size,requiring~ 40 kWh/Ton clinker grinding. In a nearbycement plant use of grinding aids tried led to some interesting results. The modified lignoslphonatefunctions both as grinding aid and super-plasticizer imparting a high strength cement for high end applications of bridges, dams, international highways, high rise buildings, runway strip in airports, ready mix concrete etc. In an integrated cement plant,in a unique situation, the carbon dioxide rich waste gas stream from soda ash plant kilnis bubbled through calcium, magnesium- and iron-rich plant effluent slurryto precipitate 2.0E+01 2.0E+00 2.0E-01 2.0E-02 2.0E-03 2.0E-04 0.0E+00 5.0E-01 1.0E+00 1.5E+00 2.0E+00 2.5E+00 3.0E+00 3.5E+00 1.0E-04 5.1E-03 1.0E-02 1.5E-02 2.0E-02 2.5E-02 3.0E-02 3.5E-02 1.0E-08 1.0E-07 1.0E-06 1.0E-05 1.0E-04 1.0E-03 1.0E-02 Surface Area, m2/g SpecificEnergy,kWh/kg BreakageRate,min-1 Particle Dia, m Figure 1 : Relation between particle size , surface area , breakage rate , and specific energy consumption Specific Energy Breakage rate
  • 4. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 147 their carbonates and filtered to get wetcake almost reduced its dependence on mining limestone.Blending fly ash from captive power plant up to 20% replaced clinker in masonry cement. Suggested cement production plantpersonnel for using topside ball size130 mm (at present top side ball size 90 mm is used)and smaller size 5 mm and 10 mm as wellfor implementation shortly. In our next work,laboratory ball mill uses 3 mm, 5 mm and 9 mm balls in which case we are optimistic to reduce grinding time and power input further to produce ultrafine particles, along side achieve cement with higher strength in relatively short grinding time, in presence of grinding aids etc. Empirical equations (1), (3) and (4) proposed by this study are consistent with our data and those from likewise systems by other researches. Visited cement machinery fabricators and suppliers ( courtesy PATFAB Engineers Pvt. Ltd., Ahmedabad, India ), to share experienceon mechanically activating fly ash as partial replacement for clinker. With increasing energy cost, in future vertical or horizontal roller mill ( ~25 kWh/Ton ) are likely to replace ball mills, to save almost 40-45% grinding energy cost. In our limited study on grinding aid use, DEG and modified ligno-sulphonates showed expected trend, an increase in throughput by 15-20% and reduction in specific energy. Further, the modified ligno- sulphonate functioned as super plasticizer for enhanced cement strength significantly. Table 2 : Plant trial results for grinding aids use Additive % Dosage level Increase in productivity Savings in grinding time Savings in energy Di ethylene glycol 0.1-0.2 20% - ~ 20% Lignin compound 0.1-0.2 15% 12% ~ 12-15% Urea 0.1-0.2 30%- - ~ 15% For commercial cement plant ball mill 12 m long, 3.8 m diameter, calculations performed using design equations showed top side steel ball size M = 127 mm; mill speed actual n = 16.6 rpm; grindability G = 1.69 g/rev, for throughput 80 T/hr clinker grinding from ~ 40 mm size down to average 5–6 microns, employing retention time in the ball mill 20 minutes, feed linear velocity 36 m/hr; hold up 70 Tons, specific energy requirement for clinker grinding ~ 40 kWh / Ton in ball mill before this study and 30 kWh/T now.Therefore there is merit in using appropriate size and number of balls, fly ash, grinding aid and mill configuration to reduce power requirement for clinkergrinding in ball mill.. Conclusions: This study proposes correlationsfor quick calculations, relating submicron/ultrafine particle size expressed in nm;specific surface area, m2 /g; simply denoted by dp = 2000/Sw . The power consumption kWh, and particle size, mm relation is given by Edp = 240.
