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Heat integration projects for 
refining processes 
Heat integration projects can deliver substantial savings, but they require 
detailed simulation and case-specific heat integration analysis 
ALis¸AN DOg˘AN 
Turkish Petroleum Refineries Corporation 
Refining is a complex operation 
involving many kinds of 
processes. All these processes 
have different principles; some 
involve fractionation, some involve 
different reactions and some have 
both. All these processes have one 
thing in common: they need 
energy. It may be a need to heat 
“cold streams”: energy to make the 
required separation between cuts, 
energy to strip off unwanted gases, 
energy to perform a reaction and so 
on. The processes also have ener-gy- 
giving streams (hot streams): 
column pumparounds, overhead 
streams, reactor effluents and so 
on, which are available to supply a 
portion of the necessary heat; 
furnaces burning fuel take care of 
the rest. Some processes are inte-grated; 
the product or residue of 
one process may be the feed to 
another. The better the heat integra-tion 
in or between process units, 
the less fuel is burned in furnaces, 
which leads to more profit. In this 
article, the basics of heat integration 
studies performed in various heat 
integration projects for different 
refinery process units are consid-ered. 
The methods, equipment and 
approaches used for heat integra-tion 
(pinch) studies of various 
refining processes, their similarities 
and differences are discussed. 
In order to make a pinch study of 
an existing unit, one should first 
define the overall picture, which is 
the energy balance and the temper-ature 
profile of all the related cold 
and hot streams. The heating cool-ing 
curves and potentials saving 
should be determined. A test run 
performed in the unit will give all 
the necessary information, such as 
flow rates, temperatures and lab 
results. Based on this test run, a 
simulation model of the unit should 
be made. For a start, only the heat 
exchanger network consisting of 
simple heat exchanger models may 
be enough to define the overall heat 
balance. However, when it comes 
to adding equipment, making accu-rate 
cost estimations and defining 
design data for retrofits and new 
equipment, a unit model with 
rigorous heat exchangers, columns 
and other equipment will be neces-sary. 
Furthermore, a complete unit 
model will let you find additional 
and more accurate saving opportu-nities 
through case studies and 
trial-and-error studies. At the end 
of the day, it is all about making 
the necessary investment in an 
existing unit to gain air- or water-cooled 
waste heat to decrease 
furnace loads or generate steam. 
Case studies will be necessary to be 
able to select the best investment 
option. When deciding on the 
design data of new equipment and 
retrofits, rating them with a second 
set of simulation data representing 
the unit (or units) will be wise in 
order to select the equipment based 
on a range of operations. 
Main steps to making a detailed 
heat integration engineering study 
are given below. The procedure 
may change from study to study, 
but the principles remain the same: 
• Rigorous simulation modelling of 
the existing unit or units within the 
boundary 
• Formation of base case heating – 
cooling composite curves 
• Determination of base case mini-mum 
approach temperature and 
potential savings 
• Determination of possible retrofit 
paths to achieve potential savings 
• Making the necessary equipment 
additions to the unit model and 
simulating the new retrofit paths 
• Repeating the first five steps for 
another base case simulation 
model, preferably a case at the 
opposite end of the operation 
envelope 
• Rating the equipment to supply 
the needs of both operation cases 
• Determination of investment 
costs and benefits of all the differ-ent 
saving opportunities (options) 
• Selecting the most appropriate 
case 
• Extracting the process data neces-sary 
for new equipment design. 
Savings may be further increased 
during the latter simulation stages 
by changing/shifting reflux duties 
and operation variables. 
Heat integration studies 
performed on different refining 
units will now be discussed, taking 
into account similarities and differ-ences 
in the approaches and their 
effects. 
Crude and vacuum distillation 
processes 
The first important step for a heat 
integration study of a crude distil-lation 
unit is drawing the 
boundary: is the unit integrated 
with the vacuum unit and, if not, 
should it be? Integrating a crude 
unit with the downstream vacuum 
unit is, most of the time, more prof-itable. 
Even if they are not 
integrated, the overall boundary 
should be drawn to include the 
vacuum side — the atmospheric 
residue (vacuum charge) preheat-ing 
train. 
www.eptq.com PTQ Q4 2013 113
residue preheating should be 
included in the heat integration 
study when drawing boundaries. 
Including only the crude unit will 
prevent one from seeing the poten-tial 
modifications, retrofits and 
benefits, which result in hotter 
atmospheric residue going to the 
vacuum unit. 
Figure 2 is the composite curve 
for the CDU unit in Figure 1, which 
is not integrated with the VDU. The 
hot-side pinch point is 129°C and 
the atmospheric residue outlet from 
crude preheating is at 127°C. 
Therefore, the atmospheric residue 
temperature is at the closest point 
to the heating curve of the cold 
streams. The minimum temperature 
difference (DTmin) between the 
curves is 30°C. Although there is 44 
Gcal/h of waste heat, the saving 
potential is limited to 7 Gcal/h 
even when you target a minimum 
temperature difference of 10°C, 
which is very hard to achieve. 
The reason for this is that if you 
bring only the CDU into the 
picture, it is not possible to gain 
substantially from the waste heat 
and keep the atmospheric residue 
temperature close to 129°C at the 
same time. 
However, when atmospheric resi-due 
preheating in the VDU is 
brought into the picture, there is no 
need to keep the atmospheric resi-due 
temperature close to the cold 
curve, because it is a cold stream 
that is heated by VDU hot streams. 
Sending atmospheric residue hotter 
to the VDU is desirable, therefore a 
potential is generated even when 
the two units are not integrated. If 
the units are to be integrated, the 
potential is much higher. 
Atmospheric residue will then be 
going to the VDU furnace directly 
in its hottest form, and the VDU 
hot streams will be used in crude 
heating (see Figure 1). 
When atmospheric residue 
preheating is added within the 
boundaries, DTmin automatically 
increases to 46°C, creating a poten-tial 
of 15 Gcal/h for DTmin = 10, 
already doubled even though the 
same atmospheric residue tempera-ture 
is targeted. The real potential, 
in fact, is much higher than this, 
considering that there is no 
Crude Heating AR Heating 
Crude unit 
Unintegrated 
357ºC 127ºC 300ºC 
AR 
duty 
HVGOPA 
duty 
Integrated 
VR 
duty 
AR 
Crude unit 
AR 
~357ºC ~357ºC and unit 
Figure 1 Drawing the CDU/VDU heat integration boundary 
Drawing the boundary 
In an integrated CDU/VDU config-uration, 
vacuum unit hot streams 
are used to heat the crude charge, 
and hot atmospheric residue is sent 
directly to the vacuum furnace to be 
heated. In a non-integrated configu-ration, 
atmospheric residue is sent 
colder to the vacuum unit after heat-ing 
the crude oil. Therefore, in a 
non-integrated layout, atmospheric 
residue is first a hot stream giving 
energy to the crude side, then a cold 
stream, which is heated by vacuum 
unit hot streams such as the HVGO 
pumparound and vacuum residue 
run-down. This is an inefficient 
design from a heat integration point 
HVGOPA 
duty 
VR 
duty 
Vacuum 
furnace 
and unit 
Vacuum 
furnace 
of view. Heat exchanger area is 
needed to first cool down the hot 
atmospheric residue in the crude 
side, and additional area is needed 
to heat it in the vacuum side. 
Furthermore, the heat that could be 
recovered would be higher in the 
integrated case, the HVGO pumpa-round 
(at high flow) and vacuum 
residue (at high temperature) being 
able to give more duty to the crude 
side and the atmospheric residue 
going much hotter to the vacuum 
furnace directly from the atmos-pheric 
column. 
Even if integration of the CDU 
and VDU is not desired for a 
specific reason, atmospheric 
dTmin = 30ºC 
Pinch = 99ºC 
Pinch = 129ºC 
0 50 100 150 200 250 
Enthalpy, Gcal/h 
600 
500 
400 
300 
200 
100 
Temperature, ºC 
0 
Figure 2 Drawing the boundary and composite curves 
114 PTQ Q4 2013 www.eptq.com
constraint on the atmospheric 
residue temperature, and even 
more when the units are to be 
integrated. 
In the example below, a heat inte-gration 
study performed on another 
CDU/VDU unit is explained in 
detail. The configuration, number 
of pumparound streams, reboiler 
hot streams and so on may differ in 
different process layouts. 
Case 1: CDU/VDU unit 
In the integrated unit discussed 
below, the preheat train consists of 
three different sections. Before the 
desalter, the heat required is 
provided by the atmospheric 
column overhead and some portion 
of the diesel pumparound duty. 
After the desalter, crude is sepa-rated 
into three streams to be 
heated by product run-downs, the 
diesel pumparound and the HVGO 
pumparound. Afterwards, the 
combination crude is further heated 
by vacuum residue before going 
into the atmospheric furnace. The 
reboiler and naphtha splitter 
reboiler duties are supplied by 
HVGO and diesel pumparounds. 
The DTmin of the light crude base 
case is ~70°C, with nearly 62 
Gcal/h of furnace process duty and 
42 Gcal/h of wasted “hot stream” 
energy. 
