Separation of Lanthanides/ Lanthanides and Actinides
A centenary of the discovery of the nucleus: Ernest Rutherford
1. A centenary of the discovery of the nucleus
Theo J. Mertzimekis
Saturday, June 4, 2011
2. The life and works of
Sir Ernest Rutherford
⚛ Some Bio
⚛ The Gold Foil experiment
⚛ The nucleus & the model of the atom
⚛ Milestones & Major Achievements
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
3. Some Bio
⚛ Born in Spring Grove, NZ on Aug 30,
1871 to James and Martha Rutherford
⚛ 2nd son, 4th child of total 12 children
⚛ Father: engineer; Mother: teacher
⚛ 1890: Canterbury College in
Christchurch
⚛ Graduates with BA in 1892 (Pure Math,
Latin, Physics)
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
4. College years
⚛ Due to his math skills he received a scholarship to
continue his studies
⚛ MA degree: original work in EM / inspired by
Tesla and his coil. He tries to determine if iron
stays magnetized under high-‐frequency currents
⚛ For that purpose he constructed two separate
devices, one to provide 10μs pulses and a
magnetic detector
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
5. @ Cambridge
⚛ Conducts second degree in Geology and
Chemistry to comply with a Royal Scholarship
requirements
⚛ He gets the Scholarship and joins J.J. Thomson at
Cambridge as the first non-‐Cambridge graduate
to be accepted for research.
⚛ He improves his detector to measure frequencies
and study the dielectric properties of insulators.
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
6. First Steps in Research
⚛ He constructs an EM detector and improves it to
apply it to sea navigation (range ~ 200 m)
⚛ Thomson invites him to study the electrical
conduction of gases. He uses high-‐f currents, X-‐
rays and radioactivity to initiate electrical
conduction.
⚛ Radioactivity itself intrigued him and soon he
tries to understand its nature.
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
7. @ McGill
⚛ w/ Brookes: Discovery of Radon (inert,
radioactive gas)
⚛ w/ Soddy: Discovery of radioactive decay law.
Some heavy atoms decay to lighter species. This
works attracts the world’s attention
⚛ Fellow of the Royal Society of Canada (1900) and
London (1903). He publishes “Radio-‐activity” in
1904 and “Radioactive transformations” in 1906
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
8. The Nobel Prize
⚛ 1908 -‐ Chemistry
"for his investigations into
the disintegration of the elements, and
the chemistry of radioactive substances".
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
9. @ Manchester
⚛ Schuster steps down and Rutherford becomes a
Professor at Manchester
⚛ w/ Geiger: Show that α particles are He atoms
stripped of their electrons.
⚛ w/ Geiger: Develop the Rutherford-‐Geiger
detector to count single atoms produced in
radioactive decays
⚛ focus on measuring physical constants, e.g.
Avogadro’s number
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
10. Geiger & Marsden
⚛ They were instructed to study reflection of α
particles impinging metals
⚛ In 1909, G&M reported that some α particles kept
bouncing back, even from a thin sheet of Au
“It is as if someone had fired a 15” naval shell at a
piece of tissue and that bounced straight on us”
10.1098/rspa.1909.0054
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
11. The experiment
Zinc Sulfide
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
12. Rutherford’s atom model
⚛ Classical picture / Planetary configuration
⚛ Main problems:
⚛ electrons should lose energy (spiral orbits)
⚛ continuous e-‐ spectra were not observed
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
13. Rutherford & Bohr
⚛ Niels Bohr came to work with Rutherford
⚛ In 1915, Bohr used the planetary model but
placed the electrons in specific orbits applying
the principles of Quantum Mechanics
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
14. Rutherford scattering
⚛ Rutherford calculated the cross section of
the scattering using classical physics
2
2
1 Z1 Z2 e 1
σR (θ) =
4 2E sin4 (θ/2)
doi: 10.1080/14786440508637080
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
15. Major achievements
⚛ Discovered the concept of half-‐life
⚛ Discovered radioactive transmutation via the
reaction α + 14N → 17O + p
⚛ Differentiated α,β radiation (Nobel)
⚛ Postulated the existence of the nucleus
⚛ Postulated the existence of the neutron
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
16. Splitting the atom
⚛ Though not in a controlled way, Rutherford was
the first to split the atom
⚛ John Cockroft and Ernest Walton finally did it in
a controlled way in 1932 using their high-‐voltage
electrostatic accelerator.
⚛ w/ Oliphant built a lower-‐V with improved flux
and used it to bombard 2D on 2D, thus ending
up in discovering 3H and 3He
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
17. Other work
⚛ During WW1, he worked on hydrophones. He
suggested the use of circus sea lions to detect
enemy submarines
⚛ Dated the age of Earth
⚛ Developed the Rutherford-‐Geiger detector
⚛ Invented the first smoke detector
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
18. Honors Awards
⚛ 1914 / Knighted
⚛ 1925 / Order of Merit
⚛ 1931 / Peerage
⚛ 1997/ Rutherfordium (Z=104)
⚛ Several other medals (Franklin, Mateucci,
Copley, Elliot Cresson, Rumford)
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011
19. The legend his legacy
⚛ Died in 1937 due to implications of a delayed
operation
⚛ His ashes are buried next to Sir Isaac Newton
⚛ Rutherford is the Father of Nuclear Physics
⚛ He is to Nuclear Physics what Darwin is to
Evolution, Einstein to Relativity, Newton to
Mechanics
Theo J. Mertzimekis
UoAthens / HNPS2011
Saturday, June 4, 2011