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States of matter & the kinetic
molecular theory.
Matter is classified into 3 states or phases:
Solids, liquids & gases
The structure, arrangement
& movement of the particles
determines the state of the
substance.
Solids liquids & gases
1
Diffusion & Brownian motion
Diffusion and Brownian motion in liquids
and gases, provides proof of the
existence of particles in matter.
Diffusion is the movement of
particles from a region of high
concentration to lower concentration -
until there is even distribution of particles
throughout the gas or liquid.
NH3 & HCl diffusion
2
Brownian motion is the haphazard,
random motion of larger particles that
are being bumped by much smaller gas
or liquid particles – ones that can’t even
be seen under a microscope.
Brownian motion
3
Forces between particles
There are forces between the particles in
each of the states of matter.
Solids – strongest forces – vibratory
motion & held close together.
Liquids – weaker forces – further apart
& able to flow past one another
Gases – weakest forces – particles far
apart & move easily
in all directions
4
Phase changes
Matter can change from one state to
another by adding or removing energy –
usually in the form of heat.
Solid to gas – sublimation
Solid to liquid – melting
Liquid to gas – evaporation
Gas to liquid – condensation
Liquid to solid – freezing
5
Temperature & Phase changes
The temperatures at which phase
changes take place have specific
names:
Solid → liquid – melting point
Liquid → gas – boiling point
Gas → liquid – condensation point
Liquid → solid – freezing point
The state of a substance at a certain
temperature, is determined from its
melting or boiling points.
States of matter
6
Temperature & Phase changes
H2O at -5 0C means it is in the solid state
(ice) – since it is below the freezing point
of 0 0C.
H2O at 120 0C means it is in the gaseous
state (steam) since it is above its boiling
point of 100 0C.
Change of state
Change of phase
7
Common melting & boiling points
Substance Melting point Boiling point
Water 0 0C 100 0C
Nitrogen -210 0C -196 0C
Oxygen -219 0C -183 0C
Diamond 3 550 0C 4 830 0C
Carbon dioxide -79 0C -57 0C
Ethanol -114 0C 78 0C
Copper 1 083 0C 2 600 0C
Mercury -39 0C 357 0C
Table salt 801 0C 1 413 0C
Iron 1 536 0C 3000 0C
Sodium 98 0C 892 0C
Lead 327 0C 1750 0C
Ammonia -78 0C -33 0C 8
Heating curve for water:
This graph shows how the curve changes
during the phase changes & heating process.
Temperature
Time
0C
-10 0C
100 0C
M.P.
B.P.
ICE
WATER
STEAM
Heating ice
9
Kinetic molecular theory
This theory explains properties of solids,
liquids & gases, relative to the particles
making up matter & their movement.
Particles in each phase are in constant
motion and thus have a kinetic energy.
Particles move at different speeds, but at
the same temperature, they have the
same average kinetic energy.
Kinetic molecular theory 10
Kinetic molecular theory: solids
Solids have:
 strong forces between particles
 a size & shape
 vibrate about a fixed point
 repulsive forces – thus no compression
11
Kinetic molecular theory: liquids
Liquids have:
 weaker forces of attraction
 move more freely past each other
 no fixed shape – shape of container
 particles have different velocities
 ave. Ek same throughout liquid
 strong repulsive forces – no
compression
 particles collide with each other &
walls of container – thus a pressure.
12
Kinetic molecular theory: gases
Gases have:
 weak forces between particles
 greater motion & thus more energy
 random motion with elastic collisions
causing pressure
 no repulsive forces – particles far
apart – easy to compress
 particles move at different
speeds but ave. Ek is the
same.
Kinetic theory &
temperature
Energy in a gas
13

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02.-Staes-of-matter-and-the-kinetic-molecular-theory.pdf

  • 1. States of matter & the kinetic molecular theory. Matter is classified into 3 states or phases: Solids, liquids & gases The structure, arrangement & movement of the particles determines the state of the substance. Solids liquids & gases 1
  • 2. Diffusion & Brownian motion Diffusion and Brownian motion in liquids and gases, provides proof of the existence of particles in matter. Diffusion is the movement of particles from a region of high concentration to lower concentration - until there is even distribution of particles throughout the gas or liquid. NH3 & HCl diffusion 2
  • 3. Brownian motion is the haphazard, random motion of larger particles that are being bumped by much smaller gas or liquid particles – ones that can’t even be seen under a microscope. Brownian motion 3
  • 4. Forces between particles There are forces between the particles in each of the states of matter. Solids – strongest forces – vibratory motion & held close together. Liquids – weaker forces – further apart & able to flow past one another Gases – weakest forces – particles far apart & move easily in all directions 4
  • 5. Phase changes Matter can change from one state to another by adding or removing energy – usually in the form of heat. Solid to gas – sublimation Solid to liquid – melting Liquid to gas – evaporation Gas to liquid – condensation Liquid to solid – freezing 5
  • 6. Temperature & Phase changes The temperatures at which phase changes take place have specific names: Solid → liquid – melting point Liquid → gas – boiling point Gas → liquid – condensation point Liquid → solid – freezing point The state of a substance at a certain temperature, is determined from its melting or boiling points. States of matter 6
  • 7. Temperature & Phase changes H2O at -5 0C means it is in the solid state (ice) – since it is below the freezing point of 0 0C. H2O at 120 0C means it is in the gaseous state (steam) since it is above its boiling point of 100 0C. Change of state Change of phase 7
  • 8. Common melting & boiling points Substance Melting point Boiling point Water 0 0C 100 0C Nitrogen -210 0C -196 0C Oxygen -219 0C -183 0C Diamond 3 550 0C 4 830 0C Carbon dioxide -79 0C -57 0C Ethanol -114 0C 78 0C Copper 1 083 0C 2 600 0C Mercury -39 0C 357 0C Table salt 801 0C 1 413 0C Iron 1 536 0C 3000 0C Sodium 98 0C 892 0C Lead 327 0C 1750 0C Ammonia -78 0C -33 0C 8
  • 9. Heating curve for water: This graph shows how the curve changes during the phase changes & heating process. Temperature Time 0C -10 0C 100 0C M.P. B.P. ICE WATER STEAM Heating ice 9
  • 10. Kinetic molecular theory This theory explains properties of solids, liquids & gases, relative to the particles making up matter & their movement. Particles in each phase are in constant motion and thus have a kinetic energy. Particles move at different speeds, but at the same temperature, they have the same average kinetic energy. Kinetic molecular theory 10
  • 11. Kinetic molecular theory: solids Solids have:  strong forces between particles  a size & shape  vibrate about a fixed point  repulsive forces – thus no compression 11
  • 12. Kinetic molecular theory: liquids Liquids have:  weaker forces of attraction  move more freely past each other  no fixed shape – shape of container  particles have different velocities  ave. Ek same throughout liquid  strong repulsive forces – no compression  particles collide with each other & walls of container – thus a pressure. 12
  • 13. Kinetic molecular theory: gases Gases have:  weak forces between particles  greater motion & thus more energy  random motion with elastic collisions causing pressure  no repulsive forces – particles far apart – easy to compress  particles move at different speeds but ave. Ek is the same. Kinetic theory & temperature Energy in a gas 13