The main waste heat streams in 
this configuration are as follows: 
• HVGO PA air cooler duty (after 
crude heating) 
• LVGO PA air cooler duty 
• Atmospheric column overhead 
duty after the top condenser 
• Run-down air cooler duties (after 
crude and desalter water heating), 
especially heavy diesel run-down. 
Basic design considerations for 
the project are: 
• Increasing the HVGO pumpa-round 
duty in the vacuum column 
automatically decreases the 
air-cooled LVGO pumparound 
duty. Even in the low HVGO 
pumparound base case, a substan-tial 
amount of duty is lost through 
air coolers. The desired HVGO 
temperature to the hydrocracker is 
150°C. Therefore, a HVGO pumpa-round 
temperature of 150°C is 
targeted. In order to make up room 
in the crude network for the exist-www. 
Kero. LAD HAD 
Desalter 
OVHD HADPA2 HADPA1 VR 
Desalter 
Crude 
Kero. LAD HAD1 
OVHD HADPA2 HADPA1 
LVGOPA HVGOPA1 
Crude 
Figure 3 CDU/VDU example crude preheat train before and after the project 
ing air-cooled duty and this 
additional duty in the HVGO 
pumparound, some duty has to be 
shifted towards the hotter side of 
the train. Therefore, a new hot 
HVGO pumparound exchanger is 
added before the existing hot VR 
exchanger, and the new cold 
HVGO pumparound heat 
exchanger is added to the cold side 
to recover the additional duties 
• The remaining LVGO pumpa-round 
duty is partially recovered 
before the HADPA exchangers in 
the second branch 
• A portion of the heavy diesel 
duty is recovered in the second 
branch, following the new LVGO 
heat exchanger 
• Additional surface area is added 
to the HADPA heat exchanger. The 
reason for this is that the crude 
temperature is much higher now 
because of the LVGO and heavy 
diesel heat exchangers 
• The new cold vacuum residue 
exchanger drops the temperature to 
its initial value before going to 
steam production 
• The overhead vapour duty after 
the first condenser (crude oil 
heater) is very high, and this is lost 
through air and water coolers. 
However, it needs a higher-grade 
material heat exchanger to recover 
because of its corrosive nature 
• Putting an additional high-grade 
material overhead exchanger and 
recovering the energy across the 
HVGOPA 
To 
furnace 
VR1 
VR2 
HAD2 
HVGOPA2 
To 
furnace 
dew point was considered. This 
would enable more heat recovery 
by shifting the diesel pumparound 
duty towards the hotter side of the 
train, making room for the over-head 
duty before the desalter. 
Diesel pumparound duty would 
be shifted by closing the bypass 
and putting additional area on the 
existing HADPA exchanger. 
However, because of the tight 
equipment layout, enough space 
could not be found in the actual 
unit conditions. This option is laid 
aside for the time being as a 
possibility. 
The simplified crude preheat 
train before and after the project is 
shown in Figure 3. 
The key to this study is that all of 
the new heat exchangers are 
considered to be plate-type heat 
exchangers. All welded-type plate 
heat exchangers, because of their 
area and space efficiency (high heat 
transfer coefficient), are well suited 
to tighter applications. If shell and 
tubes were to be selected for this 
project, a huge number of shells in 
series and the space they occupy 
would have been required. This 
would have increased the invest-ment 
cost, pressure drop and space 
requirements. With this project, 
over 15 Gcal/h of furnace duty will 
be saved even without the addi-tional 
overhead exchanger. Overall 
payback time of the project is 
almost half a year. 
eptq.com PTQ Q4 2013 115
To 
column 
Crude To 
VR1 
Kero. LAD HAD1 
OVHD HADPA2 HADPA1 HADPA 
LVGOPA HVGOPA1 
Flash drum (new) 
furnace 
driving force effect creates room for 
additional savings potential in the 
cold side of the train and decreases 
the heat exchanger investment to 
be made. In this specific layout, the 
cold preflash bottom temperature 
makes HADPA duty shift to the 
hotter side of the preheat train, 
creating room for an additional 
savings opportunity before the 
desalter. The only air-cooled stream 
available for this is the overhead 
stream. Therefore, the driving force 
effect would make additional 
savings if overhead duty were to be 
used. This effect also decreases the 
investment cost of exchangers and 
decreases the vacuum residue 
temperature going to steam 
production (by shifting some 
portion of the vacuum residue 
steam duty to crude oil heating 
furnace duty). The additional 
saving would be in the range of 
2 Gcal/hour in the light crude case 
and close to zero in the heavy 
crude case. Based on these results, 
the preflash drum option for this 
study was laid aside because of its 
low overall benefits and unit space 
constraints. 
Preflash example 2 
Another example is the initially 
non-integrated CDU/VDU unit 
illustrated in Figures 1 and 2. The 
effects of the preflash drum and 
also the importance of drawing the 
overall boundary correctly will be 
discussed in this example. When a 
typical non-integrated CDU such as 
in Figure 1 is considered, atmos-pheric 
residue is used in preheating 
crude oil, and colder atmospheric 
residue is heated again with 
vacuum-side hot streams. 
If there is an air-cooled pumpa-round, 
introducing preflash vapour 
VR2 
HAD2 
HVGOPA2 
• If pumparound duty is used 
directly in the preheat, potential 
duty gained by bypassing the 
furnace is lost as reflux duty in the 
preheat train, cancelling out the 
energy benefit 
• If pumparound duty is air cooled, 
the preflash vapour will decrease 
this duty. Energy-wise, there will 
be no loss and the furnace duty 
will be decreased 
• The saving related to the driving 
force effect with the preflash option 
depends on the waste heat availa-ble 
in the heat integration study 
and the configuration. 
Simulations are made such that 
there is no loss of valuable prod-ucts 
to less valuable ones. Some 
examples regarding the preflash 
studies made are given below. 
Preflash example 1 
In the CDU/VDU study given as 
the example project, a preflash 
study was made. A brief summary 
of the preflash option for this 
particular unit follows. 
When the preflash vapour is 
given to the flash zone, duty gained 
in the atmospheric furnace is lost in 
the vacuum furnace. 
When the preflash vapour is given 
to the upper trays at a suitable 
temperature, column pumparound 
duty decreases. There is only one 
pumparound in this particular unit 
(HADPA) and all of the duty is used 
in crude oil preheat. The potential 
duty gained by preflash vapours 
bypassing the furnace is lost in 
crude oil preheating. The column 
atmospheric residue temperature 
increases and the vacuum furnace 
load decreases. However, overall 
saving in this aspect is close to zero. 
There is a 20°C temperature drop 
in the preflash drum bottom. This 
Desalter 
Figure 4 Preflash drum option for the project 
Preflash drum option 
The feasibility of adding a preflash 
drum depends on the column oper-ation, 
pumparounds and how they 
are located in the structure of the 
heat exchanger network and the 
tray where preflash vapour is intro-duced. 
Adding a preflash drum 
changes the pinch structure, the 
potential energy savings and the 
additional area of new heat 
exchanger needed. It is a case-specific 
study, and it should not be 
decided whether an option with the 
preflash drum will be feasible or 
not without making a detailed 
study. However, the existing unit 
column and heat exchanger 
network structure will give a hint. 
It is certain that preflash vapour 
will bypass the furnace and the 
liquid load will decrease. 
Furthermore, the preflash drum 
bottom temperature will be much 
lower than the inlet. This will create 
a driving force in temperatures and 
make an opportunity for this 
stream to be heated more effi-ciently, 
which may result in duty 
shifts and savings. 
However, the main point to be 
considered in a preflash drum study 
is the cooling effect of preflash 
vapour on the tray to which it is 
introduced. If this vapour is given 
directly to the flash zone, the 
column bottom temperature will be 
lower and the direct benefit will be 
small. In fact, the only real potential 
in this case is the temperature drop 
in the preflash bottoms and the abil-ity 
to heat this stream more 
effectively. If preflash vapour is 
given to the upper trays based on its 
temperature, the pumparound duty 
on the column will decrease. 
Therefore, the question is where is 
this pumparound duty used? 
116 PTQ Q4 2013 www.eptq.com
for warming up 
and cooling down 
bronswerk.com
Effluent 
To 
air-cooler 
EFF1 EFF2 EFF3 EFF4 EFF5 EFF6 EFF7 
Fractionator 
bottom 
product 
Diesel 
product 
To reactor furnace To stripper HVGO feed Stripper feed Hydrogen 
Figure 5 Hydrocracker project existing simplified network 
Waste heat through air or water 
coolers is in total 60.3 Gcal/h. 
Nearly 24 Gcal/h is wasted 
through the effluent air cooler 
(operating from 190°C to 62°C). The 
minimum temperature difference is 
75°C between the curves. The hot 
pinch is 230°C and the cold pinch is 
154.5°C (see Figure 6). 
The link between the high-pressure 
and low-pressure heat 
exchanger trains is the stripper 
charge. Stripper feed is heated from 
~60°C to ~110°C with fractionator 
streams before going to the 
high-pressure effluent exchangers, 
where it is heated to 255°C. 
Therefore, if the stripper charge 
stream is further heated with addi-tional 
heat exchangers on the 
stripper-fractionator side (the 
low-pressure side), there will be 
available duty potential in the efflu-ent 
side to heat reactor feed streams 
or the fractionator feed stream. In 
this way, a portion of the wasted 
section will be discussed with 
regard to the hydrocracker example. 
