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Agnes Pockels Advancement of surface tension
List of Discoveries
I. The surface tension of a contaminated water surface varies if the surface is compressed or expanded. On compression, the surface tension decreases up to a factor of two. On expansion, it increases until a maximum value is reached,  then remains constant. II. Thus, a water surface can exist in two states, a normal condition in which the surface tension remains constant if the surface size is changed, and an anomalous condition, where varying the surface size leads to a change in surface tension. III. The cleaner the surface, the more it can be compressed while the surface pressure remains at its maximum value. IV. A surface in the anomalous state can be cleaned by removing the surface layer by immersing and withdrawing a paper strip. V. The lower the surface tension, the more pronounced is the wave damping.
VI. All solid bodies, no matter how clean, contaminate a water surface that is in normal state.  VII. Solid materials like glass or metals increase the relative contamination.  VIII. Other materials like camphor or flour reduce the surface tension until an equilibrium value is reached that is different for each substance. The solid is the source of a current of contaminating material. A contact line between water surface and the material current can be made visible by dusting the water with flowers of sulfur.  IX. A material current occurs between surfaces with the same surface tension if the contamination is caused by different substances. Equal relative contamination by different substances does not indicate equality of that pressure -in surface films - which is the cause of the material current between surfaces of equal surface tension.
X. Solutions of sugar have a normal surface and a higher surface tension than pure water. Yet a piece of sugar brought to its surface causes material current and surface tension reduction. XI. From these experiments I concluded (a) that the surface layer of water can take up more of soluble substances than the bulk solution; (b) that the compressed surface of a solution gets anomalous, always and only, if it contains more of the dissolved substance than the bulk.

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Agnes Pockels Discoveries

  • 1. Agnes Pockels Advancement of surface tension
  • 3. I. The surface tension of a contaminated water surface varies if the surface is compressed or expanded. On compression, the surface tension decreases up to a factor of two. On expansion, it increases until a maximum value is reached, then remains constant. II. Thus, a water surface can exist in two states, a normal condition in which the surface tension remains constant if the surface size is changed, and an anomalous condition, where varying the surface size leads to a change in surface tension. III. The cleaner the surface, the more it can be compressed while the surface pressure remains at its maximum value. IV. A surface in the anomalous state can be cleaned by removing the surface layer by immersing and withdrawing a paper strip. V. The lower the surface tension, the more pronounced is the wave damping.
  • 4. VI. All solid bodies, no matter how clean, contaminate a water surface that is in normal state. VII. Solid materials like glass or metals increase the relative contamination. VIII. Other materials like camphor or flour reduce the surface tension until an equilibrium value is reached that is different for each substance. The solid is the source of a current of contaminating material. A contact line between water surface and the material current can be made visible by dusting the water with flowers of sulfur. IX. A material current occurs between surfaces with the same surface tension if the contamination is caused by different substances. Equal relative contamination by different substances does not indicate equality of that pressure -in surface films - which is the cause of the material current between surfaces of equal surface tension.
  • 5. X. Solutions of sugar have a normal surface and a higher surface tension than pure water. Yet a piece of sugar brought to its surface causes material current and surface tension reduction. XI. From these experiments I concluded (a) that the surface layer of water can take up more of soluble substances than the bulk solution; (b) that the compressed surface of a solution gets anomalous, always and only, if it contains more of the dissolved substance than the bulk.