  • 5. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 148 Putforth a better and improved equation relating Hardgrove’s grinding index and grindability of several such mineral materials is represented by HGI = 13 + 10 m . The suggested model describes breaking rate-grinding energy-over wide range particle size excellently. Proposed to local cement plant use of topside ball size 130 mm ( topside 90 mm balls used presently ); and other end 5 mm, 10 mm as well to improve grinding efficiency ( 15 mm balls are used so far ). The fly ash blendingupto18% as clinker replacement has been achieved for masonry cement, use of chemical plant solid effluent; grinding aidssuperplasticizerligno-sulphonates; these strategies resulted in high strength,energy saving ultra-fine cement. The use of bifunctional additive lignosulphonate; up to 20% flyash replacement for clinker, rationalization of number and size of balls (adding 190 mm, 15 mm, 10 mm balls) would offer near optimal ball mill performance. In the passing, laboratory- and plant data have been incorporated to carry out set of calculations to quantify ball mill design parametersto reduce energy requirement for clinker grinding significantly as evidenced in Annexure I. These design equations and calculations are of immense help for cement plant personnel. References: 1. S. Peddanna, Energy Audit to Evolve Energy Conservation Measures by ERCOM Consulting Engineers Pvt. Ltd. India. 2. John W. Schlanz “Grinding : ( http://mrl.ncsu.edu/reports/87-31- P_Grinding_Operations_Design.pdf ) 3. (http://www.thecementgrindingoffice.com/calculators/grindability/grindability.htm):Grindability estimation. 4. B4 Milling ( Ball Mills ) Cement Plant Operations Handbook ICR 4th Edn. ( 2005 ). 5. A. Sahoo and G K Roy : “Correlation for the grindability of the ball mill as a measure of its performance” Asia Pacific Journal of Chemical Engineering 3(2) p. 230-235 ( 2008 ). 6. Balaz, P. “Mechanochemistry in Nanoscience and Minerals Engineering” P. 103-128 (2008). 7. Ernst Worrell & Christina Galitsky,: (http://www.energystar.gov/ia/business/industry/LBNL- 54036.pdf 1, March 2008 ). 8. Consistent Milling on a Nano Scale in Ceramic Industry : Ceramic Integration and Joining Technologies ( http : www.retsch-us.com ). 9. http://en.wikipedia.org/wiki/Cementmill. 10. High energy ball milling technique for ZnO nanoparticles: Intl. Jl. of Nano-medicine 6, 863-869 ( 2011 ) ( http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3124392/).
  • 6. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 149 Annexure - I Applicability of Design Equations Top side ball size ( grinding media charge ) : ( M ) M = ( F Wi / K Cs )0.5 { ρ / ( D0.5 ) }0.5 (5) M = Topside media diameter, in inches F = size in microns of the screen opening which 80% of the feed will pass ρ = specific gravity of feed Wi = work index Cs = percent critical speed D = diameter of mill inside liners, in ft. K = Constant, = 200 for ball mills and = 300 for rod mills . M = [ 40000 x 13.7 / ( 200 x 75 )]0.5 {1.2 / (3.8)0.5 }0.5 = [ 40000 x 13.7 /(200 x 75 )]0.5 { 1.2 / (3.8)0.5 }0.5 = 6.044 x 0.7846 = 4.742 inches = 12.05 cm = 120.5 mm Ball Size ( M ) : Ball size charge is computation [ Trans. Am. Inst. Min. Met. Pet. Eng. 153, 373 (1943 ) ] and the recommended optimum size make up rod and balls is given by [ Min. Eng. 10, 592-595 ( 1958) ] Db= [XpEi / Knr ]0.5 [ρ f / D0.5 ] 0.5 (6) Db = [ 0.05 x 13.7 / (35 x 75 ) ]0.5 [ 1.2 / ( 3.8 )0.5 ]0.5 = 12.67 cm = 127 mm D = ball mill diameter, m ( ft ) = 3.8 m Db = ball or rod diameter, cm or in Ei = Bond work index of the feed = 13.7 K = grindabilityconstant =35 for dolomite 55 forcherk K = constant 214 for rods when D and Db expressed in cm and 143 for balls when expressed in m