Example: hydrocracker 
In the unit studied, HVGO, hydro-gen 
and stripper feed is heated 
with reactor effluent. Before going 
into this high-pressure network, the 
stripper charge is heated with 
diesel and fractionator bottom 
product. Debutaniser and naphtha 
splitter reboiler duties are supplied 
by the diesel pumparound in the 
fractionator. Kerosene pumpa-round, 
kerosene run-down, stripper 
and fractionator overhead streams, 
and the reactor effluent stream 
going to the air cooler are the main 
sources of waste energy. There are 
two furnaces: one reactor charge 
furnace and the other fractionator 
charge (stripper bottom) furnace. A 
simplified existing heat exchanger 
layout is shown in Figure 5. 
In the base case, the furnaces 
have a process duty of 26.4 Gcal/h. 
in the upper trays creates a benefit, 
as discussed in the previous 
example. 
If all pumparound duties are used 
in preheating, one does not expect 
large amounts of savings. However, 
if you draw the boundary on the 
CDU only, the results will be differ-ent. 
The pumparound duties (there 
may be more than one pumpa-round) 
will be lower with the upper 
tray preflash option. This would 
automatically mean that crude inlet 
temperatures to the existing atmos-pheric 
residue exchangers would 
decrease, creating a driving force 
effect. This would also automatically 
mean that more duty can be recov-ered 
from atmospheric residue, 
making up for the lost duty in 
pumparounds, and the atmospheric 
residue temperature leaving the 
CDU will be lower. This is an 
energy saving if you are only 
considering the CDU. However, the 
atmospheric residue is sent directly 
to the vacuum unit, and this poten-tial 
saving is lost in the vacuum 
furnace. Therefore, if you draw the 
boundary on the CDU only, you 
will be evaluating a potential that is 
not actually there. There will be 
some shifts from steam production 
duty to furnace duty, but this is not 
an energy-saving potential in the 
CDU/VDU. It is a matter of the 
value of steam in that particular 
refinery. If the unit is integrated, 
project saving potentials are much 
bigger. However, the effect of a 
preflash drum will be similar. 
Hydrocracker and 
hydrodesulphurisation (HDS) units 
A typical hydrocracker or a HDS 
preheat train can be divided into 
two sections: the reactor effluent 
side with high pressure and 
temperature; and the stripper– 
fractionation side with run-downs, 
pumparounds, reboilers and so on. 
The main cold streams in this 
layout are the reactor input 
streams: HVGO for the hydroc-racker 
(diesel for HDS), hydrogen 
and stripper-fractionator feeds. 
In hydrocracker and HDS heat 
integration studies performed, 
similar principles were followed 
(except for the fact that there is no 
fractionator in a HDS), therefore this 
600 
500 
400 
300 
200 
100 
Temperature, ºC 
dT = 75.38ºC 
Qh = 26.4 
Qc = 60.3 
0 
0 20 40 60 80 100 120 140 160 
Enthalpy, Gcal/h 
Figure 6 Hydrocracker project base case curves 
118 PTQ Q4 2013 www.eptq.com
column overhead energy (together with other frac-tionation 
side heat) will be recovered as furnace 
duty. Once again, for the low-pressure side, weld-ed- 
type plate heat exchangers are selected. 
This approach can be applied either to keep the 
reactor effluent temperature as it is (~190°C; after 
wash water injection it is ~160°C) or maximise the 
benefits by decreasing (gaining from) the reactor 
effluent air cooler duty as well. The choice is a 
matter of the additional heat exchange area required 
in the high-pressure network to shift this duty to 
feed streams and the furnace duty benefits achieved 
from it. However, it is also a matter of corrosion. A 
lower reactor effluent air cooler temperature means 
that temperatures are shifted towards cold stream 
heating. Therefore, corrosion mechanisms will be 
shifted towards the existing or new heat exchangers. 
On the low-pressure side, diesel pumparound has 
a high flow rate and temperature to be able to heat 
up the fractionator charge with a plate-type heat 
exchanger. In order to achieve this, reboiler duties 
have to be shifted as much as possible towards the 
lower-grade heat sources. Air-cooled kerosene 
pumparound, diesel run-down and kerosene 
run-down are suitable to take a portion of this duty. 
Therefore, lower-grade heat sources are used for 
lower-grade heat, freeing up higher-grade heat to be 
used elsewhere – in this case, for heating the frac-tionator 
charge. The temperatures are tight, so 
plate-type heat exchangers are suitable for this 
purpose. 
An alternative approach is to further raise the 
fractionator feed temperature by introducing it to 
the high-pressure reactor effluent network. 
Including this stream on the effluent side by means 
of the optional exchanger shown in Figure 7 
increases the amount of savings made per amount 
of additional investment. Furthermore, the saving is 
directly from the furnace. However, introducing the 
fractionator feed to the high-pressure network may 
not be desirable because of relief load and safety 
concerns. 
In the HDS unit example without a fractionator, no 
pumparound duty may be available. However, heat-ing 
the stripper feed more effectively with stripper 
overhead and diesel product before it enters the 
high-pressure preheat train creates the opportunity to 
further heat up the reactor furnace feed streams. 
Therefore, the principle is similar. 
Alternative options 
Introducing a preflash drum 
Similar to the crude preflash study, introducing a 
preflash drum to the fractionator feed creates a 20°C 
temperature difference driving force. This stream 
can be heated with heavy diesel (heavy diesel 
pumparound) or reactor effluent, or both. This driv-ing 
force creates an additional energy-saving 
opportunity and decreases the amount of additional 
area needed. However, the main saving comes 
because the kero pumparound is air cooled. Preflash 
vapour duty directly decreases from the air cooler if 
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To reactor 
furnace 
To fractionator 
furnace 
Effluent To air cooler 
Optional EFF5 EFF6 EFF7 
Fractionator 
bottom 
product 
Diesel product 
from deb. reb. 
Fractionator 
overhead 
Hydrogen 
hydrogen through stripper charge 
and loss of hydrogen to fuel gas. It 
also means loss of C3-C4 (LPG prod-uct). 
Four separator designs can be 
selected to lower the amount of 
product lost, but cannot prevent it. 
Therefore, even though steam 
production is acceptable with the 
low-pressure fractionation streams 
and more energy is recovered over-all, 
hydrogen and LPG losses, 
together with major changes in the 
high-pressure section of the unit 
(adding two separator drums), 
make this alternative much less 
attractive among the other heat 
recovery scenarios. 
Targeting the reactor effluent 
air cooler 
The effluent air cooler is the biggest 
source of waste heat in a hydroc-racker. 
Introducing this source of 
heat to the recovery options will 
increase the potential overall savings 
and decrease the overall investment 
cost. However, the corrosive nature 
of this stream and the modifications 
that need to be done in the fraction-ation 
section of the heat exchanger 
network require a detailed analysis 
and a change of approach. 
Considering its positive effects on 
unit shutdown periods as well, this 
option may be a very good selec-investment 
EFF1 EFF2 EFF3 EFF4 
To stripper 
HVGO feed 
Stripper feed 
Debut reboiler duty shifted to 
HAD rundown. 
Portion of naphtha splitter 
reboiler duty shifted to kero 
pumparound. 
Figure 7 Hydrocracker project simplified network after possible modifications 
costs. Payback times of 
Fractionator feed 
(Preflash bottom) 
all the different scenarios are 
around, or less than, one year. 
Introducing a hot separator 
The stripper feed can be described 
as the cold reactor effluent stream 
after the air cooler and pressure 
separators. Therefore, in a way, it is 
being cooled with an air cooler and 
heated again with reactor effluent. 
From an energy point of view, 
instead of cooling it to 60°C, it can 
be kept at the desired temperature, 
say 255°C, with a new separator 
configuration including a hot 
separator. In this way, the effluent 
air cooler duty will be lower and 
duty will be transferred to the other 
cold streams, decreasing furnace 
loads. However, low-pressure side 
hot streams heating the stripper 
charge will be freed up, and they 
have to be used in steam production 
in order not to waste them and gain 
some energy overall. Whether this 
steam is needed or not is a critical 
issue when evaluating this option. If 
steam is not a good alternative in 
the refinery’s utility balance, hot 
separator designs do not bring any 
energy benefit at all when compared 
to other heat recovery scenarios. 
Furthermore, introducing a hot 
separator means more soluble 
HADPA 
vapours are introduced to the 
upper trays according to the 
temperature profile. Therefore, frac-tionator 
furnace duty is decreased 
directly. Together with the shifting 
of reboiler duties to lower-grade 
heat sources and using diesel 
pumparound duty to heat up the 
preflash bottoms (fractionator feed) 
with a new heat exchanger, furnace 
and air-cooled pumparound or 
overhead reflux duties are 
decreased substantially. 
Taking into account all of the 
design considerations discussed, a 
simplified heat exchanger configu-ration 
looks like the one shown in 
Figure 7 (new positions are shown 
in red). 
