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H+
 Fe2+
producedinreactionmustbe re-oxidizedtoFe3+
andrecycled.
 A rapiduraniumextractionneedsahighFe3+
/Fe2+
ratio
 Indentifythe heterotrophicmicroorganisms
 Run an orbital shakerexperimenttoreachthe optimizedconditionsforthe
microorganimstomaximize the uraniumextraction
 Bioleachingusinganextendedparticle sizerange (3mm - ½ " )
 Use a High pressure grindingrollsforcrushingthe ore (Micro-cracks)
 Run experimentsusingabiggercolumnwithasprayingnozzle toensure amore
homogeneousleachingcondition
H2SO4
𝑈𝑂3 + 2𝐻+ → 𝑈𝑂2
2+
+ 𝐻2 𝑂
UO2 + 3Fe3+
UO2
3+
+ 3Fe2+
𝑈𝑂2 + 3𝐹𝑒3+ → 𝑈𝑂2
3+
+ 3𝐹𝑒2+
UO3 + 2H+
UO2
2+
+ H2O
𝐸 = 𝐸1
0
+ 0,0592 .log
[𝐹𝑒3+]
[Fe2+]
𝐸ℎ 𝛼
[𝐹𝑒3+]
[Fe2+]
𝑈𝑂2 + 2𝐹𝑒3+ ⇌ (𝑈𝑂2)2+ + 2𝐹𝑒2+
𝐹𝑒𝑆2 + 7𝐹𝑒2(𝑆𝑂4)3 + 8𝐻2 𝑂 ⇌ 15 𝐹𝑒𝑆𝑂4 + 8𝐻2 𝑆𝑂4
𝑈𝑂2
2+
+ 3𝐻2 𝑂 → 𝑈𝑂2(𝑂𝐻)2. 𝐻2 𝑂 + 2𝐻+
𝐹𝑒2+ 𝐹𝑒3+
UO2
2+
+ 3SO
Fe2+
Oxidante Fe3+
𝑈𝑂2
2+
+ 3𝑆𝑂4
2−
→ [𝑈𝑂2(𝑆𝑂4)3]4−
𝑈𝑂3 + 2𝐻+ → 𝑈𝑂2
2+
+ 𝐻2 𝑂

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Apresentação uranio

  • 1. H+  Fe2+ producedinreactionmustbe re-oxidizedtoFe3+ andrecycled.  A rapiduraniumextractionneedsahighFe3+ /Fe2+ ratio  Indentifythe heterotrophicmicroorganisms  Run an orbital shakerexperimenttoreachthe optimizedconditionsforthe microorganimstomaximize the uraniumextraction  Bioleachingusinganextendedparticle sizerange (3mm - ½ " )  Use a High pressure grindingrollsforcrushingthe ore (Micro-cracks)  Run experimentsusingabiggercolumnwithasprayingnozzle toensure amore homogeneousleachingcondition H2SO4 𝑈𝑂3 + 2𝐻+ → 𝑈𝑂2 2+ + 𝐻2 𝑂 UO2 + 3Fe3+ UO2 3+ + 3Fe2+ 𝑈𝑂2 + 3𝐹𝑒3+ → 𝑈𝑂2 3+ + 3𝐹𝑒2+ UO3 + 2H+ UO2 2+ + H2O 𝐸 = 𝐸1 0 + 0,0592 .log [𝐹𝑒3+] [Fe2+] 𝐸ℎ 𝛼 [𝐹𝑒3+] [Fe2+]
  • 2.
  • 3. 𝑈𝑂2 + 2𝐹𝑒3+ ⇌ (𝑈𝑂2)2+ + 2𝐹𝑒2+ 𝐹𝑒𝑆2 + 7𝐹𝑒2(𝑆𝑂4)3 + 8𝐻2 𝑂 ⇌ 15 𝐹𝑒𝑆𝑂4 + 8𝐻2 𝑆𝑂4
  • 4. 𝑈𝑂2 2+ + 3𝐻2 𝑂 → 𝑈𝑂2(𝑂𝐻)2. 𝐻2 𝑂 + 2𝐻+ 𝐹𝑒2+ 𝐹𝑒3+
  • 5. UO2 2+ + 3SO Fe2+ Oxidante Fe3+ 𝑈𝑂2 2+ + 3𝑆𝑂4 2− → [𝑈𝑂2(𝑆𝑂4)3]4− 𝑈𝑂3 + 2𝐻+ → 𝑈𝑂2 2+ + 𝐻2 𝑂