  • 7. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 150 300 for rods when D and Db expressed in inch and 200 for balls when expressed in ft. respectively. nr = percent of critical speed = 75 % Xp = coarser feed ( to ball mill ) particle size, cm. 5 cm = 0.05 m ρ f = feed density = 1200kg/m3 . Critical Speed: Critical speed of the mill is rotational speed relative to speed at which centrifugal force just counters gravitation and holds the charge against the shell during rotation. Cement mills usually operate at 74- 76% of critical speed. nc = 42.3 / D0.5 ( 7 ) Where D = effective mill diameter, m. % critical speed = ns = 100 n / Cs and/ ornc = ( 1 / 2π ) { g /( R-r ) }0.5 (8 ) Where n = actual mill speed, rpm . Grinding Laws : These laws are all empirical derived from laboratory results based on number of assumptions and do not consider mechanical concepts such as recycle ratio, mill power lifter design, optimum media charge, changes in mill feed etc. Rittinger’sLaw : It states that the energy required to fracture particle is proportional to the new surface produced. Here, grinding rate proportional to particle size is valid for hard materials over limited size ranges ( d< 50 µ ). ER = CR ( 1/d2 – 1/d1 ) (9a) Where ER = specific energy, kWh/kg; CR = constant; d1= feed size; d2 = productsize. Kirk’s Law : Energy required for fracture is proportional to volume, implying that grinding rate is independent of particle size, as it is based on a constant and a reduction ratio. More energy is required for fine grinding. This is valid for very short grinding times with particles confined in coarse size ranges ( validity d > 5 cm ).
  • 8. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 151 EK = CK log ( d2/d1 ) (9b) Here, EK = specific energy, kWh/kg; CK = constant ; d1 = feed size ; d2 = product size . Bond’s Law : Most accepted. Work input is proportional to the new crack tip length produced in particle breakage. Applicable reasonably in conventional ball mill and rod mill grinding ( holds good for 5 cm – 50 µ ). The power input is computed from Bond work index, feed and product particle sizes by W = ( 10 Wi /P0.5 - 10 Wi /F0.5 ) (9c) W = power input ; Wi = work index ; F = 80% passing size of feed ; P = 80% passing size of product . The Bond work index ( Wi) is related to Hardgrove Index ( HGI ) : Wi= 435 / HGI0.91 (10) Grindability G( in g / rev ) : G = 1.0402 x [ { (n/nc)1.897 ( t/tc)0.073 ( N ) 0.059 } / { ( dF/db)0.054 (ρF / ρb )0.04 } ] (11) = 1.0402 x [{ (0.75)1.897 ( 1)0.073 ( 8334117) 0.059 } / { ( 4cm/5.5cm)0.054 (1.2 / 7.66 )0.04 }] = 1.691 g / rev . where G = Grindability , ( g/ rev ) n = mill speed actual, rpm nc = mill speed critical, rpm t = grinding time actual, min tc = grinding time standard, min N = number of balls in both chambers of the mill together . dF = feed clinker size, cm db = average size, cm
  • 9. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 152 ρF = specific gravity of feed charge ρb = specific gravity of media charge Grinding time is related to media diameter and mill speed. ( 3.35 MJ = 0.93 kWh/1 kg cement ) Grinding time t = KD2 /N0.5 (12 ) t = 1.43 x 3.82 / 16.30.5 = 20.65 /4.03 = 5.1 min. The nearby cement plant operates with 20 mins retention time for clinker grinding in the ball mill & 70 Ton hold up. Power consumption = kW = 7.5 x Gw x D0.5 = 7.5 x 163 x 3.80.5 = 2383 kW. (Check its correctness) (13) Grinding energy = 30-35 kWh / Ton cement . Here, Gw = ball charge, ( Ton ); and D = Effective mill diameter, ( m ). G = ( HGI – 13 ) / 6.93 (14) where, G = grindability of the mill, g/rev. Mill Power: Bond’s theory enables estimation of specific power consumption ( kwh / Ton ) from the work index, Wi of the material being ground which conforms to mill motor output power of an 8 ft diameter wet grinding overflow ball mill in closed circuit. E = ( Wi/ f1 0.5 – Wi/f2 0.5 ) C1C2 (15) E = 13.7 [ 1 / (15) 0.5 – 1 / (40000) 0.5 ] x 1.3 x 0.915 = 13.7 x 0.2534 x 1.1895 = 41.3 kWh/Ton f1 = the micron size which 80% of feed passes f2 = the micron size which 80% of product passes C1 = 1.3 for dry grinding C2 = ( 2.438 / D)0.2 = ( 2.438/3.8 )0.2 = ( 0.6416 )0.2 = 0.915 D = effective mill inside diameter, m .