The total furnace process duty 
saved with this configuration, even 
without affecting the reactor efflu-ent 
cooler and without adding 
additional area to the existing 
exchangers, is 9 Gcal/h, which is 
actually higher when furnace effi-ciency 
is considered. Together with 
kero run-down steam production 
and considering firing efficiencies, 
the total saving is nearer 13 Gcal/h. 
By adding the new heat exchang-ers 
shown and adding new shells 
to the existing heat exchangers, 
savings can rise to 18 Gcal/h, 
taking into account increased 
120 PTQ Q4 2013 www.eptq.com
Key performance indicators for ConSep trays 
sometimes very critical in heat inte-gration 
Texas, complex had a power surge 
that triggered a small fire in a pipe 
rack at the refinery’s chemical 
plant. Power surges can cause fires 
and cause breakdown in different 
units. In April 2011, Sunoco’s 
Philadelphia, Pennsylvania, refin-ery 
the ebullated-bed reactor or fed to a 
coker unit. studies. For this The study, freedom it was 
to 
considered that this stream is recy-cled 
produce steam may bring addi-tional 
types of switchgear are oil or gas 
insulated. A stray spark can cause 
these to catch on fire and fail. 
Then there are the obscure 
reasons that cannot be predicted 
and happen so infrequently that it 
is hard to protect against. In 
November 2012, Valero’s Corpus 
Christi, Texas, had a power loss 
that led to flaring due to a rodent 
contacting the primary power 
transformer. Transformers that can 
be accessed should be protected to 
allow only those working on them 
to get to them. In February 2010, 
Western Refining’s Yorktown, 
Virginia, had an unidentified unit 
shutdown due a temporary power 
blip caused by a goose flying into a 
nearby power line. Unless power 
lines are put underground, it is 
difficult to protect them from 
animals and debris. 
Power surges and fluctuations 
Power surges also occur frequently 
and can be prevented with circuit 
breakers or switchgear. In August 
2009, ExxonMobil’s Baytown, 
Parameters Design Test run 
Froth backup/CS height, % 68 60 
Tray pressure drop, mbar 12.3 9.2 
Tube flood , % 73 60 
Flow parameter 0.17 0.19 
Overall column load factor, m/s 0.12 0.10 
Flooding (CS tray), % 133 112 
benefits to overall fuel 
back to the hydroconversion 
consumption in the refinery, or it 
may not be needed at all. 
In a heat integration study, 
options should be evaluated with 
detailed simulation and heat inte-gration 
reactor, meaning that there is 
complete overall residue conver-sion 
even when the once-through 
had a power surge that 
conversion reported in Table 2 is 
78%. 
The fractionated products from 
the VTB conversion step, along 
with the corresponding VDU distil-lates, 
knocked compressors offline. In 
May 2011, Phillips analysis. 66’s Wilmington, 
Evaluations 
California, facility had a power 
fluctuation occur, temporarily shut-ting 
should be considered in a case-spe-cific 
manner with creative thinking 
3 De Villiers W E, Bravo J L, Wilkinson P M, 
Summers D R, Further advances in light 
hydrocarbon fractionation, PTQ Q3 2004. 
Kaushik Majumder is Distillation Team Lead of 
Shell Projects & Technology in Bangalore, India. 
He holds a bachelor’s degree from Jadavpur 
University, India, and a master’s and doctorate 
from Indian Institute of Technology, Delhi. 
Email: Kaushik.Majumder@shell.com 
Giuseppe Mosca is the Global Refinery 
Technology Manager of Sulzer Chemtech. 
He holds BS and MS degrees in chemical 
engineering from the University “La Sapienza” 
Rome, Italy. 
Email: Giuseppe.Mosca@sulzer.com 
Kent Mahon is a Process Engineer at Refining 
NZ. He was the Senior Process Engineer and 
Commissioning Process Engineer during the 
Point Forward Project. 
Email: Kent.Mahon@refiningnz.com 
and taking general guidelines into 
account. Most of the time, heat inte-gration 
down several refinery units. 
require further hydrotreating 
Normal operations were restored 
the next day. 
Multiple unit shutdowns 
Since most refinery units are inte-grated 
to reduce sulphur, nitrogen and 
aromatic projects contents will for bring producing 
large 
suitable blending components for 
SCO. The properties of the hydro-treated 
amounts of savings involving 
millions of dollars per year, with 
usually less than one-to–one-and-a-half- 
products and final SCO are 
year payback periods. 
and sometimes share the 
provided in Table 4. The SCO has 
no residue and very low sulphur 
and nitrogen contents. The 
coking-derived SCO is slightly 
more aromatic than that derived 
from the hydroconversion-based 
scheme. Table 5 summarises the 
details of the HDT units. It is 
observed that the hydrotreating of 
coker products requires higher 
same power supply, power failures 
could lead to the shutdown of these 
integrated units and the production 
loss of many refined products, 
thereby magnifying potential 
damages. 
In June 2009, Tesoro’s Kenai, 
Alaska, facility experienced a 
power outage. The hydrocracker 
and isomerisation unit were shut to 
Alis¸an Dog˘an is a Process and Equipment 
Development Superintendent in Head Office 
Technical Services Management with Turkish 
Petroleum Refineries Corporation (Tüpras), 
specialising in heat recovery and heat 
integration and process simulation. He holds 
a BS in chemical engineering from Middle East 
Technical University, Ankara, Turkey. 
Email: Alisan.Dogan@tupras.com.tr 
effectively from sources that would 
otherwise prove very costly and 
involve high pressure drops if shell 
and tubes were to be used. Plate-type 
test run’s results, it could be 
concluded that the revamp targets 
for the CDU-1 main fractionator 
(C-150) were achieved. No hydrau-lic 
Properties of coker and hydroconverter liquid productsa 
constraint was experienced in 
Coker Hydroconverter 
heat exchanger usage is 
achieving the design intake of 
13 000 t/d and the required prod-uct 
Property Naphtha LGO HGO Naphtha LGO HGO Vacuum residue 
Yield, wt% 26.8 34.1 39.1 14.0 37.9 27.8 20.4 
SG 60/60°F 0.7363 0.8715 0.9736 0.7365 0.8710 0.9715 1.1240 
API gravity 60.7 30.9 13.8 60.6 31.0 14.2 -5.6 
Sulphur, wt% 1.79 3.67 4.43 0.25 0.71 1.37 6.90 
Nitrogen, wppm 316 1694 3973 393 1582 3063 8905 
Aromatics, wt% 27.1 58.0 66.0 20.5 42.5 53.0 99.8 
Nickel, wppm - - 8.2 - - 3.0 262.9 
Vanadium, wppm - - 27.4 - - 6.2 458.3 
CCR, wt% - - 1.5 - - 0.2 14.3 
limited in pressure (to 40 bar) 
• Using a flash drum before a frac-tionator 
creates a driving force 
effect that may enable some addi-tional 
energy recovery or heat duty 
Table 3 
shift from steam production to cold 
feed streams (furnace duty). 
However, the main point in making 
a preflash drum a feasible option is 
whether there is wasted, air-cooled 
pumparound duty near the tray 
flash vapour. Giving preflash 
vapour to higher trays may not be 
desired because of liquid entrain-ment 
quality was achieved. 
Conclusions 
The performance of Shell ConSep 
trays in the HGO pumparound 
section of the CDU-1 main fractiona-tor 
met the target of capacity 
enhancement without any drawback 
compared to the pre-revamp condi-tions. 
During the test run, the trays 
were operating at 10-15% lower than 
the design capacity even at the 
design intake of 13 000 t/d due to 
heavier crude feed and lower feed 
temperature. However, the built-in 
capacity margin enabled stable oper-ation 
such cases. In this revamp project, 
use of only three of these trays in 
the most capacity-constrained 
section of the column made it possi-ble 
to retrofit the existing column 
and made the capex option more 
attractive over the other debottle-necking 
options. 
Properties of hydrotreated products and SCO 
concerns; therefore, special 
consideration should be given to 
the preflash drum design, such as 
high retention time, high L/D ratio 
and usage of demister pads. Even a 
preflash tower may be considered 
to eliminate risks, although this 
would, of course, increase the 
investment cost 
• Overall refinery steam balance is 
tion, in combination with the key 
points taken from the other options. 
Conclusion 
Heat integration options and stud-ies 
Substations, whether owned by 
the utility company or the refinery, 
tend to break down if not properly 
maintained. In October 2009, 
Valero’s McKee, Texas, plant had a 
substation should malfunction, be considered which 
as 
forced units offline. Substation 
malfunctions have occurred more 
frequently than many people think. 
In March 2010, Chevron’s El 
Segundo, California, refinery shut 
down due to fire at a substation. 
And, in August 2011, Tesoro’s 
Kapolei, Hawaii, complex had a 
power outage due to a failure at 
one of the local electric utility’s 
substations. 
In May 2010, BP’s Texas City, 
Texas, refinery had a power blip 
caused by switchgear failure. 
Switchgear failures also occur quite 
frequently. The relay that failed at 
the Super Bowl was a part of the 
switchgear setup that supplied 
power to the stadium. Switchgears 
operate as a protective device 
against overcurrent and arc flashes. 
They also need to be properly 
maintained to avoid failures. A few 
case-specific evaluations. There is 
no rule of thumb whether an option 
is the best for a specific unit or a 
specific refinery. Unit layout, inte-gration 
with other downstream 
units, overall refinery utility 
balance and unit-specific problems 
(such a) Yield as values the are based hydrocracker on total liquid product. 
effluent 
air cooler example) all affect the 
selection process: 
• Drawing the overall boundary is 
very important, especially in CDU/ 
VDU studies. Integration will most 
of the time bring additional benefits 
in energy savings and area effi-ciency. 
* Shell ConSep, Shell CS and Shell HiFi are Shell 
trademarks. ** Mellapak Plus 252Y is a Sulzer 
Chemtech trademark. 
Coker-based scheme Hydroconverter-based scheme 
Drawing the boundary 
Table 3 
Property Naphtha LGO HGO SCO Naphtha LGO HGO SCO 
SG 60/for 60°F the trays 0.7375 at much 0.8597 above 
0.9131 0.8680 0.7375 0.8573 0.9115 0.8665 
API gravity 60.4 33.1 23.5 31.5 60.4 33.6 23.7 31.8 
Sulphur, wt% 0.018 0.112 0.16 0.13 0.014 0.044 0.15 0.10 
Nitrogen, wppm 12 204 740 482 21 264 455 336 
Aromatics, wt% 19.9 41.8 54.2 45.9 15.8 36.5 50.9 41.7 
incorrectly may even make a feasi-ble 
the capacity limit of the first genera-tion 
option infeasible, or vice versa 
of high-capacity trays. 
The options to debottleneck 
columns already equipped with the 
first generation of high-capacity 
trays are limited. ConSep trays 
provide an attractive solution for 
(for instance, the CDU/VDU 
preflash drum example) 
• Using all welded-type plate 
exchangers Table 4 
creates the opportunity 
to recover heat efficiently and cost 
References 
1 Refinery expansion means NZ more self 
reliant, media release by NZRC, 16 July 2010. 
2 Wilkinson P M, De Villiers W E, Mosca 
G, Tonon L, Achieve challenging targets in 
propylene yield using ultra system fractionation 
trays, ERTC 2006. 
www.eptq.com PTQ Q1 2013 77 
www.eptq.com PTQ Q4 2013 121 
wwwwww..eeppttqq..ccoomm PPTTQQ QQ32 22001133 4 213

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Industrial heat pumps
 

Article - 2013 PTQ Q4

  • 1. Heat integration projects for refining processes Heat integration projects can deliver substantial savings, but they require detailed simulation and case-specific heat integration analysis ALis¸AN DOg˘AN Turkish Petroleum Refineries Corporation Refining is a complex operation involving many kinds of processes. All these processes have different principles; some involve fractionation, some involve different reactions and some have both. All these processes have one thing in common: they need energy. It may be a need to heat “cold streams”: energy to make the required separation between cuts, energy to strip off unwanted gases, energy to perform a reaction and so on. The processes also have ener-gy- giving streams (hot streams): column pumparounds, overhead streams, reactor effluents and so on, which are available to supply a portion of the necessary heat; furnaces burning fuel take care of the rest. Some processes are inte-grated; the product or residue of one process may be the feed to another. The better the heat integra-tion in or between process units, the less fuel is burned in furnaces, which leads to more profit. In this article, the basics of heat integration studies performed in various heat integration projects for different refinery process units are consid-ered. The methods, equipment and approaches used for heat integra-tion (pinch) studies of various refining processes, their similarities and differences are discussed. In order to make a pinch study of an existing unit, one should first define the overall picture, which is the energy balance and the temper-ature profile of all the related cold and hot streams. The heating cool-ing curves and potentials saving should be determined. A test run performed in the unit will give all the necessary information, such as flow rates, temperatures and lab results. Based on this test run, a simulation model of the unit should be made. For a start, only the heat exchanger network consisting of simple heat exchanger models may be enough to define the overall heat balance. However, when it comes to adding equipment, making accu-rate cost estimations and defining design data for retrofits and new equipment, a unit model with rigorous heat exchangers, columns and other equipment will be neces-sary. Furthermore, a complete unit model will let you find additional and more accurate saving opportu-nities through case studies and trial-and-error studies. At the end of the day, it is all about making the necessary investment in an existing unit to gain air- or water-cooled waste heat to decrease furnace loads or generate steam. Case studies will be necessary to be able to select the best investment option. When deciding on the design data of new equipment and retrofits, rating them with a second set of simulation data representing the unit (or units) will be wise in order to select the equipment based on a range of operations. Main steps to making a detailed heat integration engineering study are given below. The procedure may change from study to study, but the principles remain the same: • Rigorous simulation modelling of the existing unit or units within the boundary • Formation of base case heating – cooling composite curves • Determination of base case mini-mum approach temperature and potential savings • Determination of possible retrofit paths to achieve potential savings • Making the necessary equipment additions to the unit model and simulating the new retrofit paths • Repeating the first five steps for another base case simulation model, preferably a case at the opposite end of the operation envelope • Rating the equipment to supply the needs of both operation cases • Determination of investment costs and benefits of all the differ-ent saving opportunities (options) • Selecting the most appropriate case • Extracting the process data neces-sary for new equipment design. Savings may be further increased during the latter simulation stages by changing/shifting reflux duties and operation variables. Heat integration studies performed on different refining units will now be discussed, taking into account similarities and differ-ences in the approaches and their effects. Crude and vacuum distillation processes The first important step for a heat integration study of a crude distil-lation unit is drawing the boundary: is the unit integrated with the vacuum unit and, if not, should it be? Integrating a crude unit with the downstream vacuum unit is, most of the time, more prof-itable. Even if they are not integrated, the overall boundary should be drawn to include the vacuum side — the atmospheric residue (vacuum charge) preheat-ing train. www.eptq.com PTQ Q4 2013 113
  • 2. residue preheating should be included in the heat integration study when drawing boundaries. Including only the crude unit will prevent one from seeing the poten-tial modifications, retrofits and benefits, which result in hotter atmospheric residue going to the vacuum unit. Figure 2 is the composite curve for the CDU unit in Figure 1, which is not integrated with the VDU. The hot-side pinch point is 129°C and the atmospheric residue outlet from crude preheating is at 127°C. Therefore, the atmospheric residue temperature is at the closest point to the heating curve of the cold streams. The minimum temperature difference (DTmin) between the curves is 30°C. Although there is 44 Gcal/h of waste heat, the saving potential is limited to 7 Gcal/h even when you target a minimum temperature difference of 10°C, which is very hard to achieve. The reason for this is that if you bring only the CDU into the picture, it is not possible to gain substantially from the waste heat and keep the atmospheric residue temperature close to 129°C at the same time. However, when atmospheric resi-due preheating in the VDU is brought into the picture, there is no need to keep the atmospheric resi-due temperature close to the cold curve, because it is a cold stream that is heated by VDU hot streams. Sending atmospheric residue hotter to the VDU is desirable, therefore a potential is generated even when the two units are not integrated. If the units are to be integrated, the potential is much higher. Atmospheric residue will then be going to the VDU furnace directly in its hottest form, and the VDU hot streams will be used in crude heating (see Figure 1). When atmospheric residue preheating is added within the boundaries, DTmin automatically increases to 46°C, creating a poten-tial of 15 Gcal/h for DTmin = 10, already doubled even though the same atmospheric residue tempera-ture is targeted. The real potential, in fact, is much higher than this, considering that there is no Crude Heating AR Heating Crude unit Unintegrated 357ºC 127ºC 300ºC AR duty HVGOPA duty Integrated VR duty AR Crude unit AR ~357ºC ~357ºC and unit Figure 1 Drawing the CDU/VDU heat integration boundary Drawing the boundary In an integrated CDU/VDU config-uration, vacuum unit hot streams are used to heat the crude charge, and hot atmospheric residue is sent directly to the vacuum furnace to be heated. In a non-integrated configu-ration, atmospheric residue is sent colder to the vacuum unit after heat-ing the crude oil. Therefore, in a non-integrated layout, atmospheric residue is first a hot stream giving energy to the crude side, then a cold stream, which is heated by vacuum unit hot streams such as the HVGO pumparound and vacuum residue run-down. This is an inefficient design from a heat integration point HVGOPA duty VR duty Vacuum furnace and unit Vacuum furnace of view. Heat exchanger area is needed to first cool down the hot atmospheric residue in the crude side, and additional area is needed to heat it in the vacuum side. Furthermore, the heat that could be recovered would be higher in the integrated case, the HVGO pumpa-round (at high flow) and vacuum residue (at high temperature) being able to give more duty to the crude side and the atmospheric residue going much hotter to the vacuum furnace directly from the atmos-pheric column. Even if integration of the CDU and VDU is not desired for a specific reason, atmospheric dTmin = 30ºC Pinch = 99ºC Pinch = 129ºC 0 50 100 150 200 250 Enthalpy, Gcal/h 600 500 400 300 200 100 Temperature, ºC 0 Figure 2 Drawing the boundary and composite curves 114 PTQ Q4 2013 www.eptq.com