  • 10. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 153 Wi = Work Index according to Bond test mill is given by Wiin kWh / Ton = 88 / ( HGI )0.95 = It is in the range of 88/ ( 30 )0.95 to 88 / ( 50 )0.95 = 12.5 – 16.0 kWh/Ton Further, the Bond work index ( Wi) is related to HardgroveGrindability Index ( HGI ) : Wiin kWh / Ton = 435 / HGI0.91 (16) Power input to ball mill : W or E = ( 10Wi/ f1 0.5 – 10Wi/f2 0.5 ) (17) = 10Wi[1 / (15)0.5 – 1 / (40000)0.5 ] = 10 Wi [ ( 1 / 3.86 ) - ( 1 / 200 ) ] = 10 x 13.7 [0.2584 – 0.005] =34.67 kWh/Ton And for grinding to 5 microns it is E= 10 x 13.7 [0.4472 – 0.005] =60.6 kWh/Ton. Energy Conservation technique in cement production process : It is important to enhance operation efficiency of mill. Mill performance depends on various factors: critical mill speed, hardness and quantity of material to be crushed, ball charge, mill drive power etc . Mill drive power: N = Power consumption = C.G.Di.n = 0.255 x 80 x 3.8 x 16.6 = 1287 kWh (18) Considering ball load, = 0.255 x 136 x 3.8 x 16.6 =2188 kWh Where, N = Power consumption (kW) = 2161 kWh or 1245 kWh G = Weight of mill charge (Ton) = 136 Ton or 80 T/hr.?Which is correct ? Di = Internal diameter of the mill (m) = 3.8 m
  • 11. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 154 n = Actual speed of the mill (rpm) = 16.6 rpm C = power factor = 0.255 Power consumption of a mill can also be determined from: kW = 7.5Gw (d)0.5 (19) Where Gw= ball charge , Ton D = effective mill internal diameter, m Retention time, τ = Hold up in the ball mill, m3 /(Feed rate m3 /hr) = 22 m3 /66.67 m3 /hr = 20 mins. ( Plant ) (20) = mill length / linear velocity of feed material = 12 m/ 30 m/hr = 24 min. for cement plant mill. The Work Index is calculated as Wi = 1622 / ( HGI )1.08 Wi = 88 / HGI0.5 = 13.8 kWh/ Ton ( proposed by Bond in 1951 ) Wi = 1622 / HGI1.08 ( byMcintyre and Plitt in 1980 for Wi> 8.5 ) Mill Power Draw Determination( N ) : Using desired product rate and expected specific power consumption figure from the grindability testing, the net power requirement delivered by the ball mill is determined. Net power draw for an industrial mill is calculated by one of the methods as : N = k x F x n x µ x D x a (21) Where, N = Net power (kW) k = Constant for unit conversion F = Quantity ball charge, (Ton) and mill filling about 28 – 35% of available millvolume n = Mill rotation, ( rpm )
  • 12. International journal of advanced scientific and technical research Issue 4 volume 1, January-February 2014 Available online on http://www.rspublication.com/ijst/index.html ISSN 2249-9954 R S. Publication, rspublicationhouse@gmail.com Page 155 µ = Torque factor 0.7 – 0.73 D = Effective mill compartment inside diameter, ( m ) a = Distance between mill centre of gravity for the charge. Comes out to be 0.4 m .