  • 3. constraint on the atmospheric residue temperature, and even more when the units are to be integrated. In the example below, a heat inte-gration study performed on another CDU/VDU unit is explained in detail. The configuration, number of pumparound streams, reboiler hot streams and so on may differ in different process layouts. Case 1: CDU/VDU unit In the integrated unit discussed below, the preheat train consists of three different sections. Before the desalter, the heat required is provided by the atmospheric column overhead and some portion of the diesel pumparound duty. After the desalter, crude is sepa-rated into three streams to be heated by product run-downs, the diesel pumparound and the HVGO pumparound. Afterwards, the combination crude is further heated by vacuum residue before going into the atmospheric furnace. The reboiler and naphtha splitter reboiler duties are supplied by HVGO and diesel pumparounds. The DTmin of the light crude base case is ~70°C, with nearly 62 Gcal/h of furnace process duty and 42 Gcal/h of wasted “hot stream” energy. The main waste heat streams in this configuration are as follows: • HVGO PA air cooler duty (after crude heating) • LVGO PA air cooler duty • Atmospheric column overhead duty after the top condenser • Run-down air cooler duties (after crude and desalter water heating), especially heavy diesel run-down. Basic design considerations for the project are: • Increasing the HVGO pumpa-round duty in the vacuum column automatically decreases the air-cooled LVGO pumparound duty. Even in the low HVGO pumparound base case, a substan-tial amount of duty is lost through air coolers. The desired HVGO temperature to the hydrocracker is 150°C. Therefore, a HVGO pumpa-round temperature of 150°C is targeted. In order to make up room in the crude network for the exist-www. Kero. LAD HAD Desalter OVHD HADPA2 HADPA1 VR Desalter Crude Kero. LAD HAD1 OVHD HADPA2 HADPA1 LVGOPA HVGOPA1 Crude Figure 3 CDU/VDU example crude preheat train before and after the project ing air-cooled duty and this additional duty in the HVGO pumparound, some duty has to be shifted towards the hotter side of the train. Therefore, a new hot HVGO pumparound exchanger is added before the existing hot VR exchanger, and the new cold HVGO pumparound heat exchanger is added to the cold side to recover the additional duties • The remaining LVGO pumpa-round duty is partially recovered before the HADPA exchangers in the second branch • A portion of the heavy diesel duty is recovered in the second branch, following the new LVGO heat exchanger • Additional surface area is added to the HADPA heat exchanger. The reason for this is that the crude temperature is much higher now because of the LVGO and heavy diesel heat exchangers • The new cold vacuum residue exchanger drops the temperature to its initial value before going to steam production • The overhead vapour duty after the first condenser (crude oil heater) is very high, and this is lost through air and water coolers. However, it needs a higher-grade material heat exchanger to recover because of its corrosive nature • Putting an additional high-grade material overhead exchanger and recovering the energy across the HVGOPA To furnace VR1 VR2 HAD2 HVGOPA2 To furnace dew point was considered. This would enable more heat recovery by shifting the diesel pumparound duty towards the hotter side of the train, making room for the over-head duty before the desalter. Diesel pumparound duty would be shifted by closing the bypass and putting additional area on the existing HADPA exchanger. However, because of the tight equipment layout, enough space could not be found in the actual unit conditions. This option is laid aside for the time being as a possibility. The simplified crude preheat train before and after the project is shown in Figure 3. The key to this study is that all of the new heat exchangers are considered to be plate-type heat exchangers. All welded-type plate heat exchangers, because of their area and space efficiency (high heat transfer coefficient), are well suited to tighter applications. If shell and tubes were to be selected for this project, a huge number of shells in series and the space they occupy would have been required. This would have increased the invest-ment cost, pressure drop and space requirements. With this project, over 15 Gcal/h of furnace duty will be saved even without the addi-tional overhead exchanger. Overall payback time of the project is almost half a year. eptq.com PTQ Q4 2013 115
  • 4. To column Crude To VR1 Kero. LAD HAD1 OVHD HADPA2 HADPA1 HADPA LVGOPA HVGOPA1 Flash drum (new) furnace driving force effect creates room for additional savings potential in the cold side of the train and decreases the heat exchanger investment to be made. In this specific layout, the cold preflash bottom temperature makes HADPA duty shift to the hotter side of the preheat train, creating room for an additional savings opportunity before the desalter. The only air-cooled stream available for this is the overhead stream. Therefore, the driving force effect would make additional savings if overhead duty were to be used. This effect also decreases the investment cost of exchangers and decreases the vacuum residue temperature going to steam production (by shifting some portion of the vacuum residue steam duty to crude oil heating furnace duty). The additional saving would be in the range of 2 Gcal/hour in the light crude case and close to zero in the heavy crude case. Based on these results, the preflash drum option for this study was laid aside because of its low overall benefits and unit space constraints. Preflash example 2 Another example is the initially non-integrated CDU/VDU unit illustrated in Figures 1 and 2. The effects of the preflash drum and also the importance of drawing the overall boundary correctly will be discussed in this example. When a typical non-integrated CDU such as in Figure 1 is considered, atmos-pheric residue is used in preheating crude oil, and colder atmospheric residue is heated again with vacuum-side hot streams. If there is an air-cooled pumpa-round, introducing preflash vapour VR2 HAD2 HVGOPA2 • If pumparound duty is used directly in the preheat, potential duty gained by bypassing the furnace is lost as reflux duty in the preheat train, cancelling out the energy benefit • If pumparound duty is air cooled, the preflash vapour will decrease this duty. Energy-wise, there will be no loss and the furnace duty will be decreased • The saving related to the driving force effect with the preflash option depends on the waste heat availa-ble in the heat integration study and the configuration. Simulations are made such that there is no loss of valuable prod-ucts to less valuable ones. Some examples regarding the preflash studies made are given below. Preflash example 1 In the CDU/VDU study given as the example project, a preflash study was made. A brief summary of the preflash option for this particular unit follows. When the preflash vapour is given to the flash zone, duty gained in the atmospheric furnace is lost in the vacuum furnace. When the preflash vapour is given to the upper trays at a suitable temperature, column pumparound duty decreases. There is only one pumparound in this particular unit (HADPA) and all of the duty is used in crude oil preheat. The potential duty gained by preflash vapours bypassing the furnace is lost in crude oil preheating. The column atmospheric residue temperature increases and the vacuum furnace load decreases. However, overall saving in this aspect is close to zero. There is a 20°C temperature drop in the preflash drum bottom. This Desalter Figure 4 Preflash drum option for the project Preflash drum option The feasibility of adding a preflash drum depends on the column oper-ation, pumparounds and how they are located in the structure of the heat exchanger network and the tray where preflash vapour is intro-duced. Adding a preflash drum changes the pinch structure, the potential energy savings and the additional area of new heat exchanger needed. It is a case-specific study, and it should not be decided whether an option with the preflash drum will be feasible or not without making a detailed study. However, the existing unit column and heat exchanger network structure will give a hint. It is certain that preflash vapour will bypass the furnace and the liquid load will decrease. Furthermore, the preflash drum bottom temperature will be much lower than the inlet. This will create a driving force in temperatures and make an opportunity for this stream to be heated more effi-ciently, which may result in duty shifts and savings. However, the main point to be considered in a preflash drum study is the cooling effect of preflash vapour on the tray to which it is introduced. If this vapour is given directly to the flash zone, the column bottom temperature will be lower and the direct benefit will be small. In fact, the only real potential in this case is the temperature drop in the preflash bottoms and the abil-ity to heat this stream more effectively. If preflash vapour is given to the upper trays based on its temperature, the pumparound duty on the column will decrease. Therefore, the question is where is this pumparound duty used? 116 PTQ Q4 2013 www.eptq.com
  • 5. for warming up and cooling down bronswerk.com
  • 6. Effluent To air-cooler EFF1 EFF2 EFF3 EFF4 EFF5 EFF6 EFF7 Fractionator bottom product Diesel product To reactor furnace To stripper HVGO feed Stripper feed Hydrogen Figure 5 Hydrocracker project existing simplified network Waste heat through air or water coolers is in total 60.3 Gcal/h. Nearly 24 Gcal/h is wasted through the effluent air cooler (operating from 190°C to 62°C). The minimum temperature difference is 75°C between the curves. The hot pinch is 230°C and the cold pinch is 154.5°C (see Figure 6). The link between the high-pressure and low-pressure heat exchanger trains is the stripper charge. Stripper feed is heated from ~60°C to ~110°C with fractionator streams before going to the high-pressure effluent exchangers, where it is heated to 255°C. Therefore, if the stripper charge stream is further heated with addi-tional heat exchangers on the stripper-fractionator side (the low-pressure side), there will be available duty potential in the efflu-ent side to heat reactor feed streams or the fractionator feed stream. In this way, a portion of the wasted section will be discussed with regard to the hydrocracker example. Example: hydrocracker In the unit studied, HVGO, hydro-gen and stripper feed is heated with reactor effluent. Before going into this high-pressure network, the stripper charge is heated with diesel and fractionator bottom product. Debutaniser and naphtha splitter reboiler duties are supplied by the diesel pumparound in the fractionator. Kerosene pumpa-round, kerosene run-down, stripper and fractionator overhead streams, and the reactor effluent stream going to the air cooler are the main sources of waste energy. There are two furnaces: one reactor charge furnace and the other fractionator charge (stripper bottom) furnace. A simplified existing heat exchanger layout is shown in Figure 5. In the base case, the furnaces have a process duty of 26.4 Gcal/h. in the upper trays creates a benefit, as discussed in the previous example. If all pumparound duties are used in preheating, one does not expect large amounts of savings. However, if you draw the boundary on the CDU only, the results will be differ-ent. The pumparound duties (there may be more than one pumpa-round) will be lower with the upper tray preflash option. This would automatically mean that crude inlet temperatures to the existing atmos-pheric residue exchangers would decrease, creating a driving force effect. This would also automatically mean that more duty can be recov-ered from atmospheric residue, making up for the lost duty in pumparounds, and the atmospheric residue temperature leaving the CDU will be lower. This is an energy saving if you are only considering the CDU. However, the atmospheric residue is sent directly to the vacuum unit, and this poten-tial saving is lost in the vacuum furnace. Therefore, if you draw the boundary on the CDU only, you will be evaluating a potential that is not actually there. There will be some shifts from steam production duty to furnace duty, but this is not an energy-saving potential in the CDU/VDU. It is a matter of the value of steam in that particular refinery. If the unit is integrated, project saving potentials are much bigger. However, the effect of a preflash drum will be similar. Hydrocracker and hydrodesulphurisation (HDS) units A typical hydrocracker or a HDS preheat train can be divided into two sections: the reactor effluent side with high pressure and temperature; and the stripper– fractionation side with run-downs, pumparounds, reboilers and so on. The main cold streams in this layout are the reactor input streams: HVGO for the hydroc-racker (diesel for HDS), hydrogen and stripper-fractionator feeds. In hydrocracker and HDS heat integration studies performed, similar principles were followed (except for the fact that there is no fractionator in a HDS), therefore this 600 500 400 300 200 100 Temperature, ºC dT = 75.38ºC Qh = 26.4 Qc = 60.3 0 0 20 40 60 80 100 120 140 160 Enthalpy, Gcal/h Figure 6 Hydrocracker project base case curves 118 PTQ Q4 2013 www.eptq.com
  • 7. column overhead energy (together with other frac-tionation side heat) will be recovered as furnace duty. Once again, for the low-pressure side, weld-ed- type plate heat exchangers are selected. This approach can be applied either to keep the reactor effluent temperature as it is (~190°C; after wash water injection it is ~160°C) or maximise the benefits by decreasing (gaining from) the reactor effluent air cooler duty as well. The choice is a matter of the additional heat exchange area required in the high-pressure network to shift this duty to feed streams and the furnace duty benefits achieved from it. However, it is also a matter of corrosion. A lower reactor effluent air cooler temperature means that temperatures are shifted towards cold stream heating. Therefore, corrosion mechanisms will be shifted towards the existing or new heat exchangers. On the low-pressure side, diesel pumparound has a high flow rate and temperature to be able to heat up the fractionator charge with a plate-type heat exchanger. In order to achieve this, reboiler duties have to be shifted as much as possible towards the lower-grade heat sources. Air-cooled kerosene pumparound, diesel run-down and kerosene run-down are suitable to take a portion of this duty. Therefore, lower-grade heat sources are used for lower-grade heat, freeing up higher-grade heat to be used elsewhere – in this case, for heating the frac-tionator charge. The temperatures are tight, so plate-type heat exchangers are suitable for this purpose. An alternative approach is to further raise the fractionator feed temperature by introducing it to the high-pressure reactor effluent network. Including this stream on the effluent side by means of the optional exchanger shown in Figure 7 increases the amount of savings made per amount of additional investment. Furthermore, the saving is directly from the furnace. However, introducing the fractionator feed to the high-pressure network may not be desirable because of relief load and safety concerns. In the HDS unit example without a fractionator, no pumparound duty may be available. However, heat-ing the stripper feed more effectively with stripper overhead and diesel product before it enters the high-pressure preheat train creates the opportunity to further heat up the reactor furnace feed streams. Therefore, the principle is similar. Alternative options Introducing a preflash drum Similar to the crude preflash study, introducing a preflash drum to the fractionator feed creates a 20°C temperature difference driving force. This stream can be heated with heavy diesel (heavy diesel pumparound) or reactor effluent, or both. This driv-ing force creates an additional energy-saving opportunity and decreases the amount of additional area needed. However, the main saving comes because the kero pumparound is air cooled. Preflash vapour duty directly decreases from the air cooler if www.contitech.de/alw DAMPF TRIX® 6000 OIL highest quality for conveying steam according to EN ISO 6134 - 2B - The new, oil resistant DAMPF TRIX® 6000 OIL is an innovative hightech version in ContiTech's extremely successful steam hose family. It is especially suitable for conveying steam in the chemical and petrochemical industry, in refi neries, the building industry, in shipyards and for various other industrial applications under the most grueling conditions – in all places, where existing steam hoses fail at an early stage due to oil contamina-tion from outside. q heat resistant EPDM inner layer material q temperature range for saturated steam up to max. +210°C, short term +220°C at 23 bar (saturated steam) q working pressure up to 18 bar q burst pressure: min. 180 bar, safety factor 10:1 q reinforcements: 2 steel wire braids, excellent resistance to corrosion q oil resistant special cover, resistant to ozone, weather, UV and abrasion q electrically conductive, R < 106 Ω q meets all requirements as per EN ISO 6134 2B ContiTech Schlauch GmbH Postfach 1120 D-34481 Korbach industrial.hoses@fl uid.contitech.de www.eptq.com PTQ Q4 2013 119 Conti Anzeige Dampf Trix OEL GB 86x270 01-2013.indd 1 04.02.13 14:18
  • 8. To reactor furnace To fractionator furnace Effluent To air cooler Optional EFF5 EFF6 EFF7 Fractionator bottom product Diesel product from deb. reb. Fractionator overhead Hydrogen hydrogen through stripper charge and loss of hydrogen to fuel gas. It also means loss of C3-C4 (LPG prod-uct). Four separator designs can be selected to lower the amount of product lost, but cannot prevent it. Therefore, even though steam production is acceptable with the low-pressure fractionation streams and more energy is recovered over-all, hydrogen and LPG losses, together with major changes in the high-pressure section of the unit (adding two separator drums), make this alternative much less attractive among the other heat recovery scenarios. Targeting the reactor effluent air cooler The effluent air cooler is the biggest source of waste heat in a hydroc-racker. Introducing this source of heat to the recovery options will increase the potential overall savings and decrease the overall investment cost. However, the corrosive nature of this stream and the modifications that need to be done in the fraction-ation section of the heat exchanger network require a detailed analysis and a change of approach. Considering its positive effects on unit shutdown periods as well, this option may be a very good selec-investment EFF1 EFF2 EFF3 EFF4 To stripper HVGO feed Stripper feed Debut reboiler duty shifted to HAD rundown. Portion of naphtha splitter reboiler duty shifted to kero pumparound. Figure 7 Hydrocracker project simplified network after possible modifications costs. Payback times of Fractionator feed (Preflash bottom) all the different scenarios are around, or less than, one year. Introducing a hot separator The stripper feed can be described as the cold reactor effluent stream after the air cooler and pressure separators. Therefore, in a way, it is being cooled with an air cooler and heated again with reactor effluent. From an energy point of view, instead of cooling it to 60°C, it can be kept at the desired temperature, say 255°C, with a new separator configuration including a hot separator. In this way, the effluent air cooler duty will be lower and duty will be transferred to the other cold streams, decreasing furnace loads. However, low-pressure side hot streams heating the stripper charge will be freed up, and they have to be used in steam production in order not to waste them and gain some energy overall. Whether this steam is needed or not is a critical issue when evaluating this option. If steam is not a good alternative in the refinery’s utility balance, hot separator designs do not bring any energy benefit at all when compared to other heat recovery scenarios. Furthermore, introducing a hot separator means more soluble HADPA vapours are introduced to the upper trays according to the temperature profile. Therefore, frac-tionator furnace duty is decreased directly. Together with the shifting of reboiler duties to lower-grade heat sources and using diesel pumparound duty to heat up the preflash bottoms (fractionator feed) with a new heat exchanger, furnace and air-cooled pumparound or overhead reflux duties are decreased substantially. Taking into account all of the design considerations discussed, a simplified heat exchanger configu-ration looks like the one shown in Figure 7 (new positions are shown in red). The total furnace process duty saved with this configuration, even without affecting the reactor efflu-ent cooler and without adding additional area to the existing exchangers, is 9 Gcal/h, which is actually higher when furnace effi-ciency is considered. Together with kero run-down steam production and considering firing efficiencies, the total saving is nearer 13 Gcal/h. By adding the new heat exchang-ers shown and adding new shells to the existing heat exchangers, savings can rise to 18 Gcal/h, taking into account increased 120 PTQ Q4 2013 www.eptq.com
  • 9. Key performance indicators for ConSep trays sometimes very critical in heat inte-gration Texas, complex had a power surge that triggered a small fire in a pipe rack at the refinery’s chemical plant. Power surges can cause fires and cause breakdown in different units. In April 2011, Sunoco’s Philadelphia, Pennsylvania, refin-ery the ebullated-bed reactor or fed to a coker unit. studies. For this The study, freedom it was to considered that this stream is recy-cled produce steam may bring addi-tional types of switchgear are oil or gas insulated. A stray spark can cause these to catch on fire and fail. Then there are the obscure reasons that cannot be predicted and happen so infrequently that it is hard to protect against. In November 2012, Valero’s Corpus Christi, Texas, had a power loss that led to flaring due to a rodent contacting the primary power transformer. Transformers that can be accessed should be protected to allow only those working on them to get to them. In February 2010, Western Refining’s Yorktown, Virginia, had an unidentified unit shutdown due a temporary power blip caused by a goose flying into a nearby power line. Unless power lines are put underground, it is difficult to protect them from animals and debris. Power surges and fluctuations Power surges also occur frequently and can be prevented with circuit breakers or switchgear. In August 2009, ExxonMobil’s Baytown, Parameters Design Test run Froth backup/CS height, % 68 60 Tray pressure drop, mbar 12.3 9.2 Tube flood , % 73 60 Flow parameter 0.17 0.19 Overall column load factor, m/s 0.12 0.10 Flooding (CS tray), % 133 112 benefits to overall fuel back to the hydroconversion consumption in the refinery, or it may not be needed at all. In a heat integration study, options should be evaluated with detailed simulation and heat inte-gration reactor, meaning that there is complete overall residue conver-sion even when the once-through had a power surge that conversion reported in Table 2 is 78%. The fractionated products from the VTB conversion step, along with the corresponding VDU distil-lates, knocked compressors offline. In May 2011, Phillips analysis. 66’s Wilmington, Evaluations California, facility had a power fluctuation occur, temporarily shut-ting should be considered in a case-spe-cific manner with creative thinking 3 De Villiers W E, Bravo J L, Wilkinson P M, Summers D R, Further advances in light hydrocarbon fractionation, PTQ Q3 2004. Kaushik Majumder is Distillation Team Lead of Shell Projects & Technology in Bangalore, India. He holds a bachelor’s degree from Jadavpur University, India, and a master’s and doctorate from Indian Institute of Technology, Delhi. Email: Kaushik.Majumder@shell.com Giuseppe Mosca is the Global Refinery Technology Manager of Sulzer Chemtech. He holds BS and MS degrees in chemical engineering from the University “La Sapienza” Rome, Italy. Email: Giuseppe.Mosca@sulzer.com Kent Mahon is a Process Engineer at Refining NZ. He was the Senior Process Engineer and Commissioning Process Engineer during the Point Forward Project. Email: Kent.Mahon@refiningnz.com and taking general guidelines into account. Most of the time, heat inte-gration down several refinery units. require further hydrotreating Normal operations were restored the next day. Multiple unit shutdowns Since most refinery units are inte-grated to reduce sulphur, nitrogen and aromatic projects contents will for bring producing large suitable blending components for SCO. The properties of the hydro-treated amounts of savings involving millions of dollars per year, with usually less than one-to–one-and-a-half- products and final SCO are year payback periods. and sometimes share the provided in Table 4. The SCO has no residue and very low sulphur and nitrogen contents. The coking-derived SCO is slightly more aromatic than that derived from the hydroconversion-based scheme. Table 5 summarises the details of the HDT units. It is observed that the hydrotreating of coker products requires higher same power supply, power failures could lead to the shutdown of these integrated units and the production loss of many refined products, thereby magnifying potential damages. In June 2009, Tesoro’s Kenai, Alaska, facility experienced a power outage. The hydrocracker and isomerisation unit were shut to Alis¸an Dog˘an is a Process and Equipment Development Superintendent in Head Office Technical Services Management with Turkish Petroleum Refineries Corporation (Tüpras), specialising in heat recovery and heat integration and process simulation. He holds a BS in chemical engineering from Middle East Technical University, Ankara, Turkey. Email: Alisan.Dogan@tupras.com.tr effectively from sources that would otherwise prove very costly and involve high pressure drops if shell and tubes were to be used. Plate-type test run’s results, it could be concluded that the revamp targets for the CDU-1 main fractionator (C-150) were achieved. No hydrau-lic Properties of coker and hydroconverter liquid productsa constraint was experienced in Coker Hydroconverter heat exchanger usage is achieving the design intake of 13 000 t/d and the required prod-uct Property Naphtha LGO HGO Naphtha LGO HGO Vacuum residue Yield, wt% 26.8 34.1 39.1 14.0 37.9 27.8 20.4 SG 60/60°F 0.7363 0.8715 0.9736 0.7365 0.8710 0.9715 1.1240 API gravity 60.7 30.9 13.8 60.6 31.0 14.2 -5.6 Sulphur, wt% 1.79 3.67 4.43 0.25 0.71 1.37 6.90 Nitrogen, wppm 316 1694 3973 393 1582 3063 8905 Aromatics, wt% 27.1 58.0 66.0 20.5 42.5 53.0 99.8 Nickel, wppm - - 8.2 - - 3.0 262.9 Vanadium, wppm - - 27.4 - - 6.2 458.3 CCR, wt% - - 1.5 - - 0.2 14.3 limited in pressure (to 40 bar) • Using a flash drum before a frac-tionator creates a driving force effect that may enable some addi-tional energy recovery or heat duty Table 3 shift from steam production to cold feed streams (furnace duty). However, the main point in making a preflash drum a feasible option is whether there is wasted, air-cooled pumparound duty near the tray flash vapour. Giving preflash vapour to higher trays may not be desired because of liquid entrain-ment quality was achieved. Conclusions The performance of Shell ConSep trays in the HGO pumparound section of the CDU-1 main fractiona-tor met the target of capacity enhancement without any drawback compared to the pre-revamp condi-tions. During the test run, the trays were operating at 10-15% lower than the design capacity even at the design intake of 13 000 t/d due to heavier crude feed and lower feed temperature. However, the built-in capacity margin enabled stable oper-ation such cases. In this revamp project, use of only three of these trays in the most capacity-constrained section of the column made it possi-ble to retrofit the existing column and made the capex option more attractive over the other debottle-necking options. Properties of hydrotreated products and SCO concerns; therefore, special consideration should be given to the preflash drum design, such as high retention time, high L/D ratio and usage of demister pads. Even a preflash tower may be considered to eliminate risks, although this would, of course, increase the investment cost • Overall refinery steam balance is tion, in combination with the key points taken from the other options. Conclusion Heat integration options and stud-ies Substations, whether owned by the utility company or the refinery, tend to break down if not properly maintained. In October 2009, Valero’s McKee, Texas, plant had a substation should malfunction, be considered which as forced units offline. Substation malfunctions have occurred more frequently than many people think. In March 2010, Chevron’s El Segundo, California, refinery shut down due to fire at a substation. And, in August 2011, Tesoro’s Kapolei, Hawaii, complex had a power outage due to a failure at one of the local electric utility’s substations. In May 2010, BP’s Texas City, Texas, refinery had a power blip caused by switchgear failure. Switchgear failures also occur quite frequently. The relay that failed at the Super Bowl was a part of the switchgear setup that supplied power to the stadium. Switchgears operate as a protective device against overcurrent and arc flashes. They also need to be properly maintained to avoid failures. A few case-specific evaluations. There is no rule of thumb whether an option is the best for a specific unit or a specific refinery. Unit layout, inte-gration with other downstream units, overall refinery utility balance and unit-specific problems (such a) Yield as values the are based hydrocracker on total liquid product. effluent air cooler example) all affect the selection process: • Drawing the overall boundary is very important, especially in CDU/ VDU studies. Integration will most of the time bring additional benefits in energy savings and area effi-ciency. * Shell ConSep, Shell CS and Shell HiFi are Shell trademarks. ** Mellapak Plus 252Y is a Sulzer Chemtech trademark. Coker-based scheme Hydroconverter-based scheme Drawing the boundary Table 3 Property Naphtha LGO HGO SCO Naphtha LGO HGO SCO SG 60/for 60°F the trays 0.7375 at much 0.8597 above 0.9131 0.8680 0.7375 0.8573 0.9115 0.8665 API gravity 60.4 33.1 23.5 31.5 60.4 33.6 23.7 31.8 Sulphur, wt% 0.018 0.112 0.16 0.13 0.014 0.044 0.15 0.10 Nitrogen, wppm 12 204 740 482 21 264 455 336 Aromatics, wt% 19.9 41.8 54.2 45.9 15.8 36.5 50.9 41.7 incorrectly may even make a feasi-ble the capacity limit of the first genera-tion option infeasible, or vice versa of high-capacity trays. The options to debottleneck columns already equipped with the first generation of high-capacity trays are limited. ConSep trays provide an attractive solution for (for instance, the CDU/VDU preflash drum example) • Using all welded-type plate exchangers Table 4 creates the opportunity to recover heat efficiently and cost References 1 Refinery expansion means NZ more self reliant, media release by NZRC, 16 July 2010. 2 Wilkinson P M, De Villiers W E, Mosca G, Tonon L, Achieve challenging targets in propylene yield using ultra system fractionation trays, ERTC 2006. www.eptq.com PTQ Q1 2013 77 www.eptq.com PTQ Q4 2013 121 wwwwww..eeppttqq..ccoomm PPTTQQ QQ32 22001133 4 213